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Resource limitation and population fluctuation drive spatiotemporal order in microbial communities

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00066H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Rohit Khandoori, Kaustav Mondal, Pushpita Ghosh
Resource-driven dynamics in bacterial colonies. Insights into cell length regulation and spatial organization reveal the complex interplay between resources and microbial community dynamics.
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Theory and simulation of ligand functionalized nanoparticles – a pedagogical overview

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00177J, Review Article
Thi Vo
Synthesizing reconfigurable nanoscale synthons with predictive control over shape, size, and interparticle interactions is a holy grail of bottom-up self-assembly.
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Effect of equilibration time on the structural gradient in the vertical direction for bicontinuous microemulsions in Winsor-III and -IV systems

Soft Matter, 2024, Advance Article
DOI: 10.1039/D3SM01741A, Paper
Douglas G. Hayes, Brian A. Barth, Sai Venkatesh Pingali
Both equilibration time and the transfer of Winsor-III microemulsion systems from one container to another affect the structure of the bicontinuous phase in the vertical direction.
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Dynamics in polymers with phase separated dynamic bonds: the case of a peculiar temperature dependence

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00115J, Paper
Peyton Carden, Sirui Ge, Bingrui Li, Subarna Samanta, Alexei P. Sokolov
Relaxation processes in polymers with phase separated dynamic bonds include segmental (α) process, individual bond dissociation (α*) and rearrangement (intermediate), structural relaxation in clusters (α2) and terminal relaxation (c).
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Electric-field modulated energy transfer in phosphorescent material- and fluorescent material-codoped polymer light-emitting diodes

RSC Adv., 2024, 14,12294-12302
DOI: 10.1039/D4RA00669K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ling-Chuan Meng, Yan-Bing Hou
In this study, we find electric-field modulated energy transfer in phosphorescent material- and fluorescent material-codoped polymer that has never been reported.
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Synthesis and study of antibiofilm and antivirulence properties of flavonol analogues generated by palladium catalyzed ligand free Suzuki–Miyaura coupling against Pseudomonas aeruginosa PAO1

RSC Adv., 2024, 14,12278-12293
DOI: 10.1039/D3RA08617H, Paper
Open Access
Anjitha Theres Benny, Masthan Thamim, Prakhar Srivastava, Sindoora Suresh, Krishnan Thirumoorthy, Loganathan Rangasamy, Karthikeyan S., Nalini Easwaran, Ethiraj Kannatt Radhakrishnan
An overview on the mechanism of Pseudomonas aeruginosa PAO1 biofilm inhibition by Suzuki–Miyaura coupled flavonols.
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Investigation into the impact of CeO2 morphology regulation on the oxidation process of dichloromethane

RSC Adv., 2024, 14,12265-12277
DOI: 10.1039/D4RA01326C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hao Wu, Xiaoliang Zhao, Jian Li, Bandna Bharti, Yuling Tan, Hongyan Long, Jiuhu Zhao, Gang Tian, Fan Wang
Four distinct CeO2 catalysts featuring varied morphologies (nanorods, nanocubes, nanoparticles, and nano spindle-shaped) were synthesized through a hydrothermal process and subsequently employed in the oxidation of dichloromethane (DCM).
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Retraction: Synthesis and characterization of a supported Pd complex on volcanic pumice laminates textured by cellulose for facilitating Suzuki–Miyaura cross-coupling reactions

RSC Adv., 2024, 14,12463-12463
DOI: 10.1039/D4RA90042A, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Siavash Salek Soltani, Reza Taheri-Ledari, S. Morteza F. Farnia, Ali Maleki, Alireza Foroumadi
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Research on preparation and related properties of macro–micro porous mullite ceramic skeletons via twice pore-forming technology

