ic NSE expands F&O segment with 45 new stocks, including Zomato, Jio Financial, LIC, DMart, and Paytm; check full list - Upstox By news.google.com Published On :: Thu, 14 Nov 2024 02:50:22 GMT NSE expands F&O segment with 45 new stocks, including Zomato, Jio Financial, LIC, DMart, and Paytm; check full list UpstoxNSE to introduce futures and options contracts on 45 stocks from November 29, here's the full list MoneycontrolJio Financial, Zomato potential Nifty inclusion candidates? Here is what analysts said CNBCTV18Exchanges make 45 new additions in the F&O following new eligibility norms | News on Markets Business StandardNSE adds 45 new stocks to F&O segment; Jio Financial, Zomato among notable entrants The Economic Times Full Article
ic Donald Trump picks firebrand congressman Matt Gaetz for attorney general - The Times of India By news.google.com Published On :: Wed, 13 Nov 2024 23:59:00 GMT Donald Trump picks firebrand congressman Matt Gaetz for attorney general The Times of IndiaMatt Gaetz: Trump's choice for attorney general shocks Washington BBC.comWhy Matt Gaetz's momination as attorney general in Trump’s cabinet has left many Republicans 'shocked' The Times of IndiaTrump names firebrand lawmaker Matt Gaetz U.S. Attorney General The HinduVideo | US Election: Trump Taps Gaetz For Attorney General, Gabbard For Intel Chief NDTV Full Article
ic To Own A Home Is Everybody's Dream: Poet Pradeep's Couplet Finds Mention In SC's Demolition Verdict - News18 By news.google.com Published On :: Wed, 13 Nov 2024 22:31:11 GMT To Own A Home Is Everybody's Dream: Poet Pradeep's Couplet Finds Mention In SC's Demolition Verdict News18SC lays down path, timeline that bulldozers must follow The Times of IndiaVideo | Dimple Yadav Slams BJP Over 'Bulldozer Action' In Supreme Court Statement NDTVSupreme Court verdict on bulldozer demolitions: Jamiat hails verdict, victims seek compensation The HinduRight To Shelter A Facet Of Article 21; State Must Satisfy Why Entire Property Needs To Be Demolished :... Live Law - Indian Legal News Full Article
ic Delhi air pollution: AQI ‘severe’ again; thick smog reduces visibility. Schools to be closed soon? - Hindustan Times By news.google.com Published On :: Thu, 14 Nov 2024 01:18:49 GMT Delhi air pollution: AQI ‘severe’ again; thick smog reduces visibility. Schools to be closed soon? Hindustan TimesDelhi air in ‘severe’ category with AQI of 426 — worst in India The HinduFlights Impacted, Trains Running Late As ‘Severe’ Smog Chokes Delhi, Visibility Dips News18Delhi air pollution: City chokes as AQI level reaches 'severe' category The Times of IndiaDelhi Covered In Toxic Smog, Visibility Low At Airports Across North India NDTV Full Article
ic KFC Sues Church's Texas Chicken Over 'Original Recipe' By www.entrepreneur.com Published On :: Wed, 13 Nov 2024 14:58:49 GMT The Colonel is not so happy with Church's choice of words in recent ads. Full Article false
ic Donald Trump Hires Elon Musk and Vivek Ramaswamy to Bring 'Drastic Change' to the U.S. Government — And Gives Them a 2 Year Deadline By www.entrepreneur.com Published On :: Wed, 13 Nov 2024 16:05:00 GMT Musk and Ramaswamy have to find ways to cut down on government spending and overall bureaucracy. Full Article false
ic Why Your Small Business Growth Stalled — And How to Kickstart It Again By www.entrepreneur.com Published On :: Wed, 13 Nov 2024 18:30:00 GMT It's possible to scale sustainably even in uncertain times. Full Article false
ic Apple's Next Device Will Reportedly Be Mounted on Your Wall: 'They Feel Like They're Going to Sell a Lot of These Things' By www.entrepreneur.com Published On :: Wed, 13 Nov 2024 19:26:38 GMT The device will arrive by March at the earliest, according to reports. Full Article false
