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Environmental design: architecture, politics, and science in postwar America / Avigail Sachs

Rotch Library - NA2543.S6 S225 2018




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Lexique Lequeu / Laurent Baridon, Jean-Philippe Garric, Martial Guédron

Rotch Library - NA2707.L47 B37 2018




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Jean-Jacques Lequeu: bâtisseur de fantasmes / sous la direction de Laurent Baridon, Jean-Philippe Garric et Martial Guédron ; avec la collaboration scientifique de Corinne Le Bitouzé

Rotch Library - NA1053.L475 A4 2018




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[ASAP] Carbon Dioxide Reduction by Multimetallic Uranium(IV) Complexes Supported by Redox-Active Schiff Base Ligands

Organometallics
DOI: 10.1021/acs.organomet.9b00792




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[ASAP] Breaking Scaling Relationships in CO<sub>2</sub> Electroreduction with Isoelectronic Analogs [Fe<sub>4</sub>N(CO)<sub>12</sub>]<sup>-</sup> and [Fe<sub>3</sub>MnO(CO)<sub>12</sub&

Organometallics
DOI: 10.1021/acs.organomet.9b00848




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[ASAP] CO<sub>2</sub> (De)Activation in Carboxylation Reactions: A Case Study Using Grignard Reagents and Nucleophilic Bases

Organometallics
DOI: 10.1021/acs.organomet.9b00838




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[ASAP] Neutral Ni(II) Catalysts Based on Maple-Lactone Derived [N,O] Ligands for the Polymerization of Ethylene

Organometallics
DOI: 10.1021/acs.organomet.0c00061




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[ASAP] Dibromine Promoted Transmetalation of an Organomercurial by Fe(CO)<sub>5</sub>: Synthesis, Properties, and Cytotoxicity of Bis(2-C<sub>6</sub>H<sub>4</sub>-2'-py-<italic toggle="yes">?C,N</

Organometallics
DOI: 10.1021/acs.organomet.0c00107




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[ASAP] (Isonitrile)platinum(II) Complexes of an Amido Bis(N-heterocyclic carbene) Pincer Ligand

Organometallics
DOI: 10.1021/acs.organomet.0c00065




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[ASAP] Effect of Ancillary Ligands as a Part of Counteranion in Neodymium-Catalyzed Isoprene Polymerization

Organometallics
DOI: 10.1021/acs.organomet.0c00112




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[ASAP] [2 + 2] Cycloaddition of <italic toggle="yes">o</italic>-Carboryne with Vinyl Ethers: Synthesis of Carborane-Fused Cyclobutanes

Organometallics
DOI: 10.1021/acs.organomet.0c00163




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[ASAP] Development of P- and N-Chirogenic Ligands Based on Chiral Induction from a Phosphorus Donor to a Nitrogen Donor in Palladium Complexes

Organometallics
DOI: 10.1021/acs.organomet.0c00154




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[ASAP] Catalytic C–H Bond Alkylation of Azoles with Alkyl Halides Mediated by Nickel(II) Complexes of Phenanthridine-Based <italic toggle="yes">N</italic>^<italic toggle="yes">N</italic><sup><italic tog

Organometallics
DOI: 10.1021/acs.organomet.0c00161




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[ASAP] NHC-Palladium(II) Mononuclear and Binuclear Complexes Containing Phenylene-Bridged Bis(thione) Ligands: Synthesis, Characterization, and Catalytic Activities

Organometallics
DOI: 10.1021/acs.organomet.0c00091




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[ASAP] C–F Bond Activation of a Perfluorinated Ligand Leading to Nucleophilic Fluorination of an Organic Electrophile

Organometallics
DOI: 10.1021/acs.organomet.0c00176




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[ASAP] Spatial Recognition Within Terpenes: Redox and H-bond Promoted Linkage Isomerizations and the Selective Binding of Complex Alkenes

Organometallics
DOI: 10.1021/acs.organomet.0c00151




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[ASAP] Linkage Isomerism in Dinuclear Al and Ga Organometallic Complexes: Structural and Reactivity Consequences