RSC Adv., 2024, 14,12624-12632
DOI: 10.1039/D4RA01277A, Paper
Open Access
Chunxia Xu, Rui Hu, Ying Liu, Zhe Chen, Zhen Liu, Wenbin Han
The macro–micro composite porous mullite ceramic skeletons were prepared using coal gangue and α-Al2O3 as main raw materials via twice pore-forming technology. The main phase of the porous ceramic skeletons is mullite.
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Correction: Facile fabrication of a graphene-based chemical sensor with ultrasensitivity for nitrobenzene

RSC Adv., 2024, 14,12633-12633
DOI: 10.1039/D4RA90041C, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ali Raza, Zaka Ullah, Adnan Khalil, Rashida Batool, Sajjad Haider, Kamran Alam, Nazmina Imrose Sonil, Alvi Muhammad Rouf, Muhammad Faizan Nazar
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CFD simulation of silica dispersion/natural rubber latex mixing for high silica content rubber composite production

RSC Adv., 2024, 14,12612-12623
DOI: 10.1039/D4RA01348D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ekaroek Phumnok, Phonsan Saetiao, Panut Bumphenkiattikul, Sukrittira Rattanawilai, Parinya Khongprom
The impeller configuration significantly influences on the hydrodynamics and mixing performance. The optimum design is the Ruston turbine with six blades set at 45 angle. The Norwood and Metzner scaling criteria is reliable to scale up of natural latex containing high silica content stirred tank.
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Insight into the probability of ethoxy(pentafluoro)cyclotriphosphazene (PFPN) as the functional electrolyte additive in lithium–sulfur batteries

RSC Adv., 2024, 14,12754-12761
DOI: 10.1039/D3RA08379A, Paper
Open Access
Ning Li, Yu Zhang, Shun Zhang, Lu Shi, Jie-Yu Zhang, Ke-Meng Song, Jin-Chun Li, Fang-Lei Zeng
Enhancing the flame retardancy of electrolytes and the stability of lithium anodes is of great significance to improve the safety performance of lithium–sulfur (Li–S) batteries.
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Innovative surfactant-free synthesis of core–shell SiO2/ZnO particles: rapid ultrasonication and photocatalytic inhibition

RSC Adv., 2024, 14,12665-12675
DOI: 10.1039/D4RA01309C, Paper
Open Access
Lailatul Qomariyah, Tomoyuki Hirano, Nicky Rahmana Putra, Suprapto Suprapto, Hendrix Abdul Ajiz, Mar'atul Fauziyah
This study demonstrates the preparation of SiO2/ZnO core–shell nanoparticles with controllable shell size and their optical properties.
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Confined microemulsions: pore diameter induced change of the phase behavior

RSC Adv., 2024, 14,12735-12741
DOI: 10.1039/D4RA01283F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
René Haverkamp, Margarethe Dahl, Tim Julian Stank, Jessica Hübner, Peter Strasser, Stefan Wellert, Thomas Hellweg
Possible temperature-dependent structure of the microemulsion within the pores of controlled pore glasses. Small pore sizes seem to affect the temperature-dependent phase behavior of the microemulsion.
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Novel supramolecular luminescent metallogels containing Tb(III) and Eu(III) ions with benzene-1,3,5-tricarboxylic acid gelator: advancing semiconductor applications in microelectronic devices

RSC Adv., 2024, 14,12829-12840
DOI: 10.1039/D3RA07903A, Paper
Open Access
Subhendu Dhibar, Aiswarya Mohan, Kripasindhu Karmakar, Bijnaneswar Mondal, Arpita Roy, Saranya Babu, Parul Garg, Pradip Ruidas, Subham Bhattacharjee, Sanjay Roy, Ashok Bera, Soumya Jyoti Ray, Padmanabhan Predeep, Bidyut Saha
Supramolecular metallogels with Tb(III)- and Eu(III)-ions, formed using benzene-1,3,5-tricarboxylic acid, display remarkable stability at room temperature. They hold promise for use in electronics, notably as reliable ambient Schottky barrier diodes.
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Carbon dots–cadmium sulfide quantum dots nanocomposite for ‘on–off’ fluorescence sensing of chromium(VI) ions

