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Porous graphitic carbon nitride for solar photocatalytic applications

Nanoscale Horiz., 2020, 5,765-786
DOI: 10.1039/D0NH00046A, Review Article
Yang Li, Xin Li, Huaiwu Zhang, Quanjun Xiang
This review summarizes the development of PCN, i.e., synthesis, morphology, modification, and application in recent years. This review can provide a comprehensive view of PCN and lay a foundation for the design of ideal photocatalysts in the future.
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Defect engineering of 2D BiOCl nanosheets for photonic tumor ablation

Nanoscale Horiz., 2020, 5,857-868
DOI: 10.1039/C9NH00707E, Communication
Chen Dai, Ruizhi Hu, Chunmei Wang, Zhuang Liu, Shengjian Zhang, Luodan Yu, Yu Chen, Bo Zhang
Photothermal therapy (PTT) is an emerging technology as a noninvasive therapeutic modality for inducing photonic cancer hyperthermia.
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Interface engineering of two-dimensional transition metal dichalcogenides towards next-generation electronic devices: recent advances and challenges

Nanoscale Horiz., 2020, 5,787-807
DOI: 10.1039/C9NH00743A, Review Article
Wugang Liao, Siwen Zhao, Feng Li, Cong Wang, Yanqi Ge, Huide Wang, Shibo Wang, Han Zhang
This review presents recent advances and challenges in the interface engineering of 2D TMDCs and emerging electronics based on TMDCs.
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Nanoengineering to achieve high efficiency practical lithium–sulfur batteries

Nanoscale Horiz., 2020, 5,808-831
DOI: 10.1039/C9NH00730J, Minireview
Eunho Cha, Mumukshu Patel, Sanket Bhoyate, Vish Prasad, Wonbong Choi
Rapidly increasing markets for electric vehicles (EVs), energy storage for backup support systems and high-power portable electronics demand batteries with higher energy densities and longer cycle lives.
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Synthesis and optoelectronics of mixed-dimensional Bi/Te binary heterostructures

Nanoscale Horiz., 2020, 5,847-856
DOI: 10.1039/C9NH00805E, Communication
Ye Zhang, Jia Guo, Yiguo Xu, Weichun Huang, Chao Li, Lingfeng Gao, Leiming Wu, Zhe Shi, Chunyang Ma, Yanqi Ge, Xiuwen Zhang, Han Zhang
0D Bi QDs were distributed on 2D Te NSs to prepare mixed-dimensional Bi/Te heterostructure. The studies demonstrate that Bi/Te shows excellent self-power photo-response behaviors as well as the great potential for ultrafast photonic devices.
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Single atom catalysts: a surface heterocompound perspective

Nanoscale Horiz., 2020, 5,757-764
DOI: 10.1039/D0NH00088D, Focus
Zongkui Kou, Wenjie Zang, Peikui Wang, Xin Li, John Wang
Evolution of heterogeneous catalysts with steady down-sizing: from small particles, clusters, dots to single atoms, and now the “surface heterocompound”.
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Light-triggered dual-modality drug release of self-assembled prodrug-nanoparticles for synergistic photodynamic and hypoxia-activated therapy

Nanoscale Horiz., 2020, 5,886-894
DOI: 10.1039/D0NH00034E, Communication
Dongyang Zhao, Wenhui Tao, Songhao Li, Lingxiao Li, Yixin Sun, Guanting Li, Gang Wang, Yang Wang, Bin Lin, Cong Luo, Yongjun Wang, Maosheng Cheng, Zhonggui He, Jin Sun
Prodrug-nanoparticles turn the disadvantage of the aggregation-caused quenching effect into an advantage to promote dual-modality PR104A release. Besides, photodynamic therapy-induced hypoxia activates PR104A for high-efficiency synergistic therapy.
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Fast Deposition of Ultrathin, Highly Crystalline Organic Semiconductor Film for High-Performance Transistors

