s Nickel-catalyzed reductive 1,2-alkylarylation of alkenes via a 1,5-hydrogen atom transfer (HAT) cascade By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01875C, Research ArticleXi Chen, Qiang Wang, Xiao-Ping Gong, Rui-Qiang Jiao, Xue-Yuan Liu, Yong-Min LiangA nickel-catalyzed 1,2-alkylarylation of alkenes has been developed, leveraging amidyl radical-triggered 1,5-HAT with electrophiles as functionalizing reagents.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
s Iridium-catalyzed asymmetric cascade allylation/lactonization of methyl salicylates: enantioselective construction of chiral benzodioxepinones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01771D, Research ArticleBendu Pan, Yunru Wu, Yaqi Zhang, Xiaobo He, Long Jiang, Liqin QiuAn efficient asymmetric cascade allylation/lactonization of methyl salicylates is achieved. The utilization of chiral-bridged biphenyl phosphoramidite ligand resulted in good results for the construction of a wide range of chiral benzodioxepinones.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
s Stereocontrolled synthesis of heterocycles from unactivated alkynes by photoredox/nickel dual-catalyzed cyclization By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01627K, Research ArticleBo-Rong Leng, Feng Yang, Jin-Lian Bai, Yu-Wen Huang, Qing-Quan Liu, Ping Wei, De-Cai Wang, Yi-Long ZhuWe report a nickel/photoredox dual catalysis method for synthesizing heterocyclics from unactivated alkynes and aryl iodides, offering a direct, selective, and green alternative to traditional synthesis with potential in medicinal chemistry.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
s Integrating electrocatalysis with biocatalysis for asymmetric synthesis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01899K, HighlightYuqi Lin, Jiage Yu, Ke-Yin YeThis highlight presents recent advances in asymmetric synthesis that integrate electrocatalysis with biocatalysis and discusses future development directions in this field.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
s Probing Intersystem Crossing in Multi-brominated Eumelanin through Transient Absorption and Surface Hopping Dynamics By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01832J, Research Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kavya Vinod, Lukhmanul Hakeem K., Diana Thomas, Pallavi Panthakkal Das, Mahesh HariharanAchieving intersystem crossing (ISC) through structural tuning in biological systems is an evolving area for therapeutic and materials research. Eumelanin, a natural pigment, offers huge potential for bio-inspired material design,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
s Magic effect of diphenylprolinol silyl ether for the enantioselective allenation of 2-alkynals By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00984C, Research ArticleGuolin Wu, Zhen Liu, Shiwen Fan, Wenyao Li, Xue Zhang, Hui Qian, Shengming MaChiral diphenylprolinol silyl ethers have been successfully identified for the enantioselective allenation reaction of terminal alkynes and 2-alkynals, delivering a diverse set of chiral allenynes with high efficiency.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
s Visible-light responsive defluorination-acyl fluoride exchange for photoclick labeling based on phenoxazine chromophores By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01870B, Research ArticleLijun Deng, Sitong Li, Cefei Zhang, Yuqiao Zhou, Zhishan Su, Changwei Hu, Xiaohu Zhao, Zhipeng YuWe developed a new generation of photo-DAFEx reagents to realize photoaffinity labeling for drug discovery under 405 nm light control.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
s Metal–ligand cooperation and synergistic palladium catalysis for the dual ligand system [2,2'-bipyridin]-6(1H)–one/PCy3: milder conditions for the undirected C–H arylation of arenes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01877J, Research Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Cintya Pinilla, Mario García-Zarza, Ana C. AlbénizThe mixture of Pd(OAc)2 and two ligands segregate into distinct active species working synergistically for the C–H arylation of simple arenes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
s Palladium-catalyzed cascade decarboxylative cyclization of alkyne-tethered aryl iodides with o-bromobenzoic acids for the synthesis of fused isoquinolinones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01573H, Research ArticleZhaolin Quan, Yubo Duan, Zhengkai ChenA straightforward approach for the preparation of fused isoquinolinone derivatives via palladium-catalyzed cascade decarboxylative cyclization of alkyne-tethered aryl iodides with o-bromobenzoic acids is described.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