RSC Adv., 2024, 14,12923-12934
DOI: 10.1039/D4RA00436A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Anisha B. Patil, Pooja L. Chaudhary, Parag V. Adhyapak
This work involves fluorescent probe which is composed of carbon dots (CD) and cadmium sulfide quantum dots (CdS QD) for the sensitive and selective fluorescence detection of chromium(VI) ions.
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Influence of the coagulation bath on the nanostructure of cellulose films regenerated from an ionic liquid solution

RSC Adv., 2024, 14,12888-12896
DOI: 10.1039/D4RA00971A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lassi V. Tiihonen, Gabriel Bernardo, Robert Dalgliesh, Adélio Mendes, Steven R. Parnell
The structure of cellulose films prepared by nonsolvent-induced phase separation in coagulation baths of different mixtures and temperatures. High water volume fractions in the coagulation bath result in a highly reproducible gel-like structure with inhomogeneities.
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Cellulose/silica composite microtubular superfoam with excellent flame retardancy, thermal insulation and ablative resistance

RSC Adv., 2024, 14,12911-12922
DOI: 10.1039/D4RA00426D, Paper
Open Access
Ding Han, Xiankai Sun, Shichao Zhang, Linghao Wu, Bing Ai, Haoran Sun, Yufeng Chen
Cellulose/SiO2-based composite microtube superfoam exhibits excellent flame retardant, thermal insulation and ablative resistance.
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Bioactive O^N^O^ Schiff base appended homoleptic titanium(IV) complexes: DFT, BSA/CT-DNA interactions, molecular docking and antitumor activity against HeLa and A549 cell lines

RSC Adv., 2024, 14,13062-13082
DOI: 10.1039/D3RA08574K, Paper
Open Access
Sathish Thanigachalam, Madhvesh Pathak
Five new homoleptic derivatives of titanium(IV) have been developed and characterized by physicochemical techniques.
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The conjugates of 5'-deoxy-5-fluorocytidine and hydroxycinnamic acids – synthesis, anti-pancreatic cancer activity and molecular docking studies

RSC Adv., 2024, 14,13129-13141
DOI: 10.1039/D4RA01683A, Paper
Open Access
Marcin Cybulski, Magdalena Zaremba-Czogalla, Bartosz Trzaskowski, Marek Kubiszewski, Joanna Tobiasz, Anna Jaromin, Piotr Krzeczyński, Jerzy Gubernator, Olga Michalak
New conjugates 1–6 containing 5-dFCR and selected hydroxycinnamic acids were synthesized and tested in vitro against pancreatic cancer (PDAC) lines. The ADME properties and molecular docking to CES2 or human albumin were discussed.
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Effects of external light in the magnetic field-modulated photocatalytic reactions in a microfluidic chip reactor

RSC Adv., 2024, 14,13053-13061
DOI: 10.1039/D4RA00415A, Paper
Open Access
Hung Ji Huang, Yen Han Wang, Xuan-Yu Shih, Sy-Hann Chen, Hai-Pang Chiang, Yuan-Fong Chou Chau, Jeffrey Chi-Sheng Wu
Mutual enhancement of plasmonic photocatalytic reaction by both magnetic field and plasmonic enhancement was presented through Au–TiO2 nanoparticles.
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Self-supplying Cu2+ and H2O2 synergistically enhancing disulfiram-mediated melanoma chemotherapy

RSC Adv., 2024, 14,13180-13189
DOI: 10.1039/D4RA01075B, Paper
Open Access
Yingqian Gao, Xiaojun Cai, Weijuan Zou, Xiuzhen Tang, Lixian Jiang, Junnian Hao, Yuanyi Zheng, Xinhua Ye, Tao Ying, Ao Li
Disulfiram (DSF) can target and kill cancer cells by disrupting cellular degradation of extruded proteins and has therefore received particular attention for its tumor chemotherapeutic potential.
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Grind, shine and detect: mechanochemical synthesis of AIE-active polyaromatic amide and its application as molecular receptor of monovalent anions or nucleotides

