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Reactivities of tertiary phosphines towards allenic, acetylenic, and vinylic Michael acceptors

By pubs.rsc.org
Published On ::

Chem. Sci., 2024, 15,18111-18126
DOI: 10.1039/D4SC04852K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Feng An, Jan Brossette, Harish Jangra, Yin Wei, Min Shi, Hendrik Zipse, Armin R. Ofial
Combined experimental and quantum-chemical studies were used to characterise the philicity/fugality features of tertiary phosphines and Michael acceptors in phospha-Michael reactions, which are key steps in phosphine-catalysed organic reactions.
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FragGen: towards 3D geometry reliable fragment-based molecular generation

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Published On ::

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC04620J, Edge Article
Open Access
Odin Zhang, Yufei Huang, Shichen Cheng, Mengyao Yu, Xujun Zhang, Haitao Lin, Yundian Zeng, Mingyang Wang, Zhenxing Wu, Huifeng Zhao, Zaixi Zhang, Chenqing Hua, Yu Kang, Sunliang Cui, Peichen Pan, Chang-Yu Hsieh, Tingjun Hou
FragGen introduces a novel fragment-based AI-based molecular design method. It proposes the geometry handling protocol to improve the generation quality and has been applied to design highly bioactive type II kinase inhibitors.
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Photo-triggered NO release of nitrosyl complexes bearing first-row transition metals and therapeutic applications

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Published On ::

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06820C, Review Article
Open Access
Seungwon Sun, Jisu Choe, Jaeheung Cho
In biological systems, nitric oxide (NO) is a crucial signaling molecule that regulates a wide range of physiological and pathological processes. Given the significance of NO, there has been considerable...
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Probing water adsorption and stability under steam flow of Zr-based metal-organic frameworks using 91Zr solid-state NMR spectroscopy

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Published On ::

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04589K, Edge Article
Open Access
Athulya Nadol, Florian Venel, Raynald Giovine, Maeva Leloire, Christophe Volkringer, Thierry Loiseau, Christel Gervais, Caroline Mellot-Draznieks, Bertrand Doumert, Julien Trébosc, Olivier Lafon, Frédérique Pourpoint
The stability of metal-organic frameworks (MOFs) in the presence of water is crucial for a wide range of applications, including the production of freshwater, desiccation, humidity control, heat pumps/chillers and...
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Phenacylselenoesters allow facile selenium transfer and hydrogen selenide generation

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Published On ::

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05788K, Edge Article
Open Access
Utsav Dey Sarkar, Mahima Rana, Harinath Chakrapani
A new series of phenacylselenoesters that generate hydrogen selenide in the presence of esterase and a biological thiol under ambient conditions is reported.
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Steering N/S coordination number to accelerate catecholase-like catalysis over low-coordinated Cu site

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Published On ::

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05014B, Edge Article
Open Access
Meng Yuan, Nannan Xia, Ziheng Huang, Chaofeng Huang, Xun Hu, Fei He
Modulating the coordination configuration of metal Cu center through steering the N/S coordination number around Cu center boosted the catalytic activity of catechol oxidase-mimicking nanozyme.
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Strain-induced charge delocalization achieves ultralow exciton binding energy toward efficient photocatalysis

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Published On ::

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05873A, Edge Article
Open Access
Junyuan Duan, Yinghe Zhao, Yu Wu, Youwen Liu, Junnian Chen, Ruoou Yang, Jiazhao Huang, Chuanqi Luo, Mao Wu, Xiaodong Zheng, Pengyu Li, Xueliang Jiang, Jianguo Guan, Tianyou Zhai
A novel approach of strain-induced charge delocalization is developed to significantly reduce the exciton binding energy of Ta2O5 nanorods to below ambient thermal energy, leading to a remarkable enhancement in photocatalytic hydrogen evolution.
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Low temperature decoherence dynamics in molecular spin systems using the Lindblad master equation

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Published On ::