Nanoscale Horiz., 2020, Accepted Manuscript
DOI: 10.1039/D0NH00096E, Communication
Xiali Zhang, Wei Deng, Bei Lu, Xiaochen Fang, Xiujuan Zhang, Jiansheng Jie
Ultrathin organic semiconductor (OSC) crystalline films hold the promise of achieving high-performance, flexible, and transparent organic electronic devices. However, fast and high-throughput solution deposition of uniform pinhole-free ultrathin OSC crystalline...
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Understanding of copolymers containing pyridine and selenophene simultaneously and their polarity conversion in transistors

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QM00739C, Research Article
So-Huei Kang, Myeonggeun Han, Yongjoon Cho, Jisu Hong, Seongmin Heo, Seonghun Jeong, Yong-Young Noh, Changduk Yang
Two n-type pyridine and selenophene-containing polymers were synthesized and the structure–property relationships were investigated, followed by polarity switching from ambipolarity to unipolar characteristics via the doping method.
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Spatially separated bimetallic cocatalysts on hollow-structured TiO2 for photocatalytic hydrogen generation

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00042F, Research Article
Ping She, Jun-sheng Qin, Heng Rao, Buyuan Guan, Jihong Yu
A hollow-structured TiO2 decorated with spatially separated bimetallic cocatalysts (Pd@TiO2@Au) was obtained, which exhibited superior photo-induced charge separation by combining the SPR effect of Au NPs and the smaller size effect of Pd NPs.
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Near-IR absorption and photocurrent generation using a first-of-its-kind boron difluoride formazanate non-fullerene acceptor

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00109K, Research Article
Josh D. B. Koenig, Mahmoud E. Farahat, Jasveer S. Dhindsa, Joe B. Gilroy, Gregory C. Welch
We report the synthesis and characterization of the first non-fullerene acceptor containing a boron difluoride formazanate core end-capped with N-annulated perylene diimides.
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A GFP-chromophore-based C3V-symmetric tripodal receptor with selective recognition of Hg(II), Fe(III) and Cr(III)

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00108B, Research Article
Chun-Yen Chou, Robert Sung, Wei-Luen Chang, Kuangsen Sung
A novel green-fluorescent-protein-chromophore-based tripodal receptor 1 is synthesized. Its single crystal X-ray diffraction structure looks like a straight, long tube with one end closed. The diameter of the inner cavity...
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Synergy of PVP and ethanol to synthesize Ni3S4 quantum dots for high-performance asymmetric supercapacitors

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00201A, Research Article
Jinfeng Zheng, Xiao Lian, Mingzai Wu, Fangcai Zheng, Yuan hao Gao, Helin Niu
Ni3S4 quantum dots (QDs) have great potential for supercapacitors due to their unique quantum effects, high specific surface area, high water solubility and good stability, but the current preparation process...
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Charge density modulation on asymmetric fused-ring acceptors for high-efficiency photovoltaic solar cells

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00123F, Research Article
Zhuohan Zhang, Linqiang Yang, Zhenghao Hu, Jiangsheng Yu, Xin Liu, Hongtao Wang, Jinru Cao, Fujun Zhang, Weihua Tang
Charge density modulation on thieno[2'',3'':5',6']-s-indaceno[2',1':4,5]dithieno[3,2-b:2',3'-d]pyrrole core has been conducted for a systematic study of its impact on the electronic structure, molecular packing and photovoltaic performance of asymmetric fused-ring acceptors.
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A robust 3D printed multilayer conductive graphene/polycaprolactone composite electrode

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QM00780F, Research Article
Chong-Yong Lee, Sepidar Sayyar, Paul J. Molino, Gordon G. Wallace
We fabricated a 3D-printed multilayer conductive graphene/polycaprolactone composite electrode that shows excellent robustness, biocompatibility and electrochemical response.
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Near-infrared electron acceptors with fused nonacyclic molecular backbones for nonfullerene organic solar cells

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QM00754G, Research Article
Jianquan Zhang, Yunke Li, Zhengxing Peng, Fujin Bai, Lik-Kuen Ma, Harald Ade, Zhengke Li, He Yan
Two strong electron-donating moieties were fused into the molecular backbone of small molecular acceptors showing dramatically extended absorption beyond 900 nm.
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Efficient near-infrared photosensitizer with aggregation-induced emission characteristics for mitochondria-targeted and image-guided photodynamic cancer therapy