Organometallics
DOI: 10.1021/acs.organomet.0c00096




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[ASAP] Self-Assembled Redox-Active Tetraruthenium Macrocycles with Large Intracyclic Cavities

Organometallics
DOI: 10.1021/acs.organomet.0c00116




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[ASAP] Sila-Peterson Reaction of Cyclic Silanides

Organometallics
DOI: 10.1021/acs.organomet.0c00106




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[ASAP] Improving Redox Reversibility and Intermetallic Coupling of Co(III) Alkynyls through Tuning of Frontier Orbitals

Organometallics
DOI: 10.1021/acs.organomet.0c00183




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[ASAP] A Stiboranyl Platinum Triflate Complex as an Electrophilic Catalyst

Organometallics
DOI: 10.1021/acs.organomet.0c00193




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[ASAP] Synthesis and Characterization of an Oxo-Centered Homotrimetallic Uranium(IV)–Cyclobutadienyl Dianion Complex

Organometallics
DOI: 10.1021/acs.organomet.0c00104




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[ASAP] Development of Quinoline-Derived Chiral Diaminocarbene Ligands and Their Transition Metal Complexes: Synthesis, Structural Characterization, and Catalytic Properties

Organometallics
DOI: 10.1021/acs.organomet.0c00141




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[ASAP] Ga(N,P) Growth on Si and Decomposition Studies of the N–P Precursor Di-<italic toggle="yes">tert</italic>-butylaminophosphane (DTBAP)

Organometallics
DOI: 10.1021/acs.organomet.0c00078




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[ASAP] Reactivity of Amidinatosilylenes and Amidinatogermylenes with [PtMe<sub>2</sub>(?<sup>4</sup>-cod)]: <italic toggle="yes">cis</italic>- versus <italic toggle="yes">trans</italic>-[

Organometallics
DOI: 10.1021/acs.organomet.0c00188




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[ASAP] Synthesis and Characterization of Tungsten Alkylidene and Alkylidyne Complexes Featuring a New Carbazole-Based Rigid Trianionic ONO<sup>3–</sup> Pincer-Type Ligand

Organometallics
DOI: 10.1021/acs.organomet.0c00150




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[ASAP] <italic toggle="yes">O</italic>-Carboranylene versus Phenylene Backbones in Cyclization Reactions of 1,2 Diketones with Hydrosilanes

Organometallics
DOI: 10.1021/acs.organomet.0c00208




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[ASAP] Use of Ligand Steric Properties to Control the Thermodynamics and Kinetics of Oxidative Addition and Reductive Elimination with Pincer-Ligated Rh Complexes

Organometallics
DOI: 10.1021/acs.organomet.0c00122




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[ASAP] Synthesis, Structures, and Electronic Properties of O- and S-Heterocyclic Carbene Complexes of Iridium, Copper, Silver, and Gold

Organometallics
DOI: 10.1021/acs.organomet.0c00066




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Online Collaboration

But for pesky technical gremlins, this would certainly be our best episode yet. Apologies in advance for the background noise. Pre-recording testing was good, however it appears that an intermittent issue with a USB connector has caused us a few problems that can’t be edited out. Now we know we’ll do better next time.

Moving on this week’s show focuses on online document collaboration, discusses GMail’s 9th birthday, a new JS gem from Dave Rupert and much more.




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New Flickr, New Digg!

We are back behind the Yeti’s to discuss Keir’s trip to Beyond Tellerrand, the new Flickr subscription model, Digg Reader, Prism and our recent Mac email client woes. We round out the show with quite possibly the best use of technology we have come across – intrigued? You should be!




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Live with a Flat White

This week Kieran joins us live via a pair of Apple headphones from Coffee #1. Complete with baristas creating flat whites and the chitter chatter of remote workers typing away we throw audio fidelity to the wind and freestyle over a few links from Keir’s web site.