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05627B, Edge Article
Open Access
Timothy Krogmeier, Anthony W Schlimgen, Kade Head-Marsden
Understanding the spin dynamics in low-temperature settings is crucial to designing and optimizing molecular spin systems for use in emerging quantum technologies. At low temperatures, irreversible loss occurs due to...
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Noncentrosymmetric tellurite halides created by a depolymerization strategy: toward strong SHG intensity and wide bandgap

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Published On ::

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06403H, Edge Article
Open Access
Dan-Dan Zhou, Chun-Li Hu, Xin-Wei Zhang, Jiang-Gao Mao, Fang Kong
Successful synthesis of centrosymmetric Ga(Te3O7)Br and non-centrosymmetric M2(OH)(TeO3)(Te2O5)X (M = Al, Ga; X = Br, Cl) using a depolymerization strategy.
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Rare-earth metal complexes bearing electrophilic and nucleophilic carbon centres and their unique reactivity patterns towards pyridine derivatives

By pubs.rsc.org
Published On ::

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04197F, Edge Article
Open Access
weikang Wu, Thayalan Rajeshkumar, Shan Zhu, Fuxiang Chai, Dongjing Hong, ZeMing Huang, Qingbing Yuan, Laurent Maron, Shaowu Wang
The rare-earth metal dialkyl complexes (κ2-L1)RE(CH2SiMe3)2(THF)2 [RE = Lu(1a), Yb(1b), Er(1c), Y(1d), Dy(1e)] (L1 = 1-(2-N-C5H10NCH2CH2)-3-(2,6-iPr2C6H3N=CH)-C8H4N) and the rare-earth metal monoalkyl complexes (κ2-L1)2RE(CH2SiMe3)(THF)n [n = 0, RE = Lu(2a), Yb(2b);...
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Depolymerisation of Poly(Lactide) Under Continuous Flow Conditions

By pubs.rsc.org
Published On ::

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05891G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sophie Ellis, Antoine Buchard, Tanja Junkers
Poly(L-lactic acid) (PLLA) is commercially successful bio-based plastic, where end-of-life materials can undergo industrial composting. To create a circular economy, a desirable alternative to composting is chemical recycling to monomer...
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When a drummer sits down to write music

By www.thehindu.com
Published On :: Thu, 27 Oct 2016 00:00:00 +0530

Rijul Victor’s experiments with EDM led him to start a solo project, which is now releasing his debut album as an electronic music producer


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Following a seven-day cinema diet

By www.thehindu.com
Published On :: Fri, 28 Oct 2016 00:00:00 +0530

The Mumbai Film Festival this year had themes of suffocation, alienation, personal struggle, politics, rape, morality, gender, family…and a few characters we fell in love with, says Namrata Joshi


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Curtains come down on MAMI

By www.thehindu.com
Published On :: Fri, 28 Oct 2016 00:00:00 +0530

Diamond Island,Godless,Everything Else,Lady of the LakeandThe Narrow Pathamong big winners


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Finding her own path

By www.thehindu.com
Published On :: Fri, 04 Nov 2016 00:00:00 +0530

Kathak exponent Rachana Yadav draws parallels between the universe and human life in her latest productionSwaraah


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A mirror unto her own life

By www.thehindu.com
Published On :: Tue, 08 Nov 2016 00:00:00 +0530

It’s no surprise that Usha Bane’s one and only tryst with acting inCourtwas a such a standout one. She played a manual scavenger’s widow, whose life struggles resonated with eerie similarity to her own


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Low notes for film trade

By www.thehindu.com
Published On :: Fri, 11 Nov 2016 00:00:00 +0530

How do box office revenues get affected with the recent move to discontinue old Rs. 500 and Rs. 1,000 notes? Deborah Cornelious asks trade experts


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The pain and power of multiples

By www.thehindu.com
Published On :: Tue, 15 Nov 2016 00:00:00 +0530

With as many as 14 Bollywood franchise films seeing the light of the day in 2016, we decode the phenomenon


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Abhishek Bachchan has ten million followers on Twitter

By www.thehindu.com
Published On :: Fri, 18 Nov 2016 00:00:00 +0530


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Back to Basics: What should you know about Exchange Traded Funds?

