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Synthesis of lignin-functionalized phenolic nanosphere supported Ag nanoparticles with excellent dispersion stability and catalytic performance

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04311J, Paper
Shilin Chen, Guanhua Wang, Wenjie Sui, Ashak Mahmud Parvez, Chuanling Si
This work presents a novel and green lignin-based nanocomposite and highlights the synergism of lignin's multiple functions (surfactant, sacrificial template, and reducing agent) in the material preparation process.
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One-pot hydrodeoxygenation of biomass furan derivatives into decane under mild conditions over Pd/C combined with phosphotungstic acid

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00428F, Paper
Song Li, Long Yan, Qiying Liu, Jianguo Liu, Qiyu Liu, Wei Fan, Xuelai Zhao, Xinghua Zhang, Chenguang Wang, Longlong Ma, Qi Zhang
One-pot hydrodeoxygenation of δ-furfurylidenelevulinic acid over Pd/C combined with phosphotungstic acid through successive hydrogenolysis and HDO of furans and lactones.
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Water Effects in the Heterogeneous Catalytic Valorization of Levulinic Acid into γ-Valerolactone and its Derivatives

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01082K, Critical Review
Rengui Weng, Zhihao Yu, Jian Xiong, Xuebin Lu
Levulinic acid (LA), which has been hailed as a versatile biomass-derived platform molecular, typically occupy a core position in the cellulosic biorefinery system. The heterogeneous catalytic valorization of LA for...
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Ni-Catalyzed hydrocyanation of alkenes with formamide as the cyano source

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04275J, Communication
Xiao Shu, Yuan-Yuan Jiang, Lei Kang, Luo Yang
A novel Ni-catayzed hydrocyanation of various alkenes to provide aliphatic nitriles is developed by generating hydrocyanic acid in situ from safe and readily available formamide.
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New biobased-zwitterionic ionic liquids: efficiency and biocompatibility for the development of sustainable biorefinery processes

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC01002B, Paper
Gaël Huet, Monica Araya-Farias, Ranim Alayoubi, Sylvain Laclef, Benjamin Bouvier, Isabelle Gosselin, Christine Cézard, Romain Roulard, Matthieu Courty, Caroline Hadad, Eric Husson, Catherine Sarazin, Albert Nguyen Van Nhien
A combination of experiments and modeling reveals the influence of alkyl chain lengths in biobased ZILs on the biocompatibility towards various microorganisms.
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Ga/ZSM-5 catalyst improves hydrocarbon yields and increases alkene selectivity during catalytic fast pyrolysis of biomass with co-fed hydrogen

Green Chem., 2020, 22,2403-2418
DOI: 10.1039/C9GC03408K, Paper
Kristiina Iisa, Yeonjoon Kim, Kellene A. Orton, David J. Robichaud, Rui Katahira, Michael J. Watson, Evan C. Wegener, Mark R. Nimlos, Joshua A. Schaidle, Calvin Mukarakate, Seonah Kim
An integrated experimental and computational study to understand the catalytic upgrading of biomass vapors into high yield of alkenes.
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Synthesis of renewable C–C cyclic compounds and high-density biofuels using 5-hydromethylfurfural as a reactant

Green Chem., 2020, 22,2468-2473
DOI: 10.1039/D0GC00195C, Paper
Taimei Cai, Qiang Deng, Hailong Peng, Jin Zhong, Rui Gao, Jun Wang, Zheling Zeng, Ji-Jun Zou, Shuguang Deng
Renewable C–C six-membered ring compound and high-density biofuel are synthesized using 5-hydromethylfurfural as a reactant.
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Sustainability by design: automated nanoscale 2,3,4-trisubstituted quinazoline diversity

Green Chem., 2020, 22,2459-2467
DOI: 10.1039/D0GC00363H, Paper
Open Access
Mojgan Hadian, Shabnam Shaabani, Pravin Patil, Svitlana V. Shishkina, Harry Böltz, Alexander Dömling
Automated, one step, nanoscale synthesis of 2,3,4-trisubstituted quinazoline derivatives using positive pressure facilitated dispensing to access a very large chemical space exemplified by more than 1000 compounds.
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Novel insights into biomass delignification with acidic deep eutectic solvents: a mechanistic study of β-O-4 ether bond cleavage and the role of the halide counterion in the catalytic performance