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00170H, Research Article
Hanxiao Yang, Jiabao Zhuang, Nan Li, Yue Li, Shiyu Zhu, Jiaxin Hao, Jiayao Xin, Na Zhao
A highly efficient near-infrared photosensitizer with aggregation-induced emission characteristics was developed for mitochondria-targeted and image-guided photodynamic cancer therapy.
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Oxygen Vacancy Induced Superior Visible-light-driven Photo-catalytic Performance in BiOCl Homojunction

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00187B, Research Article
Si-Ying Niu, Ruoyu Zhang, Chongfeng Guo
The photocatalytic performance of semiconductor can be enhanced by expanding the spectral response and accelerating the photo-induced charge separation. Introduction of oxygen vacancies and construction of homo-junction in BiOCl were...
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Lithium bis(oxalate)borate additive in electrolyte to improve Li-rich layered oxide cathode materials

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00094A, Research Article
Zi Xiao, Jiuding Liu, Guilan Fan, Meng Yu, Junxiang Liu, Xinglong Gou, Mingjian Yuan, Fangyi Cheng
Lithium-rich layered oxides (LLO), as the most attractive cathode materials for high-energy lithium-ion batteries (LIBs), are plagued by poor cyclability due to structural and electrode/electrolyte interface instability. Herein, we report...
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Electrical stability study of polymer-based organic transistors in ambient air using an active semiconducting/insulating polyblend-based pseudo-bilayer

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00048E, Research Article
Bo-Ren Lin, Horng-Long Cheng, Hung-Han Lin, Fu-Chiao Wu, Jia-Hui Lin, Wei-Yang Chou, Jrjeng Ruan, Yu-Wu Wang
Polymeric transistors with unexpected nondecaying features even in ambient air are fabricated based on a P3HT/PMMA pseudo-bilayer with microphase separation morphology.
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Polydopamine sacrificial layer mediated SiOx/C@C yolk@shell structure for durable lithium storage

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00120A, Research Article
Yuanyuan Zhang, Guangwu Hu, Qiang Yu, Zhenhui Liu, Chang Yu, Longsheng Wu, Liang Zhou, Liqiang Mai
Yolk@shell structured SiOx/C@C has been constructed through a polydopamine sacrificial layer mediated strategy, and the SiOx/C@C displays high specific capacity and durable cyclability in lithium storage.
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Multicationic AIEgens for unimolecular photodynamic theranostics and two-photon fluorescence bioimaging

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00119H, Research Article
Yuting Gao, Haoke Zhang, Zhenyan He, Fang Fang, Chao Wang, Kanghua Zeng, Shangbang Gao, Fanling Meng, Liang Luo, Ben Zhong Tang
This work reports multicationic AIEgens for unimolecular photodynamic theranostics, and an investigation of the relationship between their structures and activities, including PDT performance, 2-photon bioimaging, and self-reporting characteristics.
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AIEgen based polymorphs with solvent regulated crystal-to-crystal switch properties

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00154F, Research Article
Liming Lai, Bing Fang, Wenyu Cheng, Pengyu Li, Yantu Zhang, Meizhen Yin
An AIEgen with tunable polymorphism-dependent emission and solvent regulated crystal-to-crystal switch properties is reported. Our study has provided insight into the relationship between molecular stacking and emission properties.
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Fluoro-alkyl substituted isothianaphthene bisimides as stable n-type semiconductors

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00137F, Research Article
Xiaolong Chen, Dongwei Zhang, Yaowu He, Muhammad Umair Ali, Yuting Wu, Changbin Zhao, Peiheng Wu, Chaoyi Yan, Fred Wudl, Hong Meng
Two fluoro-alkyl substituted isothianaphthene bisimide materials with high solubility and their applications in stable n-type OTFTs are demonstrated.
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Boosting the piezocatalytic performance towards degradation of organic pollutant of Bi2WO6 nanosheets