By www.thehindubusinessline.com
Published On :: Fri, 10 May 2024 20:29:24 +0530

Navigating the intricacies of ETF-investing involves understanding the disparity between an ETF’s market price and its Net Asset Value (NAV)


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Why this dividend yield fund may suit investors seeking lower volatility

By www.thehindubusinessline.com
Published On :: Thu, 13 Jun 2024 09:42:09 +0530

Since its inception in December 2020, HDFC Dividend Yield fund has outperformed the broader markets convincingly


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Three key MF inflow trends in May 2024

By www.thehindubusinessline.com
Published On :: Fri, 14 Jun 2024 20:27:04 +0530

Monthly investments via SIPs crossed the ₹20,000-crore mark for the second successive month.


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Why this consumption thematic fund is an attractive investment now

By www.thehindubusinessline.com
Published On :: Thu, 20 Jun 2024 12:10:01 +0530

Nippon India Consumption fund has been a consistent outperformer across market cycles


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Mutual Funds and NRIs: If you are a non-resident Indian, here is how you can partake in the India growth story

By www.thehindubusinessline.com
Published On :: Sat, 22 Jun 2024 17:52:44 +0530

If you’re a Non-Resident Indian eyeing India’s growth story, here are the basics that matter


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How NRIs can make the most of mutual fund platforms

By www.thehindubusinessline.com
Published On :: Thu, 27 Jun 2024 23:12:48 +0530

From WhatsApp support to chatbot help, many options are available for those residing abroad


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At ₹40,608 crore, MFs asset and equity inflows hit a new high in June

By www.thehindubusinessline.com
Published On :: Tue, 09 Jul 2024 18:54:17 +0530

Industry AUM crosses ₹60 lakh-crore on new fund offers, mark-to-market gain


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SBI Innovative Opportunities Fund: What you should know

By www.thehindubusinessline.com
Published On :: Fri, 09 Aug 2024 18:35:47 +0530

The recently-launched fund, open till August 12, is a high risk and unknown rewards scenario


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What you need to know about SWP

By www.thehindubusinessline.com
Published On :: Fri, 23 Aug 2024 20:01:06 +0530

Guide to withdrawing a fixed sum from MF investments at regular intervals for a fixed period


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Mutual Funds: Does past performance indicate how they’ll perform in the future?

By www.thehindubusinessline.com
Published On :: Sat, 28 Sep 2024 21:25:19 +0530

An analysis on if and how historical outperformance of mutual funds foretell their future returns


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Chinmaya Mission takes up growing challenges of mental health

By www.newkerala.com
Published On :: Mon, 11 Nov 2024 22:50:02 +0530


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The Art and Soul of Baking Named Best How-To Book

By andrewsmcmeelpublishing.blogspot.com
Published On :: Sun, 11 Jan 2009 16:06:00 +0000

Library Journal included The Art and Soul of Baking by Sur La Table with Cindy Mushet on its list of Best How-To Books of 2008.

This addition to renowned culinary authority Sur La Table's cookbook series, The Art and Soul of Baking (Andrews McMeel Publishing, LLC; $40.00 hardcover), guides readers through the world of baking, where the tantalizing aromas of chocolate, vanilla, butter, and cinnamon fill the air and tempt the palate. Whether turning out a rustic olive and thyme bread or crafting a show-stopping triple-layer chocolate cake, pastry chef and baking instructor Cindy Mushet provides indispensable tips and tricks to help home bakers achieve professional-looking—and professional-tasting—results.

More than 275 tested and delectable recipes cover all the bases from tasty pies, tantalizing tarts, melt-in-your-mouth meringues, and delicious cookies to more complicated creations such as flaky pastries, decadent cakes, and lighter-than-air soufflés. Novice bakers and pastry perfectionists alike will be tempted by such treats as Dulce De Leche Éclairs with Milk Chocolate Glaze; Pumpkin Spice Cake with Maple-Cream Cheese Frosting; Gingerbread Shortcakes with Caramelized Apples and Cider Sabayon; and Warm Cranberry Crumble Tart. Of course, there are savory recipes, too, including fragrant Parmesan-Herb Popovers; Potato, Onion, and Gruyère Galette; and a perfect Herbed Chicken Pot Pie. And for a delicious twist on tried-and-true favorites, there are recipes for Bananas Foster Bread Pudding; Citrus-Goat Cheese Cheesecake; Chocolate Velvet Pound Cake; and Peanut Butter Thumbprints with Peanut Caramel.


