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Polymeric polyiodo-chlorotellurates(IV): new supramolecular hybrids in halometalate chemistry

CrystEngComm, 2024, 26,2018-2024
DOI: 10.1039/D4CE00088A, Paper
Nikita A. Korobeynikov, Andrey N. Usoltsev, Maxim N. Sokolov, Alexander S. Novikov, Sergey A. Adonin
Reaction between TeO2 and I2 in HCl afforded a series of supramolecular hybrids Cat2{[TeCl6](I2)} (1–5) where diiodine fragments are linked to [TeCl6]2− octahedra via halogen bonds (XB).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Introduction of new guest molecules into BEDT-TTF radical-cation salts with tris(oxalato)ferrate

CrystEngComm, 2024, 26,1962-1975
DOI: 10.1039/D4CE00099D, Paper
Open Access
Toby J. Blundell, Elizabeth K. Rusbridge, Rebecca E. Pemberton, Michael J. Brannan, Alexander L. Morritt, Joseph O. Ogar, John D. Wallis, Hiroki Akutsu, Yasuhiro Nakazawa, Shusaku Imajo, Lee Martin
We present the crystal structures of five new BEDT-TTF radical-cation salts with tris(oxalato)ferrate anions using solid or liquid additives toluene, phenol, benzaldehyde, 4-bromobenzaldehyde, and kojic acid.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Two multifunctional Dy(III)-based metal–organic frameworks exhibiting proton conduction, magnetic properties and second-harmonic generation

CrystEngComm, 2024, 26,2033-2042
DOI: 10.1039/D4CE00065J, Paper
Ya-Qing Liao, Tian-Zheng Xiong, Kang-Le Xie, Huan Zhang, Jun-Jie Hu, He-Rui Wen
Two novelty Dy-MOFs were synthesized using H4DTTP-2OMe ligand. MOF 1 displays a more superior proton conductivity, field-induced single molecule magnets behavior and obvious second-order nonlinear optical properties.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Zn1−xMgxTe and P:Zn1−xMgxTe (x = 0.06–0.25) bulk crystals grown by travelling Te solution method

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00081A, Paper
Yuchen Song, Tingting Zhang, Jiahui Lv, Guorong Zhang, Changyou Liu, Tao Wang, Gangqiang Zha, Wanqi Jie
Zn1−xMgxTe and P:Zn1−xMgxTe (x = 0.06–0.25) bulk crystals were successfully grown by travelling Te solution method. The segregation of Mg with the growth of crystal is weaken and the as-grown crystal has high homogeneity.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Modulating the active phase in perovskite LaCoO3 with B-site doping of Cu for efficient methanol reforming to produce hydrogen

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01268A, Paper
Weiling Zhang, Peiwei Han, Juan Li, Zizhen Niu, Guowei Wang, Nan Wang, Xiangnan Li, Lyumeng Ye, Xinjun Li
The structure transformation of Cu+–Ov–Co2+ and Cu2+–O–Co3+ on the efficient MSR reaction.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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New 8-hydroxy quinoline-polycyclic aromatic hydrocarbon (PAH) conjugates and their sulfonated derivatives: effects of sulfonation and PAH size on their structural, supramolecular and cytotoxic properties

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00105B, Paper
Suman Sehlangia, Surbhi Dogra, Prosenjit Mondal, Chullikkattil P. Pradeep
The ring size of polycyclic aromatic hydrocarbons (PAHs) and sulfonation affect the supramolecular interactions and cytotoxic properties of a new series of 8-hydroxy quinoline-PAH conjugates.
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Metal–organic polyhedron from a flexible tetrakis(thiobenzyl-carboxylate)-tetrathiafulvalene

CrystEngComm, 2024, 26,2072-2077
DOI: 10.1039/D3CE01251D, Paper
Yohan Cheret, Narcis Avarvari, Nicolas Zigon
Wiggle, wiggle… Stay! A redox-active tetrakis(thiobenzyl-carboxylate)-TTF with a high degree of flexibility stands still in a self-assembled cage upon complexation with Cu(II).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Highly enhanced cationic dye adsorption from water by nitro-functionalized Zn-MOF nano/microparticles and a biomolecular binder for improving the reusability

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00131A, Paper
Gunasekaran Arunkumar, Mehboobali Pannipara, Abdullah G. Al-Sehemi, Savarimuthu Philip Anthony
Zn-MOF with a nitro-functionalized ligand exhibited enhanced cationic dye adsorption, and binder coating improved the reusability.
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Orthogonal stimulation of structural transformations in photo-responsive MOF films through linker functionalization

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00221K, Communication
Open Access
Sumea Klokic, Benedetta Marmiroli, Denys Naumenko, Giovanni Birarda, Simone Dal Zilio, Miriam de J. Velásquez-Hernández, Paolo Falcaro, Lisa Vaccari, Heinz Amenitsch
Controlling the magnitude of structural dynamics in flexible MOF films by an applied stimulus is largely desired for specific applications such as energy storage.
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Twitter applies temporary limit to address data scraping, system manipulation: Elon Musk

That comes after Twitter had announced that it will require users to have an account on the social media platform to view tweets.




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Zuckerberg’s Threads could disrupt Musk’s Twitter

New platform garnered over 30 million users after its debut




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Twitter may face difficulties showing Meta stole trade secrets

Legal experts say while many companies have accused competitors that hired former employees and have a similar product of stealing trade secrets, the cases are difficult to prove




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Elon Musk congratulates PM Modi for becoming most followed leader on X

Modi recently reached 100.1 million followers on X, surpassing other global leaders such as US President Joe Biden and Turkiye’s Recep Tayyip Erdogan. 




