o Palladium-catalyzed hydrocarbonylative cross-coupling with two different alkenes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01312C, Research ArticleYi Chen, Jianing Wu, Yongzheng Ding, Hanmin HuangTransition metal-catalyzed hydrocarbonylation of alkenes has been widely studied; however, the hydrocarbonylation reaction that took place between two alkenes has been largely unexplored.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o I2-Promoted oxidative annulation of three different amines to access diverse biheteroaryls By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01801J, Research ArticleGuangping Fan, Penghui Cao, Fang Bai, Yanyan Yin, Xueyan Hou, Yani Liu, Zhenzhen Xing, Yanhui Wang, Tangqiang Sun, Qinghe GaoAn I2-promoted oxidative annulation of three different amines enables the assembly of nonsymmetrical 2,2'-biquinolines and related bis-azines through a [4π + 2σ] annulation reaction.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o HSAB theory guiding electrophilic substitution reactions of o-carborane By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01546K, Research ArticleYan Wang, Yi-Ge Li, Feijing Chen, Yan-Na Ma, Xuenian ChenHerein, we systematically compared the reactivity of o-carborane and benzene toward different electrophiles and explained the results with the HSAB principle.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Facile one-pot synthesis of novel imidates as multifunctional organic fluorescent materials By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01628A, Research ArticleFeng-Ting Liu, Shuo Wang, Yong-Shun Chen, Jun-Ying Miao, Bao-Xiang Zhao, Zhao-Min LinA novel one-pot synthesis of multifunctional organic fluorescent imidates from quinolinium salt derivatives, nitrosoarenes and alcohols was presented. This method had a wide substrate scope and excellent isolated yields.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o General ppm-level Pd-catalysed asymmetric diarylalkyne hydrosilylation to access structurally diverse Si-stereogenic vinylsilanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01698J, Research ArticleHeng Xu, Han-Xiao Yu, An-Jiu Wen, Fang-Ying Ling, Fei Ye, Li Li, Fuk Yee Kwong, Li-Wen XuThe first example of enantioselective Pd-catalyzed hydrosilylation of symmetric and asymmetric diarylalkynes to access novel Si-stereogenic vinylsilanes with excellent ee and a high TON is realized under mild reaction conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Mechanistic insight into the dehydrogenation reaction catalyzed by an MLC catalyst with dual ancillary ligand sites By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01767F, Research ArticleGui-Xiang Zhou, Cheng HouThis study reveals a mechanism in which a ruthenium complex catalyst improves catalytic efficiency and lowers the energy barrier in the dehydrogenation of benzyl alcohol by dynamically switching ligand sites.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Metal-free visible-light-induced borylative/silylative pyridylation of vinylarenes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01702A, Research ArticleYiting Zhou, Bin LiuWe present a metal-free and mild three-component reaction involving vinylarenes, NHC–BH3 complexes, hydrosilanes, and 4-cyanopyridine. Remarkably, this reaction was performed with simple and inexpensive benzophenone.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Palladium-catalyzed synthesis of indene-1-acetates via sequential double carbopalladation and aryloxycarbonylation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01570C, Research ArticleFei Sun, Yiyi Zheng, Zhongyao Jiang, Mingxia Wu, Zeng Lv, Hongsen Ji, Xin-Xing WuA novel palladium-catalyzed cascade reaction of o-iodostyrenes, internal alkynes and formates to access various indene-1-acetates through sequential double carbopalladation and aryloxycarbonylation under a palladium/air system was developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Synthesis of bambusurils with perfluoroalkylthiobenzyl groups as highly potent halide receptors By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01746C, Research Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Matúš Chvojka, Hennie Valkenier, Vladimír ŠindelářFour new fluorinated bambusuril macrocycles were prepared to show exceptional high binding affinity towards halide anions in acetonitrile.