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Jurassic Towel Origami Featured on Teen Vogue

By andrewsmcmeelpublishing.blogspot.com
Published On :: Mon, 16 Mar 2009 22:17:00 +0000

People Are Talking About columnist Danielle Nussbaum on Teen Vogue called Jurassic Towel Origami "The best thing we got in the mail this week."

http://www.teenvogue.com/industry/blogs/entertainment/2009/03/best-thing-we-got-in-the-mail-this-week.html

Thanks to Jurassic Towel Origami, readers can amaze their houseguests and friends. It's also the perfect craft book for kids with its combo of dinos and origami.

Discover and create 15 distinct dino projects from Stegosaurus to Brontosaurus. With easy step-by-step instructions and photos, it's simple and fun to make extinct creatures come alive.

This interactive book is an imaginative and humorous gift for just about anyone.

Towel meets T. rex and lives to tell about it.

  • This book is quirky and unique, just like most houseguests, making it the perfect self-purchase or gift.


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Towards real-time myocardial infarction diagnosis: a convergence of machine learning and ion-exchange membrane technologies leveraging miRNA signatures

By pubs.rsc.org
Published On ::

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00640B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiang Ren, Ruyu Zhou, George Ronan, S. Gulberk Ozcebe, Jiaying Ji, Satyajyoti Senapati, Keith L. March, Eileen Handberg, David Anderson, Carl J. Pepine, Hsueh-Chia Chang, Fang Liu, Pinar Zorlutuna
Rapid diagnosis of acute myocardial infarction (AMI) is crucial for optimal patient management.
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Rapid low-cost assembly of modular microvessel-on-a-chip with benchtop xurography

By pubs.rsc.org
Published On ::

Lab Chip, 2024, 24,5065-5076
DOI: 10.1039/D4LC00565A, Paper
Open Access
Shashwat S. Agarwal, Marcos Cortes-Medina, Jacob C. Holter, Alex Avendano, Joseph W. Tinapple, Joseph M. Barlage, Miles M. Menyhert, Lotanna M. Onua, Jonathan W. Song
Our study is a novel implementation of xurography for multi-layer microfluidic device fabrication. We demonstrate the versatility of this approach by presenting several modular 3D vessel-matrix arrangements.
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Applying Low Levels of Strain to Model Nascent Phenomenon of Retinal Pathologies

By pubs.rsc.org
Published On ::

Lab Chip, 2024, Accepted Manuscript
DOI: 10.1039/D4LC00205A, Paper
Chase Paterson, Elizabeth Vargis
Age-related macular degeneration (AMD) is a leading cause of vision loss in the elderly. A better understanding of the mechanisms of the disease, especially at early stages, could elucidate new...
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3D-printed microfluidic–microwave device for droplet network formation and characterisation

By pubs.rsc.org
Published On ::

Lab Chip, 2024, 24,5101-5112
DOI: 10.1039/D4LC00387J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kai Silver, Jin Li, Adrian Porch, William David Jamieson, Oliver Castell, Pantelitsa Dimitriou, Colin Kallnik, David Barrow
A 3D-printed microwave–microfluidic device using a liquid metal resonator for droplet network formation and characterisation.
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Real-time impedance-activated dielectrophoretic actuation for reconfigurable manipulation of single flowing particles

By pubs.rsc.org
Published On ::

Lab Chip, 2024, 24,5145-5154
DOI: 10.1039/D4LC00622D, Paper
Alexis Lefevre, Cristian Brandi, Adele De Ninno, Filippo Ruggiero, Enrico Verona, Michaël Gauthier, Paolo Bisegna, Aude Bolopion, Federica Caselli
We present an original all-electrical platform that combines MIC-sensing and DEP-actuation for precise and selective trajectory control of single flowing particles.
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Integrated device for plasma separation and nucleic acid extraction from whole blood toward point-of-care detection of bloodborne pathogens