RSC Adv., 2024, 14,13227-13236
DOI: 10.1039/D4RA02129K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jakub S. Cyniak, Artur Kasprzak
The mechanochemical synthesis of AIE-active amide, as well as the application of the title compound as molecular receptor of monovalent anions and nucleotides, are described.
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Quinazolines and thiazolidine-2,4-dions as SARS-CoV-2 inhibitors: repurposing, in silico molecular docking and dynamics simulation

RSC Adv., 2024, 14,13237-13250
DOI: 10.1039/D4RA02029D, Paper
Open Access
Sanadelaslam S. A. El-Hddad, Mohamed H. Sobhy, Ahmed El-morsy, Nabil A. Shoman, Khaled El-Adl
This paper presents an extensive analysis of COVID-19 with a specific focus on VEGFR-2 inhibitors as potential treatments.
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Dispersive micro solid phase extraction of glibenclamide from plasma, urine, and wastewater using a magnetic molecularly imprinted polymer followed by its determination by a high-performance liquid chromatography-photodiode array detector

RSC Adv., 2024, 14,13168-13179
DOI: 10.1039/D4RA00452C, Paper
Open Access
Najmeh Sabbaghi, Shayessteh Dadfarnia, Ali Mohammad Haji Shabani, Majid Farsadrooh
The present study describes the development of a simple and selective analytical method for dispersive micro solid phase extraction and determination of glibenclamide (GLB) using magnetic molecularly imprinted polymer (MMIP) as a sorbent.
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1D hollow tubular/2D nanosheet hybrid dimensional porous carbon prepared by one-step carbonization using natural minerals as templates for supercapacitors

RSC Adv., 2024, 14,13190-13199
DOI: 10.1039/D4RA01873G, Paper
Open Access
Fangfang Liu, Chao Zhang, Weiwei Huang, Lei Chen, Yuanshuang Wang, Jinan Niu, Xiuyun Chuan
1D hollow tubular/2D nanosheet hybrid dimensional porous carbon was synthesized through one-step carbonization using 1D fibrous brucite and 2D layered magnesium carbonate hydroxide as templates.
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A multi-channel microfluidic platform based on human flavin-containing monooxygenase 3 for personalised medicine

RSC Adv., 2024, 14,13209-13217
DOI: 10.1039/D4RA01516A, Paper
Open Access
Melissa De Angelis, Silvia Schobesberger, Florian Selinger, Viktor Laurin Sedlmayr, Martin Frauenlob, Orsola Corcione, Shiman Dong, Gianfranco Gilardi, Peter Ertl, Sheila J. Sadeghi
A microfluidic platform with immobilized human flavin-containing monooxygenase for high-throughput screening of drugs with relevance to personalised medicine.
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Tight-binding model describes frontier orbitals of non-fullerene acceptors

Mol. Syst. Des. Eng., 2024, 9,382-398
DOI: 10.1039/D3ME00195D, Paper
Vishal Jindal, Michael J. Janik, Scott T. Milner
HOMO and LUMO of conjugated molecules as superposition of HOMO and LUMO of individual moieties.
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Two-state nanocomposite based on symmetric diblock copolymer and planar nanoparticles: mesoscopic simulation

Mol. Syst. Des. Eng., 2024, 9,409-422
DOI: 10.1039/D3ME00176H, Paper
Maxim Malyshev, Daria Guseva, Pavel Komarov
A method for controlling the distribution and orientation of 2D fillers in the copolymer matrix is presented.
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3-Perfluoroalkylated fluorescent coumarin dyes: rational molecular design and photophysical properties

