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INDIAN SUPER LEAGUE | Chennaiyin needs to be wary of Mohammedan

FOOTBALL | The hosts got off to a good start to the season with a win over Odisha while the visitors will be smarting after conceding late goals in its previous outings




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Man United stunned 1-1 by Dutch club Twente in revamped Europa League

99% is not enough, You have to give 100%. You have kill the game. You have to finish it off, says Manchester United manager Erik ten Hag




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UEFA bans Barcelona fans from one Champions League game for Nazi-style flag

Barcelona was charged with “racism and/or other discriminatory conduct”




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Super League Kerala | Dorielton sizzles as Forca Kochi downs Thiruvananthapuram Kombans




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Champions League returns missing Mbappé, Rodri, Barella as injury wave hits European soccer

Champions League resumes with key players sidelined due to injuries, reshaping the competition landscape




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Real Madrid draws against Atletico in derby interrupted after objects thrown on the field

The derby was interrupted shortly after Real Madrid's goal at the Metropolitano, with the referee sending the players to the locker rooms after Atletico fans kept throwing objects onto the field.




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Tottenham beat 10-man Manchester United to up pressure on Ten Hag

Tottenham should have added to their lead long before United were reduced to 10 men when captain Fernandes was shown a straight red card on 42 minutes.




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Ten Hag demands Manchester United’s response in Europa League

The record 20-time English champions are off to their joint-worst start in the Premier League era, collecting just seven points from six games and scoring a mere five goals




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Villa shock Bayern in Champions League thanks to Duran's superb late strike

Duran ran onto a high ball in the 79th minute, spotted goalkeeper Manuel Neuer off his line, and scooped the ball over him to send Villa Park into delirium.




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Real Madrid suffers shock defeat to Lille in Champions League as Mbappe comes off bench

Lille’s goal came from Canada striker Jonathan David‘s penalty deep into first-half stoppage time




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Man United draws at Porto in Europa League as Bruno Fernandes gets sent off again

Substitute Harry Maguire came from the bench late to salvage a 3-3 draw for 10-man Manchester United at Porto in the Europa League




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ISL 11: Mohun Bagan SG returns to form with 3-0 drubbing of Mohammedan Sporting

Mohun Bagan seemed to have got the wake-up call in its previous defeat against Bengaluru FC and went for the kill right from the start




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Ten Hag future up in the air after Man United draws at Villa; Tottenham collapses in 3-2 loss

United heads into the two-week international break on a five-match winless run in all competitions and languishing in 14th place in the league, having won just two of its opening seven games this campaign




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First-half hat-trick for Lewandowski as Barcelona top league ahead of international break

Lewandowski has 12 goals in 11 games in all competitions, and has scored eight times in his last five matches.




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Mohun Bagan considered withdrawn from ACL 2: AFC

Mohun Bagan Super Giant had last month decided against travelling to Iran for the October 2 match owing to the volatile situation that prevailed in the west Asian nation at that time




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Super League Kerala | Dorielton saves the day for Kochi against Kannur

With one of the floodlight towers going off, the match had a forced break for some 10 minutes around the 80th minute




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France defeats Belgium, Germany beats Netherlands in Nations League

On his debut for Germany, Jamie Leweling scored in the side’s 1-0 win over the Netherlands; Kolo Muani nets a brace for France in the absence of Kylian Mbappe




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Liverpool stays ahead of Man City by beating Chelsea 2-1 in Premier League

Liverpool is looking more and more like Manchester City’s main title rival after beating resurgent Chelsea 2-1 to stay top of the Premier League table




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Vinicius hat-trick saves Real Madrid in Champions League, Villa go top

Real Madrid beats Borussia Dortmund 5-2 with Vinicius Junior’s hat-trick, while Aston Villa stays unbeaten in Champions League




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Champions League: Raphinha scores hat-trick as Barcelona romps Bayern; Liverpool, City notch up wins

Liverpool edged Leipzig 1-0 with a goal from Darwin Nunez; Manchester City routed Sparta Prague 5-0 with Erling Haaland scoring twice.




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Jose Mourinho gets red card against Man United as Fenerbahce holds on for draw in Europa League

Chelsea routed Panathinaikos 4-1 in Athens to make it two wins from two in the third-tier Conference League.




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ISL: Bengaluru rides on Mendez’s brace against Kerala Blasters, ends two-year wait for a win in Kochi

Bengaluru FC defeated Kerala Blasters 3-1 in the Indian Super League match




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Erik ten Hag fired as Manchester United fire manager after troubled start to season

Erik Ten Hag, who was hired in 2022, paid the price for leading United to just three wins in nine league games in the opening months of the campaign. Ruud van Nistelrooy was named interim coach.




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League Cup: Man United routs Leicester days after firing Ten Hag; Tottenham eliminates Manchester City

Liverpool continued its title defense with a 3-2 win over Brighton; Newcastle beat Chelsea 2-0




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Real Madrid Liga match against Valencia postponed due to deadly floods

Villarreal's home match against Rayo Vallecano was also suspended after the devastating flash floods in eastern Spain




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PSG moves 6 points clear at top of French league after beating Lens 1-0

Barcola has been PSG's best attacking player this season. Near the end of the first half, he played a through ball to Marco Asensio but goalkeeper Brice Samba saved his angled shot.




