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NFL Network's Steve Smith Sr.: 'Beware' of creative tricks from New England Patriots head coach Bill Belichick in 2020

NFL Network's Steve Smith Sr. warns to "beware' of creative tricks from New England Patriots head coach Bill Belichick in 2020.




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Chargers top pick Herbert focusing on playbook at minicamp

Justin Herbert should have been walking onto a Los Angeles Chargers practice field Friday for the first time. Herbert, who was selected with the sixth overall pick in last month's draft, is back in Southern California as the Chargers begin their virtual rookie minicamp this weekend. The former University of Oregon standout has resumed on-field workouts in Huntington Beach with John Beck, a former NFL quarterback and personal coach with whom he worked out before the draft.




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NFL Network's Jane Slater: Dallas Cowboys owner Jerry Jones 'had a hand in' Dallas Cowboys playing opening game at SoFi Stadium

NFL Network's Jane Slater says Dallas Cowboys owner Jerry Jones "had a hand in" Dallas Cowboys playing opening game at SoFi Stadium.




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NFL Network's Mike Robinson, Steve Wyche discuss Los Angeles Rams' top questions for 2020

NFL Network's Mike Robinson and Steve Wyche discuss Los Angeles Rams' top questions for 2020.




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Thoughts of opening SoFi Stadium minus fans brings an empty feeling

When the Rams debut in SoFi Stadium, will the 70,240-seat stadium be filled with fans, empty or somewhere in between? Ticket holders are anxious to know.




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Whole lot of 'revenge' games for Tom Brady in this Buccaneers schedule

Don't you want me, baby?...DJ Bean points out that Tom Brady's first season in Tampa Bay is loaded with games against teams who passed on the legendary former Patriots quarterback in free agency.




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Texans' Deshaun Watson tweets about Bears' lack of interest during 2017 draft

Everything's totally fine!




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Report: Bears considering pursuit of Larry Warford

As expected, Larry Warford quickly has become a highly sought-after free agent. Hours after the Saints released the offensive guard, the Texans expressed interest. The Bears also are considering pursuing Warford, Brad Biggs of the Chicago Tribune reports. They might not have long to consider whether they're interested. The Bears signed Germain Ifedi, a first-round [more]




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Sports Talk Live Podcast: Breaking down the Bears' 2020 schedule

David Haugh, Chuck Garfien and Mark Carman join Kap for a casual Friday edition of SportsTalk Live.




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Rams still hoping for guests at SoFi Stadium opening party

The Los Angeles Rams finally have a date and an opponent for the long-awaited opening of SoFi Stadium, the multibillion-dollar reason for their return to California over four years ago. The Rams still don't know for sure whether they'll actually be able to have their big Sunday night against the Dallas Cowboys on Sept. 13. The coronavirus pandemic is occurring during a historic year for this NFL franchise.




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Looking forward to these fun rookie matchups

Here are some rookie-against-rookie battles we can't wait to see in 2020.




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The controllable synthesis of substitutional and interstitial nitrogen-doped manganese dioxide: the effects of doping sites on enhancing the catalytic activity

J. Mater. Chem. A, 2020, 8,8383-8396
DOI: 10.1039/D0TA01346C, Paper
Taohong He, Xiaoshan Zeng, Shaopeng Rong
N atoms were selectively doped at substitutional or interstitial sites in the MnO2 lattice using N2 plasma. This research provides a site-selective N-doping method and a deep insight into the different effects of doping sites.
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Two-step sequential blade-coating of high quality perovskite layers for efficient solar cells and modules

J. Mater. Chem. A, 2020, 8,8447-8454
DOI: 10.1039/D0TA02043E, Paper
Junwen Zhang, Tongle Bu, Jing Li, Hengyi Li, Yanping Mo, Zhengli Wu, Yifan Liu, Xiao-Li Zhang, Yi-Bing Cheng, Fuzhi Huang
A two-step sequential blade-coating process in air to fabricate high-efficiency perovskite solar cells and modules.
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Engineering yolk–shell P-doped NiS2/C spheres via a MOF-template for high-performance sodium-ion batteries