By pubs.rsc.org
Published On ::

Lab Chip, 2024, 24,5124-5136
DOI: 10.1039/D4LC00571F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Abigail G. Ayers, Christia M. Victoriano, Samuel K. Sia
This work presents PRECISE, a device that integrates plasma separation and nucleic acid extraction, enabling streamlined sample preparation of whole blood for point-of-care diagnostics without external equipment or electricity.
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Dual-drive acoustic micromixer for rapid nucleation and ultrafast growth of perovskite nanoparticles

By pubs.rsc.org
Published On ::

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00721B, Paper
Zhifang Liu, Yuwen Lu, Wei Tan, Guorui Zhu
An acoustic micromixer driven by bubbles and sharp edges, controlling the nucleation and growth of perovskite nanoparticles.
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Observing root growth and signalling responses to stress gradients and pathogens using the bi-directional dual-flow RootChip

By pubs.rsc.org
Published On ::

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00659C, Paper
Open Access
Claudia Allan, Yiling Sun, Stephen C. Whisson, Michael Porter, Petra C. Boevink, Volker Nock, Claudia-Nicole Meisrimler
Using a bi-directional dual-flow RootChip with integrated force sensing micropillars, root growth and signalling responses to stress gradients and pathogens were studied in Arabidopsis thaliana, Nicotiana benthamiana and Solanum lycopersicum.
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An imaging scheme to study the flow dynamics of co-flow regimes in microfluidics: implications for nanoprecipitation

By pubs.rsc.org
Published On ::

Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00652F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Wali Inam, Anton Vladyka, Joanna W. Pylvänäinen, Junel Solis, Dado Tokic, Pasi Kankaanpää, Hongbo Zhang
Herein, by presenting a novel imaging-based scheme for analyzing fluid interactions in co-flow regimes, we identify oscillatory and chaotic flow behaviors to optimize nanoprecipitation through controlled fluid manipulation.
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ERCMPU set to become fully solar-powered dairy cooperative

By www.thehindu.com
Published On :: Tue, 05 Nov 2024 21:40:39 +0530


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Kerala HC adjourns hearing on plea against land acquisition for Wayanad township

By www.thehindu.com
Published On :: Wed, 06 Nov 2024 20:09:32 +0530


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Allow only dolly workers with police verification certificate to carry pilgrims to Sabarimala: Kerala HC

By www.thehindu.com
Published On :: Thu, 07 Nov 2024 11:44:35 +0530


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Laugh in life: Kochi-based comedians Abhishek and Akshay on their latest show, their inspirations and more

By www.thehindu.com
Published On :: Thu, 07 Nov 2024 15:15:48 +0530

The duo has been performing stand-up comedy for around three years now.


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A champion pole-vaulter aims to bow out on a high

By www.thehindu.com
Published On :: Thu, 07 Nov 2024 20:13:00 +0530


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CM owes Oommen Chandy an apology for sabotaging seaplane project: Sudhakaran 

By www.thehindu.com
Published On :: Sat, 09 Nov 2024 21:49:31 +0530


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Union Minister inaugurates Milma’s fully solar-powered dairy

By www.thehindu.com
Published On :: Sun, 10 Nov 2024 02:50:00 +0530

Milma Federation Chairman K.S. Mani handed over the keys of the Central Quality Control Lab to National Dairy Development Board Chairman Meenesh Shah.


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HC allows medical termination of pregnancy of minor rape survivor

By www.thehindu.com
Published On :: Sun, 10 Nov 2024 18:21:23 +0530

Division Bench passed the order while allowing an appeal filed against a single judge’s order declining permission. Medical board said that termination of pregnancy was most appropriate


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Hits below the belt

By www.thehindubusinessline.com
Published On :: Fri, 07 Jun 2013 16:38:07 +0530

"John le Carré's conduct in your pages is like ... that of a man who, having relieved himself in his own hat, makes haste to clamp the brimming chapeau on his head."


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  • R K Nair