o

Organic/inorganic heterostructures templated by interfacial instability-driven BCP colloids in deformable emulsion droplets

Soft Matter, 2024, 20,8174-8180
DOI: 10.1039/D4SM00921E, Communication
Yuqing Song, Nan Yan, Lingli Wan, Jingjing Li, Ye Gao
Core–shell colloids are self-assembled in emulsion droplets driven by interfacial instability, which serve as excellent scaffolds for designing organic/inorganic heterostructures.
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Dynamics of phase-separated microdroplets near the contact line of evaporating all-aqueous drops

Soft Matter, 2024, 20,8260-8266
DOI: 10.1039/D4SM01056F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Rahul Rai, Maheshwar Gopu, Senthan Pugalneelam Parameswaran, Tapan Chandra Adhyapak, Dileep Mampallil
Evaporation of multicomponent drops can induce liquid–liquid phase separation and spatial reconfiguration of phases through complex dynamics near the contact line.
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Revisiting the density profile of the fuzzy sphere model for microgel colloids

Soft Matter, 2024, 20,8181-8184
DOI: 10.1039/D4SM01045K, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Frank Scheffold
Microgel density profiles evaluated with the complementary error function and the popular fuzzy sphere model are not compatible with each other.
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o

Chain stretching in brushes favors sequence recognition for nucleobase-functionalized flexible precise oligomers

Soft Matter, 2024, 20,8303-8311
DOI: 10.1039/D4SM00866A, Paper
Kseniia Grafskaia, Qian Qin, Jie Li, Delphine Magnin, David Dellemme, Mathieu Surin, Karine Glinel, Alain M. Jonas
Flexible oligomers having precise sequences of nucleobases do not specifically recognize surface-grafted target chains at low grafting density. Moderately higher grafting densities promote sequence-specific recognition thanks to chain stretching.
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o

Ion effects on minimally hydrated polymers: hydrogen bond populations and dynamics

Soft Matter, 2024, 20,8291-8302
DOI: 10.1039/D4SM00830H, Paper
Open Access
Eman Alasadi, Carlos R. Baiz
Compared to bulk water, ions in confined environments or heterogeneous solutions can significantly disrupt hydrogen bond networks.
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o

Co-encapsulation of organic polymers and inorganic superparamagnetic iron oxide colloidal crystals requires matched diffusion time scales

Soft Matter, 2024, 20,8312-8325
DOI: 10.1039/D4SM00935E, Paper
Open Access
Brian K. Wilson, Robert K. Prud’homme
Composite nanoparticles co-encapsulate organic materials with inorganic primary colloids. Producing “stoichiometric NPs”, where all NPs contain organic and inorganic species at similar ratios, requires matched diffusion-aggregation time scale.
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The impact of cross-linker distribution on magnetic nanogels: encapsulation, transport and controlled release of the tracer

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00797B, Paper
Open Access
Ivan S. Novikau, Ekaterina V. Novak, Sofia S. Kantorovich
Differences in crosslinker concentration between the core and periphery of a magnetic nanogel slow down the release of a non-magnetic cargo.
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Geometrical impacts of platonic particles on nematic liquid crystal dynamics

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00870G, Paper
Stiven Villada-Gil, Monirosadat Sadati, Juan D. Ospina-Correa, Daniel A. Olaya-Muñoz, Juan P. Hernández-Ortiz, José A. Martínez-González
In this work, we studied the defect dynamics of platonic-like colloidal particles immersed in a nematic liquid crystal under flow conditions, analyzing the behavior of disclinations for each of these polyhedra.
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o

Stochastic migrations of Marangoni surfers between two lobes of a dumbbell-shaped confinement

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00914B, Paper
Alakesh Upadhyaya, V. S. Akella
We report an experimental investigation on the stochastic migration dynamics of Marangoni surfers (camphor-infused paper disks) between the two lobes of a dumbbell-shaped chamber.
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o

Stress amplification and relaxation imaging around cracks in nanocomposite gels using ultrasound elastography

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00909F, Paper
H. Le Blay, T. Deffieux, L. Laiarinandrasana, M. Tanter, A. Marcellan
Stress visualization around cracks in NC gels was performed using ultrasonic elastography. Temporal and spatial mapping are performed non-invasively. Over time, the stress gradient is erased by large-scale reorganization of the polymer network.
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o