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00179A, Research Article
Aize Hao, Xueer Ning, Yali Cao, Jing Xie, Dianzen Jia
The novel piezocatalyst of Bi2WO6 nanosheets (BWO NS) are successfully synthesized by a simple, green and harmless solid-state chemistry method. The BWO NS present excellent piezocatalytic activity in contrast with...
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Linking silole to triptycene : a fruitful association

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00087F, Research Article
Kassem Amro, Anil K Thakur, Marc Rolland, Arie van der Lee, Vincent Lemaur, Roberto Lazzaroni, Cyril Poriel, Joëlle Rault-Berthelot, Lionel Hirsch, Sébastien Clément, Philippe Gerbier
1,1’-disubstituted-2,3,4,5-tetraphenylsiloles incorporating triptycene moieties Tp-DMTPS and Tp-MPTPS were prepared and characterized. Like other 2,3,4,5-tetraphenylsiloles, both compounds exhibit aggregation-induced emission (AIE) behavior. Unexpectedly, the solid state PL emission of Tp-DMTPS show...
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Non-equilibrium kinetics and trajectory thermodynamics of synthetic molecular pumps

Mater. Chem. Front., 2020, 4,1304-1314
DOI: 10.1039/D0QM00022A, Review Article
R. Dean Astumian, Cristian Pezzato, Yuanning Feng, Yunyan Qiu, Paul R. McGonigal, Chuyang Cheng, J. Fraser Stoddart
Hypothetical transmembrane rotaxane as a model for trajectory thermodynamic theory of synthetic molecular pumps.
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The origin of the unusual red-shifted aggregation-state emission of triphenylamine-imidazole molecules: excimers or a photochemical reaction?

Mater. Chem. Front., 2020, 4,1411-1420
DOI: 10.1039/C9QM00737G, Research Article
Jin Liu, Jianai Chen, Yujie Dong, Yue Yu, Shitong Zhang, Jianli Wang, Qingbao Song, Weijun Li, Cheng Zhang
Revealing the actual origin of the unusual red-shifted aggregation-state emission of triphenylamine-imidazole molecules: is the photochemical reaction rather than the excimers.
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Dual-doping of ruthenium and nickel into Co3O4 for improving the oxygen evolution activity

Mater. Chem. Front., 2020, 4,1390-1396
DOI: 10.1039/D0QM00079E, Research Article
Beibei Guo, Ruguang Ma, Zichuang Li, Jun Luo, Minghui Yang, Jiacheng Wang
Ru and Ni co-doped Co3O4 with improved OER activity were synthesized by a one-step hydrothermal method. Ru doping increases the intrinsic activity, while Ni doping creates more oxygen vacancies and exposes more active sites.
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From simple Katritzky salts to AIEgens: mechanochromic luminescence and heparin detection

Mater. Chem. Front., 2020, 4,1492-1499
DOI: 10.1039/C9QM00783K, Research Article
Faxu Lin, Yang Feng, Xiaoqing Liu, Lei Wang, Zhen-Qiang Yu, Yi Liu
A series of novel AIEgens based on Katritzky pyridinium salts were readily synthesized and exhibited interesting aggregation-induced emission behaviors, remarkable mechanochromic luminescence, and promising heparin detection.
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Sandwich structured dielectrics for air-stable and flexible low-voltage organic transistors in ultrasensitive pressure sensing

Mater. Chem. Front., 2020, 4,1459-1470
DOI: 10.1039/D0QM00062K, Research Article
Yue Jiang, Ziyang Liu, Zhigang Yin, Qingdong Zheng
A novel type of polymer sandwich dielectric is developed for air-stable, hysteresis-free and flexible OTFTs which can be used for low-power pressure sensors with ultrahigh sensitivity, wide detection range and fast response.
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The role of dipole moment in two fused-ring electron acceptor and one polymer donor based ternary organic solar cells

