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Efficient CO2 electroreduction to CO at low overpotentials using a surface-reconstructed and N-coordinated Zn electrocatalyst

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Dalton Trans., 2020, 49,5434-5439
DOI: 10.1039/D0DT00800A, Communication
Wanan Deng, Shixiong Min, Fang Wang, Zhengguo Zhang, Chao Kong
A surface-reconstructed and N-coordinated Zn electrocatalyst exhibits enhanced activity and selectivity for CO2 electroreduction to CO at reduced overpotentials.
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Coordination chemistry of [Y(pypa)]− and comparison immuno-PET imaging of [44Sc]Sc- and [86Y]Y-pypa-phenyl-TRC105

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Dalton Trans., 2020, 49,5547-5562
DOI: 10.1039/D0DT00437E, Paper
Lily Li, María de Guadalupe Jaraquemada-Peláez, Eduardo Aluicio-Sarduy, Xiaozhu Wang, Todd E. Barnhart, Weibo Cai, Valery Radchenko, Paul Schaffer, Jonathan W. Engle, Chris Orvig
H4pypa was conjugated to an antibody via a newly synthesized H4pypa-phenyl-NCS; promising immuno-PET imaging with 44Sc was demonstrated.
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Trinuclear Mn2+/Zn2+ based microporous coordination polymers as efficient catalysts for ipso-hydroxylation of boronic acids

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Dalton Trans., 2020, 49,5454-5462
DOI: 10.1039/D0DT00794C, Paper
Sanchay J. Bora, Rima Paul, Anurag Dutta, Shyam Goswami, Ankur K. Guha, Ashim J. Thakur
Two efficient catalysts based on trinuclear Mn(II)/Zn(II) clusters were synthesized and used for ipso-hydroxylation of phenylboronic acids into the corresponding phenols with excellent yields.
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Hollow-structure engineering of a silicon–carbon anode for ultra-stable lithium-ion batteries

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Dalton Trans., 2020, 49,5669-5676
DOI: 10.1039/D0DT00566E, Paper
Hongbin Liu, Yun Chen, Bo Jiang, Yue Zhao, Xiaolin Guo, Tingli Ma
Hollow silicon nanotubes were successfully synthesized in situ on a carbon substrate, which effectively accommodate the volume expansion of silicon and exhibit ultra-stable performance as the anode of lithium-ion batteries.
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Time-resolved infra-red spectroscopy reveals competitive water and dinitrogen coordination to a manganese(I) carbonyl complex

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Dalton Trans., 2020, 49,5463-5470
DOI: 10.1039/C9DT04878B, Paper
Jonathan B. Eastwood, L. Anders Hammarback, Matthew T. McRobie, Ian P. Clark, Michael Towrie, Ian. J. S. Fairlamb, Jason M. Lynam
Photolysis of [Mn(C^N)(CO)4] (C^N = bis-(4-methoxyphenyl)methanimine) in heptane solution results in ultra-fast CO dissociation and ultimate formation of a rare Mn-containing dinitrogen complex fac-[Mn(C^N)(CO)3(N2)].
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Templated syntheses of heterometal tungsten–cobalt–sulfur clusters with different nuclearities

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Dalton Trans., 2020, 49,5523-5530
DOI: 10.1039/D0DT00765J, Paper
Jia-Ting Guo, Xu-Dong Chen
A series of heterometal tungsten–cobalt–sulfur clusters with different nuclearities have been synthesized rationally using a chelating template.
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Chemoselective oxidative addition of vinyl sulfones mediated by palladium complexes bearing picolyl-N-heterocyclic carbene ligands.

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Dalton Trans., 2020, 49,5684-5694
DOI: 10.1039/D0DT01144D, Paper
Thomas Scattolin, Claudio Santo, Nicola Demitri, Luciano Canovese, Fabiano Visentin
We have examined in depth the features of oxidative addition of (E)-1,2 ditosylethene on palladium(0) complexes bearing picolyl-N-heterocyclic carbenes.
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Efficient removal of methyl orange by a flower-like TiO2/MIL-101(Cr) composite nanomaterial

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Dalton Trans., 2020, 49,5722-5729
DOI: 10.1039/D0DT00778A, Paper
Wan Wu, Tiantian Yao, Ye Xiang, Hao Zou, Yi Zhou
Nano-scale MOF composite materials prepared by combining inorganic semiconductors with controllable pore structures and functional active sites for the effective removal of organic dyes will exhibit more excellent adsorption activity.
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A bimetallic MOF@graphene oxide composite as an efficient bifunctional oxygen electrocatalyst for rechargeable Zn–air batteries