Green Chem., 2020, 22,2474-2487
DOI: 10.1039/C9GC02569C, Paper
André M. da Costa Lopes, José R. B. Gomes, João A. P. Coutinho, Armando J. D. Silvestre
The potentiality of acidic deep eutectic solvents for β-O-4 ether bond cleavage is herein demonstrated from a mechanistic point of view.
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Efficient base-free oxidation of monosaccharide into sugar acid under mild conditions using hierarchical porous carbon supported gold catalysts

Green Chem., 2020, 22,2588-2597
DOI: 10.1039/C9GC04333K, Paper
Xintong Meng, Zengyong Li, Di Li, Yiming Huang, Jiaojiao Ma, Chuanfu Liu, Xinwen Peng
The highly selective synthesis of D-xylonic acid and D-gluconic acid from monosaccharide catalyzed by Au/NC-3 under base-free aerobic oxidation conditions.
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Direct C(sp3)–H acyloxylation of indolin-3-ones with carboxylic acids catalysed by KI

Green Chem., 2020, 22,2354-2358
DOI: 10.1039/C9GC04446A, Communication
Yong-Long Zhao, Yong-Qin Tang, Xing-Hai Fei, Fen-Fen Yang, Zhuo-Xian Cao, Dong-Zhu Duan, Qing-Jie Zhao, Yuan-Yong Yang, Meng Zhou, Bin He
The first KI-catalyzed direct acyloxylation of indolin-3-ones with carboxylic acids has been developed using 30% aq. H2O2 as a green oxidant at room temperature. Moreover, mechanism studies indicated that a radical oxidation process may be involved for this transformation.
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Synthesis of bioderived polycarbonates with adjustable molecular weights catalyzed by phenolic-derived ionic liquids

Green Chem., 2020, 22,2488-2497
DOI: 10.1039/D0GC00493F, Paper
Wei Qian, Lei Liu, Zengliang Zhang, Qian Su, Weizhen Zhao, Weiguo Cheng, Li Dong, Zifeng Yang, Ruibing Bai, Fei Xu, Yanqiang Zhang, Suojiang Zhang
Phenolic ionic liquid structure can be designed readily to control the molecular weight of isosorbide-derived polycarbonates.
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Fabrication of highly proton-conductive chitosan whole-bio-membrane materials functionalized with adenine and adenosine monophosphate

Green Chem., 2020, 22,2426-2433
DOI: 10.1039/C9GC04104D, Paper
Guanglei Zhao, Yuanyuan Chen, Xiao-Feng Li, Sihan Zhang, Yuanqiu Situ
A successful strategy to prepare novel proton-conductive chitosan membrane biomaterials functionalized with adenine and adenosine monophosphate via a one-pot grafting procedure.
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A non-phosgene process for bioderived polycarbonate with high molecular weight and advanced property profile synthesized using amino acid ionic liquids as catalysts

Green Chem., 2020, 22,2534-2542
DOI: 10.1039/D0GC00265H, Paper
Zhencai Zhang, Fei Xu, Yaqin Zhang, Chenhao Li, Hongyan He, Zifeng Yang, Zengxi Li
Bio-based polycarbonate with high molecular weight and advanced property profile was synthesized using amino acid ionic liquids as catalysts.
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Visible-light-induced photocatalyst-free C-3 functionalization of indoles with diethyl bromomalonate

Green Chem., 2020, 22,2543-2548
DOI: 10.1039/D0GC00292E, Paper
Guangmiao Gu, Mengmeng Huang, Jung Keun Kim, Jianye Zhang, Yabo Li, Yangjie Wu
A visible-light-induced and XB-promoted green approach to construct α-indolyl diethyl malonates was developed.
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Solvent-free and montmorillonite K10-catalyzed domino reactions for the synthesis of pyrazoles with alkynylester as a dual synthon