ic Don Lemon officially leaves Elon Musk’s X By techcrunch.com Published On :: Wed, 13 Nov 2024 21:14:19 +0000 Former CNN anchor Don Lemon said on Wednesday he is leaving Elon Musk’s X, a decision made less than a year after X announced that “The Don Lemon Show” would appear on the social media platform three times a week. That deal was canceled before it was ever signed, and Lemon sued Musk and X […] © 2024 TechCrunch. All rights reserved. For personal use only. Full Article Media & Entertainment TC Elon Musk social media Twitter
ic Apple faces UK ‘iCloud monopoly’ compensation claim worth $3.8 billion By techcrunch.com Published On :: Thu, 14 Nov 2024 00:01:00 +0000 U.K. consumer rights group ‘Which?’ is filing a legal claim against Apple under competition law on behalf of some 40 million users of iCloud, its cloud storage service. The collective proceeding lawsuit, which is seeking £3 billion in compensation damages (around $3.8 billion at current exchange rates), alleges that Apple has broken competition rules by […] © 2024 TechCrunch. All rights reserved. For personal use only. Full Article Apps
ic Public Eye vs Union Of India on 7 November, 2024 By indiankanoon.org Published On :: Dr. A.K.Jayasankaran Nambiar, J. These writ petitions raise an interesting question as regards the scope, content and extent of the right to freedom of speech and expression enuring to the media when they report facts about ongoing criminal investigations or the proceedings in cases pending adjudication before the various adjudicatory forums in the country. The writ petitions were initially considered by a Full Bench of this Court. However, by an order dated 24.05.2018, the Full Bench took the view that in the light of an earlier decision of another Full Bench of this Court in S. Sudin v. Union of India and Others - [2015 (2) KLT 296 (FB)], these matters needed to be referred to a Larger Bench of five Judges for consideration. It is thus, and pursuant to an order dated 02.09.2024 of the Hon'ble the Acting Chief Justice, that these matters are now before us. Full Article
ic Jmc-Mske(Jv),,Ahmedabad vs Income Tax Officer, Ward-5(2)(3),, ... on 7 November, 2024 By indiankanoon.org Published On :: These four appeals filed by two separate assessees have arisen from separate appellate orders passed by learned Commissioners of Income-tax (Appeals), Ahmedabad for the assessment years, 2010-11 & 2011-12. 2. Since facts and issues involved in all these four appeals are similar which is agreed to by both the rival parties before us and that these four appeals were heard together, we deem it appropriate to dispose of all these appeals by this consolidated order for the sake of brevity and convenience. We will first take up the appeal of the assessee in ITA No. 2498/Ahd/2013 for A.Y. 2010-11, and our decision in this appeal shall apply mutatis mutandis to remaining three appeals. Full Article
ic Bgsctpl- Mskel Consortium,,Ahmedabad vs The Income Tax Officer, Ward-10(1),, ... on 7 November, 2024 By indiankanoon.org Published On :: These four appeals filed by two separate assessees have arisen from separate appellate orders passed by learned Commissioners of Income-tax (Appeals), Ahmedabad for the assessment years, 2010-11 & 2011-12. 2. Since facts and issues involved in all these four appeals are similar which is agreed to by both the rival parties before us and that these four appeals were heard together, we deem it appropriate to dispose of all these appeals by this consolidated order for the sake of brevity and convenience. We will first take up the appeal of the assessee in ITA No. 2498/Ahd/2013 for A.Y. 2010-11, and our decision in this appeal shall apply mutatis mutandis to remaining three appeals. Full Article