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Liverpool goes top of Premier League as Man City’s 32-game unbeaten streak ends at Bournemouth

Manchester City’s 32-game unbeaten streak in the Premier League has ended in a 2-1 loss at Bournemouth as Liverpool wrested back the lead in the title race




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No extra pressure on in-form Barcola, says PSG manager Enrique

The Spaniard said he was relying on all his players when asked about French forward Randal Kolo Muani, who has been linked with a move away from the reigning Ligue 1 champions




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Man United makes its worst league start in almost 40 years after 1-1 draw with Chelsea

Moises Caicedo’s stunning long-range volley has secured a 1-1 draw for Chelsea against Manchester United in the Premier League




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Real Madrid, Manchester City humiliated in Champions League; Liverpool enjoys Alonso’s return

Defending champion Madrid was humbled 3-1 at home by AC Milan; City lost 4-1 at Sporting Lisbon




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Barcelona, Inter and upstart Brest win again in Champions League; bizarre penalty dooms Aston Villa

Barcelona and Inter Milan lead Champions League standings, with Brest as a surprising newcomer in contention




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Rhenium(I) and technetium(I) complexes with megazol derivatives: towards the development of a theranostic platform for Chagas disease

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02714K, Paper
Ana Cristina Resende Gonçalves, Silvia Helena Libardi, Júlio Cesar Borges, Ronaldo Junio de Oliveira, Carla Gotzmann, Olivier Blacque, Sergio Albuquerque, Carla Duque Lopes, Roger Alberto, Pedro Ivo da Silva Maia
The diagnosis and treatment of Chagas disease (CD) in the chronic phase remains a challenge. With that in mind, a potential theranostic device based on the trypanocidal agent known as...
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Solvent-dependent Ln(III) clusters assembled by immobilization of CO2 in the air: zero-field single-molecule magnets and magnetic refrigerant materials

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02310B, Paper
Cai-Ming Liu, Xiang Hao, Zhao-Bo Hu, He-Rui Wen
The automatic fixation of CO2 in the air plays a key role in the construction of Dy(III) single-molecule magnets (SMMs) and Gd(III) magnetic refrigeration molecular materials using Ln(III)Cl3 (Ln =...
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Titanosiloxanes Consisting of Tetrahedrally Coordinated Ti Cores and Branched Siloxane Cages

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02848A, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shohei Saito, Kenta Kawamura, Naoto Sato, Takamichi Matsuno, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima
Well-defined titanosiloxane molecules with tetrahedrally coordinated Ti centers are synthesized by using mono-silanol functionalized siloxane cages as building blocks. The Ti sites are modified with the OSi(OSi)3 units, which is...
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β-Cyclodextrin and cucurbit[7]uril as protective encapsulation agents of the CO-releasing molecule [CpMo(CO)3Me]

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT01863J, Paper
Rodrigo P. Monteiro, Isabel B. Calhau, Ana C. Gomes, André D. Lopes, José P. Da Silva, Isabel S. Gonçalves, Martyn Pillinger
For inclusion compounds between the complex [CpMo(CO)3Me] (1) and β-cyclodextrin or cucurbit[7]uril, the macrocyclic hosts modulate to different degrees the UV light-mediated CO release from encapsulated 1.
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Excited-state intramolecular proton transfer (ESIPT) active interwoven polycatenated coordination polymer for selective detection of Al3+ and Ag+ ions along with water detection in less polar solvents

Dalton Trans., 2024, 53,18003-18012
DOI: 10.1039/D4DT02285H, Paper
Anupam Maiti, Rakesh Kumar, Bidyadhar Mahato, Debajyoti Ghoshal
An ESIPT active coordination polymer is successfully synthesized, exhibiting ESIPT induced blue shift for Al3+ ions and ESIPT-off for Ag+ ions. The material can also detect polar water, dimethylformamide and methanol in less polar organic solvents.
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Asymmetric magnetic nanosnowman loaded with AgPd nanocage toward NIR-enhanced catalytic activity

Dalton Trans., 2024, 53,17864-17879
DOI: 10.1039/D4DT02425G, Paper
Jie Jin, Haoran Li, Hongfa Wang, Qunling Fang, Yunqi Xu, Weili Kong, Xia Chen, Ken Cham-Fai Leung, Hailong Wang, Shouhu Xuan
An asymmetric Fe3O4@AgPd/PDA nanosnowman embedded with an AgPd nanocage shows significantly enhanced catalytic activity under near-infrared (NIR) light.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Optimizing synergistic effects: creating oxygen vacancies in NiCoWO4via a solid-state grinding method for improved energy storage performance

Dalton Trans., 2024, 53,17948-17962
DOI: 10.1039/D4DT02118E, Paper
Anandhavalli Jeevarathinam, Arun Annamalai, Ramya Ravichandran, Kumaresan Annamalai, Sundaravadivel Elumalai
We disclose, for the first time we report the synthesis of an oxygen vacancy-enriched NiCoWO4 electrode by a simple solid state grinding method using NaBH4 as a mild reducing agent without any solvents.
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Coinage metal(I) clusters supported by a 1,10-phenanthroline-phosphine: orange-to-NIR phosphorescence, metallophilic interactions and enhanced cytotoxicity

