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Ligand Cross-Links as a Design Element in Oligo- and PolyMOFs

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06109H, Edge Article
Open Access
Debobroto Sensharma, Seth M Cohen
Metal-Organic Frameworks (MOFs) constructed using cross-linked oligomeric or polymeric ligands (OligoMOFs and PolyMOFs respectively) have so far relied on a handful of canonical structural blueprints, in which the cross-links have...
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Surfing the Limits of Cyanine Photocages One Step at a Time

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC07165D, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hana Janeková, Sergey Fisher, Tomas Solomek, Peter Stacko
Near-infrared light-activated photocages enable controlling molecules with tissue penetrating light. Understanding the structural aspects that govern the photouncaging process is essential to enhancing their efficacy, crucial for practical applications. Here...
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Understanding ketone hydrogenation catalysis with anionic iridium(III) complexes: The crucial role of counterion and solvation

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04629C, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Paven Kisten, Sandrine Vincendeau, Eric Manoury, Jason Martin Lynam, John M. Slattery, Simon B Duckett, Agusti Lledos, Rinaldo Poli
The catalytic asymmetric hydrogenation of ketones reflect an important way to prepare valuable chiral alcohols. Understanding how transition metals promote these reactions is key to the rational design of more...
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Tailoring Hierarchical MnO2 Nanostructures on Self-Supporting Cathodes for High-Mass-Loading Zinc-Ion Batteries

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06182A, Edge Article
Open Access
Weijie Zheng, Zhibiao Cui, Cong Liu, Libei Yuan, Shengsong Li, Lilin Lin, Tao Meng, Liangui Yang, Yexiang Tong, Dong Shu
Aqueous zinc-ion batteries (AZIBs) with MnO2 cathodes have promising application prospects, however, their performance is hindered by their low efficiency and insufficient life. By leveraging the nanomicellar properties of cetyltrimethylammonium...
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Simultaneous generation of hydroxyl and hydrogen radicals from H+/OH− pairs caused by water–solid contact electrification

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06227B, Edge Article
Open Access
Fengjie Chen, Jingde Wu, Dou Wang, Yu Xia, Qingyuan Song, Ying Liang, Pu Wang, Bolei Chen, Yong Liang, Yongguang Yin, Yawei Wang, Maoyong Song, Guibin Jiang
Water–solid contact electrification is a common physical phenomenon involving interfacial electron and ion transfer, recently discovered to trigger unique redox reactions.
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Low temperature decoherence dynamics in molecular spin systems using the Lindblad master equation

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05627B, Edge Article
Open Access
Timothy Krogmeier, Anthony W Schlimgen, Kade Head-Marsden
Understanding the spin dynamics in low-temperature settings is crucial to designing and optimizing molecular spin systems for use in emerging quantum technologies. At low temperatures, irreversible loss occurs due to...
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Understanding the Formation of Nitrate from Nitrogen at the Interface of Gas-Water Microbubbles

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06989G, Edge Article
Open Access
Sandeep Bose, Yu Xia, Richard N. Zare
Understanding the Formation of Nitrate from Nitrogen at the Interface of Gas-Water MicrobubblesWater microbubbles containing Fe2+ ion has been found to efficiently transform nitrogen (N2) to nitrate (NO3-) by initiating...
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Organic dopant cyclization and significantly improved RTP properties

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06213B, Edge Article
Open Access
Shiguo Zhang, Guanyu Liu, Zhichao Mao, Shanfeng Xue, Qikun Sun, Wenjun Yang
Synthesized CDIA and ODIA via cyclization, obtained long-lived RTP polymers with lifetimes of 2146 and 2656 ms. Experimental and theoretical data show cyclization effectively restrains intramolecular rotation and stabilizes triplet populations.
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Delocalization error poisons the density-functional many-body expansion

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05955G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Dustin R. Broderick, John M. Herbert
Self-interaction error leads to runaway error accumulation when density functional theory is used in conjunction with the many-body expansion.
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Differentiating carrier protein interactions in biosynthetic pathways using dapoxyl solvatochromism

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05499G, Edge Article
Open Access
Matthew G. Miyada, Yuran Choi, Kyle Rich, James J. La Clair, Michael D. Burkart
A highly sensitive solvatochromic system was developed to monitor the loading and interactivity of carrier proteins associated with fatty acid, polyketide and non-ribosomal peptide biosynthesis.
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Electrochemical reconstruction of metal–organic gels into crystalline oxy-hydroxide heterostructures for efficient oxygen evolution electrocatalysis