ic Bgsctpl- Mskel (Jv),Ahmedabad vs The Income Tax Officer, Ward-5(2)(1),, ... on 7 November, 2024 By indiankanoon.org Published On :: These four appeals filed by two separate assessees have arisen from separate appellate orders passed by learned Commissioners of Income-tax (Appeals), Ahmedabad for the assessment years, 2010-11 & 2011-12. 2. Since facts and issues involved in all these four appeals are similar which is agreed to by both the rival parties before us and that these four appeals were heard together, we deem it appropriate to dispose of all these appeals by this consolidated order for the sake of brevity and convenience. We will first take up the appeal of the assessee in ITA No. 2498/Ahd/2013 for A.Y. 2010-11, and our decision in this appeal shall apply mutatis mutandis to remaining three appeals. Full Article
ic Jmc-Mske(Jv),,Ahmedabad vs Income Tax Officer, Ward-5(2)(3),, ... on 7 November, 2024 By indiankanoon.org Published On :: These four appeals filed by two separate assessees have arisen from separate appellate orders passed by learned Commissioners of Income-tax (Appeals), Ahmedabad for the assessment years, 2010-11 & 2011-12. 2. Since facts and issues involved in all these four appeals are similar which is agreed to by both the rival parties before us and that these four appeals were heard together, we deem it appropriate to dispose of all these appeals by this consolidated order for the sake of brevity and convenience. We will first take up the appeal of the assessee in ITA No. 2498/Ahd/2013 for A.Y. 2010-11, and our decision in this appeal shall apply mutatis mutandis to remaining three appeals. Full Article
ic M/S. Cadila Pharmaceuticals Ltd. ... vs The Dy.Commissioner Of Income Tax, ... on 12 November, 2024 By indiankanoon.org Published On :: These cross appeals are filed by the Revenue and Assessee against order dated 12.03.2020 passed by the CIT(A)-1, Ahmedabad for the Assessment Year 2012-13. 2. The Revenue has raised the following grounds of appeal :- ITA Nos.345 & 383/Ahd/2020 Assessment Years: 2012-13 "(1) The ld. CIT(A) has erred in facts and law in deleting the transfer pricing adjustment made in respect of Corporate guarantee fees of Rs.60,83,440/- (2) The id. CIT(A) has erred in facts and law in deleting the interest disallowance of Rs.1,64,86,560/- u/s.36(1)(iii) of the Act. Full Article
ic The Dy.Commissioner Of Income Tax, ... vs M/S. Cadila Pharmaceuticals Ltd. , ... on 12 November, 2024 By indiankanoon.org Published On :: These cross appeals are filed by the Revenue and Assessee against order dated 12.03.2020 passed by the CIT(A)-1, Ahmedabad for the Assessment Year 2012-13. 2. The Revenue has raised the following grounds of appeal :- ITA Nos.345 & 383/Ahd/2020 Assessment Years: 2012-13 "(1) The ld. CIT(A) has erred in facts and law in deleting the transfer pricing adjustment made in respect of Corporate guarantee fees of Rs.60,83,440/- (2) The id. CIT(A) has erred in facts and law in deleting the interest disallowance of Rs.1,64,86,560/- u/s.36(1)(iii) of the Act. Full Article
ic Rajiv Singh vs Department Of Telecommunications on 13 November, 2024 By indiankanoon.org Published On :: and background of the case: The Appellant filed an RTI application dated 21.09.2023 seeking information on following points:- "What kind of punishment is sanctioned by the law for any Pilot who gets the RTR permit or licence on the basis of false documents?" The CPIO, Sr. DWA (COP & regulations) vide letter dated 05.10.2023 replied as under:- "- Information sought does not fall under purview of RTI Act 2005, hence this RTI is closed" Dissatisfied with the response received from the CPIO, the Appellant filed a First Appeal dated 08.10.2023. The FAA vide order dated 08.11.2023 stated as under:- "Reply :- I have gone through the case and found that information sought was denied by the CPIO stating that the information did not fall under the purview of the RTI Act, 2005. The undersigned is convinced with the above reply in view of Section 8-1(j) of the RTI Act. 2005." Full Article