Dalton Trans., 2024, 53,18027-18036
DOI: 10.1039/D4DT02642J, Paper
Alexander V. Artem'ev, Maria P. Davydova, Lyubov S. Klyushova, Evgeniy H. Sadykov, Mariana I. Rakhmanova, Taisiya S. Sukhikh
Based on 2-(diphenylphosphino)-1,10-phenanthroline, a series of small metal(I) clusters, exhibiting orange to NIR phosphorescence and strong dose-dependent cytotoxicity.
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An acidity-triggered aggregation nanoplatform based on degradable mesoporous organosilica nanoparticles for precise drug delivery and phototherapy of focal bacterial infection

Dalton Trans., 2024, 53,17893-17901
DOI: 10.1039/D4DT02111H, Paper
Yunhan Huang, Wei Guo, Xinyu Wang, Jingrui Chang, Bo Lu
An acidity-triggered aggregation antibacterial nanoplatform based on biodegradable mesoporous organic silica nanoparticles, is reported. It enables precise drug release and spatial accuracy for photodynamic therapy and photothermal therapy.
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Unprecedented C–F bond cleavage in perfluoronaphthalene during cobaltocene reduction

Dalton Trans., 2024, 53,17789-17793
DOI: 10.1039/D4DT02791D, Communication
Gargi Kundu, Debjit Pramanik, Soumya Ranjan Dash, Ravi Kumar, Mayur Sangole, Srinu Tothadi, Aryya Ghosh, Kumar Vanka, Kirandeep Singh, Sakya S. Sen
The reduction of octafluoronapthalene by cobaltocene in preence of NHC led to a distinct Co(I) species with the cleavage of the C–F bond and the formation of Co–C bond.
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Synthesis and relaxivity of gadolinium-based DOTAGA conjugated 3-phosphoglycerate

Dalton Trans., 2024, 53,17777-17782
DOI: 10.1039/D4DT02766C, Communication
Open Access
Andrew R. Brotherton, Shifa Noor Mohamed, Thomas J. Meade
A Gd-DOTAGA based MR contrast agent conjugated to 3-phosphoglycerate for enhanced relaxivity and investigation into its metabolism.
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The effect of second coordination sphere interactions on the magnetic anisotropy of transition metals

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02873B, Paper
Sofie S. Leiszner, Mauro Perfetti, Emil Damgaard-Møller, Yu-Sheng Chen, Bo B. Iversen
By investigating second coordination sphere effects on the magnetic anisotropy of a Co(II) single molecule magnet (SMM), we aim to clarify their role in magneto-structural correlations to enhance the performance of transition metal SMMs.
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Mechanistic studies of NOx reduction reactions involving copper complexes: encouragement of DFT calculations

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02420F, Frontier
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yohei Kametani, Yoshihito Shiota
Mechanistic analysis of nitrite (NO2) and nitric oxide (NO) reduction reactions promoted by copper complexes provides a reliable view of electron transfer and atom movement.
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Modular synthesis of triphenylphosphine-derived cage ligands for rhodium-catalyzed hydroformylation applications

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02627F, Paper
Wenlong Wang, Cunyao Li, Wenhao Wang, Yuqin Qiu, Hongguang Liu, Jinlong Lu, Yizhou Zhan, Li Yan, Yunjie Ding
Cage ligands can be easily synthesized via dynamic imine chemistry, and a specific cage ligand exhibits excellent performance in Rh-catalyzed hydroformylation reaction (TOF up to 2665 h−1 and the l/b ratio reaches 2.6).
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Asymmetric triply bridged lanthanide binuclear clusters with distinctly different magnetic behaviors

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02652G, Communication
Yue Yang, Yu-Xia Wang, Yu-Zhe Lei, Peng Cheng
Isomorphic binuclear clusters Gd and Dy with antiferromagnetic and ferromagnetic couplings are separately exhibiting single-molecule magnetic behavior and strong magnetocaloric entropy.
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Single-ion magnetism in novel Btp-based cobalt complexes of different charge

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02338B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Gustavo Rama-Martínez, Marcelo Osorio-Celis, Yolanda Sabater-Algarra, Diego Sánchez-Brunete, Antonio L. Llamas-Saiz, Eugenia P. Quirós-Díez, M. Eugenio Vázquez, Miguel Vázquez López, María del Carmen Giménez López
By deprotonating Btp-derived ligands, precise control over counterions in the outer-coordination sphere is achieved in both neutral and charged anisotropic CoII complexes exhibiting field-induced single-ion magnetism.
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Tie the knot on extravagant weddings

In conducting the feast and ceremonies, families spend as if there is no tommorow




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The richness of Indian languages

The idioms in everyday usage display the creativity and punch of the tongues




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A shrinking Himalayan passage

A visit to Nagmithong Nala near Kargil, where the threat of a glacial lake outburst flood looms large and Botkol Pass is set to become inaccessible