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Lost with Lindberg

This week we celebrate the internet’s very own Oliver Lindberg as we get #lostwithlindberg. Given our distinct lack of direction for this episode, it seemed only right and proper that our favourite editor of the internet takes this week’s naming rights. If you are ever lost, and if you can find him, maybe you can also get “lost with Lindberg”. Cue the music.

We might not be a crack commando unit but we did our best to highlight a few choice topics from the internet underground. In this week’s show, we speak out in favour of the new Instagram logo, welcome the Lord of the .io domain to the UK’s most hipster city, discuss a big man with a new big book, see the sunset on sunrise, and finally get all excited about our new startup!




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The Super Lit, Fam, Dope, En Flique Episode

It feels like only last week that the two “K Units” got behind the Samson CO1UPRO‘s and recorded episode #43. So close in fact, that we even manage to think we are still actually recording episode #43!

In this short 53 minute episode, we catch up on recent life goings on, learn that Kieran has been “tamping hard” in his role as “Digital Guy” at the bespoke artisanal coffee roasting company, discuss language used by people under the age of 30, announce our new club, and round out with a chat about Kickstarter. There may even be a mention of earphones!




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Back Stories with Oliver Lindberg

In this episode of Back Stories, Keir chats with Oliver Lindberg— founder of the new Pixel Pioneers web conference series and all round content guru. Topics covered include how to find speakers for your conference, the role of a good editor, how to improve your writing skills, and how to pitch to an editor.

Oliver Online




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At frontline, junior docs are soldiers, generals

In the ward of Covid-19 patients, one could expect the medicine, anaesthesia or pulmonology experts at work. But if one visits Civil Hospital, the treating doctor could well be on his/ her way to become ophthalmologist, gynaecologist or general surgeon! In SVP hospital, he or she may be specialising in psychiatry too!




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Migrant workers clash with police in Surat

Demanding a return passage to their home states, hundreds of agitated migrant workers clashed with the police at Mora village in Gujarat's Surat district on Saturday, an official said.




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Resource Showcase: National Emergency Library

Internet Archive has launched a National Emergency Library, containing over 1.4 million ebooks that are usually restricted by institutional passwords and paywalls. These are freely available during the Covid-19 crisis until 30 June 2020. Read more about additional e-resources currently available See what e-resources we currently have on trial See what other resources the library has for your subject




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Synthesis of lignin-functionalized phenolic nanosphere supported Ag nanoparticles with excellent dispersion stability and catalytic performance

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04311J, Paper
Shilin Chen, Guanhua Wang, Wenjie Sui, Ashak Mahmud Parvez, Chuanling Si
This work presents a novel and green lignin-based nanocomposite and highlights the synergism of lignin's multiple functions (surfactant, sacrificial template, and reducing agent) in the material preparation process.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Simplifying levulinic acid conversion towards a sustainable biomass valorisation

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04306C, Paper
Chiara Defilippi, Daily Rodríguez-Padrón, Rafael Luque, Cristina Giordano
In the range of biomass valorisation, hydroconversion of levulinic acid (one of the products of the hydrolysis of lignocellulosic biomass) was tested for the first time using nanosized Ni3N and Ni0 catalysts, with very promising results alongside high stability.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Water Effects in the Heterogeneous Catalytic Valorization of Levulinic Acid into γ-Valerolactone and its Derivatives

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01082K, Critical Review
Rengui Weng, Zhihao Yu, Jian Xiong, Xuebin Lu
Levulinic acid (LA), which has been hailed as a versatile biomass-derived platform molecular, typically occupy a core position in the cellulosic biorefinery system. The heterogeneous catalytic valorization of LA for...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Methylation-triggered fractionation of lignocellulosic biomass to afford cellulose-, hemicellulose-, and lignin-based functional polymers via click chemistry

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00451K, Paper
Kentaro Miki, Hiroshi Kamitakahara, Arata Yoshinaga, Yuki Tobimatsu, Toshiyuki Takano
This paper reports a new concept for the biorefinery of lignocellulosic biomass where the derivatisation and fractionation of lignocellulose are accomplished at the same time.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Sustainable synthesis of cobalt and cobalt oxide nanoparticles and their catalytic and biomedical applications