Mol. Syst. Des. Eng., 2024, 9,332-344
DOI: 10.1039/D4ME00006D, Paper
Ayano Ikemura, Yukiko Karuo, Yuki Uehashi, Tomohiro Agou, Masahiro Ebihara, Yasuhiro Kubota, Toshiyasu Inuzuka, Masaaki Omote, Kazumasa Funabiki
The photochemical properties of a coumarin derivative with a promising electron-withdrawing fluoroalkyl group at the 3-position in solution and in the crystal were investigated in detail.
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Augmentation of inductive effects through short range intramolecular hydrogen bonds for the improvement of cooperativity of trimeric rosettes

Mol. Syst. Des. Eng., 2024, 9,345-351
DOI: 10.1039/D4ME00008K, Paper
Andre Nicolai Petelski, Tamara Bundrea, Nélida María Peruchena
Three key design elements improve the binding strength of trimeric rosettes: the direction of hydrogen bonds, the addition of groups with inductive effects, and the presence of ambifunctional intramolecular hydrogen bonds between the substituents.
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A molecular-design approach for selective sulfate separation from competitive acidic and alkaline aqueous media

Mol. Syst. Des. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4ME00031E, Review Article
Arghya Basu, Sandeep Kumar Dey
Selective and efficient removal of sulfate from aqueous solution having a high concentration of other competing ions is an important aspect of separation science technology and has attracted considerable attention...
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Design and engineering of an artificial disulfide bond in human cytochrome c to regulate the protein structure and function

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D3ME00196B, Paper
Yan-Yan Li, Yu Feng, Lu Yu, Shuang-Shuang Long, Shu-Qin Gao, Ying-Wu Lin
An artificial disulfide bond was rationally constructed in human cytochrome c (hCyt c) via double mutations (A51C/G77C), which weakened the coordination of Met80 to the heme iron and enhanced the peroxidase activity of hCyt c.
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Rural report card: Worker population ratio




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A fruitful time for migrant labourers

The apple season in Himachal Pradesh spells good earnings for workers from India and Nepal




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Apples on the vine — for bountiful yield and income

Project Apple Unnati helps Uttarakhand farmers grow the fruit as a creeper




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Floriculture fortune: Gujarat farmers strike gold with marigold

Their fields, and lives, are blooming, thanks to horticulture and improved farming techniques




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‘Doc, you’re wanted online for consultation’

Telemedicine and IT-enabled healthcare systems are making distance treatment a reality in rural Rajasthan




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Corona heavy on young shoulders

Youth in UP, Bihar and Rajasthan are finding the ongoing pandemic challenging in more ways than one, reveals a recent survey




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Cellular Jail’s unfettered appeal

The 104-year-old prison in Andaman & Nicobar Islands, steeped in history, is fascinating, says its top official




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Influence of polyol impurities on the transesterification kinetics, molecular structures and properties of isosorbide polycarbonate

Polym. Chem., 2024, 15,4204-4220
DOI: 10.1039/D4PY00840E, Paper
Mingfa Guo, Yaning Wang, Zhenguang Li, Jielin Xu, Qian Chen, Jing Wu, Huaping Wang
A so-called “reverse-addition” model protocol based on two kinds of polyol impurities (glycerol and 2-deoxy-D-ribose) was established to systematically demonstrate their influence on the polymerization and properties of PIC.
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Mechanical properties and molecular adhesion exhibited by inorganic–organic composite elastomers

Polym. Chem., 2024, 15,4196-4203
DOI: 10.1039/D4PY00879K, Paper
Naoki Yamashita, Ryohei Ikura, Kenji Yamaoka, Nobu Kato, Masanao Kamei, Kentaro Ogura, Minoru Igarashi, Hideo Nakagawa, Yoshinori Takashima
Organic–inorganic composite elastomers with reversible cross-links formed by β-cyclodextrin and adamantane (Ad) were prepared. Excess Ad units improve the mixability of polydimethylsiloxane and poly(ethyl acrylate) to increase the healing ratio.
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Versatile poly(N-vinylcaprolactam)-grafted-hydroxypropyl cellulose polymers with tailored thermo- and pH-responsive properties via sustainable organocatalyzed atom transfer radical polymerization