Green Chem., 2020, 22,2388-2393
DOI: 10.1039/D0GC00162G, Communication
Sesuraj Babiola Annes, Rajendhiran Saritha, Saravanan Subramanian, Bhaskaran Shankar, Subburethinam Ramesh
A highly regioselective, solvent-free and montmorillonite K10 clay-catalyzed domino process with an unprecedented C–C bond formation reaction is described for the synthesis of new class of tri-substituted and di-substituted pyrazole derivatives.
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Base-mediated benzannulation of α-cyanocrotonates with ynones: facile synthesis of benzonitriles and fluorenes

Green Chem., 2020, 22,2370-2374
DOI: 10.1039/D0GC00608D, Communication
Maneesh Kumar Reddy Singam, Attunuri Nagireddy, Sridhar Reddy Maddi
Benzonitriles and cyanofluorenes have been rapidly obtained via the [3 + 3] benzannulation of readily available alkynones and α-cyanocrotonates using KOtBu as the only reagent and EtOH (and CO2) is the only by-product.
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One-pot synthesis of 1,3-butanediol by 1,4-anhydroerythritol hydrogenolysis over a tungsten-modified platinum on silica catalyst

Green Chem., 2020, 22,2375-2380
DOI: 10.1039/D0GC00244E, Communication
Lujie Liu, Takehiro Asano, Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige
Chemical production of 1,3-butanediol from biomass-derived compounds was first reported by 1,4-anhydroerythritol hydrogenolysis over a Pt–WOx/SiO2 catalyst.
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Iridium-catalyzed orthogonal and regioselective synthesis of triazole disulfides in aqueous media under mild conditions

Green Chem., 2020, 22,2394-2398
DOI: 10.1039/D0GC00555J, Communication
Ming Li, Nan Zheng, Junhao Li, Yubin Zheng, Wangze Song
Triazole disulfides were prepared in water or biological media under mild conditions by orthogonal and regioselective Ir-catalyzed reactions.
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Using dialkyl amide via forming hydrophobic deep eutectic solvents to separate citric acid from fermentation broth

Green Chem., 2020, 22,2526-2533
DOI: 10.1039/C9GC04401A, Paper
Lijuan Liu, Qifeng Wei, Yong Zhou, Xiulian Ren
The separation of citric acids was realized by utilizing hydrophobic deep eutectic solvents (DESs), which were formed by using N,N-dibutylacetamide as a hydrogen acceptor and citric acid as the hydrogen bond.
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An entirely solvent-free photooxygenation of olefins under continuous flow conditions

Green Chem., 2020, 22,2359-2364
DOI: 10.1039/D0GC00436G, Communication
Patrick Bayer, Axel Jacobi von Wangelin
Photooxygenations of alkenes with singlet oxygen have been performed under solvent-free conditions in a flow reactor under VIS irradiation. The reaction operates at very high substrate/sensitizer ratios and enables high space–time yields.
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Properties and activity of Zn–Ta-TUD-1 in the Lebedev process

Green Chem., 2020, 22,2558-2574
DOI: 10.1039/D0GC00103A, Paper
Open Access
Guillaume Pomalaza, Pardis Simon, Ahmed Addad, Mickaël Capron, Franck Dumeignil
A zinc and tantalum-containing mesoporous silica catalyst highly active and selective in the Lebedev process has been prepared using the one-pot TUD-1 methodology. Characterization established a correlation between acidity and butadiene formation.
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Improving process efficiency of gold-catalyzed hydration of alkynes: merging catalysis with membrane separation

Green Chem., 2020, 22,2598-2604
DOI: 10.1039/D0GC00498G, Paper
Tahani A. C. A. Bayrakdar, Fady Nahra, Oihane Zugazua, Lies Eykens, Dominic Ormerod, Steven P. Nolan
In this report, we investigate the integration of a membrane separation protocol in line with the gold-catalyzed hydration of alkynes.
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Introducing deep eutectic solvents as flux boosting and surface cleaning agents for thin film composite polyamide membranes