s Mechanism and origins of regioselectivity of selenium-catalyzed allylic amination reactions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01794C, Research ArticleXiaoxiao Hu, Dengmengfei Xiao, Yu Chen, Yi Lu, Zhihan Zhang, Peiyuan YuThe mechanism of selenium-catalyzed allylic amination reactions with different ligands has been explored using density functional theory calculations.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
s Synthesis of oxa-bridged carbocycles via rhodium/Lewis acid catalyzed [3 + 3] and [4 + 3] cycloadditions of carbonyl ylides with donor–acceptor strained carbocycles By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01831A, Research ArticleJiale Li, Lingfei Wang, Pei-Nian Liu, Xingguang LiA method for cooperative rhodium/Lewis acid-catalyzed cycloadditions of carbonyl ylides with donor–acceptor (D–A) strained carbocycles is described. It affords structurally diverse oxa-bridged carbocycles with high efficiency and stereoselectivity.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
s Transition-metal-free skeletal editing of benzoisothiazol-3-ones to 2,3-dihydrobenzothiazin-4-ones via single-carbon insertion By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01714E, Research ArticleKe Yang, Qin Li, Yanqi Luo, Dan Yuan, Chunjian Qi, Zhengyi Li, Bijin Li, Xiaoqiang SunTransition-metal-free ring expansion of benzoisothiazol-3-ones has been established to construct various 2,3-dihydrobenzothiazin-4-ones via single-carbon insertion.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
s Rh-Catalysed Hydroacyloxylation of Cyclopropenes: Regio- and Diastereoselective Synthesis of Acyloxycyclopropanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01810A, Research ArticleÁngel Manu Martínez, Gema Domínguez, Ines Alonso, Marta Palaín, Javier Perez-CastellsCyclopropyl carboxylates are essential building blocks in biological and medicinal chemistry. However, their accessibility is severely limited by the need to pre-synthesise highly reactive cyclopropane derivatives. Herein, we report an...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
s PIFA-Mediated cyclization of methyl(2-(1-phenylvinyl)phenyl)sulfane for the concise, flexible, and scalable de novo synthesis of C3-arylated benzo[b]thiophenes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01589D, Research ArticleXinya Liu, Olivier Provot, Christine Tran, Jean-Francois Soule, Abdallah HamzeThe well-decorated arylated benzo[b]thiophene scaffold is a pivotal structural motif with diverse applications in medicinal chemistry. This paper outlines a de novo synthesis of C3-arylated benzo[b]thiophenes, showcasing its flexibility and...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
s Influence of hydrogen bonds and π-π stacking on the self-assembly of aryldipyrrolidones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01577K, Research Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Pedro Ximenis, Llorenç Rubert, Heike Ehmann, Bartolome SoberatsWe report on the self-assembly behaviour in solution and solid-state of two newly designed bisdendronized aryldipyrrolidones (BDP and NDP) dyes with two free N-H at the lactam positions. Interestingly, while...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
s Modular dehydrogenative cross-nucleophile coupling for direct construction of tetrasubstituted carbons By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01641F, Research ArticlePeng Wang, Qiang Wang, Meng Wang, Liang Wang, Lubin Xu, Xiong-Li Liu, Fangzhi Hu, Shuai-Shuai LiAn FeCl3-catalyzed cross-dehydrogenative coupling reaction for the construction of various types of C–Y (Y = C, N, O, S) bonds with air as a green oxidant.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
s Hemilabile P,N-Ligand-Assisted Gold Catalyzed Hiyama Allylation to Access Allylarenes and 1,4-Dienes Derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01879F, Research ArticleYuanhao He, Wanping Ma, Yu Zhong, Yanfei Hu, Mingou Li, Fen Zhao, Zhonghua Xia, Baomin FanOxidant-free gold-catalyzed reactions are emerging as a novel synthetic tool for organic transformations. Here in, we reported a hemilabile P,N-ligand-assisted gold-catalyzed Hiyama cross coupling reaction of aryl and alkenyl iodides...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