J. Mater. Chem. A, 2020, 8,8612-8619
DOI: 10.1039/D0TA02568B, Paper
Liqin Wang, Zhanli Han, Quanqing Zhao, Xiuyun Yao, Youqi Zhu, Xilan Ma, Shide Wu, Chuanbao Cao
The stable yolk–shell P-doped NiS2/C spheres were successfully fabricated via MOFs template, and first adopted phytic acid as P source. Due to the unique framework and synergistic effect, P-doped NiS2/C sample displayed high sodium storage capacity.
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Enhancing the average thermoelectric figure of merit of elemental Te by suppressing grain boundary scattering

J. Mater. Chem. A, 2020, 8,8455-8461
DOI: 10.1039/D0TA02660C, Paper
Yehao Wu, Feng Liu, Qi Zhang, Tiejun Zhu, Kaiyang Xia, Xinbing Zhao
Suppressed grain boundary scattering contributes to enhanced electrical conductivity and device zT in elemental Te based thermoelectric materials.
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An environmentally adaptive quasi-solid-state zinc-ion battery based on magnesium vanadate hydrate with commercial-level mass loading and anti-freezing gel electrolyte

J. Mater. Chem. A, 2020, 8,8397-8409
DOI: 10.1039/D0TA01033B, Paper
Weijun Zhou, Jizhang Chen, Minfeng Chen, Anran Wang, Aixiang Huang, Xinwu Xu, Junling Xu, Ching-Ping Wong
A quasi-solid-state zinc-ion battery exhibits remarkable areal and volumetric energy/power densities and excellent cyclability from −30 to 60 °C.
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Screening metal-free photocatalysts from isomorphic covalent organic frameworks for the C-3 functionalization of indoles

J. Mater. Chem. A, 2020, 8,8706-8715
DOI: 10.1039/D0TA02164D, Paper
Ziping Li, Songjie Han, Chunzhi Li, Pengpeng Shao, Hong Xia, He Li, Xiong Chen, Xiao Feng, Xiaoming Liu
An excellent framework photocatalyst was screened from a series of isomorphic COFs. The photocatalytic properties of C-3 functionalization of indoles by COF-based photocatalysts were first reported.
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Sodium phthalate as an anode material for sodium ion batteries: effect of the bridging carbonyl group

J. Mater. Chem. A, 2020, 8,8469-8475
DOI: 10.1039/D0TA01281E, Paper
Liang-Yu Wang, Chao Ma, Xiao Wei, Baobao Chang, Kai-Xue Wang, Jie-Sheng Chen
The bridging carbonyl group initiates the insertion of sodium ions and activates the ortho-carbonyl functional groups of sodium phthalate.
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Rocking-chair capacitive deionization with flow-through electrodes

J. Mater. Chem. A, 2020, 8,8476-8484
DOI: 10.1039/C9TA14112J, Paper
Yong Liu, Xin Gao, Kai Wang, Xinyue Dou, Haiguang Zhu, Xun Yuan, Likun Pan
Flow-through Rocking-chair Capacitive Deionization system with ultrahigh desalination rate is built for the first-time, in which sodium-pre-intercalated MnO2 coated carbon nanofiber aerogels are employed as the flow-through electrode.
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Large energy-storage density in transition-metal oxide modified NaNbO3–Bi(Mg0.5Ti0.5)O3 lead-free ceramics through regulating the antiferroelectric phase structure

J. Mater. Chem. A, 2020, 8,8352-8359
DOI: 10.1039/D0TA02285C, Paper
Ao Tian, Ruzhong Zuo, He Qi, Min Shi
The combination of AFE phase structural regulation and breakdown strength optimization through chemical modification leads to a large energy-storage density of Wrec ∼ 5.57 J cm−3 in NN–BMT lead-free bulk ceramics.
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Thermodynamic stability, phase separation and Ag grading in (Ag,Cu)(In,Ga)Se2 solar absorbers