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05799F, Edge Article
Open Access
Kang Liu, Haikuo Lan, Yuting Chen, Weicheng Tang, Zhenyu Xiao, Yunmei Du, Jun Xing, Zexing Wu, Lei Wang
An amorphous MOG electrochemically reconstitutes to a crystalline NiOOH/FeOOH heterostructure with the morphology changed from nanofibers to nanosheets as a high-performance OER electrocatalyst.
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Pnictogen-based vanadacyclobutadiene complexes

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05884D, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Mehrafshan G. Jafari, John B. Russell, Hwan Myung, Seongyeon Kwon, Patrick J. Carroll, Michael R. Gau, Mu-Hyun Baik, Daniel J. Mindiola
The reactivity of a [VV] alkylidyne with unsaturated substrates such as NCR (R = Ad or Ph) and PCAd leads to the formation of rare transition metal complexes featuring an α-aza-vanadacyclobutadiene and a β-phospha-vanadacyclobutadiene moieties.
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Dual ligand-enabled iron and halogen-containing carboxylate-based photocatalysis for chloro/fluoro-polyhaloalkylation of alkenes

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC04038D, Edge Article
Open Access
Wanru Han, Zhenyan Zhao, Kui Jiang, Yu Lan, Xuehan Yu, Xiaoyu Jiang, Wei Yang, Donghui Wei, Shi-Jun Li, Linbin Niu
Dual ligand-enabled iron photocatalysis for the conversion of all kinds of halogen-containing carboxylates (CnXmCOO, X: F, Cl, Br) to CnXm radicals is disclosed for chloro/fluoro-polyhaloalkylation of non-activated alkenes.
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Noncentrosymmetric tellurite halides created by a depolymerization strategy: toward strong SHG intensity and wide bandgap

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06403H, Edge Article
Open Access
Dan-Dan Zhou, Chun-Li Hu, Xin-Wei Zhang, Jiang-Gao Mao, Fang Kong
Successful synthesis of centrosymmetric Ga(Te3O7)Br and non-centrosymmetric M2(OH)(TeO3)(Te2O5)X (M = Al, Ga; X = Br, Cl) using a depolymerization strategy.
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An interactive dual energy storage mechanism boosts high-performance aqueous zinc-ion batteries

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05710D, Edge Article
Open Access
Shengen Gong, Meihua Zhu, Yan Zhou, Runan Li, Jianhua Zhang, Xiaoteng Jia, Danming Chao, Caiyun Wang
A conductive polymer cathode with high redox potential is realized by pre-doping Mn2+ into PANI, which demonstrates an interactive dual energy storage mechanism of reversible doping of multiple cations and dissolution–deposition of Mn2+.
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Allosteric release of cucurbit[6]uril from a rotaxane using a molecular signal

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC03970J, Edge Article
Open Access
Aneta Závodná, Petr Janovský, Václav Kolařík, Jas S. Ward, Zdeňka Prucková, Michal Rouchal, Kari Rissanen, Robert Vícha
Repulsions between portals of cucurbit[n]urils are sufficiently strong to unlock the rotaxane structure.
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Direct synthesis of N-perfluoro-tert-butyl secondary amines from N-trifluoromethyl secondary amines

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06335J, Edge Article
Open Access
Leibing Wang, Zhongyu Feng, Zhen Luo, Zihao Guo, Jieping Wang, Wenbin Yi
The one-step direct synthesis of N-perfluoro-tert-butyl secondary amines utilizes TMSCF3 as the sole CF3 source and the starting material N-CF3 secondary amine itself as the hydrogen source. PFtB amines can be effectively employed in 19F MRI.
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Pathway control in metallosupramolecular polymerization of a monoalkynylplatinum(II) terpyridine complex through competitive complex formation

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06083K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Minhye Kim, Heekyoung Choi, Minjoo Kim, Seonghan Kim, Seohyeon Yun, Eunji Lee, Jaeheung Cho, Sung Ho Jung, Jong Hwa Jung
The modification of metalloligands based on bis-type amideterpyridine platinum(II) complexes not only induces the formation of helical supramolecular polymers but also introduces a kinetic trapping strategy in competitive conditions.
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Photochemical carboborylation and three-component difunctionalization of α,β-unsaturated ketones with boronic acids via tosylhydrazones

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06537A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Álvaro Valdés-Maqueda, Manuel Plaza, Carlos Valdés
The photochemical carboborylation of α,β-unsaturated tosylhydrazones with boronic acids gives tertiary allylboronates. A one pot sequence involving an aldehyde allylation provides a powerful three-component method for diversity oriented synthesis.
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Bipolar electrochemiluminescence at the water/organic interface