Polym. Chem., 2024, 15,4244-4254
DOI: 10.1039/D4PY00931B, Paper
Muhammad Asif Iqbal, Asif Mahmood, Waheed Al-Masry, Chan Ho Park, Sadaf Ul Hassan, Toheed Akhter
This study explores the synthesis of dual pH- and thermo-responsive poly(N-vinylcaprolactam)-grafted-hydroxypropyl cellulose (PNVCL-g-HPC) polymers via visible-light-driven, metal-free organocatalyzed atom transfer radical polymerization (O-ATRP).
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Heterogenous catalysis for oxygen tolerant photoredox atom transfer radical polymerization and small-molecule dehalogenation

Polym. Chem., 2024, 15,4264-4280
DOI: 10.1039/D4PY00899E, Paper
Open Access
Kriti Kapil, Mingkang Sun, Ting-Chih Lin, Hironobu Murata, Grzegorz Szczepaniak, Khidong Kim, Stephen DiLuzio, Jaepil Jeong, Mitchell Baumer, Stefan Bernhard, Tomasz Kowalewski, Krzysztof Matyjaszewski
Heterogeneous photocatalysts (PCs) have garnered attention for their sustainability and cost-effectiveness.
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Tetrazine-based inverse-electron-demand Diels–Alder reaction: a powerful tool for fabrication and functionalization of polymeric materials

Polym. Chem., 2024, 15,4173-4195
DOI: 10.1039/D4PY00912F, Review Article
Open Access
Mehmet Arslan, Aysun Degirmenci, Rana Sanyal, Amitav Sanyal
The IEDDA click reaction plays an important role in the fabrication and functionalization of polymeric materials.
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Vinylene-linked fully conjugated porous organic polymers based on difluoroboron β-diketonate complexes for green and efficient photocatalysis

Polym. Chem., 2024, 15,4281-4287
DOI: 10.1039/D4PY00947A, Paper
Wenshuo Xu, Zehao Zhao, Yiqiong Liu, Dongxin Yang, Weitao Gong
Two distinct vinylene-linked fully conjugated POPs were achieved by reacting difluoroboron β-diketonate complexes with reactive methyl groups and a carbazole-bearing aldehyde.
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Emerging trends in the chemistry of polymeric resists for extreme ultraviolet lithography

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00957F, Review Article
Jie Cen, Zhengyu Deng, Shiyong Liu
Patterning materials have advanced significantly to achieve high-resolution fabrication of integrated circuits for extreme ultraviolet (EUV) lithography. Emerging trends in the chemistry of polymeric resists for EUV lithography are summarized.
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Rapid formation of antifouling coatings via cation–π interactions

Polym. Chem., 2024, 15,4465-4473
DOI: 10.1039/D4PY00859F, Paper
Zhicheng Huang, Kaijie Zhao, Shaoyin Wei, Yingxin Hao, Qina Yu, Jingcheng Hao, Jiwei Cui, Peiyu Zhang
Antifouling coatings can be quickly prepared on various substrates through cation–π interactions between copolymers and MPNs. In addition, block copolymers exhibited superior antifouling capabilities compared to random copolymers.
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Acid-labile and non-degradable cross-linked star polymer model networks by aqueous polymerization for in situ encapsulation and release

Polym. Chem., 2024, 15,4454-4464
DOI: 10.1039/D3PY00677H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Gavin Irvine, Stuart Herron, Daniel W. Lester, Efrosyni Themistou
Aqueous RAFT polymerization for the preparation of degradable and non-degradable cross-linked star polymer model networks, in situ dye encapsulation and release.
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Enhanced mechanical properties of acrylate and 5-vinyl-2-norbornene-based ethylene terpolymers: rational design and synthesis using remotely modulated phosphine–sulfonate palladium complexes

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00722K, Paper
Yong-Qing Li, Gui-Ping Cao, Yu-Cai Cao
From a practical perspective, it is important to maintain or increase the mechanical properties of functional ethylene copolymers to those of nonpolar polyethylene (PE).
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