J. Mater. Chem. A, 2020, 8,8740-8751
DOI: 10.1039/D0TA00363H, Paper
Open Access
Kostiantyn V. Sopiha, Jes K. Larsen, Olivier Donzel-Gargand, Faraz Khavari, Jan Keller, Marika Edoff, Charlotte Platzer-Björkman, Clas Persson, Jonathan J. S. Scragg
Herein, we prove that (Ag,Cu)(In,Ga)Se2 alloy system has a wide miscibility gap, which can induce compositional grading and cause phase separation in thin-film solar absorbers.
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NixRh1−x bimetallic alloy nanofibers as a pH-universal electrocatalyst for the hydrogen evolution reaction: the synthetic strategy and fascinating electroactivity

J. Mater. Chem. A, 2020, 8,8629-8637
DOI: 10.1039/D0TA02005B, Paper
Dasol Jin, Areum Yu, Youngmi Lee, Myung Hwa Kim, Chongmok Lee
NixRh1–x bimetallic alloy nanofibers synthesized by H2-reduction of NiRh2O4 exhibited outstanding pH-universal HER electrocatalytic activity with high stability.
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PCE11-based polymer solar cells with high efficiency over 13% achieved by room-temperature processing

J. Mater. Chem. A, 2020, 8,8661-8668
DOI: 10.1039/D0TA02271C, Paper
Jianyun Zhang, Wenrui Liu, Ming Zhang, Shengjie Xu, Feng Liu, Xiaozhang Zhu
Non-fullerene acceptors featuring excellent miscibility with temperature-dependent aggregation polymer PCE11 enable room-temperature processed polymer solar cells with high efficiency over 13%.
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Enhancing the operational stability of unencapsulated perovskite solar cells through Cu–Ag bilayer electrode incorporation

J. Mater. Chem. A, 2020, 8,8684-8691
DOI: 10.1039/D0TA01606C, Paper
Chieh-Ting Lin, Jonathan Ngiam, Bob Xu, Yu-Han Chang, Tian Du, Thomas J. Macdonald, James R. Durrant, Martyn A. McLachlan
Incorporation of bilayer electrodes (Cu:Ag) significantly reduces electrode corrosion and device degradation in perovskite solar cells operating in air. A symbiosis exists whereby Ag inhibits Cu oxidation and Cu prevents interfacial reactions between the perovskite (MAPbI3) and Ag.
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Anderson polyoxometalate built-in covalent organic frameworks for enhancing catalytic performances

J. Mater. Chem. A, 2020, 8,8548-8553
DOI: 10.1039/D0TA02443K, Paper
Rui Ma, Naifang Liu, Ting-Ting Lin, Tianbo Zhao, Sheng-Li Huang, Guo-Yu Yang
Anderson polyoxometalate-based covalent organic frameworks exhibited the highest catalytic activity in the photodegradation of RhB and MB, as well as 100% selective oxidation of sulfides to sulfoxides.
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Achieving ultrahigh volumetric performance of graphene composite films by an outer–inner dual space utilizing strategy

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/C9TA13585E, Paper
Cong Huang, Qunli Tang, Qiushui Feng, Yanhua Li, Yali Xu, Yan Zhang, Aiping Hu, Shiying Zhang, Weina Deng, Xiaohua Chen
An outer–inner dual space utilizing strategy is reported for the fabrication of an ultrahigh volumetric performance polydopamine-coated dopamine/reduced graphene oxide composite film.
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Identifying Raman modes of Sb2Se3 and their symmetries using angle-resolved polarised Raman spectra