Drop deformation in a planar elongational flow: impact of surfactant dynamics

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00642A, Paper
Julian Wailliez, Paul Regazzi, Anniina Salonen, Paul G. Chen, Marc Jaeger, Marc Leonetti, Emmanuelle Rio
We measure the deformation of a drop under an extensional flow. The drop is less deformed than for a pure liquid because of the depletion of surfactants at the tips, which we attribute to the adsorption/desorption dynamics of the surfactants.
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o

Telephone cord blister formation in solvent swollen elastomer films

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM01035C, Paper
Open Access
James S. Sharp, Nathaniel M. Roberts, Sam Walker
Telephone cord blister formation is studied in PDMS films swollen in four different solvents. Buckling and fracture mechanics theories are developed to interpret blister morphology and growth rates. A simple surface patterning method is introduced.
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o

Network interactions simultaneously enhance stiffness and lubricity of triple-network hydrogels

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00969J, Paper
Nabila Ali, Connor J. Demott, Olivia F. Dingus, Melissa A. Grunlan, Alison C. Dunn
Tough hydrogels with a charge-variable third network were assessed for biomimicking lubricity in both water and FBS solution.
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o

Long range signature of liquid's inertia in nanoscale drainage flows

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM01006J, Paper
Nathan Bigan, Mathieu Lizée, Marc Pascual, Antoine Niguès, Lydéric Bocquet, Alessandro Siria
In confinement, liquid flows are governed by a complex interplay of molecular, viscous and elastic forces.
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o

Microrheology of gemini surfactants at interfaces and in solutions in the dilute and semidilute regimes

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00860J, Paper
Mayssa Medfai, Antonio Stocco, Christophe Blanc, Maurizio Nobili, Martin In
The interface of semidilute Gemini surfactant solutions remains fluid and is less viscous than the bulk. Depletion of the viscosity near the interface plays a key role in microrheology.
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o

Carboxymethyl cellulose-stabilized calcium phosphate particles for injectable hydrogel-based bone tissue engineering

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00670D, Paper
Piyaporn Srisura, Yuwaporn Pinyakit, Umphan Ngoensawat, Pongsakorn Yuntasiri, Khoiria Nur Atika Putri, Theerapat Chanamuangkon, Waranyoo Phoolcharoen, Varol Intasanta, Voravee P. Hoven
Carboxymethyl cellulose-stabilized calcium phosphate particles well-dispersed in aqueous solution can be integrated into an injectable hydrogel made of methacrylated hyaluronic acid which is a promising material for bone regeneration applications.
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o

Bubble dynamics manipulation in polymeric foaming

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM01040J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lorenzo Miele, Antonio Abate, Kentaro Taki, Ernesto Di Maio
The inverse pressure quenching treatment is proposed to decouple bubble nucleation from growth, advancing our understanding of the physics governing bubble growth and evolution in polymer foaming.
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o

Nature of barriers determines first passage times in heterogeneous media

Soft Matter, 2024, 20,8353-8362
DOI: 10.1039/D4SM00908H, Paper
Moumita Dasgupta, Sougata Guha, Leon Armbruster, Dibyendu Das, Mithun K. Mitra
The nature of barriers control the first passage times in heterogenous media. For entropic barriers, the first passage times increases monotonically with increasing number of barriers, while for energetic barriers, passage times show a non-monotonic behaviour with increasing barriers.
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A macroscopic magneto-optical response resulting from local effects in ferronematic liquid crystals

Soft Matter, 2024, 20,8363-8372
DOI: 10.1039/D4SM00577E, Paper
Xiangshen Meng, Xiaowei Li, Jian Li, Yueqiang Lin, Xiaodong Liu, Zhenghong He
The dynamic rotational behavior of composite chains under a rotating magnetic field was observed. The birefringence and dichroism variations in FNLCs mainly stem from the magnetic response of the composite chains, indicating local effects.
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o

Emulsifying mechanisms of phospholipids in high-pressure homogenization of perfluorocarbon nanoemulsions