ic Shiv Kumar vs Office Of The Chief Minister Delhi on 13 November, 2024 By indiankanoon.org Published On :: : The Appellant filed an (offline) RTI application dated 31.05.2023 seeking the following information: Page 1 of 3 "1- द ल सरकार के SC/ST DEPARTMENT 2018,2019,2020,2021,2022 तक कतना फ ड पछले चार साल म कतनी योजनाओंपर खच कया है उसक" पण ू जानकार द जाये 2- द ल सरकार ने 2014 से 2022 तक अपने व'ापन पर कतना फ ड द ल व ् द ल से बाहार खच कया है उसक" जानकार द जाये 3- द ल के मु+यमं ,ी ने JANUARY 2014 से 2023 JANUARY तक द ल से बाहार के दोरो पर कतना फ ड खच कया है उसक" जानकार द जाये 4- द ल सरकार ने पछले 8 साल म वधायक. को गाडी खर दने के 0लए कतना फ ड दया है उसक" जानकार द जाये" Full Article
ic Rajiv Singh vs Department Of Telecommunications on 13 November, 2024 By indiankanoon.org Published On :: and background of the case: The Appellant filed an RTI application dated 21.09.2023 seeking information on following points:- "To, Shri Umang Srivastva Sr.DWA (COP) I had complained on 05/05/2023 against Rahul Sinha regarding his COP permit. What action or inquiry has been conducted in this regard?" The CPIO, Sr DWA (COP & Regulation) vide letter dated 05.10.2023 replied as under:- "Information sought does not fall under purview of RTI Act 2005, hence this RTI is closed" Dissatisfied with the response received from the CPIO, the Appellant filed a First Appeal dated 08.10.2023. The FAA, JWA vide order dated 08.11.2023 stated as under:- "Reply :- I have gone through the case and found that information sought was denied by the CPIO stating that the information did not fall under the purview of the RTI Act, 2005. The undersigned is convir.ced with the above reply in view of Section 8-1(j) of the RTI Act. 2005." Full Article
ic Lalit Kamal vs Geological Survey Of India on 13 November, 2024 By indiankanoon.org Published On :: and background of the case: The Appellant filed an RTI application dated 19.07.2023 seeking information on following points:- "1. Copy of complete report with all supporting documents submitted by FFC 2. List of the name of the officials/persons to whom the letters were issued by FFC 3. List of Officials who appeared before FFC along with their copy of all statements and supporting documents provided by them. 4. List of Officials who DID NOT appear before FFC 5. List officials/person from the statements/documents was taken on record by FFC The copy of statements along with supporting documents is requested to be provided. Full Article
ic Vishnu Kumar Kashram Patel vs Department Of Scientific & Industrial ... on 13 November, 2024 By indiankanoon.org Published On :: and background of the case: The Appellant filed an RTI application dated 10.07.2023 seeking information on following points:- "(1) Copy of filled up application form in which my name & designation is mentioned submitted by Avani seeds Ltd, Ahmedabad to Department of Scientific and Industrial Research to get In-house R &D Units certificate issued in FY 2019 (on March 2019 vide certificate F.No.TU/TV- RD/4444/2019). (2) Copy of filled up application form in which my name & designation is mentioned submitted by Avani seeds Ltd, Ahmadabad to Department of Scientific and Industrial Research to get In-house R&D Units certificate issued in FY 2021." Full Article
ic R S Bhati vs Office Of The Chief Minister Delhi on 13 November, 2024 By indiankanoon.org Published On :: : The Appellant filed an (offline) RTI application dated 06.02.2023 seeking the following information: Page 1 of 7 " नवेदन यह है क नेह वहार वाड मु तफाबाद वधान सभा म कर ब चार वष पहले सीवर क" लाईन डाल गई थी और अब सीवर क" लाइन से घर-घर तक सीवर कने*शन का काम चल रहा है । सीवर लाइन के -.येक मैन होल म घर0 म कने*शन करने के 1लए चार चीनी के पाइप लगाए गए थे। इ3ह ं पाइप0 म घर0 के कने*शन जोड़ने थे। ले कन उन चीनी पाइप0 से कने*शन नह ं 8दए जा रहे ह9 और म9ने होलो म कने*शन दे ने के 1लए नये सरु ाख करके पाईप लगाये जा रहे ह9 और नये सरु ाख0 क" मर;मत भी नह ं क" जा रह है और जो पहले से ह -.येक मैन होलो म चार पाईप लगाये गये ह9। उन पाईप0 से 1स वर ओवर=लो होने पर पानी अ3दर ह अ3दर मकान0 क" नींव म जाएगा। और कने*शन के 1लये अब नये पाईप डाले जा रहे ह9 वह रोड से एक से डेढ़ फुट गहराई पर ह9 और जो मकान नीचे पड़ गए ह9 उनका 1सवरे ज का पानी म9न होल म नह जायेगा। और मैन होल म जो नए सरु ाख कये गये है उनसे मैनहोल बहुत कमजोर हो गये है अतः Aीमान जी से नवेदन है क R.T.I Act न;न1लBखत सच ू ना दे ने क" कृEया करे । Full Article