J. Mater. Chem. A, 2020, 8,8337-8344
DOI: 10.1039/D0TA01783C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nicole Fleck, Theodore D. C. Hobson, Christopher N. Savory, John Buckeridge, Tim D. Veal, Maria R. Correia, David O. Scanlon, Ken Durose, Frank Jäckel
Vibrational symmetry assignments using Raman spectroscopy and density functional theory on oriented crystals also enabling orientation optimisation of thin films.
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Testing the predictive power of theory for PdxIr(100−x) alloy nanoparticles for the oxygen reduction reaction

J. Mater. Chem. A, 2020, 8,8421-8429
DOI: 10.1039/C9TA13711D, Paper
Hongyu Guo, Jamie A. Trindell, Hao Li, Desiree Fernandez, Simon M. Humphrey, Graeme Henkelman, Richard M. Crooks
PdxIr(100−x) alloys synthesized via a microwave-assisted polyol method serve as an ideal experimental system to improve theoretical insight of the material properties towards the ORR.
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Understanding the mechanism of byproduct formation with in operando synchrotron techniques and its effects on the electrochemical performance of VO2(B) nanoflakes in aqueous rechargeable zinc batteries

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA00858C, Paper
Qiang Pang, Hainan Zhao, Ruqian Lian, Qiang Fu, Yingjin Wei, Angelina Sarapulova, Junqi Sun, Chunzhong Wang, Gang Chen, Helmut Ehrenberg
The byproduct protects the vanadium-based positive electrode of ARZBs and facilitates Zn2+ insertion into the electrode.
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A universal cross-linking binding polymer composite for ultrahigh-loading Li-ion battery electrodes

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA00714E, Paper
Dong Wang, Qian Zhang, Jie Liu, Erying Zhao, Zhenwei Li, Yu Yang, Ziyang Guo, Lei Wang, Shanqing Zhang
A general, facile-operability, and sustainable strategy to achieve ultrahigh-loading electrodes has been proposed that is simply replacing the traditional PVDF binder with an eco-friendly and robust c-PAA-XG binder with a high-efficiency damper.
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Achieving a 2.7 V aqueous hybrid supercapacitor by the pH-regulation of electrolyte

J. Mater. Chem. A, 2020, 8,8648-8660
DOI: 10.1039/D0TA02926B, Paper
Lijun Su, Qingnuan Zhang, Yue Wang, Jianing Meng, Yongtai Xu, Lingyang Liu, Xingbin Yan
We present an effective electrolyte pH-regulation strategy for cation-intercalated manganese oxides to extend the voltage window of aqueous supercapacitors.
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Simultaneously improving the photovoltaic parameters of organic solar cells via isomerization of benzo[b]benzo[4,5]thieno[2,3-d]thiophene-based octacyclic non-fullerene acceptors

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA00451K, Paper
Zhijie Zhou, Jiamin Duan, Linglong Ye, Guo Wang, Bin Zhao, Songting Tan, Ping Shen, Hwa Sook Ryu, Han Young Woo, Yanming Sun
Three isomeric FREAs were synthesized and applied in organic solar cells. The OSC devices based on Z1-bb exhibited a PCE of 12.66%. The isomerization of a fused-ring core could be achieve high-performance OSCs with high Jsc, Voc, and FF.
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Hexagonal boron nitride induces anion trapping in a polyethylene oxide based solid polymer electrolyte for lithium dendrite inhibition

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03677C, Paper
Yuhan Li, Libo Zhang, Zongjie Sun, Guoxin Gao, Shiyao Lu, Min Zhu, Yanfeng Zhang, Zhiyu Jia, Chunhui Xiao, Huaitian Bu, Kai Xi, Shujiang Ding
Lithium ion conductivity and mechanical strength of a PEO based composite solid polymer electrolyte are improved by adding h-BN.
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A highly efficient artificial light-harvesting system with two-step sequential energy transfer based on supramolecular self-assembly