Soft Matter, 2024, 20,8373-8384
DOI: 10.1039/D4SM00828F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Larissa J. Lubitz, Harden Rieger, Gero Leneweit
An optimized PFC/W emulsion contains 1 mM lipid per 1% (v/v) dispersed phase for an emulsifying monolayer; higher ratios result in triple layers. Low viscosity ratios ηD/ηC ≤ 5 and low PFC volume fractions lead to smaller monodisperse droplets.
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o

The cellular Potts model on disordered lattices

Soft Matter, 2024, 20,8337-8352
DOI: 10.1039/D4SM00445K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hossein Nemati, J. de Graaf
Extending the cellular Potts model to disordered Voronoi lattices reduces artifacts observed on regular lattices. An order–disorder transition is observed as a function of surface tension on the disordered lattice and the regular lattices.
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Chemo-mechanical model of cell polarization initiated by structural polarity

Soft Matter, 2024, 20,8407-8419
DOI: 10.1039/D4SM00800F, Paper
Hexiang Wang, Zhimeng Jia, Yuqiang Fang
We establish a multiscale model of a cell to explore the chemomechanical mechanisms of cell polarization initiated by structural polarity. The two-dimensional vertex model is built by coupling the cytoskeletal reorganization and the Cdc42 activation.
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o

Bubbles and drops between circular frames: shape, force and stability analysis

Soft Matter, 2024, 20,8420-8435
DOI: 10.1039/D4SM00919C, Paper
Open Access
Friedrich Walzel, Jonathan Dijoux, Leandro Jacomine, Élodie Harle, Pierre Muller, Thierry Charitat, Wiebke Drenckhan
Combining experiments, simulations and theory, we provide a complete shape analysis of two bubbles held by circular frames in the parameter space of different frame radii, distances between frames and contact angle between bubbles (0°, 60° and 90°).
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o

Controlling wall–particle interactions with activity

Soft Matter, 2024, 20,8395-8406
DOI: 10.1039/D4SM00634H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Luke Neville, Jens Eggers, Tanniemola B. Liverpool
The interaction between a disk and wall in an active nematic depends on a combination of activity and anchoring, with contractile nematics repelling disks with planar anchoring.
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o

Nanoconfinement effects on the dynamics of an ionic liquid-based electrolyte probed by multinuclear NMR

Soft Matter, 2024, 20,8436-8445
DOI: 10.1039/D4SM01058B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Andrei Filippov, Maiia Rudakova, Victor P. Archipov, Faiz Ullah Shah
Diffusivity is controlled by exchange of ions between “narrow” and “large” pores that results in an abnormal temperature variation. Li+ ions are solvated inside the porous glasses and their diffusivity remains slower as compared to the organic ions.
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Development of a coarse-grained molecular dynamics model for poly(dimethyl-co-diphenyl)siloxane

Soft Matter, 2024, 20,8480-8492
DOI: 10.1039/D4SM00875H, Paper
Weikang Xian, Amitesh Maiti, Andrew P. Saab, Ying Li
Polydimethylsiloxane and its copolymer systems have a wide range of application. We systematically develop a coarse-grained MD model for PDMS-co-PDPS system. The model preserves the structural and dynamic properties of the material quantitatively.
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o

Effective patchiness from critical points of a coarse-grained protein model with explicit shape and charge anisotropy

Soft Matter, 2024, 20,8455-8467
DOI: 10.1039/D4SM00867G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jens Weimar, Frank Hirschmann, Martin Oettel
Critical points of an anisotropic, coarse-grained protein model are used to detemine an “effective patchiness” by comparison to the Kern–Frenkel patchy model.
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The surface diffusivity of nanoparticles physically adsorbed at a solid–liquid interface

Soft Matter, 2024, 20,8446-8454
DOI: 10.1039/D4SM00992D, Paper
Troy Singletary, Nima Iranmanesh, Carlos E. Colosqui
This work proposes an analytical model considering the effects of hydrodynamic drag and energy barriers induced by liquid solvation forces to predict the in-plane translational diffusivity of a nanoparticle physically adsorbed on a wetted surface.
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Segregative phase separation of strong polyelectrolyte complexes at high salt and high polymer concentrations

Soft Matter, 2024, 20,8505-8514
DOI: 10.1039/D4SM00994K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Conner H. Chee, Rotem Benharush, Lexi R. Knight, Jennifer E. Laaser
Complexes of strong polyelectrolytes prepared well above the binodal are shown to undergo hydrophobicity-driven segregative phase separation.
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Self-assembly of amphiphilic homopolymers grafted onto spherical nanoparticles: complete embedded minimal surfaces and a machine learning algorithm for their recognition