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Photocatalytic arylation/alkylation of olefins/alkynes via halogen-atom transfer mediated by NHC-BH3 By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01562B, Research ArticleXinhan Li, Yao Zhong, Fengsong Tan, Yusong Fei, Xiaohan Zhao, Jianbin Xu, Baomin FanA versatile method for radical reductive cross-coupling of iodides and activated olefins under mild conditions, facilitated by NHC-BH3 through photocatalysis, was developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Stereoselective access to furan-fused [5.5.0] bicyclic heterocycles enabled by gold-catalyzed asymmetric [8 + 4] cycloaddition By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01841A, Research ArticleXunhua Wang, Jianhua Wang, Xiaoxun LiA gold-catalyzed asymmetric [8 + 4] cycloaddition was developed to afford highly functionalized furan/pyrrole-fused [5.5.0] polycyclic heterocycles with good diastereo- and enantioselectivity.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Photoinduced cobaloxime catalysis for allylic mono- and diphosphinylation of alkenes with hydrogen evolution By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01638F, Research ArticleAijun Zhang, Miao-Miao Li, Lei Guo, Huaixiang Yang, Jiefei Guo, Da Xu, Wei DingA highly efficient allylic radical mono- and diphosphinylation of alkenes with secondary phosphine oxides is developed, via visible-light-induced cobaloxime catalysis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o The reactivity of alkenyl boron reagents in catalytic reactions: recent advances and perspectives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01703J, Review ArticleYa-Li Feng, Bo-Wen Zhang, Youzhi Xu, Shengnan Jin, Daniele Mazzarella, Zhong-Yan CaoRecent advances focusing on novel reactivity of alkenyl boron reagents in polar or radical pathways within catalytic reactions by employing transition metal catalysis, organocatalysis have been summarized and discussed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Impact of boron desymmetrization on supramolecular polymerization of BODIPY dyes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01848F, Research Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Tobias B. Tischer, Zulema Fernandez, Lorenz Borsdorf, Constantin Daniliuc, Shigehiro Yamaguchi, Soichiro Ogi, Gustavo FernandezSupramolecular polymers are often investigated for highly symmetric and planar molecules, such as typically explored BF2-substituted BODIPY dyes . However, it is surprising that the possibility of desymmetrizing the sp3...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Visible-light mediated selective phosphonylation modification of tryptophan residues in oligopeptides By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6287-6292DOI: 10.1039/D4QO01028K, Research ArticleWenfang Xiong, Junye He, Jinyao Liu, Peiru Chen, Shiqi Xu, Yipeng Liu, Shiting Chen, Yuanyuan You, Zhenyu Chen, Jinwu ZhaoA direct C2-H phosphonylation strategy driven by visible light for specific modification of tryptophan-containing peptides has been reported, providing a plethora of phosphorylated tryptophan-containing peptidesThe content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Towards the total synthesis of mandelalide B: construction of the tetrahydrofuran/α-hydroxyl lactone fragment By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6353-6357DOI: 10.1039/D4QO01433B, Research ArticleJia-Lei Yan, Jie Yu, Yingying Cheng, Mingze Yang, Zhengshuang Xu, Tao YeA stereocontrolled synthesis of the tetrahydrofuran/α-hydroxy lactone fragment of mandelalide B has been accomplished. The synthesis features a Horner-Wadsworth-Emmons fragment assembly strategy and a highly stereospecific iodine-induced cyclization.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Total synthesis of spiro Ganoderma meroterpenoids spiroapplanatumines B, D, F, and H By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6333-6339DOI: 10.1039/D4QO01147C, Research ArticleJia-Hao Zhang, Wen-Cai Luo, Wen-Tao Chen, Yu-Tao He, Ya-Jian HuThe first total synthesis of spiroapplanatumines B, D, F, and H as well as the possibly undiscovered natural product spiroapplanatumine R has been achieved.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Pd-catalyzed S-glycosylation of cysteine-containing peptides at room temperature By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6347-6352DOI: 10.1039/D4QO01389A, Research ArticleLinhua Shen, Franck Le Bideau, Gong Chen, Samir MessaoudiThis study reports the synthesis of thioglycopeptides via a Pd-catalyzed coupling of cysteine-containing peptides with iodoglycals. A variety of cysteine-containing peptides and other thiol nucleophiles including thiosugars and thiophenols were used.