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Dalton Trans., 2020, 49,5730-5735
DOI: 10.1039/D0DT00976H, Paper
Yao Xiao, Beibei Guo, Jing Zhang, Chun Hu, Ruguang Ma, Deyi Wang, Jiacheng Wang
A bimetallic ZnCo-ZIF@graphene oxide (ZnCo-ZIF@GO) composite was synthesized via an in situ growth strategy. As the air cathode of Zn–air batteries, ZnCo-ZIF@GO showed good charge/discharge performance and long-term stability.
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Two amino acid-templated metal phosphates: surfactant-thermal synthesis, water stability, and proton conduction

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Dalton Trans., 2020, 49,5440-5444
DOI: 10.1039/D0DT00966K, Communication
Lijuan Huang, Lei Wang, Yan Zhao, Ling Huang, Jian Bi, Guohong Zou, Zhien Lin, Daojiang Gao
An amino acid-templated gallium phosphate with a zeolitic topology has been prepared under surfactant-thermal conditions and it shows exceptional water stability and interesting proton-conducting properties.
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Two novel lead-based coordination polymers for luminescence sensing of anions, cations and small organic molecules

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Dalton Trans., 2020, 49,5695-5702
DOI: 10.1039/D0DT00533A, Paper
Xue-Yan Zhao, Bing Liang, Ke-Cai Xiong, Yu-Wen Shi, Si-Lei Yang, Ting-Yu Wei, Hui Zhang, Qing-Fu Zhang, Yan-Li Gai
A novel lead-based compound is reported as a multi-responsive luminescent sensor for detecting anions, cations and small organic molecules, especially Cr2O72−, CrO42−, Fe3+ and nitrobenzene.
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Photo-reduction enables catalyst regeneration in Fenton reaction on an Fe2O3-decorated TiO2 nanotube-based photocatalyst

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00670J, Paper
Quanming Peng, Guiming Peng, Liangpeng Wu, Yaqian Chen, Bin Han, Qiucheng Su, Shijun Liu, Xinjun Li
Active Fe2+ sites of TNT(Pd)/Fe2O3 with a unique electronic structure for the Fenton reaction can be self-generated.
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A novel self-assembled-derived 1D MnO2@Co3O4 composite as a high-performance Li-ion storage anode material

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00980F, Paper
Zongtang Li, Xiao Lian, Mingzai Wu, Fangcai Zheng, Yuanhao Gao, Helin Niu
Manganese dioxide (MnO2) is a high-performance anodic material and applied widely in lithium-ion batteries (LIBs).
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Comment on “Investigation on the structure and thermoelectric properties of CuxTe binary compounds” by Shriparna Mukherjee et al., Dalton Trans., 2019, 48, 1040

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Dalton Trans., 2020, 49,5736-5737
DOI: 10.1039/C9DT03607E, Comment
Aarón H. Barajas-Aguilar, A. M. Garay-Tapia, Sergio J. Jiménez-Sandoval
Copper telluride sensitivity to laser power: effect on the Raman spectra.
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Reply to the ‘Comment on “Investigation on the structure and thermoelectric properties of CuxTe binary compounds”’ by A. H. Barajas-Aguilar, A. M. Garay-Tapia, and S. J. Jiménez-Sandoval, Dalton Trans., 2020, 49, DOI: 10.1039/C9DT03607E

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Dalton Trans., 2020, 49,5738-5740
DOI: 10.1039/D0DT00412J, Comment
Shriparna Mukherjee, Raju Chetty, P. V. Prakash Madduri, Ajaya K. Nayak, Krzysztof Wojciechowski, Tanmoy Ghosh, Kamanio Chattopadhyay, Satyam Suwas, Ramesh Chandra Mallik
In a communication to Dalton Transaction and in a paper in Journal of Physics: Condensed Matter, Aarón H. Barajas-Aguilar et al. have raised comments on our paper published earlier in Dalton Transactions.
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NHC–Au(I) complexes bearing trispyrazolyl borate (Tp) ligands: efficient platforms for bimetallic species