Soft Matter, 2024, 20,8385-8394
DOI: 10.1039/D4SM00616J, Paper
D. A. Mitkovskiy, A. A. Lazutin, A. L. Talis, V. V. Vasilevskaya
Amphiphilic macromolecules grafted onto spherical nanoparticles can self-assemble into morphological structures corresponding to the family of complete embedded minimal surfaces. They arise situationally, can coexist and transform into each other.
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o

Optimality and cooperativity in superselective surface binding by multivalent DNA nanostars

Soft Matter, 2024, 20,8515-8523
DOI: 10.1039/D4SM00704B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christine Linne, Eva Heemskerk, Jos W. Zwanikken, Daniela J. Kraft, Liedewij Laan
Our study shows that DNA nanostars with three binding sites (ligands) can (1) bind superselectively to surfaces based on receptor density, and (2) that interactions between ligands affect the optimum number of ligands required for superselectivity.
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o

Random field reconstruction of three-phase polymer structures with anisotropy from 2D-small-angle scattering data

Soft Matter, 2024, 20,8493-8504
DOI: 10.1039/D4SM00721B, Paper
Open Access
Stephen Kronenberger, Nitant Gupta, Benjamin Gould, Colin Peterson, Arthi Jayaraman
We present a computational method to analyze 2D small-angle scattering data from three-phase soft materials systems with structural anisotropy and output representative real-space structures of the three phases.
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o

Strain rate controls alignment in growing bacterial monolayers

Soft Matter, 2024, 20,8468-8479
DOI: 10.1039/D4SM00625A, Paper
Blake Langeslay, Gabriel Juarez
A model of cell alignment in confined growing bacterial monolayers connecting net monolayer deformation to the behavior of individual cells.
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o

Cell shape and orientation control galvanotactic accuracy

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00952E, Paper
Ifunanya Nwogbaga, Brian A. Camley
We study the physical factors that control the accuracy with which elongated cells can sense the direction of an electric field, exploring whether cells are more accurate sensors when oriented parallel to the field or perpendicular to it.
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Mechanical characterization of freestanding lipid bilayers with temperature-controlled phase

Soft Matter, 2024, 20,8524-8537
DOI: 10.1039/D4SM00706A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Arash Yahyazadeh Shourabi, Roland Kieffer, Djanick de Jong, Daniel Tam, Marie-Eve Aubin-Tam
Lipid membranes formed in a microfluidic device are studied with temperature-controlled optical tweezers, revealing how mechanical properties of ripple phase and gel-fluid phase-separated membranes change when heated above the transition temperature.
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pH and glucose dual-responsive phenylboronic acid hydrogels for smart insulin delivery

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM01004C, Paper
Keke Yang, Hou Bo, Dewei Ma, Mingwei Peng, Qinglong Liu, Ziwen Heng, Zhongwei Gu, Xuhan Liu, Siyuan Chen
Phenylboronic acid (PBA) is a widely exploited glucose-sensitive element for constructing glucose-responsive hydrogels to enable smart insulin delivery.
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o

Jamming crossovers in a confined driven polymer in solution

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00761A, Paper
Setarehalsadat Changizrezaei, Mikko Karttunen, Colin Denniston
A polymer confined in a nanochannel undergoes a crossover to a jammed state when pushed by a large spherical colloid. We examine the system using simulations that incorporate the full hydrodynamic driving and fluctuating forces.
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Retraction: Self-assembled organic nanotubes embedding hydrophobic molecules within solid bilayer membranes

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM90171A, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Naohiro Kameta, Masumi Asakawa, Mitsutoshi Masuda, Toshimi Shimizu
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Retraction: Supramolecular organic nanotubes: how to utilize the inner nanospace and the outer space

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM90172J, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Naohiro Kameta, Hiroyuki Minamikawa, Mitsutoshi Masuda
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Linking local microstructure to fracture location in a two-dimensional amorphous solid under isotropic strain

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00486H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Max Huisman, Axel Huerre, Saikat Saha, John C. Crocker, Valeria Garbin
Machine learning predicts possible crack location in experiments of a fracturing colloid monolayer, shown along with the actual crack path.
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Rolling and ordering of micro rods in shear flow induced by rod wall interactions