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Visible-light excited copper activating unactivated alkyl iodides for radical addition/cyclization to access oxindole derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6380-6384DOI: 10.1039/D4QO01329H, Research ArticleHang Luo, Fangnian Yu, Luqing LinThe photocopper catalyst facilitates halogen atom transfer to give unactivated alkyl radicals, which is critical for achieving radical cyclization in the absence of an exogenous photocatalyst.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Iridium/palladium dual photocatalysis for oxidative decarboxylative esterification of alcohols using α-keto acids By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6367-6379DOI: 10.1039/D4QO01452A, Research ArticleSubal Mondal, Soumya Mondal, Debabrata Halder, Siba P. Midya, Ankan Paul, Pradyut GhoshHerein, we report an unprecedented oxidative decarboxylative C–O cross-coupling reaction for the esterification of feedstock α-keto carboxylic acids and alcohols under mild conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Transition-metal-catalyzed regiodivergent sulfonylation of aziridrines for the synthesis of β-amino sulfones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6340-6346DOI: 10.1039/D4QO01376J, Research ArticleQinqiong Zeng, Yujia Gong, Xiaochun He, Xuemei Zhang, Zhong LianWe developed the first transition-metal-catalyzed, regiodivergent sulfonylation of aziridines, enabling the efficient synthesis of diverse β-amino sulfones under mild conditions with broad substrate compatibility and high regioselectivity.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Structure determination of difficult-to-crystallize organic molecules by co-crystallization of a phosphorylated macrocycle By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6358-6366DOI: 10.1039/D4QO01498G, Research ArticleHeng Li, Zhijin Li, Juli Jiang, Chen Lin, Leyong WangThis work reported that 37 different difficult-to-crystallize guest molecules were co-crystallized with the host macrocycle F[3]A1-[P(O)Ph]3 at room temperature, and the molecular structures of the guests could be determined by SCXRD.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Phosphine-controlled divergent reactions of MBH-carbonates with azaheptafulvenes: access to o-anilinyl diene and benzazepine derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6418-6425DOI: 10.1039/D4QO01298D, Research ArticleWei Hao, Yiwen Zhang, Xiao Han, Zhen Wang, Weijun YaoA phosphine controlled divergent cascade reaction of MBH-carbonates with azaheptafulvenes was disclosed. PPh3 provided o-aminophenyl diene while PCy3 offered benzazepine derivative through formal [8 + 3] annulation/ring contraction cascade.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o A cucurbit[8]uril-mediated host–guest complex for red-light photocatalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6327-6332DOI: 10.1039/D4QO01492H, Research ArticleWeiquan Xu, Yinghao Du, He Ma, Xingchen Tang, Jiang-Fei Xu, Xi ZhangTwo-step host–guest complexation can occur between an elongated dye and CB[8], leading to the formation of CB[8]@2TPP and 3CB[8]@2TPP sequentially. Of these species, 3CB[8]@2TPP in particular can act as an efficient red-light photocatalyst.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o 18F-labelling of nitrogen-containing aryl boronates – anti-cancer drug melflufen as a case study By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6411-6417DOI: 10.1039/D4QO01594K, Research Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kevin Bajerke, Fredrik Lehmann, Gunnar Antoni, Kálmán J. SzabóThis study addresses the 18F-labelling of nitrogen-containing arenes via copper-mediated radiofluorination (CMRF). In this case study, derivatives/fragments of the anti-cancer drug melflufen were targeted.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Chiral synthetic unprecedented spiro[indoline-2,3'-thiophen]-3-ones via an organocatalytic asymmetric sulfa-Michael/aldol cascade reaction By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6426-6436DOI: 10.1039/D4QO01551G, Research ArticleMao Zhang, Xing-Hai Fei, Gui-Ping Yang, Cheng Lin, Wen-Jie Li, Ming-Liang Rao, Meng Zhou, Chong Zhao, Bin He, Yong-Long ZhaoA cinchona-derived squaramide-catalyzed asymmetric sulfa-Michael/aldol cascade reaction of 2-ylideneoxindoles with 1,4-dithiane-2,5-diol was developed to realize the chiral synthesis of spiro[indoline-2,3'-thiophen]-3-ones.