Green Chem., 2020, 22,2381-2387
DOI: 10.1039/D0GC00762E, Communication
Nidhi Maalige R., Sweedal A. Dsouza, Matheus M. Pereira, Veerababu Polisetti, Dibyendu Mondal, Sanna Kotrappanavar Nataraj
This study introduced DESs as versatile and multi-tasking agents to modify the surface roughness and wettability of a TFC-PA membrane to boost the permeate flux rate and they also proved to be cleaning agents for organically fouled TFC-PA membranes.
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Sustainable remediation with an electroactive biochar system: mechanisms and perspectives

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00717J, Critical Review
Zhonghao Wan, Yuqing Sun, Daniel C. W. Tsang, Deyi Hou, Xinde Cao, Shicheng Zhang, Bin Gao, Yong Sik Ok
Biochar-based carbocatalysis is synergized from electroactive components including reactive-active moieties, metals, defective sites, heteroatoms, and graphitic structure for sustainable remediation.
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One-step catalytic amination of naphthalene to naphthylamine with exceptional yield

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00633E, Communication
Fang Hao, Xin Wang, Linfang Huang, Wei Xiong, Pingle Liu, Hean Luo
This is the first time to synthesize naphthylamine from one-step naphthalene amination by vanadium catalysts with high yield under mild condition. It could obtain ∼70% yield of naphthylamine, with major product of valuable 1,5-diaminonaphthalene.
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Highly efficient bioconversion of flavonoid glycosides from citrus-processing wastes in solvent-buffer systems

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00669F, Paper
Yucong Zou, Xuan Xin, Haixia Xu, Hongwei Yuan, Xiaofeng Li, Yigang Yu, Guanglei Zhao
The present study demonstrates that whole-cell catalysis is a good choice to hydrolyze citrus flavonoid glycosides and their derivatives.
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Role of life-cycle externalities in the valuation of protic ionic liquids – a case study in biomass pretreatment solvents

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00058B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Husain Baaqel, Ismael Díaz, Víctor Tulus, Benoît Chachuat, Gonzalo Guillén-Gosálbez, Jason P. Hallett
The combination of LCA and monetization has revealed that protic ionic liquids can be sustainable alternatives to conventional solvents.
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Achieving visible light-driven hydrogen evolution at positive bias with a hybrid copper–iron oxide|TiO2-cobaloxime photocathode

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00979B, Paper
C. Tapia, E. Bellet-Amalric, D. Aldakov, F. Boudoire, K. Sivula, L. Cagnon, V. Artero
H2 is an environmentally-friendly fuel that would allow for a circular economy but its sustainable production from solar energy and water using stable, efficient and scalable Earth-abundant materials, remains a challenge.
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Ethyl lactate participated three-component dehydrogenative reactions: biomass feedstock in diversity oriented quinoline synthesis

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00738B, Communication
Lu Yang, Jie-Ping Wan
Ethyl lactate participated three-component dehydrogenative reactions: biomass feedstock in diversity oriented quinoline synthesis
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Development and validation of an ecofriendly HPLC-DAD method for the determination of oleuropein and its applicability to several matrices: olive oil, olive leaf extracts and nanostructured lipid carriers.

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00965B, Paper
Amaia Huguet-Casquero, Tania Belen Lopez-Mendez, Eusebio Gainza, Jose Luis Pedraz
Oleuropein is a natural ingredient largely used in nutritional supplements. This study reports on the development, validation and application of an HPLC method based on UV-vis detection for determining oleuropein...
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Sulfonic acid modified hollow polymer nanospheres with tunable wall-thickness for improving biodiesel synthesis efficiency

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00905A, Paper
Wenliang Song, Yu Zhang, Anuraj Varyambath, Ji Su Kim, Il Kim
Precisely designing the morphology and size of nanostructures is vital in green chemistry as various advanced applications depend upon the shapes and dimensions of the functionalised materials. Herein, we report...
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MOFs come up to scratch: an environmentally benign route to oxidative [4 + 2] cycloaddition on maleimides solely via MOFs in water

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00619J, Paper
Masoumeh Abbasnia, Mehdi Sheykhan, Mona Bahmani, Parvaneh Taghizadeh
The first Diels–Alder reaction of vinyl arenes with ene systems catalyzed by MOFs is reported.
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Yb(OTf)3 and Visible Light Relay Catalyzed [3+2] Cycloaddition/[3,3]-Rearrangement/[4+2] Cycloaddition in One Pot to Prepare Oxazonine-Fused Endoperoxides

