it

Spectroscopic investigations under whole-cell conditions provide new insight into the metal hydride chemistry of [FeFe]-hydrogenase

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00512F, Edge Article
Open Access
Lívia S. Mészáros, Pierre Ceccaldi, Marco Lorenzi, Holly J. Redman, Emanuel Pfitzner, Joachim Heberle, Moritz Senger, Sven T. Stripp, Gustav Berggren
The mechanism of hydrogen gas formation by [FeFe] hydrogenase is probed under whole cell conditions, revealing the formation of reactive metal hydride species under physiologically relevant conditions.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Structure-mechanics statistical learning unravels the linkage between local rigidity and global flexibility in nucleic acids

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00480D, Edge Article
Open Access
Yi-Tsao Chen, Haw Yang, Jhih-Wei Chu
The mechanical properties of nucleic acids underlie biological processes ranging from genome packaging to gene expression. We devise structural mechanics statistical learning method to reveal their molecular origin in terms of chemical interactions.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




it

The assemble, grow and lift-off (AGLO) strategy to construct complex gold nanostructures with pre-designed morphologies

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00553C, Edge Article
Open Access
Xin Luo, Christophe Lachance-Brais, Amy Bantle, Hanadi F. Sleiman
The AGLO strategy generates complex gold nanostructures with user-designed morphologies in solution, using only a simple 2D DNA origami sheet as a versatile transient template. The products are robust and stable as standalone gold nanostructures.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Allylic C(sp3)–H alkylation via synergistic organo- and photoredox catalyzed radical addition to imines

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00819B, Edge Article
Open Access
Jiaqi Jia, Rajesh Kancherla, Magnus Rueping, Long Huang
A new catalytic method for the direct alkylation of allylic C(sp3)–H bonds from unactivated alkenes via synergistic organo- and photoredox catalysis is described.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Ultrafast Amidation of Esters using Lithium Amides under Aerobic Ambient Temperature Conditions in Sustainable Solvents

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01349H, Edge Article
Open Access
Michael Fairley, Leonie Bole, Florian Mulks, Laura Main, Alan Kennedy, Charles T. O'Hara, Joaquín García-Álvarez, Eva Hevia
Lithium amides constitute one of the most commonly used class of reagents in synthetic chemisty. However, despite many applications, their use is handicapped by their requirements of low temperatures, in...
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Nitric oxide monooxygenation (NOM) reaction of cobalt-nitrosyl {Co(NO)}8 to CoII-nitrito {CoII(NO2−)}: base induced hydrogen gas (H2) evolution

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01572E, Edge Article
Open Access
Sandip Das, Kulbir, Somnath Ghosh, Subash Chandra Sahoo, Pankaj Kumar
Base-induced hydrogen (H2) gas evolution in the nitric oxide monoxygenation reaction.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




it

A straightforward approach to antibodies recognising cancer specific glycopeptidic neoepitopes

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00317D, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hajime Wakui, Yoshikazu Tanaka, Toyoyuki Ose, Isamu Matsumoto, Koji Kato, Yao Min, Taro Tachibana, Masaharu Sato, Kentaro Naruchi, Fayna Garcia Martin, Hiroshi Hinou, Shin-Ichiro Nishimura
We developed new class of designated antibodies targeting of “dynamic neoepitopes” elaborated by disease-specific O-glycosylation at the immunodominant mucin domains.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Structure of Copper sites in Zeolites Examined by Fourier and Wavelet Transform Analysis of EXAFS

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01472A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Vitaly L. Sushkevich, Olga V. Safonova, Dennis Palagin, Mark A Newton, Jeroen van Bokhoven
Copper-exchanged zeolites are a class of redox-active materials that find application in the selective catalytic reduction of exhaust gases of diesel vehicles, and, more recently, the selective oxidation of methane...
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Molecular recognition of pyrazine N,N'-dioxide using aryl extended calix[4]pyrroles

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01496F, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Chenxing Guo, Hu Wang, Vincent M. Lynch, Xiaofan Ji, Zachariah A. Page, Jonathan L. Sessler
The molecular recognition of pyrazine N,N'-dioxide by aryl extended 'two-walled' calix[4]pyrrole-based receptors is seen to stabilise two different binding modes in the solid state.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Efficient alkene hydrosilation with bis(8-quinolyl)phosphine (NPN) nickel catalysts. The dominant role of silyl-over hydrido-nickel catalytic intermediates