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Visible light-induced aerobic photooxidative cleavage of C(sp3)–C(sp2) σ-bonds of allylarenes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6385-6392DOI: 10.1039/D4QO01243G, Research ArticleJinyu Tang, Xi Zhao, Jinxuan Ni, Yanping Huo, Yang Gao, Xianwei Li, Yan Liu, Keiji Maruoka, Qian ChenA cleavage of C(sp3)–C(sp2) σ-bonds of allylarenes to aromatic aldehydes and ketones has been achieved via a visible light-induced photocatalysis.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Asymmetric synthesis of (aza)flavanones by the evolution of CarOx ligands By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6444-6449DOI: 10.1039/D4QO01345J, Research ArticleJuan Yang, Wenlong Kong, Mingxin Chang, Jixing Lai, Shengkun LiAmino-pyridine-oxazoline (NHPyOx) is conceived as an unprecedented model via the core-emulating optimization of CarOx ligands.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Well-defined chiral dinuclear copper-catalyzed tandem asymmetric propargylic amination–carboxylative cyclization sequence toward chiral 2-oxazolidinone derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6319-6326DOI: 10.1039/D4QO01368A, Research ArticleYu Lan, Peng Liu, Zekai Fang, Lili Shao, Qilong Cai, Xiaoming WangA variety of chiral 2-oxazolidinones was obtained via a dinuclear copper-catalyzed asymmetric propargylic amination–carboxylative cyclization sequence of propargylic esters with alkyl amine hydrochlorides and CO2.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Theoretical insights into Pd-catalyzed dual γ-1,1-C(sp3)–H activation of aliphatic carboxylic acids: mechanistic pathways, substituent influence on product selectivity, diastereoselectivity, and additive effects By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6393-6410DOI: 10.1039/D4QO01451K, Research ArticleJiaoyang Liu, Li-juan Huang, Zeang Sun, Juan LiDFT calculations were employed to explore the detailed reaction mechanism and the origins of the experimentally observed product, regio-, and diastereoselectivities in the Pd-catalyzed dual-γ-1,1-C(sp3)–H activation of aliphatic carboxylic acids.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o A pillar[5]arene-based three-component supramolecular copolymer for the fluorescence detection of spermine By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6293-6303DOI: 10.1039/D4QO01470G, Research Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Martina Mazzaferro, Daniele Crisafulli, Francesca Mancuso, Marco Milone, Fausto Puntoriero, Anna Irto, Salvatore Patanè, Valentina Greco, Alessandro Giuffrida, Ilenia Pisagatti, Anna Notti, Melchiorre F. Parisi, Giuseppe GattusoA supramolecular copolymer, composed of a bis-pillar[5]arene diacid and complementary alkylidene- and perylene-bisimide-bis-imidazole comonomers, acts as an OFF/ON luminescent sensor for spermine.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Design, synthesis and application of bipyridine-N,N'-dioxide catalysts in asymmetric synthesis of chiral cyclopropanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6470-6476DOI: 10.1039/D4QO01532K, Research ArticleXiaoying Cao, Xue Tian, Minmin Liu, Shi-Wu LiA novel type of highly efficient chiral C2-symmetric bipyridine-N,N'-dioxide ligands was prepared and successfully applied in the synthesis of optically pure 1,2,3-trisubstituted cyclopropanes.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o A general method for E-selective olefination of acylsilanes with isocyanides via silver catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6450-6458DOI: 10.1039/D4QO01528B, Research ArticleXiu-Xia Liang, Dan-Ni Yang, Xiao-Hui Yan, Peng Wang, Man-Yi HanA silver-catalyzed olefination reaction between acylsilanes and isocyanides is developed, resulting in E-vinylsilanes with good yields and high stereoselectivities.