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Asymmetric Organocatalytic Double 1,6-Addition: Rapid Access to Chiral Chromans with Molecular Complexity

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00354A, Research Article
Indranil Chatterjee, Sourav Roy, Suman Pradhan, Krishan Kumar
An organocatalytic cascade vinylogous double 1,6-addition strategy for the synthesis of chiral chroman derivatives is reported. The cascade reaction follows oxa-Michael/1,6-addition reactions between ortho-hydroxyphenyl-substituted para-quinone methadies and 2,4-dienal derivatives to...
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Organocatalytic 1,5-trifluoromethylthio-sulfonylation of vinylcyclopropane mediated by visible light in the water phase

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00343C, Research Article
Junkai Liu, Hong Yao, Xinnan Li, Hongyu Wu, Aijun Lin, Hequan Yao, Jinyi Xu, Shengtao Xu
1,2-Difunctionalization has developed into a robust tool for the preparation of complex organic molecules, and remote difunctionalization has also aroused widespread interest to achieve pluripotency of difunctionalization.
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Ag2O-catalysed nucleophilic isocyanation: selective formation of less-stable benzylic isonitriles

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00336K, Research Article
Taiga Yurino, Yuji Tange, Ryutaro Tani, Takeshi Ohkuma
Both primary and secondary benzylic isonitriles were exclusively produced by the Ag2O-catalysed reaction of benzylic phosphates and trimethylsilyl cyanide without formation of the thermodynamically favoured regioisomers, benzylic nitriles.
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Hyperforones A–C, benzoyl-migrated [5.3.1]-type polycyclic polyprenylated acylphloroglucinols from Hypericum forrestii

Org. Chem. Front., 2020, 7,1070-1076
DOI: 10.1039/D0QO00152J, Research Article
Wei-Jia Lu, Wen-Jun Xu, Yan-Qiu Zhang, Yi-Ran Li, Xin Zhou, Qi-Ji Li, Hao Zhang, Jun Luo, Ling-Yi Kong
Unprecedented benzoyl-migrated polycyclic polyprenylated acylphloroglucinols with a unique C-1 H-substituted bicyclo[5.3.1]hendecane framework, hyperforones A–C (1–3), were isolated from Hypericum forrestii.
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Discrete boronate ester ladders from the dynamic covalent self-assembly of oligo(phenylene ethynylene) derivatives and phenylenebis(boronic acid)

Org. Chem. Front., 2020, 7,1082-1094
DOI: 10.1039/D0QO00083C, Research Article
Vasileios Drogkaris, Brian H. Northrop
Reversible boronate ester chemistry enables the controlled, dynamic self-assembly of olig(phenylene ethynylene)s into highly conjugated ladder frameworks.
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Topomeric aza/thia cryptands: synthesis and theoretical aspects of in/out isomerism using n-alkyl bridging

Org. Chem. Front., 2020, 7,1164-1176
DOI: 10.1039/D0QO00123F, Research Article
Ian S. Taschner, Tia L. Walker, Sharath Chandra M., Briana R. Schrage, Christopher J. Ziegler, Xinfeng Gao, Steven E. Wheeler
A series of heterobicyclic aza/thia-lactams and cryptands incorporating changes in n-alkyl bridging length have been synthesized, characterized, chelated to heavy metals and computationally assessed.
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The origin of regioselectivity in Cu-catalyzed hydrocarbonylative coupling of alkynes with alkyl halides

Org. Chem. Front., 2020, 7,1137-1148
DOI: 10.1039/D0QO00214C, Research Article
Shengnan Liu, Jianbiao Liu, Qiong Wang, Jin Wang, Fang Huang, Wenjuan Wang, Chuanzhi Sun, Dezhan Chen
Steric interactions mediate a switch between a ketone and allylic alcohol in Cu-catalyzed hydrocarbonylative coupling of alkynes with alkyl halides.
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Rh(III)-Catalyzed switchable C–H functionalization of 2-(1H-pyrazol-1-yl)pyridine with internal alkynes

Org. Chem. Front., 2020, 7,1158-1163
DOI: 10.1039/D0QO00248H, Research Article
Shaonan Wu, Zhuo Wang, Dianxue Ma, Chen Chen, Bolin Zhu
We reported a Rh(III)-catalyzed switchable C–H functionalization of 2-(1H-pyrazol-1-yl)pyridine with internal alkynes, which provided diversiform functionalized N,N-bidentate chelating compounds.
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Tricarabrols A–C, three anti-inflammatory sesquiterpene lactone trimers featuring a methylene-tethered linkage from Carpesium faberi

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00093K, Research Article
Jie Yuan, Xuelan Wen, Chang-Qiang Ke, Tian Zhang, Ligen Lin, Sheng Yao, Jason D. Goodpaster, Chunping Tang, Yang Ye
Three anti-inflammatory trimeric compounds constructed from carabrol-type sesquiterpenoids through a methylene-tethered linkage were characterized from Carpesium faberi.
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An exocyclic π-system extension of the phenanthriporphyrin framework: towards azaaceneporphyrinoids

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00436G, Research Article
Bartosz Szyszko, Damian Dróżdż, Aleksandra Sarwa, Sebastian G. Mucha, Agata Białońska, Michał J. Białek, Katarzyna Matczyszyn, Lechosław Latos-Grażyński
An exocyclic π-extension of phenanthriporphyrin reduces the macrocyclic antiaromaticity of the formed expanded carbaporphyrinoids.
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Mechanism and Origins of Stereo- and Enantioselectivities of Palladium-Catalyzed Hydroamination of Racemic Internal Allenes via Dynamic Kinetic Resolution: A Computational Study