s Convergent Synthetic Approaches to Polycyclic Aromatic Dicarboximides By pubs.rsc.org Published On :: Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01828A, Review ArticleKazutaka Shoyama, Frank WuerthnerPolycyclic aromatic dicarboximides (PADIs) as represented by naphthalene and perylene bis(dicarboximide) are useful molecules for a variety of functional materials and remain important synthetic targets for organic chemists. In this...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
s Rhodium-catalyzed synthesis of N-substituted 3-acylpyrroles from enaminones and vinylene carbonate By pubs.rsc.org Published On :: Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01816H, Research ArticleSheng-Jiao Yan, Jian-Bo Ma, Yi-Mai Yin, Xing-Mei Hu, Bi-Na Shao, Kun Huang, Qing-Sheng ZhaoSkeletal editing is a highly efficient strategy for modifying the core scaffolds of drug molecules, with multi-atomic editing as an emergent approach. Herein, we present a protocol for constructing N-substituted...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
s π-extended regioisomeric dithienoacenes fused pyrenes: structures, properties, and application in field-effect transistors By pubs.rsc.org Published On :: Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01592D, Research ArticleBin Lu, Shiqian Zhang, Dong Liu, Wendong Jin, Dalin Li, Zhiqiang Liu, Tao HeThe development of π-conjugated semiconducting molecules with fused rings has been a focus of research in organic electronics. In this study, optoelectronic and field-effect transistors (FET) properties of two novel...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
s Mechanistic insights into rhodium-catalyzed C−H activation and annulation using vinyl acetate to access cinnolines and cinnolin-4(1H)-ones By pubs.rsc.org Published On :: Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01734J, Research ArticleYuqin Wang, Yiling Zeng, Ya-Nan Tian, Zheng Liu, Jinhua Wang, Shuyou Chen, Shiqing LiTransition metal-catalyzed C−H activation and annulation involving vinyl acetate remains a significant challenge, and the mechanistic process following vinyl insertion is ambiguous. Herein, we report the Rh(III)-catalyzed two-fold C−H activation...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
s Intermolecular Defluorinative 1,2-Diamination of Fluoroalkenyl Iodides with Sulfonamides: Synthesis of Acyclic and Cyclic Fluorinated 1,2-Enediamines By pubs.rsc.org Published On :: Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01913J, Research ArticleXue-Qiang Chu, Yu-Lan Chen, Chi Zhang, Xue-Ying Huang, Yu Ding, Danhua Ge, Zhi-Liang ShenAlkene diamination represents one of the most straightforward strategies for 1,2-diamine derivatives synthesis. However, transition-metal-free 1,2-diamination of fluoroalkenes has been less studied. Here we report an intermolecular defluorinative vicinal diamination...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
s Telangana Cyber Security Bureau conducts digital awareness campaign for senior citizens By www.thehindu.com Published On :: Thu, 07 Nov 2024 11:06:15 +0530 Full Article Telangana
s Telangana CID arrests two involved in pan-India job fraud racket By www.thehindu.com Published On :: Thu, 07 Nov 2024 11:29:31 +0530 Full Article Telangana
s At Via Milano in Hyderabad, the pizza can wait, go for the chops By www.thehindu.com Published On :: Thu, 07 Nov 2024 13:44:23 +0530 Full Article Dining
s Usha Rk on the visual splendour of Adi Shankaracharya’s Ashtakams By www.thehindu.com Published On :: Thu, 07 Nov 2024 16:31:17 +0530 Usha Rk, former director of Jawaharlal Nehru Cultural Center (JNCC) of the Embassy of India in Moscow, shares her vision of bringing Adi Shankaracharya’s Ashtakams to life through a dance form Full Article Entertainment
s Woman arrested after kidnap attempt in Koti Government Maternity Hospital By www.thehindu.com Published On :: Thu, 07 Nov 2024 18:41:29 +0530 The accused was a habitual offender and had made a vain bid on Tuesday night, before being caught by the hospital staff and police on Wednesday Full Article Telangana
s Six awarded life imprisonment for trafficking Bangladeshi girls By www.thehindu.com Published On :: Thu, 07 Nov 2024 18:47:05 +0530 Full Article Telangana
s Cong. govt cheating paddy farmers on procurement: Kishan Reddy By www.thehindu.com Published On :: Thu, 07 Nov 2024 18:50:38 +0530 Full Article Telangana
s Telangana pharmaceutical industries logged 97 major fire accidents in past decade: Fire Services Director-General Y. Nagi Reddy By www.thehindu.com Published On :: Thu, 07 Nov 2024 18:58:18 +0530 The new government would like to decentralise and set up pharma villages, in 10 clusters, Special Chief Secretary Jayesh Ranjan said Full Article Telangana