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Visible-light-promoted catalytic epoxidation of alkenes under metal-free conditions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6437-6443DOI: 10.1039/D4QO01265H, Research ArticleDabao Tan, Xiaoyan Cai, Lele Zhang, Boyu Liu, Jianbin Zeng, Feiming Li, Zhixiong Cai, Mingqiang Huang, Xiaoping Chen, Shunyou CaiIn this work, we report a method for the synthesis of functionalized epoxy analogues using the synergistic interaction of 4CzIPN and oxygen under visible light stimulation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Nickel-catalysed enantioselective cross-electrophile coupling reaction with the retention of the β-fluorine atom By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6459-6469DOI: 10.1039/D4QO01555J, Research ArticleXin-Yi Shi, Xueyuan Yan, Xiaodong Tang, Shi-Jing Zhai, Genping Huang, Jun-An Ma, Fa-Guang ZhangA nickel-catalysed enantioselective reductive cross-coupling reaction of a new monofluoromethyl building block with acid chlorides is developed to give chiral α-monofluoromethyl acyloin derivatives.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Activation of donor–acceptor cyclopropanes under basic conditions: ring opening of 2-(p-siloxyaryl)cyclopropane 1,1-dicarboxylates with nitro compounds and other C-nucleophiles By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6483-6494DOI: 10.1039/D4QO01472C, Research ArticleYulia A. Antonova, Andrey A. TabolinA new activation mode for donor–acceptor cyclopropanes was proposed and implemented in their reaction with nitro compounds and other common C-nucleophiles.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Electrochemical approach for upgrading the pollutant CS2: three-component N–H thiocarbamylation of sulfoximines By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6477-6482DOI: 10.1039/D4QO01310G, Research ArticlePeng Qian, Wenjing Xiong, Qian Meng, Jinxiu Liu, Xiyuan Li, Liangquan ShengWe report an electrochemical approach for upgrading the pollutant CS2via the thiocarbamylation of sulfoximines, in which CS2 and amines are incorporated as a readily available source of dithiocarbamate.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Carbonate-assisted selectively deoxygenative cross-coupling reaction between aryl and aliphatic aldehydes: a straightforward route to access α-alkylated aryl ketones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6510-6517DOI: 10.1039/D4QO01517G, Research ArticleYu Sun, Yi Wang, Zhijun ZuoA novel reductive cross-coupling reaction of two different aldehydes for rapidly assembling α-alkylated aryl ketones has been developed. The inexpensive carbonate served not only as a base but also as an efficient electron donor.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Anomalous magnetic behaviour induced by a structural phase transition with anisotropic thermal expansion in a spirodiradical By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6495-6502DOI: 10.1039/D4QO01098A, Research Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Takuya Kanetomo, Daigo Matsunaga, Shinichi Ogawa, Masaya EnomotoA Ge-centred spirodiradical exhibited anomalous magnetic behaviour, influenced by two key structural factors: negative thermal expansion and a structural phase transition.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Sulfenylation of bioactive maleimides, acrylates and cyclohexenones under ambient organophotocatalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6503-6509DOI: 10.1039/D4QO01342E, Research ArticleDebanjana Bag, Rajjakfur Rahaman, Anindya S. Manna, Subhasis Pal, Rajesh Nandi, Shobhon Aich, Narendra Nath Ghosh, Dilip K. MaitiA novel visible light-induced sulfenylation of biologically important maleimides, acrylates and cyclohexenones has been developed using cheap and easily available organophotoredox catalyst Eosin Y with thiols under ambient conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Cobalt-catalyzed enantioselective reductive addition of ketimine with cyclopropyl chloride to construct chiral amino esters bearing cyclopropyl fragments By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6311-6318DOI: 10.1039/D4QO01474J, Research ArticleJiangtao Hu, Tingting Xia, Xianqing Wu, Hongrui Feng, Jingping Qu, Yifeng ChenCo-catalyzed asymmetric reductive addition of ketimine with cyclopropyl chloride has been realized to access diverse chiral amino esters bearing cyclopropyl fragments with broad functional group tolerance and excellent enantioselectivities.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Transition-metal-catalyzed C–Ge coupling reactions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6558-6572DOI: 10.1039/D4QO01637H, Review ArticleJie Ke, Cadmus Du Chen, Li-Qing Ren, Bing Zu, Bin Li, Chuan HeThis review covers the development and recent progress in transition-metal-catalyzed C–Ge coupling reactions. The goal is to provide a clear overview of the field, identify current challenges, and inspire further applications in this growing area.