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06103A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yuheng Fu, Bingbing Xie, Miaoxia Liu, Shaojuan Hou, Qunyan Zhu, Alexander Kuhn, Lin Zhang, Wensheng Yang, Neso Sojic
A novel bipolar electrochemistry approach for wireless dual-color ECL emission at the water/organic interface is developed. This system overcomes spatial limitations of conventional methods, enabling imaging of complex multiphase environments.
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Mechanism of action and evaluation of ratiometric probes for uric acid using lanthanide complexes with tetraazatriphenylene sensitisers

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05743K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xinyi Wen, Huishan Li, Zhijie Ju, Renren Deng, David Parker
Six Eu(III) and Tb(III) complexes are evaluated for the rapid ratiometric analysis of urate in diluted serum, together with mechanistic studies probing the intermediate exciplex and the excited state dynamics by transient absorption spectroscopy.
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Cationic Al oxo-hydroxide clusters: syntheses, molecular structures, and functional applications

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05707D, Perspective
Open Access
Naoki Ogiwara, Wei Zhou, Sayaka Uchida
Al oxo-hydroxide clusters are formed through the hydrolysis of Al3+-containing solutions, exhibiting a diversity of sizes and shapes. The assembly of these clusters demonstrates functional applications, such as adsorption and heterogeneous catalysis.
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Direct Ladderization of Cyclooctatetraene-containing, Processable Conjugated Ladder Polymers from Annulated bis-Zirconacyclopentadienes

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06902A, Edge Article
Open Access
August J. Rothenberger, Harrison M. Bergman, He Li, Miao Qi, Yunfei Wang, Yi Liu, T. Don Tilley
Conjugated ladder polymers (CLPs) are difficult yet captivating synthetic targets due to their fully unsaturated fused backbones. Inherent challenges associated with their synthesis often lead to low yields, structural defects,...
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Synergetic effect of mild hypothermia and antioxidant treatment on ROS-mediated neuron injury under oxygen-glucose deprivation investigated by scanning electrochemical microscopy

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05977H, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Junjie Zhang, Yulin Liu, Yuxiang Zhao, Siyu Zhang, Feng Xu, Fei Li
Ischemic stroke and reperfusion injury result in neuronal damage and dysfunction associated with oxidative stress, leading to overproduction of cellular reactive oxygen species (ROS) and reactive nitrogen species (RNS). In...
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Triple-Function Porphyrin in Glycopolymeric Photosensitizer: From PhotoATRP to Targeted PDT

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06466F, Edge Article
Open Access
Jiahui Lin, Zhiyuan Ma, Weiwei Zuo, Meifang Zhu
Porphyrin derivatives serve as photocatalysts in reversible-deactivation radical polymerization and as photosensitizers in photodynamic therapy (PDT). Herein, a triple function porphyrin, ZnTPPC6Br, was synthesized as photocatalyst and initiator for photoATRP....
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Morphology of Lithium Halides in Tetrahydrofuran from Molecular Dynamics with Machine Learning Potentials

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04957H, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Marinella de Giovanetti, Sondre H. Hopen Eliasson, Sigbjørn L. Bore, Odile Eisenstein, Michele Cascella
The preferred structures of lithium halides (LiX, with X = Cl, Br, I) in organic solvents have been the subject of a wide scientific debate, and a large variety of...
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Rapid, Potent, and Persistent Covalent Chemical Probes to Deconvolute PI3Kα Signaling

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05459H, Edge Article
Open Access
Lukas Bissegger, Theodora Alexandra Alexandra Constantin, Erhan Keles, Luka Raguž, Isobel Barlow-Busch, Clara Orbegozo, Thorsten Schaefer, Valentina Borlandelli, Thomas Bohnacker, Rohitha SriRamaratnam, Alexander Schäfer, Matthias Gstaiger, John E. Burke, Chiara Borsari, Matthias Wymann
Chemical probes have gained importance in the elucidation of signal transduction in biology. Insufficient selectivity and potency, lack of cellular activity and inappropriate use of chemical probes has major consequences...
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Photoactivated hydride therapy under hypoxia beyond ROS

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06576J, Edge Article
Open Access
Xia Wang, Yijian Gao, Ting Wang, Zhaobin Wang, He Hang, Shengliang Li, Fude Feng
As compared to oxidative phototherapy, studies on reactive reductive species-participating photodynamic therapy (PDT) are rare. Porphyrins are typical photosensitizers restricted with oxygen level, but efficacy and selectivity are always uncompatible...
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Rare-earth metal complexes bearing electrophilic and nucleophilic carbon centres and their unique reactivity patterns towards pyridine derivatives