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00908C, Paper
Carlos Ángel-Jijón, David Rendón-Nava, Jose M. Vazques-Pérez, Alejandro Álvarez-Hernández, Daniel Mendoza-Espinosa, Verónica Salazar-Pereda
Treatment of NHC–AuCl (NHC = IPr and IMes) complexes with equimolar amounts of KTpR2 (R = Me, H) salts in tetrahydrofuran produces in high yields the heteroleptic complexes 3–6 with the general formula NHC–Au–TpR2.
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Retraction: Determination of chemical affinity of graphene oxide nanosheets with radionuclides investigated by macroscopic, spectroscopic and modeling techniques

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Dalton Trans., 2020, 49,5741-5741
DOI: 10.1039/D0DT90074E, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Congcong Ding, Wencai Cheng, Yubing Sun, Xiangke Wang
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Retraction: Enhanced adsorption of Eu(III) on mesoporous Al2O3/expanded graphite composites investigated by macroscopic and microscopic techniques

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Dalton Trans., 2020, 49,5742-5742
DOI: 10.1039/D0DT90075C, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yubing Sun, Changlun Chen, Xiaoli Tan, Dadong Shao, Jiaxing Li, Guixia Zhao, Shubin Yang, Qi Wang, Xiangke Wang
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Enhancing the energy barrier by replacing the counterions in two holmium(III)-pentagonal bipyramidal single-ion magnets

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00905A, Paper
Lei-Lei Li, Hong-Dan Su, Shuang Liu, Wen-Zhen Wang
Upon changing the employed halide ions as counterions, Ueff increases from 290 K to 320 K in two HoIII-SIMs with pentagonal-bipyramidal structures.
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Pyridylamido hafnium complexes with a silylene bridge: synthesis and olefin polymerization

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01031F, Paper
Pavel S. Kulyabin, Dmitry V. Uborsky, Alexander Z. Voskoboynikov, Jo Ann M. Canich, John R. Hagadorn
Pyridylamido hafnium complexes with a silylene bridge were synthesized, characterized with X-ray crystal structure analysis and shown to polymerize 1-hexene and propene and copolymerize ethylene and 1-octene.
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Structural design of cubic Sr,V:CeFeO3 thin films with a strong magneto-optical effect and high compatibility with a Si substrate

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/C9DT04837E, Paper
Nanxi Lin, Shengnan Zhang, Haixin Chen, Yunjin Chen, Xin Chen, Yongfan Zhang, Xiaolin Hu, Naifeng Zhuang
Orthorhombic CeFeO3 is optimized to be cubic perovskite with high compatibility with Si substrate by introducing Sr, V ions into lattice. Cubic Sr,V:CeFeO3 film exhibit strong magneto-optical effect due to spin-coupling hybrid of Ce 4f with Fe/V 3d.
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Theoretical rationalization for the equilibrium between (μ–η2:η2-peroxido)CuIICuII and bis(μ-oxido)CuIIICuIII complexes: perturbational effects from ligand frameworks

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01001D, Paper
Tsukasa Abe, Yoshihito Shiota, Shinobu Itoh, Kazunari Yoshizawa
DFT calculations are carried out to investigate the geometric effects of the supporting ligands in the relative energies of the (μ–η2:η2-peroxido)CuIICuII complex 1 and the bis(μ-oxido)CuIIICuIII complex 2.
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Structure and magnetic properties of a novel heteroheptanuclear metal string complex [Ni3Ru2Ni2(μ7-teptra)4(NCS)2](PF6)

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00156B, Paper
Cheng-Chang Chiu, Ming-Chuan Cheng, Sheng-Hsiang Lin, Cheng-Wei Yan, Gene-Hsiang Lee, Mu-Chieh Chang, Tien-Sung Lin, Shie-Ming Peng
A novel heteroheptanuclear metal string complex was synthesized by using nickel and ruthenium metal ions to explore the electronic structure and magnetic property.
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Synthesis and characterisation of light lanthanide bis-phospholyl borohydride complexes

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01241F, Paper
Jingjing Liu, Lydia E. Nodaraki, Philip J. Cobb, Marcus J. Giansiracusa, Fabrizio Ortu, Floriana Tuna, David P. Mills
Two families of lanthanide(III) phospholyl borohydride complexes are reported (carbon = grey, hydrogen = white, oxygen = red, boron = yellow, phosphorus = magenta, potassium = blue, lanthanides = teal; only BH4 hydrogens are shown for clarity).
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Conductivity and mixed conductivity of a novel dense diffusion barrier and the sensing properties of limiting current oxygen sensors