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00997K, Edge Article
Open Access
Jian Yang, Verònica Postils, Michael I. Lipschutz, Meg Fasulo, Christophe Raynaud, Eric Clot, Odile Eisenstein, T. Don Tilley
A cationic nickel complex of the bis(8-quinolyl)(3,5-di-tert-butylphenoxy)phosphine (NPN) ligand, [(NPN)NiCl]+, is a precursor to efficient catalysts for the hydrosilation of alkenes with hydrosilanes under mild conditions and low catalyst loadings.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Triblock polyester thermoplastic elastomers with semi-aromatic polymer end blocks by ring-opening copolymerization

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00463D, Edge Article
Open Access
Georgina L. Gregory, Gregory S. Sulley, Leticia Peña Carrodeguas, Thomas T. D. Chen, Alba Santmarti, Nicholas J. Terrill, Koon-Yang Lee, Charlotte K. Williams
A new series of block polyester thermoplastic elastomers are prepared by a one-pot procedure; they show properties competitive or better than conventional materials and can be fully degraded after use.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Protease-Responsive Mass Barcoded Nanotranslaters for Simultaneously Quantifying the Intracellular Activity of Cascaded Caspases in Apoptosis Pathways

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01534B, Edge Article
Open Access
Hongmei Xu, Xiaodan Huang, Zhenzhen Zhang, xuemeng zhang, Qianhao Min, Jun-Jie Zhu
Quantitatively delineating the activation network of multiple proteases that participate in cellular processes is highly essential to understanding physiological and pathological states of cells. In this study, protease-responsive mass barcoded...
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Highly efficient non-doped blue fluorescent OLEDs with low efficiency roll-off based on hybridized local and charge transfer excited state emitters

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01341B, Edge Article
Open Access
Xianhao Lv, Mizhen Sun, Lei Xu, Runzhe Wang, Huayi Zhou, Yuyu Pan, Shitong Zhang, Qikun Sun, Shanfeng Xue, Wenjun Yang
A new pure fluorescent blue HLCT-emitter was designed and synthesized. Highly efficient non-doped blue OLEDs with low efficiency roll-off were achieved.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Rapidly Self-deoxygenating Controlled Radical Polymerization in water via in-situ Disproportionation of Cu(I)

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01512A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
David Haddleton, Evelina Liarou, Yisong Han, Marc Walker, Ana Sanchez
The first rapidly self-deoxygenating Cu-RDRP in aqueous media is investigated. The disproportionation of Cu(I)/Me6Tren in water towards Cu(II) and highly reactive Cu(0) leads to O2-free reaction environments within the first...
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Structural trends in the dehydrogenation selectivity of palladium alloys

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00875C, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Stephen C. Purdy, Ranga Rohit Seemakurthi, Garrett M. Mitchell, Mark Davidson, Brooke A. Lauderback, Siddharth Deshpande, Zhenwei Wu, Evan C. Wegener, Jeffrey Greeley, Jeffrey T. Miller
Alloying is well-known to improve the dehydrogenation selectivity of pure metals, but there remains considerable debate about the structural and electronic features of alloy surfaces that give rise to this behavior.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Evolution of pure hydrocarbon hosts: simpler structure, higher performance and universal application in RGB phosphorescent organic light-emitting diodes

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01238F, Edge Article
Open Access
Qiang Wang, Fabien Lucas, Cassandre Quinton, Yang-Kun Qu, Joëlle Rault-Berthelot, Olivier Jeannin, Sheng-Yi Yang, Fan-Cheng Kong, Sarvendra Kumar, Liang-Sheng Liao, Cyril Poriel, Zuo-Quan Jiang
In this work, we propose pure hydrocarbon materials as universal hosts for high-efficiency red, green and blue phosphorescent organic light-emitting diodes.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Exploiting single-electron transfer in Lewis pairs for catalytic bond-forming reactions

Chem. Sci., 2020, 11,4305-4311
DOI: 10.1039/D0SC01159B, Edge Article
Open Access
Yoshitaka Aramaki, Naoki Imaizumi, Mao Hotta, Jun Kumagai, Takashi Ooi
Radical–ion pair generation from common Lewis pairs and its application to catalytic carbon–carbon bond formation.
The content of this RSS Feed (c) The Royal Society of Chemistry




it

An RGB-emitting molecular cocktail for the detection of bacterial fingerprints

Chem. Sci., 2020, 11,4403-4409
DOI: 10.1039/D0SC01704C, Edge Article
Open Access
Sheng Hong, Di-Wei Zheng, Qiu-Ling Zhang, Wei-Wei Deng, Wen-Fang Song, Si-Xue Cheng, Zhi-Jun Sun, Xian-Zheng Zhang
A technique named the Microcolor system was developed to detect microbes and diagnose diseases based on changes in microbiota signatures.
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Redox-inactive ions control the redox-activity of molecular vanadium oxides