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00174K, Research Article
Zhenzhen Wu, Mei Zhang, Yu Shi, Genping Huang
Density functional theory calculations have been performed to investigate the Pd-catalyzed hydroamination of racemic internal allenes with pyrazoles. The computations show that the originally proposed reaction mechanisms initiated by the...
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Rhodium(III)-catalyzed synthesis of 3-trifluoromethylindanones from N-Methoxybenzamides via C-H activation and Claisen/Retro-Claisen reaction

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00330A, Research Article
Satyasheel Sharma, Bharatkumar Chaudhary, Neeraj Kulkarni
The Rhodium(III)-catalyzed reaction of N-methoxybenzamides as a directing group with β-trifluoromethyl-α,β-unsaturated ketones is reported. The reaction involved sp2 C−H activation, followed by Claisen condensation involving C-N bond cleavage to form...
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How to write and publish a scientific paper / Robert A. Day

Day, Robert A., 1924-




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Scientists must write : a guide to better writing for scientists, engineers and students / Robert Barrass

Barrass, Robert




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Writing scientific papers in English : an ELSE-Ciba Foundation guide for authors / Maeve O'Connor and F.Peter Woodford

O'Connor, Maeve




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The ACS style guide : a manual for authors and editors / Janet S. Dodd, editor ; Marianne C. Brogan, advisory editor




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The art of scientific writing : from student reports to professional publications in chemistry and related fields / Hans F. Ebel, Claus Bliefert, William E. Russey

Ebel, Hans Friedrich




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Communicating in science : writing and speaking / Vernon Booth

Booth, Vernon




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How to write and publish a scientific paper / Robert A. Day

Day, Robert A., 1924-




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Writing successfully in science / Maeve O'Connor ; with cartoons by Jenny Gretton

O'Connor, Maeve




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A guide to scientific writing : manual for students and research workers / David Lindsay

Lindsay, David




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Handbook of writing for the mathematical sciences / Nicholas J. Higham

Higham, N. J




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Communicating in science : writing a scientific paper and speaking at scientific meetings / Vernon Booth

Booth, Vernon




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How to write & publish a scientific paper / by Robert A. Day

Day, Robert A., 1924-




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Writing scientific English : a textbook of English as a foreign language for students of physical and engineering sciences / John Swales

Swales, John




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A primer of mathematical writing : being a disquisition on having your ideas recorded, typeset, published, read and appreciated / Steven G. Krantz

Krantz, Steven G. (Steven George), 1951-




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Writing to learn biology / Randy Moore

Moore, Randy




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How to write & illustrate a scientific paper / Björn Gustavii

Gustavii, Björn, 1932-




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Springer handbook of nanotechnology / Bharat Bhushan (ed.)




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A guide to scientific writing / David Lindsay

Lindsay, D. R




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Writing and presenting scientific papers / Birgitta Malmfors, Phil Garnsworthy, Michael Grossman

Malmfors, Birgitta




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Nanoelectromechanics in engineering and biology / Michael Pycraft Hughes

Hughes, Michael Pycraft, 1970-




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A student handbook for writing in biology / Karin Knisely

Knisely, Karin




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Noncontact atomic force microscopy / S. Morita, R. Wiesendanger, E. Meyer (eds.)




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Molecular engineering of nanosystems / Edward A. Rietman

Rietman, Ed




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Nano-engineering in science and technology : an introduction to the world of nano-design / Michael Rieth

Rieth, Michael




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Principles of nanotechnology : molecular-based study of condensed matter in small systems / G. Ali Mansoori

Mansoori, G. A. (G. Ali)




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Nanotechnology : environmental implications and solutions / Louis Theodore, Robert G. Kunz ; foreword - Rita D'Aquino

Theodore, Louis




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Good style : writing for science and technology / John Kirkman

Kirkman, John




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Nanostructured and advanced materials for applications in sensor, optoelectronic and photovaltaic technology / edited by A. Vaseashta, D. Dimova-Malinovska and J. M. Marshall

NATO Advanced Study Institute on Nanostructured and Advanced Materials for Applications in Sensors, Optoelectronic and Photovoltaic Technology (2004 : Sozopol, Bulgaria)




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Functional nanomaterials / edited by Kurt E. Geckeler, Edward Rosenberg




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Nanochemistry : a chemical approach to nanomaterials / Geoffrey A. Ozin and André C. Arsenault

Ozin, Geoffrey A., 1943-




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What is what in the nanoworld : a handbook on nanoscience and nanotechnology / Victor E. Borisenko and Stefano Ossicini

Borisenko, V. E. (Viktor Evgenʹevich)




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How to write and publish a scientific paper / Robert A. Day and Barbara Gastel

Day, Robert A., 1924-




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Nanostructures & nanomaterials : synthesis, properties & applications / Guozhang Cao

Cao, Guozhong




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Micromanufacturing and nanotechnology / N.P. Mahalik (ed.)




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Carbon nanomaterials / edited by Yury Gogotsi




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Biomolecular computation for bionanotechnology / Jian-Qin Liu, Katsunori Shimohara

Liu, Jian-Qin




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Environmental applications of nanomaterials : synthesis, sorbents and sensors / editors, Glen E. Fryxell, Guozhong Cao




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Environmental nanotechnology : applications and impacts of nanomaterials / editors, Mark R. Wiesner, Jean-Yves Bottero