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00496K, Paper
Ke Shan, Zhong-Zhou Yi, Xi-Tao Yin, Davoud Dastan, Hamid Garmestani
First-principles calculations were used to explore the effect of various Y-doping levels on the electrical conductivity of SrTiO3.
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Facile synthesis of Mn-doped NiCo2O4 nanoparticles with enhanced electrochemical performance for a battery-type supercapacitor electrode

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01177K, Paper
To Van Nguyen, Le The Son, Vu Van Thuy, Vu Dinh Thao, Masahito Hatsukano, Koichi Higashimine, Shinya Maenosono, Sang-Eun Chun, Tran Viet Thu
We report the synthesis of manganese-doped nickel cobalt oxide (Mn-doped NiCo2O4) nanoparticles (NPs) by an efficient hydrothermal and subsequent calcination route.
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Self-assembled gold nanoparticles and amphiphile peptides: a colorimetric probe for copper(II) ion detection

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00844C, Paper
Juliane N. B. D. Pelin, Charlotte J. C. Edwards-Gayle, Herculano Martinho, Barbara B. Gerbelli, Valeria Castelletto, Ian W. Hamley, Wendel A. Alves
We show that arginine/phenylalanine based peptides can be used to control the aggregation of gold nanoparticles in different ways. The arrangement provides a colorimetric approach to detect Cu2+ ions in water.
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Highly covalent metal–ligand π bonding in chelated bis- and tris(iminoxolene) complexes of osmium and ruthenium

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01287D, Paper
Jacqueline Gianino, Seth N. Brown
Describing the π bonding in ruthenium and osmium iminoxolenes as highly covalent allows one to experimentally dissect the electron distribution in these compounds.
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Copolymerization of CHO/CO2 catalyzed by a series of aluminum amino-phenolate complexes and insights into structure–activity relationships

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00726A, Paper
Hart Plommer, Laura Stein, Jennifer N. Murphy, Nduka Ikpo, Nelaine Mora-Diez, Francesca M. Kerton
Five aluminum catalysts demonstrated different selectivity and activity during reactions of carbon dioxide and epoxides.
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Self-assembly of mixed-valent and heterometallic metallocycles: efficient catalyst for oxidation of alcohols to aldehydes with ambient air

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01340D, Communication
Ya-Liang Lai, Xue-Zhi Wang, Rui-Rong Dai, Yong-Liang Huang, Xian-Chao Zhou, Xiao-Ping Zhou, Dan Li
Two mixed-valent CuII/CuI and two heterometallic CuII/AgI metallocycles have been synthesized by the assembly of designed metalloligands and CuI/AgI ions, respectively. The CuII/CuI metallocycle can catalyze oxidation of alcohols to...
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Water-locking molecule-assisted fabrication of natural-inspired Mg(OH)2 for high-efficient and economical uranium capture

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00618A, Paper
Hengbin Xu, Zhenyuan Bai, Milin Zhang, Jun Wang, Yongde Yan, Min Qiu, Jiaming Chen
With the depletion of uranium terrestrial deposits, researchers have focused on the development of adsorbents to extract radioactive uranium from seawater/wastewater. However, there are still considerable challenges to manipulate this...
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Modulation of the driving forces for adsorption on MIL-101 analogues by decoration with sulfonic acid functional groups: superior selective adsorption of hazardous anionic dyes

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00978D, Paper
Ji-Min Yang, Wei Zhang, Run-Zhi Zhang, Meng-Xuan Tong
MIL-101-SO3H analogues functionalized with –SO3H groups exhibited superior CR, MO and AC adsorption capacities because of their distinct adsorption mechanisms.
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Structural, spectroscopic and electronic properties of a family of bi-octahedral Ru25+/6+ complexes with a bridging 2,5-di(2-pyridyl)pyrrolide ligand

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01325K, Paper
Shi-Rui Kang, Qin Zi Zhou, Chang-Fang Xiong, Bin Liu, John E. McGrady, Mohammed Obies, Chao Liu, Piao He, Xiao-Yi Yi
A family of Ru2 dimers, [Ru2(μ-κ2N,N’:κ2N’,N’’-dpp)2(μ-X)(X)2]q+ (X = Cl, Br, q = 0 and X = I, q = 1) is synthesized from a [Ru2(OAc)4Cl] paddlewheel starting material. The neutral...
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An ultra-effective pathway for fully removing the oxygen components of graphene oxide by a flame-assisted microwave process