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03169K, Paper
Guangping Sun, Weirui Qian, Jianmin Jiao, Tingting Han, Yukun Shi, Xiao-Yu Hu, Leyong Wang
An efficient artificial light-harvesting system with two-step sequential energy transfer has been successfully constructed based on supramolecular self-assembly.
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Inexpensive thermochemical energy storage utilising additive enhanced limestone

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03080E, Paper
Kasper T. Møller, Ainee Ibrahim, Craig E. Buckley, Mark Paskevicius
A thermochemical energy storage capacity retention of up to 90% over 500 cycles is achieved in cheap and abundant limestone.
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Co-gel strategy for preparing hierarchically porous silica/polyimide nanocomposite aerogel with thermal insulation and flame retardancy

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/C9TA13011J, Paper
Xinhai Zhang, Xingxing Ni, Chenxi Li, Bo You, Gang Sun
Co-gel strategy for preparing hierarchically porous silica/polyimide aerogel with low density, high specific modulus, hydrophobicity, flame retardancy, and thermal insulation.
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Hollow PtCu Nanoparticles Encapsulated into Carbon Shell via Mild Annealing of Metal-Organic Frameworks

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA01549K, Paper
Guanjun Chen, Huaqiang Shan, Yan Li, Hongwei Bao, Tingwei Hu, Long Zhang, Shuai Liu, Fei Ma
Alloying Pt with less expensive 3d transition metal to form bimetallic nanoparticles (NPs) has been proven to be an ideal strategy for synthesis of catalysts, especially in the field of...
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Optical in-situ monitoring during the synthesis of halide perovskite solar cells reveals formation kinetics and evolution of optoelectronic properties

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA01237H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Klara Suchan, Justus Just, Pascal Becker, Eva Lisa Unger, Thomas Unold
The formation mechanism and the evolution of optoelectronic properties during annealing of chlorine-derived methylammonium lead iodide (MAPbI3-xClx) is investigated in detail combining in-situ und ex-situ optical and structural characterization. Using...
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Reversible changes in the electronic structure of carbon nanotube-hybrids upon NO2 exposure under ambient conditions

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02749A, Paper
Open Access
Filippo Fedi, Oleg Domanov, Hidetsugu Shiozawa, Kazuhiro Yanagi, Paolo Lacovig, Silvano Lizzit, Andrea Goldoni, Thomas Pichler, Paola Ayala
Single-walled carbon nanotubes have enormous potential for gas sensing. This study shows that cluster filling is a key to high sensitivity and it opens the possibility for a very high desorption at ambient temperature.
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Formation of Ga double grading in submicron Cu(In,Ga)Se2 solar cells by pre-depositing a CuGaSe2 layer

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02710C, Paper
Yifan Kong, Jianmin Li, Zengyang Ma, Zheng Chi, Xudong Xiao
By introducing a pre-deposited CuGaSe2 layer, a steep Ga back grading has been formed in a submicron CIGS layer with a high-temperature process for the first time.
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Fe/Fe3C nanoparticle-decorated N-doped carbon nanofibers for improving the nitrogen selectivity of electrocatalytic nitrate reduction

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02317E, Paper
Yue Lan, Junliang Chen, Hui Zhang, Wei-xian Zhang, Jianping Yang
N-doped carbon nanofibers embedded with Fe/Fe3C nanodomains demonstrate superior electrocatalytic nitrate reduction ability and nitrogen selectivity.
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Semiconducting polymer contributes favorably to the Seebeck coefficient in multi-component, high-performance n-type thermoelectric nanocomposites

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02388D, Paper
Junhui Tang, Ruisi Chen, Lidong Chen, Guillermo C. Bazan, Ziqi Liang
n-Type Co NWs/N2200 TENCs yield a high S, mainly from the semiconducting polymer, yet σ is limited by poor connectivity between inorganic and organic domains. By adding flexible n-doped SWCNTs to yield more conductive paths, σ and mechanical bendability are greatly enhanced.
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Rational design of high nitrogen-doped and core–shell/mesoporous carbon nanospheres with high rate capability and cycling longevity for pseudocapacitive sodium storage