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00929F, Paper
Xiao-Pan Ma, Cai-Mei Nong, Yu-Feng Liang, Pei-Pei Xu, Xiu-Yun GUO, Cui Liang, Chengxue Pan, Gui-Fa SU, Dong-Liang Mo
We report a relay catalysis for the highly stereoselective synthesis of densely substituted oxazonine-fused endoperoxides in good yields. This domino reaction is based on a Yb(OTf)3 and visible light promoted...
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CO2-switchable non-Newtonian fluids

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00877J, Paper
Xiang Hao, Zejian Leng, Hairong Wang, Feng Peng, Qiang Yan
We report a new class of CO2-regulated non-Newtonian polymeric fluids that can switch between shear thinning and shear thickening states.
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Clean synthesis of linear and star amphiphilic poly(ε-caprolactone)-block-poly(ethyl ethylene phosphonate) block copolymers: assessing self-assembly and surface activity

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00819B, Paper
Payal Baheti, Timo Rheinberger, Olinda Gimello, Cécile Bouilhac, Frederik R. Wurm, Patrick Lacroix-Desmazes, Steven M. Howdle
Synthesis by ROP of star-like amphiphilic block copolymer surfactants composed of PCL hydrophobic segments and poly(phosphonate) as biodegradable segments.
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A safe and compact flow platform for the neutralization of a mustard gas simulant with air and light

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC01142H, Communication
Noémie Emmanuel, Pauline Bianchi, Julien Legros, Jean-Christophe M. Monbaliu
Intensified chemical neutralization of a chemical warfare agent simulant CEES with air and light under continuous flow conditions.
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Catalytic C–C coupling of diazo compounds with arylboronic acids: using surface modified sewage sludge as catalyst

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00317D, Paper
Zhipeng Zhang, Yang Yu, Yuxing Xie, Timothy Hughes, Jun Xu, Fei Huang, He Huang
A green, mild and efficient synthesis of diarylmethines using sewage sludge-derived carbonaceous materials (SW) by perchloric acid catalyzed coupling reactions between diazo compounds and arylboronic acids was developed.
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Incorporation of novel degradable oligoester crosslinkers into waterborne pressure sensitive adhesives: towards removable adhesives

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00463D, Paper
Fabian Wenzel, Amaia Agirre, Miren Aguirre, Jose Ramon Leiza
Novel partially degradable waterborne pressure sensitive adhesives can be easily removed from substrates under mild alkali conditions opening the door for sustainable (less solvent and energy consumption) recycling processes.
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Boosting the efficiency of solution-based CZTSSe solar cells by using supercritical carbon dioxide treatment

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01355B, Paper
Hai-Qin Xiao, Wen-Hui Zhou, Dongxing Kou, Zheng-Ji Zhou, Yue-Na Meng, Yafang Qi, Shengjie Yuan, Qingwen Tian, Si-Xin Wu
Cu2ZnSn(S,Se)4 (CZTSSe) solar cells are receiving considerable attention in recent years, owing to the low cost and toxicity as well as high abundance of their constituent elements. Solution-based (mainly precursor...
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Electrochemical Oxidative C(sp3)-H Azolation of Lactams Under Mild Conditions

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00687D, Communication
Zhaohua Wan, Dan Wang, Zixuan Yang, Heng Zhang, Shengchun Wang , Aiwen Lei
Lactam-containing structural compounds are ubiquitous in drugs and biomolecules. An electrochemical oxidative direct C(sp3)-H azolation of lactams has been reported under metal catalyst free and external oxidant free conditions. This...
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Reporting the unreported: the reliability and comparability of the literature on organic solvent nanofiltration

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00775G, Perspective
Hai Anh Le Phuong, Christopher F Blanford, Gyorgy Szekely
Organic solvent nanofiltration (OSN) is an energy-efficient separation technique that has the potential to improve environmental sustainability in many industrial sectors, including food processing, biorefineries, and in the production of...
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