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Edible oil imports up 28% in July as traders buy more RBD palmolein, soya oil

Global decline in their prices aid the trend




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Export growth decelerates in July as global uncertainty rises

Imports rise sharply, trade deficit almost triples




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July retail inflation eases to 5-month low

At 6.7%, still far from RBI’s target; industrial growth dips to 12.3% in June




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Goyal calls for self-regulation in entertainment industry

The Minister added that the government is making efforts to simplify the permission mechanism for shooting of content at various locations in the country




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FinMin claims enough opportunity given to trade unions to present views during pre-budget consultations

FinMin officials say issue raised by the Trade Unions is politically motivated




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Centre weighs new WFH rules for SEZs to balance needs of units, developers

IT firms units want WHF for more employees for a longer period, developers are concerned about losing customers for office space




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Q2 GDP growth slows to 6.3%; Centre hopeful of 6.8-7% growth for full fiscal

Providing relief. Softening commodity prices, good rabi crop expectations likely to ease domestic inflation, says CEA




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Operating profit margin of 625 listed companies hits multi-year low

This, even as earnings jumped 27 per cent y-on-y, finds an ICRA study




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PFRDA wants Govt depts to fully adopt e-NPS method for onboarding new employees

Adopting ‘e-NPS Government’ method is necessary to align with goals of Centre’s Digital India program, PFRDA tells govt departments




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Government amends rules to place online gaming under MeitY

The appointment of MeitY as the central regulatory authority will provide clarity and certainty to investors, industry and consumers, says Federation of Indian Fantasy Sports




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CPSEs hired more contractual staff in FY22; regular, women employees drop out

Total staff count up 2.74%, but still lower than pre-Covid levels




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A single adverse weather event such as El Niño may not be a threat to macroeconomic stability, RBI Bulletin

There were years when, despite El Niño, rainfall was close to normal and inflation remained benign; the officials




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Prolonged Persian Gulf crisis can affect India’s economic activity: FinMin

Depending on how the situation develops, crude oil prices may push higher, says Finance Ministry’s monthly economic review




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Dialogue of books: Navigating a turbulent world with literature’s map of imaginary places

The case for rereading cannot be made emphatically enough as we see how the armchair nature of David Damrosch’s travels serves as a nudge to readers to structure their favourite books




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Shogo hits the right chord to fulfil his wanderlust

The 26-year old from Japan’s Tokyo has so far visited 36 countries making use of his social media connections




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India says oil prices would have rocketed without its Russian imports

India, the world's third largest oil importer and consumer, has become the top buyer of discounted Russian sea-borne oil shunned by Western countries since Ukraine's invasion began in early 2022




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India to focus on climate finance, accountability, protection for vulnerable communities at COP29

India's national statement is scheduled for November 18-19




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Govt hopeful of meeting capital expenditure target for FY25

Big Push. Aims to meet ₹11.11 lakh crore capex target, may relax cash management norms in Jan-March quarter




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Heightened tensions between China and the US: RBI’s easing cycle could be delayed, says DBS Research




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Two arrested for assaulting police officer




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Rahul Gandhi joins bypoll campaign in Wayanad, vows to make it global tourism hub

Campaigning for Priyanka Gandhi, Rahul Gandhi says people of Wayanad have taught him that the ‘word love has a great place in politics’




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Wayanad bypoll: Priyanka Gandhi leads roadshow with Rahul on last day of campaigning

Addressing the crowd after roadshow, Priyanka Gandhi expresses her appreciation for diverse communities within Wayanad constituency




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Officials violating service rules will face action, says Revenue Minister

Minister was responding to questions by mediapersons in connection with the recent Facebook posts by IAS officer N. Prasanth against his senior colleague A. Jayathilak




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Bengal cultural festival kicks off in Thrissur




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Bombay House guards assault photographers




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Buldhana school rape: main accused not an employee, say cops




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Three more held in Bombay House assault on photojournalists




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State housing regulator to inherit backlog of 15,905 complaints

The proposed authority is expected to streamline Mumbai’s largely unorganised real estate sector




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HC directs Collector to probe encroachments on Mulund land




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Man rapes 23-year-old in Nerul after promising job

Police working on call detail record to trace him




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Hawala operators, bullion traders face I-T heat

The I-T searches followed "specific and definitive information" against at least a dozen hawala operators and jewellers.




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Gulshan Kumar murder convict deported, brought to Mumbai




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At APMCs, no takers for agricultural produce




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Court grants bail to Rahul in RSS defamation case




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Financial aid and social mobility [electronic resource] : evidence from Colombia's Ser Pilo Paga / Juliana Londono-Velez, Catherine Rodriguez, Fabio Sanchez, Luis E. Alvarez-Arango

Cambridge, MA. : National Bureau of Economic Research, 2023




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The central bank's dilemma [electronic resource] : look through supply shocks or control inflation expectations? / Paul Beaudry, Thomas J. Carter, Amartya Lahiri

Cambridge, MA. : National Bureau of Economic Research, 2023




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Discovery of unregulated contaminants in drinking water [electronic resource] : evidence from PFAS and housing prices / Michelle M. Marcus, Rosie Mueller

Cambridge, MA. : National Bureau of Economic Research, 2023