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00885K, Critical Review
Siavash Iravani, Rajender S. Varma
Recent advances and essential challenges as well as catalytic and biomedical applications of cobalt oxide and cobalt nanoparticles are highlighted.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Photocatalyst-free visible light promoted E → Z isomerization of alkenes

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04303A, Communication
Jianbin Xu, Na Liu, Haiping Lv, Chixian He, Zining Liu, Xianfu Shen, Feixiang Cheng, Baomin Fan
A photocatalyst-free, simple and green method of visible light driven photocatalytic E to Z isomerization of alkenes has been developed.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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New biobased-zwitterionic ionic liquids: efficiency and biocompatibility for the development of sustainable biorefinery processes

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC01002B, Paper
Gaël Huet, Monica Araya-Farias, Ranim Alayoubi, Sylvain Laclef, Benjamin Bouvier, Isabelle Gosselin, Christine Cézard, Romain Roulard, Matthieu Courty, Caroline Hadad, Eric Husson, Catherine Sarazin, Albert Nguyen Van Nhien
A combination of experiments and modeling reveals the influence of alkyl chain lengths in biobased ZILs on the biocompatibility towards various microorganisms.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A Strategy for The Assembly of Glypromate® and Structure-Related Analogues by Tandem Sequential Peptide Coupling

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00143K, Paper
Ivo E Sampaio-Dias, Luís Pinto da Silva, Sandra G Silva, Xerardo Garcia-Mera, José Enrique Rodriguez-Borges
This work describes an improved and greener methodology in solution-phase synthesis for the preparation of Glypromate® (glycyl-L-prolyl-L-glutamic acid, GPE), a potent neuropeptide with applications in neurodegenerative conditions such as Huntington's,...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Thermophilic bio-electro CO2 recycling into organic compounds

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00320D, Paper
Open Access
Laura Rovira-Alsina, Elisabet Perona-Vico, Lluís Bañeras, Jesús Colprim, M. Dolors Balaguer, Sebastià Puig
Many industrial combustion processes produce carbon dioxide (CO2) at high temperature, which may be electrically recycled into valuable chemicals using microorganisms as catalysts.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Solvent-free hydrogenation of levulinic acid to γ-valerolactone using a Shvo catalyst precursor: optimization, thermodynamic insights, and life cycle assessment

Green Chem., 2020, 22,2443-2458
DOI: 10.1039/C9GC02088H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christian A. M. R. van Slagmaat, Marie A. F. Delgove, Jules Stouten, Lukas Morick, Yvonne van der Meer, Katrien V. Bernaerts, Stefaan M. A. De Wildeman
We studied the solvent-free hydrogenation of levulinic acid to γ-valerolactone with the Shvo catalyst involving comparative catalysis, DFT, and LCA.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of renewable C–C cyclic compounds and high-density biofuels using 5-hydromethylfurfural as a reactant

Green Chem., 2020, 22,2468-2473
DOI: 10.1039/D0GC00195C, Paper
Taimei Cai, Qiang Deng, Hailong Peng, Jin Zhong, Rui Gao, Jun Wang, Zheling Zeng, Ji-Jun Zou, Shuguang Deng
Renewable C–C six-membered ring compound and high-density biofuel are synthesized using 5-hydromethylfurfural as a reactant.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Sustainability by design: automated nanoscale 2,3,4-trisubstituted quinazoline diversity

Green Chem., 2020, 22,2459-2467
DOI: 10.1039/D0GC00363H, Paper
Open Access
Mojgan Hadian, Shabnam Shaabani, Pravin Patil, Svitlana V. Shishkina, Harry Böltz, Alexander Dömling
Automated, one step, nanoscale synthesis of 2,3,4-trisubstituted quinazoline derivatives using positive pressure facilitated dispensing to access a very large chemical space exemplified by more than 1000 compounds.
The content of this RSS Feed (c) The Royal Society of Chemistry