ic Manish Agarwal vs Military Engineer Services on 13 November, 2024 By indiankanoon.org Published On :: : The Appellant filed an (online) RTI application dated 24.04.2023 seeking the following information: Querry is in reference to Chief Engineer Central Command. Index No 5-28 -Central Command. For renewal of Security Deposit of FDR wherein many letters were sent for sending to bank FDRs for renewal. However, no reply has been received. Letters dated 08.08.2022, No 4501-244 dated 08.08.2022, letter No 4501-245 dated 06.10.2022, dated 15.11.2022 & dated 20.12.2022 & letter No 4501-248 datet25.01.2023, and 20.03.2023. FDR bearing No.7 15474 Folio 127180-98 dt.25.9-98 for Rs.60,000.00, (Maturity Date :3-7-2001 FDR bearing No.715475 Follo 127198/98) dated 23.9.98 for Rs.60,000.00. Full Article
ic Devendra Singh vs Department Of Agriculture & ... on 13 November, 2024 By indiankanoon.org Published On :: and background of the case: The Complainant filed an RTI application dated 12.07.2023 seeking information on following points:- "1. Total number of employees whose Pension Payment Orders (PPOs) were issued between 01.01.2018 to 30.6.2023 from the office of the PAO, PP&M, Faridabad. 2. Total number of employees whose Pension Payment Orders (PPOs) were issued after the date of their retirement or delayed due to any reason. Information may be provided from 01.01.2018 to 30.6.2023 only. 3. Photocopy of note sheet in respect of my (Devendra Singh, Applicant) pension file maintained in your office to date. 4. Photocopies of the dispatch register maintained in your office for the dates 14.3.2023 to 17.3.2023 and 20.3.2023 to 22.3.2023." Full Article
ic Publicitarul Bogdan Naumovici lansează lungmetrajul „Țăndări” în ianuarie 2025 By www.forbes.ro Published On :: Wed, 13 Nov 2024 10:40:58 +0000 Bogdan Naumovici, om de publicitate, își lansează lungmetrajul de debut pe 28 ianuarie 2025. Comedia „Țăndări”, distribuită de Forum Film, are în distribuție actori precum Alin Florea, Constantin Florescu, Cristian Bota, Nicodim Ungureanu, Cătălin Neamțu, Carmen Tănase, Dan Badea, Alex Conovaru, Sergiu Costache, Robert Tudor, Andreea Samson, și Gabriel Spahiu. De la spoturi publicitare pentru ... The post Publicitarul Bogdan Naumovici lansează lungmetrajul „Țăndări” în ianuarie 2025 appeared first on Forbes Romania. Full Article Afaceri Media şi entertainment Bogdan Naumovici lungmetraj publicitate Țăndări
ic Commerzbank ia în considerare achiziționarea unui rival german pentru a respinge UniCredit By www.forbes.ro Published On :: Wed, 13 Nov 2024 13:08:08 +0000 Commerzbank analizează opțiunea de a achiziționa o bancă germană de dimensiuni medii ca parte a strategiei de a evita o posibilă preluare de către UniCredit, potrivit Reuters. Planurile sunt într-o etapă incipientă, iar posibilele ținte ar putea include Hamburg Commercial Bank sau Oldenburgische Landesbank. Potrivit surselor Reuters, Commerzbank încearcă să conceapă un plan de apărare, ... The post Commerzbank ia în considerare achiziționarea unui rival german pentru a respinge UniCredit appeared first on Forbes Romania. Full Article Actualitate Afaceri Bani și Investiţii
ic Servicii AI pentru Bazilica Sf. Petru lansate de Vatican înainte de anul jubiliar By www.forbes.ro Published On :: Wed, 13 Nov 2024 13:11:29 +0000 Vatican a lansat o serie de servicii noi bazate pe inteligență artificială pentru Bazilica Sf. Petru, permițând acces virtual la comorile arhitecturale din perioada Renașterii și tururi îmbunătățite pentru vizitatori – zilnic aproximativ 40.000-50.000 de oameni. Noile experiențe au fost prezentate în pregătirea pentru Anul Sfânt sau Jubileul Bisericii Catolice din 2025, care are loc ... The post Servicii AI pentru Bazilica Sf. Petru lansate de Vatican înainte de anul jubiliar appeared first on Forbes Romania. Full Article Actualitate Afaceri Bani și Investiţii
