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Holding building sites accountable for their actions

To combat air pollution New Delhi attempts to rein in construction and demolition waste




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UDAN scheme helps improve passenger footfall at Mysore Airport: Airport Director




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Vistara merger with Air India takes off, Group to now operate 300 aircraft




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Telangana: BR Naidu appointed TTD Board chairman




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Telangana government adopted Indiramma as role model: Revanth Reddy




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Telangana to strictly enforce prohibition on caging of birds




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Wish him long, healthy life: PM Modi on Revanth Reddy's birthday




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PM Modi, Spanish counterpart to launch C-295 aircraft facility in Vadodara on Monday




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PM Modi, Spanish Prez greet specially-abled girl as she gifts them portraits during Vadodara roadshow




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PM Modi virtually inaugurates new manufacturing plant of medical devices at Meril Company in Vapi




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Kerala Govt to foot hospital bills of people injured in temple fire




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Temple firecrackers blast: Kerala cabinet sanctions Rs 4 lakh compensation for next of kin of deceased




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Kerala first seaplane service to be launched at Kochi on Monday




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Seaplane tourism takes off in Kerala after first plane touches down




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Priyanka Gandhi offers prayers at Thirunelli temple where Rajiv Gandhi's ashes immersed




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Get Started in AI and NFTs with the Limewire API (Sponsored)

AI media creation has expanded to incredible video art and a host of other important improvements, and LimeWire is leading the way in creating an awesome interface for the average user to become an AI artist. Limewire has just released its Developer API, a method for engineers like us to create dynamic AI art on […]

The post Get Started in AI and NFTs with the Limewire API (Sponsored) appeared first on David Walsh Blog.




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Europa PIX: Maguire to Manchester United's rescue

IMAGES from the Europa League matches played on Thursday




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PIX: Spain's first transgender football team

Fenix's first game of the season on September 21 ended with a 19-0 defeat. But for its fans and players, trans men having the right to play their favourite sport on equal terms is far more important than the score.




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Kashmir Marathon: '42 kilometres in a paradise!'

Around 2000 runners, including 59 internationals athletes, took part in the inaugural Kashmir Marathon in Srinagar.




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PIX: Man United log first Europa League win

The win leaves United in 15th place in the Europa League standings on six points from four games.




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TRAI monthly data: BSNL gains subscribers in August on losses of Airtel, RJio, VIL

The three private players increased their tariffs by 11-25 per cent in July




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Elon Musk, Jeff Bezos’s satcom firms push for 1% spectrum charges

They have also sought a 20-year licence for providing satcom services




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Bharti Airtel Q2 preview: Consolidated net profit expected to grow multifold

According to analysts, industry-leading ARPU and support from other businesses bode well for Airtel’s revenue growth during the quarter




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Cyient acquires 27.3% stake in Azimuth AI

The investment aligns with India’s initiatives to boost domestic semiconductor innovation and follows Cyient’s establishment of a fully owned semiconductor subsidiary in July 2024




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Shashwat Sharma to take over as MD and CEO of Airtel from January 2026

Gopal Vittal to be Executive Vice-Chairman; Q2 consolidated net profit jumps 168 per cent YoY to ₹3,593 crore




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Airtel Q2 FY25 net profit jumps 168% YoY to ₹3,593 crore

Mobile ARPU increased to ₹233 in Q2 FY25 vs ₹203 in Q2 FY24




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Airtel’s new MD & CEO has spearheaded multiple innovations




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Cognizant’s Synapse skilling initiative impacts 275,000 individuals in its first year

The rapid progress of Synapse comes at a time when there is a growing desire from organisations to train and redevelop talent




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India’s Satcom landscape expands as global firms seek market entry

These companies have written to the Telecom Regulatory Authority of India expressing their willingness to launch satcom services in India




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IT sector records positive net hiring from top four firms for first time in two years

Despite this positive trend, industry experts caution that the current demand environment remains uncertain, and graduates have expressed frustrations over delayed joining dates 




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SaaS can help firms enhance their cybersecurity posture: CyberArk official

Contrary to common misconceptions, SaaS solutions will be helpful in managing complex IT environments, says Rohan Vaidya




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Tessolve to acquire German chip design company for up to ₹400 crore

It will expand Tessolve’s European operations by adding four delivery locations across Germany and the Netherlands, including a specialized ADAS and imaging centre-of-excellence lab




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Airtel expands with AI data centres and high-altitude network, shares rise 

Bharti Airtel’s subsidiary, Nxtra, becomes India’s first AI-powered data centre operator, while the company expands mobile connectivity to military outposts along the Indo-China border




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Elon Musk’s broadband ambitions in India: Why Jio and Airtel are feeling the heat

Tech advancements have made it possible for satcom players to offer data services directly to the users’ smartphones, bypassing traditional cellular operators altogether




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Airtel, Jio clash with Amazon, Starlink over satcom spectrum

Telcos bat for level playing field; satcom firms say customers have right to choose




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AppLovin CEO once spurned by VC firms now worth $11 billion

Shares of Palo Alto, California-based AppLovin have surged seven-fold this year, giving co-founder Adam Foroughi a net worth of $10.9 billion




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Ringing in their independence

On this day in 1776, the Liberty Bell rang out from the tower of the Pennsylvania State House.




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Bird brained

YW storyteller contest: We were flooded with stories for the YW Storyteller contest announced on June 24. Here are some of the entries that almost made it… Congratulations!