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00999A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Martin Wittmann, Igor M. Kulić, Antonio Stocco, Juliane Simmchen
We use experiments and theoretical models to investigate the rolling and translational motion of rod-shaped micro particles close to a solid wall in the presence or absence of shear flow.
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Modeling nematic phase main-chain liquid crystal elastomer synthesis, mechanics, and thermal actuation via coarse-grained molecular dynamics

Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D4SM00528G, Paper
Nicolas Herard, Raja Annapooranan, Todd Henry, Martin Kroger, Shengqiang Cai, Nicholas Boechler, Yelena Sliozberg
This paper presents a coarse-grained molecular dynamics simulation study of the synthesis, mechanics, and thermal actuation of nematic phase main-chain liquid crystal elastomers (LCEs), a type of soft, temperature-responsive, polymeric...
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Coupled dynamics in binary mixtures of model colloidal Yukawa systems

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM01123F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Daniel Weidig, Joachim Wagner
Self- and collective dynamics in mixtures of highly charged binary colloidal particles is analyzed by Brownian dynamics simulations. For equally charged, but differently sized particles coupling effects in their long-time dynamics are observed.
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o

Src kinase slows collective rotation of confined epithelial cell monolayers

Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D4SM00827H, Paper
Nastassia Pricoupenko, Flavia Marsigliesi, Philippe Marcq, Carles Blanch-Mercader, Isabelle A Bonnet
Collective cell migration is key during development, wound healing and metastasis and relies on coordinated cell behaviors at the group level. Src kinase is a key signalling protein for physiological...
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Enhanced gravitational trapping of bottom-heavy Janus particles over parallel microgrooves

Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D4SM00989D, Paper
Yan Wen, Jiayu Liu, Wei Wang, Pik-Yin Lai, Penger Tong
We report a systematic study of barrier-crossing dynamics of bottom-heavy self-propelled particles (SPPs) over a one-dimensional periodic potential landscape $U_0(x)$, which is fabricated on a microgroove-patterned polydimethylsiloxane (PDMS) substrate. From...
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Thickness-dependent response of aerosol-jet-printed ultrathin high-aspect-ratio electrochemical microactuators

Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D4SM00886C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ji Zhang, Jeremy J. Baumberg, Sohini Kar-Narayan
Trilayer electrochemical actuators comprising an electrolyte layer sandwiched between two electrode layers have been shown to exhibit large deformations at low actuation voltages. Here we report aerosol-jet printing (AJP) of...
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Long-lived unidirectional flow of active particles within long narrow channels

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00879K, Paper
Man Xu, Ying Lan, Yuehua Yang, Hongyuan Jiang
We present the dynamics of particles in a device divided into two chambers by V-shaped barriers and connected by a narrow channel. Here three distinct movement modes occur, including stochastic movement, oscillation and unidirectional flows.
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Mapping deformation dynamics to composition of topologically-active DNA blends

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM01065E, Paper
Karthik R. Peddireddy, Ryan McGorty, Rae M. Robertson-Anderson
We leverage in situ enzymatic topological conversion and OpTiDDM to map the deformation dynamics of DNA blends with over 70 fractions of linear, ring and supercoiled molecules that span the phase space of possible topological compositions.
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Scale-dependent interactions enable emergent microrheological stress response of actin–vimentin composites

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00988F, Paper
Julie Pinchiaroli, Renita Saldanha, Alison E. Patteson, Rae M. Robertson-Anderson, Bekele J. Gurmessa
The unique mechanical behaviors of actin–vimentin composites in both linear and nonlinear regimes are shaped by the complex interactions among actin entanglements, vimentin crosslinking, and poroelastic properties.
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Liquid crystalline collagen assemblies as substrates for directed alignment of human Schwann cells

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00534A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Homa Ghaiedi, Luis Carlos Pinzon Herrera, Saja Alshafeay, Leonard Harris, Jorge Almodovar, Karthik Nayani
Collagen is a key component of the extracellular matrix (ECM) and well-oriented domains of collagen are important for mimicking the local cell environment in vitro. Here, we demonstrate macroscopic alignment on collagen in 2-D substrates and 3-D hydrogels.
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