ic Vânzările globale de automobile electrice și hibride, în creștere cu 35% în octombrie By www.forbes.ro Published On :: Wed, 13 Nov 2024 13:11:40 +0000 Vânzările globale de automobile complet electrice şi vehicule hibride de tip plug-in au crescut cu 35% în luna octombrie a acestui an comparativ cu aceeaşi lună a anului trecut, graţie în primul rând unui salt de 54% al vânzărilor de pe piaţa chineză, arată cifrele publicate de firma de cercetare de piaţă Rho Motion. Potrivit ... The post Vânzările globale de automobile electrice și hibride, în creștere cu 35% în octombrie appeared first on Forbes Romania. Full Article Actualitate autovehicule electrice Rho Motion sondaj EV vehicule hibride
ic Eurostat: România a fost al șaptelea producător agricol din UE în 2023 By www.forbes.ro Published On :: Wed, 13 Nov 2024 13:14:46 +0000 Valoarea producţiei agricole a blocului comunitar a scăzut cu 1,5% în 2023, comparativ cu 2022, până la 537,1 miliarde de euro, însă România se numără printre ţările UE a căror valoare a producţiei agricole a crescut de la un an la altul, arată datele publicate miercuri de Eurostat. Scăderea uşoară din 2023 vine după o ... The post Eurostat: România a fost al șaptelea producător agricol din UE în 2023 appeared first on Forbes Romania. Full Article Actualitate Eurostat producator agricol Romania UE
ic 'Priyanka Chopra was out...': Arjun Kapoor talks about his terrific chemistry with Ranveer Singh in Gunday By www.dnaindia.com Published On :: Wed, 13 Nov 2024 16:22:00 GMT Talking about Priyanka Chopra, Arjun admitted that she was already a big star when they made the film. Full Article Entertainment
ic Chennai Rains: IMD predicts heavy showers for 2 days in Tamil Nadu; Are schools, colleges closed today? By www.dnaindia.com Published On :: Thu, 14 Nov 2024 02:35:00 GMT The city experienced heavy rainfall on Wednesday night, and the IMD bulletin indicates that several isolated areas of the capital are expected to see heavy downpours on Thursday. Full Article India
ic Synthesis of 10B-enriched 2,1-borazaronaphthalenes from o-aminostyrenes and 10BF3 By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00176A, Research ArticleWeihua Qiu, Jide Zhu, Rencai Tao, Kai Yang, Qiuling SongHerein we present a practical approach for preparing 10B-enriched 2,1-borazaronaphthalenes from o-aminostyrenes and 10BF3 (the primary source of boron-10) in the presence of chlorosilane.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic A Mn(III)-catalyzed arylboronic acid-based cascade reaction via a nonclassical organometallic-radical mechanism By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00244J, Research ArticleHui-Min Qian, Jian-Dong Zhang, Shun-Jun Ji, Xiao-Ping XuAn efficient Mn(III)-catalyzed cascade reaction of arylboronic acids, o-cyanoaryl isocyanides, and indoles was developed. The mechanism was fully investigated and elucidated.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Practical photocatalytic hydroalkylation of alkenes with chloroacetates mediated by the formate ion By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00228H, Research ArticleEkaterina V. Malakhova, Vladislav S. Kostromitin, Vitalij V. Levin, Alexander D. DilmanCommodity chemicals are used as alkylating and reducing agents for radical addition to alkenes. The method is based on activation of the strong C–Cl bond by the radical anion of carbon dioxide.