Chem. Sci., 2020, 11,4450-4455
DOI: 10.1039/D0SC01401J, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Simon Greiner, Benjamin Schwarz, Mark Ringenberg, Maximilian Dürr, Ivana Ivanovic-Burmazovic, Maximilian Fichtner, Montaha Anjass, Carsten Streb
The enhanced redox-activity of a molecular vanadium oxide cluster upon functionalization with redox-inert Ca2+ ions is reported together with initial insights into its performance as a lithium ion battery cathode.
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Chemical control of competing electron transfer pathways in iron tetracyano-polypyridyl photosensitizers

Chem. Sci., 2020, 11,4360-4373
DOI: 10.1039/C9SC06272F, Edge Article
Open Access
Kristjan Kunnus, Lin Li, Charles J. Titus, Sang Jun Lee, Marco E. Reinhard, Sergey Koroidov, Kasper S. Kjær, Kiryong Hong, Kathryn Ledbetter, William B. Doriese, Galen C. O'Neil, Daniel S. Swetz, Joel N. Ullom, Dale Li, Kent Irwin, Dennis Nordlund, Amy A. Cordones, Kelly J. Gaffney
Photoinduced intramolecular electron transfer in Fe tetracyano-polypyridyl complexes was investigated with static and time-resolved UV-visible absorption and resonant inelastic X-ray scattering which revealed a competition of two relaxation pathways.
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Self-enhanced multicolor electrochemiluminescence by competitive electron-transfer processes

Chem. Sci., 2020, 11,4508-4515
DOI: 10.1039/D0SC00853B, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Silvia Voci, Romain Duwald, Stéphane Grass, David J. Hayne, Laurent Bouffier, Paul S. Francis, Jérôme Lacour, Neso Sojic
Controlling electrochemiluminescence (ECL) color(s) is crucial for many applications ranging from multiplexed bioassays to ECL microscopy.
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Designing naphthopyran mechanophores with tunable mechanochromic behavior

Chem. Sci., 2020, 11,4525-4530
DOI: 10.1039/D0SC01359E, Edge Article
Open Access
Brooke A. Versaw, Molly E. McFadden, Corey C. Husic, Maxwell J. Robb
Structure–activity relationships for strategic substitution of the naphthopyran mechanophore scaffold enable polymeric materials with tunable mechanochromic behavior.
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Multifunctional streptavidin–biotin conjugates with precise stoichiometries

Chem. Sci., 2020, 11,4422-4429
DOI: 10.1039/D0SC01589J, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Dongdong Xu, Seraphine V. Wegner
Multifunctional streptavidin-biotin conjugates with defined stoichiometry and number of open binding pockets provide molecularly precise alternatives to the statistical mixture of products that typically forms.
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Synthesis and properties of hypervalent electron-rich pentacoordinate nitrogen compounds

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00002G, Edge Article
Open Access
Chenting Yan, Masato Takeshita, Jun-ya Nakatsuji, Akihiro Kurosaki, Kaoko Sato, Rong Shang, Masaaki Nakamoto, Yohsuke Yamamoto, Yohei Adachi, Ko Furukawa, Ryohei Kishi, Masayoshi Nakano
Structural characterization of hypervalent electron-rich pentacoordinate nitrogen species has long been a synthetic challenge. Here we report the first nitrogen cationic radical (11-N-5) species featuring a weak hypervalent 3c-5e interaction.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Geometric landscapes for material discovery within energy–structure–function maps

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00049C, Edge Article
Open Access
Seyed Mohamad Moosavi, Henglu Xu, Linjiang Chen, Andrew I. Cooper, Berend Smit
We introduce a representation for the geometric features of the pores of porous molecular crystals. This representation provides a good basis for supervised (predict adsorption properties) and unsupervised (polymorph classification) tasks.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Determination of protein-ligand binding modes using fast multi-dimensional NMR with hyperpolarization

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC00266F, Edge Article
Open Access
Yunyi Wang, Jihyun Kim, Christian Hilty
Elucidation of small molecule-protein interactions provides essential information for understanding biological processes such as cellular signaling, as well as for rational drug development. Here, multi-dimensional NMR with sensitivity enhancement by...
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Regioselective Molybdenum-catalyzed allylic substitution of tertiary allylic electrophiles: methodology development and applications

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01763A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Muhammad Salman, Yaoyao Xu, Shahid Khan, Junjie Zhang, Ajmal Khan
The first molybdenum-catalyzed allylic sulfonylation of tertiary allylic electrophile is described. The method utilizes a readily accesable catalyst (Mo(CO)6/2,2'-bipyridine, both are commercially available) and represent the first example of the...
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Direct and quantitative monitoring of catalytic organic reactions under heterogeneous conditions using direct analysis in real time mass spectrometry