s Two from Hyderabad, including government employee, lose ₹50 lakh in separate scams By www.thehindu.com Published On :: Thu, 07 Nov 2024 19:01:55 +0530 Full Article Telangana
s Mahabubnagar District Education Officer in ACB net By www.thehindu.com Published On :: Thu, 07 Nov 2024 19:16:55 +0530 Full Article Telangana
s TGSRTC Karimnagar region to operate special buses to Arunachala Hill in Tamil Nadu on November 13 By www.thehindu.com Published On :: Thu, 07 Nov 2024 20:04:23 +0530 Full Article Telangana
s GHMC official sentenced to one-year RI in ACB case By www.thehindu.com Published On :: Thu, 07 Nov 2024 20:18:55 +0530 Full Article Telangana
s Thousands gather for Chhath Puja at Bathukamma ghats By www.thehindu.com Published On :: Thu, 07 Nov 2024 20:22:39 +0530 In addition to Hussainsagar, Chhath Puja is being celebrated at 49 other locations across the twin cities of Hyderabad and Secunderabad. Full Article Hyderabad
s Moneylenders push family to end life, man his daughter die, wife survives By www.thehindu.com Published On :: Thu, 07 Nov 2024 21:07:01 +0530 Head of the family was being harassed and intimidated by two Nizamabad-based moneylenders Full Article Telangana
s ₹4.8 crore loan fraud scheme unearthed at SBI Sanathnagar, eight more arrested By www.thehindu.com Published On :: Thu, 07 Nov 2024 21:26:49 +0530 Full Article Telangana
s HYDRAA created fear among encroachers and big builders and not common people: Telangana CM By www.thehindu.com Published On :: Thu, 07 Nov 2024 21:49:14 +0530 Full Article Telangana
s 75th anniversary of Bharat Scouts and Guides celebrated By www.thehindu.com Published On :: Thu, 07 Nov 2024 22:58:00 +0530 Full Article Hyderabad
s Traffic diversions in Rachakonda from Friday 8 a.m. for CM’s visit to Yadadri-Bhuvanagiri district By www.thehindu.com Published On :: Thu, 07 Nov 2024 23:19:05 +0530 Full Article Telangana
s Nampally court takes cognisance of ED’s prosecution complaint against AgriGold By www.thehindu.com Published On :: Fri, 08 Nov 2024 03:03:10 +0530 Full Article Telangana
s When hope meets hurdles: stark reality of Telangana’s job market By www.thehindu.com Published On :: Fri, 08 Nov 2024 08:17:07 +0530 The State’s job crisis has come back to haunt the Congress party, which rode to power last year on promises of employment. While local youth wait, worry, and exchange dreams about securing government jobs, short-term opportunities are drawing people from other States. This dynamic has transformed Telangana into a job magnet for outsiders but a desert for its own aspirants, reports Serish Nanisetti Full Article Telangana
s Cyberabad | Four arrested for vandalising Gandhi statue By www.thehindu.com Published On :: Fri, 08 Nov 2024 11:42:57 +0530 Full Article Hyderabad
s Mother-daughter duo to showcase Andhra Natyam and Perini Tandavam in Hyderabad By www.thehindu.com Published On :: Fri, 08 Nov 2024 15:20:10 +0530 Duvvuri Vathsalendra redefines tradition by mastering Perini Thandavam and sharing its power on stage with her daughter Abhimanika Full Article Entertainment
s ‘Rahasyam Idham Jagath’ movie review: Earnest but far from engrossing By www.thehindu.com Published On :: Fri, 08 Nov 2024 15:36:40 +0530 Director Komal R Bharadwaj’s Telugu indie ‘Rahasyam Idham Jagath’ is ambitious in using science, technology and stories from the Indian epics for an adventure drama, but falls short in its execution Full Article Movies
s Telangana set to unveil new industrial sectoral policies By www.thehindu.com Published On :: Fri, 08 Nov 2024 16:06:35 +0530 Electric Mobility and Storage, Electronics, Life Sciences, Defence and Aerospace sectors to get new growth guiding documents as some existing policies have become outdated and those in other States are superior, senior official Full Article Telangana
s Owaisi hails Supreme Court ruling on AMU’s minority status By www.thehindu.com Published On :: Fri, 08 Nov 2024 17:12:58 +0530 The Modi government should take this judgement in its stride, says Asad Full Article Telangana
s Congress shedding ‘çrocodile tears’ over BCs welfare: BJP leader Laxman By www.thehindu.com Published On :: Fri, 08 Nov 2024 17:55:32 +0530 Full Article Telangana
s Varni police SI in ACB net By www.thehindu.com Published On :: Fri, 08 Nov 2024 18:00:40 +0530 Full Article Telangana
s Raid on hospitals in Hyderabad and Secunderabad leads to seizure of controlled drugs By www.thehindu.com Published On :: Fri, 08 Nov 2024 18:03:20 +0530 The raiding teams found substances which are are classified as controlled drugs and their sale and possession are strictly regulated under the Narcotic Drugs and Psychotropic Substances (NDPS) Act Full Article Hyderabad