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Organocatalyzed double dearomatization reaction of non-functionalized phenols and propargylic alcohols: the important regulating effect of steric hindrance By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00103F, Research ArticleXihong Liu, Boyan Zhu, Panpan Zhou, Jingying Zhang, Anqi Chu, Rui WangSteric hindrance-regulated double dearomatization reaction of non-functionalized phenols and propargylic alcohols for the efficient synthesis of polycyclic diketones is reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Photoredox catalyzed hydroazolylation of alkenes via phosphoranyl radicals By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00233D, Research ArticleFan Zhu, Zhi Qiao, Na He, Chunxiao Nong, Qiping He, Meilan Xi, Xizhong Song, Jun Lin, Jingbo Chen, Yi JinA general protocol for the hydroazolylation of alkenes with N-hydroxyl azoles is reported. These reactions proceed via a phosphoranyl radical, followed by radical coupling of the resulting azole radical to the alkene radical.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Recent advances in the metal-catalyzed asymmetric alkene hydrogenation of cyclic conjugated carbonyl compounds By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00227J, Review ArticleMin Tan, Bram B. C. Peters, Pher G. Andersson, Taigang ZhouThis review summarizes the recent advances (2016–2023) in the stereoselective metal-catalyzed hydrogenation of cyclic α,β-unsaturated ketones, lactams and lactones since considerable developments were made. Where possible the application of these methodologies in synthesis is outlined.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Modular synthesis of C2-symmetric nitrogen-containing polyaromatics via visible light-enabled reductive aza-6π electrocyclization By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00140K, Research ArticleQun-Liang Zhang, Qing-Tian Fan, Yirong Zhou, Jingli Zhang, Fang-Lin ZhangHere, an unprecedented one-step modular construction of C2-symmetric N-PACs through reduction/aza-6π electrocyclization was reported and the resultant C2-symmetric N-PAC could be converted into a powerful organic photocatalyst.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Neighboring group-directed asymmetric [2 + 2 + 2] cycloaddition to access C–N axially chiral indoles By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00042K, Research ArticleXuan Zhang, Qi Teng, Yanru Ren, Baitong Wei, Chen-Ho Tung, Zhenghu XuA Rh-catalyzed neighboring group-directed asymmetric [2 + 2 + 2] cycloaddition of 1,6-diynes and ynamides to generate C–N axially chiral indole derivatives has been developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Computational insights into the synergistic interplay of ligand and fluorine effects in palladium-catalyzed regiodivergent decarboxylative allylic alkylation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00147H, Research ArticleShiyu Wang, Hongli Wu, Xiangyang Tang, Genping HuangDFT calculations were performed to investigate palladium-catalyzed decarboxylative allylic alkylation of allyl difluoro-β-ketoesters. The synergistic effects of ligand and fluorine substituents on regioselectivity were uncovered.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Sustainable synthesis of long-acting local anesthetics ropivacaine and levobupivacaine under batch and continuous flow via asymmetric hydrogenation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00072B, Research ArticleZhi Yang, Hanlin Chen, Linxi Wan, Xinyi Feng, Lingshuang Ma, Pei Tang, Fen-Er ChenA sustainable synthesis method was developed for long-acting local anesthetics, ropivacaine and levobupivacaine, using both batch and continuous flow processes via asymmetric hydrogenation.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Synthesis of a helical boron-doped PAH by post-functionalization of 3,9-diboraperylene By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00421C, Research ArticleCarina Mützel, Kazutaka Shoyama, Ana-Maria Krause, Frank WürthnerA doubly helical boron-doped polycyclic aromatic hydrocarbon was synthesized, which showed a low LUMO level, a high absorption coefficient and fluorescence (ΦF = 0.73), combined with a one-dimensional π–π stacking interaction in the solid state.