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00021C, Edge Article
Open Access
Koichiro Masuda, Shū Kobayashi
A direct and quantitative method for monitoring heterogeneous organic reactions has been developed by using direct analysis in real time mass spectrometry (DART-MS) with an isotope-labeled reaction product as an internal standard.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




it

Cancer cell discrimination and dynamic viability monitoring through wash-free bioimaging using AIEgens

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01213K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ruoyao Zhang, Guangle Niu, Qing Lu, Xiaolin Huang, Joe H. C. Chau, Ryan T. K. Kwok, Xiaoqiang Yu, Min-Hui Li, Jacky W. Y. Lam, Ben Zhong Tang
We present a series of AIEgens for cancer cell discrimination and dynamic viability monitoring.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




it

The Role of Porphyrin Peripheral Substituents in Determining the Reactivities of Ferrous Nitrosyl Species

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01625J, Edge Article
Open Access
Sk Amanullah, Abhishek Dey
Ferrous nitrosyl {FeNO}7 species are intermediates common to the catalytic cycles of Cd1NiR and CcNiR, two heme-based nitrite reductases (NiR), and its reactivity vary dramatically in these enzymes. The former...
The content of this RSS Feed (c) The Royal Society of Chemistry




it

It's not the right stage to put differential premium on banks: Finance Secy

Finance minister had announced hiking the deposit insurance limit to Rs 5 lakh for each bank depositor




it

YES Bank okays board reconstitution; Prashant Kumar to be new MD & CEO

The other board members will be Sunil Mehta, former non-executive chairman of Punjab National Bank, as the non executive chairman of YES Bank




it

Now, write letters & send cards to Covid warriors

Writing letters may have become a passé, but thanks to the initiative of Patna postal division, many city residents are now thanking corona warriors by sending them personal handwritten letters or greeting cards.




it

Monitor kitchens at quarantine centres: Bihar CM

CM Nitish Kumar on Friday asked chief secretary Deepak Kumar to increase the number of kitchens proportionate to people staying at each quarantine centre so that they could get quality meals on time.




it

Bihar man held, stolen gold biscuits seized

Police arrested one Mohan Kumar (30) from Shivaji Nagar Bagicha under the Digha police station area in Patna on Friday and recovered stolen gold biscuits, jewellery and cash worth around Rs 20 lakh from his possession.




it

Is it possible to enter an IPO bid below floor price?

Floor price is the minimum price at which bids can be made for offer.




it

What is ASBA with respect to IPOs?

As of April 1, 2019, there were 66 SCSBs such as HDFC Bank, SBI, ICICI Bank, PNB, Kotak Mahindra Bank, SBI and Axis Bank, among others, which are recognised as being capable of providing ASBA services to customers.




it

Japan IPO cancellations hit record this month on coronavirus

Investors who had planned to buy new offerings might opt for existing start-up shares instead.




it

Sebi extends regulatory approval validity for IPO, rights issue by 6 months

Sebi's observation is necessary for any company to launch public issues.




it

Preschool in three cultures revisited : China, Japan, and the United States / Joseph Tobin, Yeh Hsueh, and Mayumi Karasawa

Tobin, Joseph Jay




it

Photosensitive students and digital media : a survey of educators regarding knowledge and self efficacy / Janene Sproul

Sproul, Janene, author




it

Academic culture : a student's guide to studying at university / Jean Brick, Maria Herke, Deanna Wong ; editor: Laura Davies

Brick, Jean, author




it

International guide to student achievement / edited by John Hattie, Eric M. Anderman




it

Interim report : first steps for improving educational opportunities for Aboriginal and Torres Strait Islander students / House of Representatives Standing Committee on Indigenous Affairs

Australia. Parliament. House of Representatives. Standing Committee on Indigenous Affairs, author, issuing body




it

Educating for sustainability / Energy Action Australia

Energy Action Australia




it

Creating environments for learning : birth to age eight / Julie Bullard, University of Montana Western

Bullard, Julie, author




it

Researching higher education : international perspectives on theory, policy and practice / edited by Jennifer M. Case and Jeroen Huisman




it

The Humboldtian tradition : origins and legacies / edited by Peter Josephson, Thomas Karlsohn, Johan Östling




it

The value of international education to Australia / prepared by Deloitte Access Economics

Deloitte Access Economics




it

Understanding the University : institution, idea, possibilities / Ronald Barnett

Barnett, Ronald, 1947- author