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01483D, Communication
Xuefeng Zou, Qin Hu, Hengxiu Yang, Feng Chen, Bin Xiang, Xinyue Liang, Qibing Wu, Hujun Shen
Here we report an ultra-effective, reliable pathway to reduce GO into graphene by an about 4-seconds flame-assisted microwave process. A holey graphene with a C/O atom ratio of 31.1, a...
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Temperature-dependent hysteretic two-step spin crossover in two-dimensional Hofmann-type compounds

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00866D, Paper
Jun Tao, Yue Li, Min Liu, Zi-Shuo Yao
Hofmann-type spin-crossover (SCO) frameworks attract much attention due to their predictable structures and diverse SCO behaviours. In this paper, we report two isostructural two-dimensional (2D) Hofmann-type SCO frameworks [FeII(ppe)2MII(CN)4]·3H2O (ppe...
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Color Tuning in Ca3-xMx(PO4)2: Eu2+ (M = Sr, Ba) Phosphors via Cation Substitution

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01130D, Paper
Huiling Zhang, Dengwen Yuan, Xiaoyun Mi, Xiuling Liu, Jun Lin
A series of Ca3-xMx(PO4)2: Eu2+ (M = Sr, Ba) phosphors were prepared via high-temperature solid-state reaction process. The X-ray diffraction and Rietveld refinements were used to verify the incorporations of...
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Multicolor tunable luminescence and energy transfer of core-shell structured SiO2@Gd2O3 microspheres co-activated with Dy3+/Eu3+ under single UV excitation

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00735H, Paper
Jie Chen, Yixin Gao, Haifeng Jiang, Yan Liu, Zhaohui Jin
Optimizing structure and varing doped ions are two main strategies to obtain excellent luminescence performance. Spherical morphology is considered to be the most ideal phosphor structure due to the least...
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Influence of Eu valence in the optical activity of BaTiO3 decorated with CaF2 synthesized by microwave-assisted hydrothermal method

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01321H, Paper
Tatiane Strelow Lilge, Adriano Borges Andrade, Claudiane dos Santos Bezerra, Giordano Frederico da Cunha Bispo, Zélia Soares Macedo, Mario Lucio Lúcio Moreira, Mário Ernesto Giroldo Valerio
Inorganic hybrid materials are promising applications in absorbers and photon harvesting of solar irradiation, such as DSSC cell photoanodes. Moreover, the investigation of the interaction between the photoanode constituent materials...
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Luminescent organic dyes containing a phenanthro[9,10-D]imidazole core and [Ir(N^C)(N^N)]+ complexes based on the cyclometalating and diimine ligands of this type

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00568A, Paper
Anastasia I. Solomatina, Kirill M. Kuznetsov, Vladislav V. Gurzhiy, Vladimir V. Pavlovskiy, Vitaly V. Porsev, Robert A. Evarestov, Sergey P. Tunik
New N^N and N^C luminescent ligands with solvatochromic behavior and their iridium complexes were synthesized, characterized and investigated.
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MnO2 flowery nanocomposites for efficient and fast removal of mercury(II) from aqueous solution: a facile strategy and mechanistic interpretation

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01054E, Paper
Sankar Das, Arnab Samanta, Kanika Kole, Gautam Gangopadhyay, Subhra Jana
MnO2 flowery nanocomposites were explored as a novel and cost effective nanoadsorbent for the fast and efficient extraction of toxic inorganic contaminants from aqueous solution.
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Three diphosphates, α-Li2Na2P2O7, Li8Pb3Ba(P2O7)4 and Li7Rb(P2O7)2: influences of co-substitution on the crystal structure

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01070G, Paper
Ming Wen, Cong Hu, Hongping Wu, Zhihua Yang, Xiaohong Wu, Shilie Pan
We reported the synthesis, structure, characterization and first-principles calculations of diphosphates, α-Li2Na2P2O7, Li8Pb3Ba(P2O7)4 and Li7Rb(P2O7)2, and studied the influences of co-substitution on the crystal structure.
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Influence of magnetic dilution on relaxation processes in a solid solution comprising tetrahedral Co/ZnII complexes