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Enantioselective synthesis of 8-membered lactone derivatives via organocatalytic cascade reactions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00148F, Research ArticleDong-Sheng Ji, Rui Zhang, Xu-Yan Han, Hai-Long Chai, Yucheng Gu, Xiu-Qin Hu, Peng-Fei XuThe challenging 8-membered lactone derivatives bearing two vicinal chiral stereocenters were synthesized via a cascade reaction mediated by the chiral squaramide.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Review of application of the I2 and dimethyl sulfoxide combined reagent system to aryl methyl ketones for diverse transformations By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00396A, Review ArticleDong-Sheng Yang, Xiang-Long Chen, An-Xin WuThe synthesis of small molecules and complex scaffolds is one of the most important topics in organic synthesis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Asymmetric [3 + 2] cycloaddition of donor–acceptor cyclopropanes with azadienes enabled by Brønsted base catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00002A, Research ArticleShu Li, Zhi-Hong Dong, Si-Yu Dan, Mei-Jun Zheng, Teng Long, Jie Zhan, Qing Zhou, Wen-Dao Chu, Quan-Zhong LiuA chiral bifunctional Brønsted base-catalyzed enantioselective [3 + 2] cycloaddition of D–A cyclopropanes and azadienes is reported. The protocol features broad substrate scope, mild reaction conditions and high functional group tolerance.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Organocatalytic formal [4 + 2] cycloaddition of o-quinone-methyl derivatives and 2-isocyanatomalonate diesters for the construction of chroman derivatives with adjacent quaternary chiral centers By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00141A, Research ArticleTong Xiong, Yi-Zhao Xu, Yao Wang, You-Cai Xiao, Fen-Er ChenAn asymmetric organocatalytic formal [4 + 2] cycloaddition/annulation cascade of ortho-quinone methides with 2-isocyanatomalonate diesters has been reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Stereodivergent synthesis of chiral spiropyrazolones through Pd-catalyzed asymmetric sequential hydroalkylation of 1,3-enynes: unusual solvent effects on the enantioselectivity By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00358F, Research ArticleShan Wang, Long Li, Yifei Zheng, Luqing Li, Yingcheng Wang, Fangzhi Peng, Zhihui ShaoChiral spiropyrazolones were constructed through Pd-catalyzed asymmetric sequential hydroalkylation of 1,3-enynes. Four stereoisomers could be obtained through substrate control and chiral ligand control.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Electrochemically dehydrogenative C(sp2)–H/S–H cross-coupling: efficient synthesis of ortho-aminophenyl thioglycoside derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00171K, Research ArticleLi-Yan Hu, Li Zhu, Shen-Yuan Zhang, Yu-Xin Guo, Yuan Li, Jie Zhu, Lei WuA method has been reported for synthesizing aryl thioglycosides through direct electrocatalytic dehydrogenative C(sp2)–H/S–H cross-coupling.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ic Blue light-mediated carbene transfer reaction of thioesters with diazoesters: efficient synthesis of tetrasubstituted Z-enol esters By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00265B, Research ArticleShuncheng Wang, Hua Zhang, Jin Yang, Dongfang Zhang, Xin-Ping HuiAn efficient metal-free, blue light-mediated carbene transfer reaction of thioesters with diazoesters has been achieved. This protocol produced tetrasubstituted Z-enol esters containing arylsulfur groups in good yields under mild conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article