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04197F, Edge Article
Open Access
weikang Wu, Thayalan Rajeshkumar, Shan Zhu, Fuxiang Chai, Dongjing Hong, ZeMing Huang, Qingbing Yuan, Laurent Maron, Shaowu Wang
The rare-earth metal dialkyl complexes (κ2-L1)RE(CH2SiMe3)2(THF)2 [RE = Lu(1a), Yb(1b), Er(1c), Y(1d), Dy(1e)] (L1 = 1-(2-N-C5H10NCH2CH2)-3-(2,6-iPr2C6H3N=CH)-C8H4N) and the rare-earth metal monoalkyl complexes (κ2-L1)2RE(CH2SiMe3)(THF)n [n = 0, RE = Lu(2a), Yb(2b);...
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Pronounced Electronic Modulation of Geometrically-Regulated Metalloenediyne Cyclization

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05396F, Edge Article
Open Access
Sarah E. Lindahl, Erin M. Metzger, Chun-Hsing Chen, Maren Pink, Jeff Zaleski
Using a diverse array of thermally robust phosphine enediyne ligands (dxpeb, X = Ph, Ph-pOCH3, Ph-pCF3, Ph-m2CH3, Ph-m2CF3, iPr, Cy, and tBu) a novel suite of cisplatin-like Pt(II) metalloenediynes (3,...
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Discovery of penicillic acid as a chemical probe against tau aggregation in Alzheimer’s Disease

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05469E, Edge Article
Open Access
Jennifer Shyong, Jinliang Wang, Tran Quoc Dung Huynh, Marina Fayzullina, Bo Yuan, Ching-Kuo Lee, Thomas Minehan, Paul M. Seidler, Clay Wang
Alzheimer’s Disease (AD) is a neurodegenerative disorder proven to be caused by the aggregation of protein tau into fibrils, resulting in neuronal death. The irreparable neuronal damage leads to irreversible...
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Sequence-dependent Conformational Transitions of Disordered Proteins During Condensation

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05004E, Edge Article
Open Access
Jiahui Wang, Dinesh Devarajan, Keerthivasan Muthukumar, Youngchan Kim, Arash Nikoubashman, Jeetain Mittal
Intrinsically disordered proteins (IDPs) can form biomolecular condensates through phase separation. It is recognized that the conformation of IDPs in the dense and dilute phases, as well as at the...
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Depolymerisation of Poly(Lactide) Under Continuous Flow Conditions

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05891G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sophie Ellis, Antoine Buchard, Tanja Junkers
Poly(L-lactic acid) (PLLA) is commercially successful bio-based plastic, where end-of-life materials can undergo industrial composting. To create a circular economy, a desirable alternative to composting is chemical recycling to monomer...
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Spin State Modulation and Kinetic Control of Thermal Contraction in a [Fe2Co2] Discrete Prussian Blue Analogue

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05792A, Edge Article
Open Access
Jyoti Yadav, Sanjit Konar
Stimuli-responsive switchable molecules represent an important category of magnetic materials with significant potential for functional devices. However, engineering complexes with controlled switchability remains challenging due to their sensitivity to lattice...
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13/09:44 EST Flood Warning Summary for Queensland




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13/09:43 EST Final Flood Warning for the Logan River




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13/09:26 EST Minor Flood Warning for the Bremer River and Warrill Creek




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‘I’d like to think that one day I’ll be Chinese’

Committed Sinophile and one of the debut filmmakers at MAMI this year, Jordan Schiele is alsoan enthusiastic Mumbaikar discovers Satya Kandala




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Crushing on candy

Witness the theatrics of customised sweet-making at the city’s newest confectionery store




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The young and the restless

With top female stars pairing up with younger heroes, Hindi cinema is showing a marked change in the age gap debate




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The seven qualities of successful male playback singers




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Curating history through cinema

The New Medium, which debuted at MAMI, showcased a history of the moving picture and its formal innovation




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When a drummer sits down to write music

Rijul Victor’s experiments with EDM led him to start a solo project, which is now releasing his debut album as an electronic music producer




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Following a seven-day cinema diet

The Mumbai Film Festival this year had themes of suffocation, alienation, personal struggle, politics, rape, morality, gender, family…and a few characters we fell in love with, says Namrata Joshi




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An ear for music, an eye for art

Much sought-after exhibition designer Mark Prime’s first Indian solo art show is a playful mix of abstract patterns




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Curtains come down on MAMI

Diamond Island,Godless,Everything Else,Lady of the LakeandThe Narrow Pathamong big winners




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A fresh wind from the desert

Elite Zexer’s film about two Bedouin women was as warmly received in Mumbai as it was at Sundance and Berlin says Satya Kandala




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The future of flashbacks




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An auteur of diverse genres

Cary Fukunaga on his favourite version ofTrue Detective, the challenges of working onBeast of Nations, and why he’s a student of history




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Food trucking through India

AfterAirlift, Raja Krishna Menon is makingChef, a road movie that explores the flavours in the country