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01058H, Paper
Magdalena Ceglarska, Olaf Stefańczyk, Shin-ichi Ohkoshi, Anna M. Majcher-Fitas
Dilution with diamagnetic species in a SIM solid solution leads to an increase in relaxation times at low temperatures and monotonously reduces the probability of quantum tunneling of magnetization and the direct process.
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Recent advances in coordination-driven polymeric gel materials: design and applications

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00863J, Frontier
Papri Sutar, Tapas Kumar Maji
In this article, we reviewed recent advances in coordination-driven polymeric gels and highlighted their design and applications in various fields.
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Effects of ligand substituents on the single-molecule magnetic behavior of quinonoid-bridged dicobalt compounds

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00033G, Paper
Xiao-Quan Zhu, Wen-Hai Cao, Shao-Dong Su, Xin-Tao Wu, Tian-Lu Sheng
The SMM behavior weakens until its disappearance with the substituent changing from Br, H to OMe in the quinonoid-bridged dicobalt compounds [(N4Co)2LX](ClO4)2, (X = H, Cl, Br, and OMe).
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Metal–metal bond formation of triplatinum cores with a silver(I) ion affording a heptanuclear cluster bearing four Pt–Ag bonds

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01227K, Communication
Natsuki Yabune, Hiroshi Nakajima, Takanori Nishioka
A triplatinum complex with chelating NHC ligands reacts with Ag(I) and affords a heptanuclear cluster bearing four Ag–Pt bonds.
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Selenotungstates incorporating organophosphonate ligands and metal ions: synthesis, characterization, magnetism and catalytic efficiency in Knoevenagel condensation reaction

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00444H, Paper
Jingyang Niu, Hui Kong, Peipei He, Zongfei Yang, Qiaofei Xu, Jiawei Wang, Ran Ban, Pengtao Ma, Jingping Wang
Three sandwich-type TM-containing (TM = transition metal) organophosphonate-based polyoxotungstate clusters, [TM(H2O)4(SeW6O21)2{Co(OOCCH2NCH2PO3)2}3]12– (TM = Co, Ni), have been successfully synthesized, which is the first reported TMs-containing organophosphonate-based selenotungstates. They were structurally...
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Luminescent lanthanide complexes with a pyridine-bis(carboxamide)-bithiophene sensitizer showing wavelength-dependent singlet oxygen generation

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01034K, Paper
Katherine R. Johnson, Sebastian B. Vittardi, Manuel A. Gracia-Nava, Jeffrey J. Rack, Ana de Bettencourt-Dias
A new pyridine-bis(carboxamide)-based ligand with a bithiophene pendant, 2Tcbx, was synthesized.
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Amorphous Co-doped MoSex Effectively Enhances Photocatalysis in Visible Light

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01295E, Paper
Rui Feng, Rong Wu, Yuncheng Cao, Xiaolin Guo, Xu Ma
Molybdenum selenide has great potential for degradation of water pollutants，but its performance is limited by the active sites and recombination of photogenerated electron-hole pairs. In this study, amorphous Co-doped MoSex...
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Tin based organic-inorganic hybrid semiconductors with reversible phase transition and dielectric anomaly

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01401J, Paper
Zhenhong Wei, Xiuli You, Jiaojiao Yao
Organic−inorganic hybrid materials with perovskite structure have recently attracted tremendous interest due to their structural tunability and rich functional properties, such as phase transition and photoelectric properties. Within this context,...
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Double addition of phenylacetylene onto the mixed bridge phosphinito–phosphanido Pt(I) complex [(PHCy2)Pt(μ-PCy2){κ2P,O-μ-P(O)Cy2}Pt(PHCy2)](Pt–Pt)

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00923G, Paper
Stefano Todisco, Mario Latronico, Vito Gallo, Nazzareno Re, Alessandro Marrone, Iogann Tolbatov, Piero Mastrorilli
Double addition of phenylacetylene onto the Pt(I)–Pt(I) complex [(PHCy2)Pt(μ-PCy2){κ2P,O-μ-P(O)Cy2}Pt(PHCy2)] (Pt–Pt) affords the η1-alkenyl-μ,η1:η2-alkynyl complex [(η1-trans-(Ph)HCCH)(PHCy2)Pt(μ-PCy2)(μ,η1:η2-PhCC)Pt{κP-P(O)Cy2}(PHCy2)].
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