Mater. Chem. Front., 2020, 4,1507-1518
DOI: 10.1039/D0QM00016G, Research Article
Xunfan Liao, Yongjie Cui, Xueliang Shi, Zhaoyang Yao, Heng Zhao, Yongkang An, Peipei Zhu, Yaxiao Guo, Xiang Fei, Lijian Zuo, Ke Gao, Francis Lin, Qian Xie, Lie Chen, Wei Ma, Yiwang Chen, Alex K.-Y. Jen
The dipole moment of FREAs’ terminals has been unveiled as an important factor and its working mechanism has been thoroughly investigated. Our results demonstrate that the dipole moment should also be taken into account in designing ternary OSCs.
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Opportunities and critical factors of porous metal-organic frameworks for the industrial separation of light olefins

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00186D, Review Article
Tianhao Lan, Libo Li, Yang Chen, Xiaoqing Wang, Jiangfeng Yang, Jinping Li
Light olefins (ethylene, propylene, and 1,3-butadiene) are widely used as building blocks in the petrochemical industry and for the fabrication of everyday products. Developing energy cost-efficient porous materials for the...
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Tread and Other Stories—Barry Dempster

ISBN: 9781988040424 Price: $21.95 Pub date: Fall 2018 Tread and Other Stories is a moving, unsettling, and ferociously humane collection of short fiction. The characters are achingly real: the moments at once gut-wrenchingly singular and utterly recognizable. There’s a satisfying range here—from a female prison guard with a yen for bad boys to a lost young man who [...]




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[ASAP] Amine <italic toggle="yes">N</italic>-Oxide Kinetic Hydrate Inhibitor Polymers for High-Salinity Applications

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00838




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[ASAP] Chemical Looping Gasification of Torrefied Biomass Using NiFe<sub>2</sub>O<sub>4</sub> as an Oxygen Carrier for Syngas Production and Tar Removal

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00584




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[ASAP] Enhanced Performance of Adsorptive Removal of Thiophene from Model Fuel over Micro–Mesoporous Binderless ZSM-5 Prepared by <italic toggle="yes">In Situ</italic> Crystallization

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00198




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[ASAP] Oxygen Uncoupling Property and Kinetics of a Copper Manganese Composite Oxygen Carrier in a Packed-Bed Reactor

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00574




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[ASAP] Pore Network Changes Due to Polymer Flooding: Hebron Field Case

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00487




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[ASAP] Depolymerization of Wheat Straw to Produce Glucose by Self-Catalyzed Hydrolysis

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00525




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[ASAP] Interplay between Viscous Pressure and Capillary Pressure on Polymer Gel Dehydration and Water Shutoff in Hydraulically Fractured Reservoirs

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00368




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[ASAP] Designing Novel High-Performance Shale Inhibitors by Optimizing the Spacer Length of Imidazolium-Based Bola-Form Ionic Liquids

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00788




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[ASAP] A Simple and Direct Route to High-Performance Acrylamido-Based Kinetic Gas Hydrate Inhibitors from Poly(acrylic acid)

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00726




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[ASAP] Preface to the PetroPhase 2019 Special Issue

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c01275




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[ASAP] Effect of Partial Rapid Pyrolysis on Bituminous Properties: From Structure to Reactivity

Energy & Fuels
DOI: 10.1021/acs.energyfuels.9b04439




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[ASAP] Optimization of Biomass Pyrolysis Vapor Upgrading Using a Laminar Entrained-Flow Reactor System

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00649




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[ASAP] Characterization and Distillation of Pyrolysis Liquids Coming from Polyolefins Segregated of MSW for Their Use as Automotive Diesel Fuel

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00403




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[ASAP] Torrefaction of Sorghum Straw Pellets in a Stationary Reactor with a Feeding Screw

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00531




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[ASAP] Influence of the Combination System of Wet Flue Gas Desulfurization and a Wet Electrostatic Precipitator on the Distribution of Polycyclic Aromatic Hydrocarbons in Flue Gas from a Coal-Fired Industrial Plant

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00389




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[ASAP] Investigation on Ash-Fusion Characteristics of Livestock Manure and Low-Rank Coals

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00587