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03229H, Paper
Jiayi Mao, Dechao Niu, Nan Jiang, Guangyu Jiang, Meiwan Chen, Yongsheng Li, Jianlin Shi
A facile soft-template strategy is developed to construct high-nitrogen-doped and core–shell/mesoporous carbon nanospheres for high-rate and long-term stable sodium-ion batteries.
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Smart Porous Wood Supported Flower-like NiS/Ni Conjuction with Vitrimer Co-effect as Multifunctional Material with Reshaping, Shape-memory and Self-healing for High-Performance Supercapacitors, Catalysts and Sensors

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA03664A, Paper
Chuanyin Xiong, Bingbing Li, Heguang Liu, Wei Zhao, Chao Duan, Haiwei Wu, Yong Ni
Wood-based materials are attracting more and more attention for applications in energy storage, due to their environment friendly and numerous channels structure. However, the poor conductivity and flexibility of wood...
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A novel integrated Cr(VI) adsorption–photoreduction system using MOF@polymer composite beads

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA01046D, Paper
Bardiya Valizadeh, Tu N. Nguyen, Stavroula Kampouri, Daniel T. Sun, Mounir D. Mensi, Kyriakos Stylianou, Berend Smit, Wendy L. Queen
Herein, a novel integrated adsorption–photoreduction system, which captures highly mobile and toxic hexavalent chromium (Cr(VI)) from real-world water samples and reduces it to less mobile and benign Cr(III) species, was designed.
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Polyimide/ZIF-7 Mixed-Matrix Membranes: Understanding in-situ Confined Formation of ZIF-7 Phases inside Polymer and Their Effects on Gas Separations

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA02761H, Paper
Sunghwan Park, Kie Yong Cho, Hae-Kwon Jeong
Polymer-modification-enabled in-situ metal-organic framework formation (PMMOF) is potentially a paradigm-shifting preparation method for polymer/MOF mixed-matrix membranes (MMMs). However, the actual reaction conditions of in-situ formation of MOF in the confined...
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Recent progress in carbonyl-based organic polymers as promising electrode materials for lithium-ion batteries (LIBs)

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03321A, Review Article
Hao Wang, Chang-Jiang Yao, Hai-Jing Nie, Ke-Zhi Wang, Yu-Wu Zhong, Pengwan Chen, Shilin Mei, Qichun Zhang
Lithium-ion batteries (LIBs) have been demonstrated as one of the most promising energy storage devices for applications in electric vehicles, smart grids, large-scale energy storage systems, and portable electronics.
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Ferrites: emerging light absorbers for solar water splitting

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA01554G, Review Article
Jeong Hun Kim, Hyo Eun Kim, Jin Hyun Kim, Jae Sung Lee
Ferrites are promising photoelectrode materials for solar water splitting to produce clean and storable hydrogen energy.
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Power and carbon monoxide co-production by a proton-conducting solid oxide fuel cell with La0.6Sr0.2Cr0.85Ni0.15O3−δ for on-cell dry reforming of CH4 by CO2

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03458D, Paper
Tong Wei, Peng Qiu, Lichao Jia, Yuan Tan, Xin Yang, Shichen Sun, Fanglin Chen, Jian Li
Highly efficient on-cell dry reforming of CH4 for power and CO co-production by H-SOFCs is achieved with an engineered LSCN@Ni layer.
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Understanding the structural phase transitions in lithium vanadium phosphate cathode for lithium-ion batteries

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/C9TA12435G, Paper
Woong Oh, Hyunyoung Park, Bong-Soo Jin, Ranjith Thangavel, Won-Sub Yoon
Developing high-energy lithium-ion batteries with long stability is critical for realizing sustainable energy applications; however, it remains highly challenging. Exploring multi-redox based electrode materials can help to achieve high capacity...
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