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Fine bubble technology for the green synthesis of fairy chemicals

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00237G, Paper
Arun Kumar Manna, Mizuki Doi, Keiya Matsuo, Hiroto Sakurai, Ch. Subrahmanyam, Kohei Sato, Tetsuo Narumi, Nobuyuki Mase
Fairy chemicals (FCs) such as 2-azahypoxanthine (AHX), isolated from naturally occurring sources, are potential phytohormones in plants and efficiently synthesized by fine bubble technology consisting of micro- to nano-sized bubbles.
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Metal- and light-free decarboxylative direct C–H alkylation of heteroarenes at room temperature

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00187G, Paper
Tong-Bo Zhang, Xi-Dong Guan, Yan Gao, Shi-Chao Lu, Bing-Long Li
This study reports a metal- and light-free decarboxylative C–H alkylation of heteroarenes at room temperature.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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A water mediated multicomponent reaction for the synthesis of novel spirooxindole derivatives and their antifungal activity

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00256C, Paper
Min Zhang, Liang Shi, Li Chen, Zhengyu Liu, Ting Zhao, Chunyin Zhu, Liuqing Yang
A total of 27 novel spirooxindoles were synthesized through a water mediated three-component reaction of isatin, 4-aminocoumarin, and 1,3-cyclodicarbonyl compounds. Several compounds showed excellent antifungal activity against Physalospora piricola.
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Diastereoselective synthesis of functionalized spiroindolines via intramolecular ipso-iodocyclization/nucleophile addition cascade reactions of indole-tethered ynones

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00112E, Paper
Debojyoti Bag, Sanghapal D. Sawant
Herein, we describe a highly diastereoselective approach for synthesizing polyfunctionalized spiroindolines from indolyl-ynones involving an ipso-iodocyclization/nucleophile addition cascade.
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Kinetic resolution of 1,1'-binaphthyl-2,2'-diamine derivatives by chiral calcium phosphate-catalyzed acylation

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00355A, Paper
Tatsuhiro Uchikura, Yuki Kanno, Yukino Fukuda, Mikoto Sato, Takahiko Akiyama
Chiral calcium phosphate-catalyzed kinetic resolution of BINAM derivatives.
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Chemoenzymatic total synthesis of rotigotine via IRED-catalyzed reductive amination

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00072B, Communication
Dongyu Tang, Yaqing Ma, Jinping Bao, Shushan Gao, Shuli Man, Chengsen Cui
An engineered imine reductase (IRED) was developed specifically for 2-tetralone substrate, and utilized in the total synthesis of rotigotine.
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Structural flexibility of favipiravir and its structural analogues in solutions: experimental and computational insight

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00404C, Paper
Tatiana P. Gerasimova, Almaz A. Zagidullin, Anastasiia N. Nikolaeva, Robert R. Fayzullin, Aliya M. Saitova, Vasili A. Miluykov, Stefan Grimme, Sergey A. Katsyuba
Keto-enol transformations of 6-R-3-hydroxy-2-pyrazinecarboxamides in solutions are accompanied by deprotonation of enol tautomers and the formation of corresponding anionic species. The key factors determining these processes have been identified.
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Recent advances in spirocyclization of maleimides via transition-metal catalyzed C–H activation

Org. Biomol. Chem., 2024, 22,2916-2947
DOI: 10.1039/D3OB01904G, Review Article
Swadhin Swaraj Acharya, Sagarika Patra, Rojalini Maharana, Manaswini Dash, Liza Mama Barad, Bibhuti Bhusan Parida
In recent years, the maleimide scaffold has received a great deal of attention in C–H activation.
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Iron-catalyzed selective construction of indole derivatives via oxidative C(sp3)–H functionalization of indolin-2-ones

Org. Biomol. Chem., 2024, 22,3073-3079
DOI: 10.1039/D4OB00133H, Paper
Wei Chen, Lang-Qi Wen, Xiao-Bing Lu, Hui Zhou
We have developed a clean and efficient iron-catalyzed C(sp3)–H functionalization of indolin-2-ones for the chemodivergent synthesis of value-added indole derivatives, including isatins, and symmetrical and non-symmetrical isoindigos.
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Direct access to pyrrole anhydrides via oxidative self-coupling of pyrrole carboxaldehydes

Org. Biomol. Chem., 2024, 22,3045-3052
DOI: 10.1039/D4OB00052H, Paper
Surabhi Panday, Tapas Maity, Pratibha Bhatti, Joydev K. Laha
An elegant synthesis of pyrrole-2-carboxylic acid anhydrides from pyrrole-2-carboxaldehydes using TBAI as a catalyst and tert-butyl hydroperoxide (TBHP) as an oxidant is described herein.
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BBr3-mediated dearomative spirocyclization of biaryl ynones: facile access to spiro[5.5]dienones

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00274A, Communication
Gaurav Jaiswal, Subhas Chandra Pan
BBr3 mediated dearomative spirocyclization of biaryl ynones has been reported for the direct synthesis of spiro[5.5]dienones with a tri-substituted double bond.
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Photoproperties of Favipiravir and their 6-Substituted Analogues: Fluorescence Controlled through Halogen Substitution and Tautomerism

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00397G, Paper
Angel H Romero, Marcos Couto, Ivan E Romero, German Fuentes, Matías N. Möller
Herein, we showed the photophysical properties of the favipiravir and their 6-substituted analogues. Also, we interpreted the origin of the fluorescence of the favipiravir and their 6-substituted analogues as function...
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