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Recent developments in the ring-opening transformations of gem-difluorocyclopropanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6518-6533DOI: 10.1039/D4QO01583E, Review ArticleLeiyang Lv, Junqi Su, Zhiping LiThis review summarizes the advances of gem-F2CPs as fluoroallylic synthons in transition metal-catalysed ring-opening/cross-coupling reactions via single, double or no C-F bond cleavage on the last two years.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Shining light on sulfonium salts and sulfur ylides: recent advances in alkylation under photoredox catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6573-6588DOI: 10.1039/D4QO01644K, Review ArticleZhe Jin, Tingwei Yu, Hui Wang, Penghao Jia, You HuangRecent advancements in photoredox alkylation with sulfur ylides, sulfonium salts and related analogues are summarized in this review.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Dendron-mediated control over self-assembly of chlorophyll rosettes into columnar vs. discrete aggregates By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6304-6310DOI: 10.1039/D4QO01629G, Research Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ryo Kudo, Hiroki Hanayama, Balaraman Vedhanarayanan, Hitoshi Tamiaki, Nobuyuki Hara, Sarah E. Rogers, Martin J. Hollamby, Biplab Manna, Koji Harano, Shiki YagaiBy controlling the π-π stacking of chlorophyll supramolecular rosettes through steric hindrance of alkyl dendrons, it become possible to create chlorophyll tubes and discrete rings that resemble to natural chlorophyll assemblies.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Recent advances in asymmetric synthesis of chiral benzoheterocycles via Earth-abundant metal catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6534-6557DOI: 10.1039/D4QO01686F, Review ArticleJinhui Cai, Wenting Zhang, Usman Muhammad, Weishuang Li, Yanjun XieThis review mainly focus on the assembly of chiral benzoheterocycles, such as dihydrobenzofurans, chromans, indolines, tetrahydroquinolines, etc., via Earth-abundant metal-catalyzed (Cu, Fe, Ni, and Ti) asymmetric synthesis in the last few decades.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o LiTMP-LiBr complex-induced lateral lithiation and cross ester condensation: direct access to isocoumarins from 2-methoxy o-toluate esters By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01678E, Research Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Mintu Rehman, Sajib Daimary, Rasajna Madhusudhana, Rajendar GoretiLiTMP-LiBr complex promotes cross-ester coupling of 2-methoxy o-toluate esters to directly yield isocoumarin is demonstrated. Method applied to many natural product precursors including synthesis of (+)- and (−)-lunatinins.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o A two-step Kinugasa/Conia-ene-type sequential reaction for the asymmetric synthesis of 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01388C, Research ArticleShanyue Li, Qicai Ma, Bohua Wu, Haowen Ma, Wei Zhou, Qian CaiA two-step Kinugasa/Conia-ene-type sequential reaction is developed. The process provided a simple and efficient access to chiral 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Copper-catalyzed alkynyldisulfuration of arynes: an efficient access to unsymmetrical disulfides By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01844C, Research ArticleShuai Huang, Yumin Zhang, Yuekai Li, Chen-Ho Tung, Xin Li, Zhenghu XuThis article investigates a copper-catalyzed alkynyl disulfuration reaction of aryne formed in situ to synthesize o‑alkynyl aryl disulfides. The transformation proceeds through the in situ generation of aryne, followed by...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
o Enantioselective Addition of 3-hydroxyquinolin-2(1H)-one to Isatin and Pyrazole-4,5-dione Derived Ketimines By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01895H, Research ArticleYue Wei, Guishun Bai, Jiamin Wu, Yi Hua, Tao Zhang, Congyong Yue, Hong Wang, Xiaoze BaoThe enantioselective reactivity of 3-hydroxyquinolin-2(1H)-ones was developed through their addition to isatin and pyrazole-4,5-dione derived ketimines, affording novel architectures featuring multiple natural products scaffolds in high yield with excellent enantioselectivities....The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
