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Muppetry & other Stories

Happy 2018! Eschewing a long-standing tradition of not actually releasing shows we are kicking off the year as we mean to go on (for now) with a brand spanking new edition!

Join us for 50 glorious high fidelity minutes (true for one of us) and celebrate five years of the show. We don’t dwell too long on our golden non-award winning archive and go on to indulge in some chat, review a book, have a moan about Kickstarter projects, and for once don’t end on dog tech!




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Saurashtra on edge over infection due to influx

The district administration in Saurashtra is jittery fearing import of coronavirus cases into the district with the permission for intrastate travel granted by the state government. Jamnagar, which had only one Covid case till now reported five new cases in the past one week.




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Ahmedabad lockdown: Today's news from the city




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Covid-19 medical staff to get addl compensation

The Amdavad Municipal Corporation (AMC) has decided to give additional financial compensation to health and paramedical staff of AMC and private designated Covid-19 hospitals who contact coronavirus infection on duty.




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Gujarat's Covid-19 tally 7,403; death toll 449

With as many as 390 more people testing coronavirus positive since previous night, the total number of Covid-19 cases in Gujarat reached 7,403 on Friday, a health official said.




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Gujarat HC restores land to civic body from royals

The Gujarat high court rebuked the erstwhile royal family of the princely state of Bhavnagar for its "dishonest intention" to claim a land parcel in an unauthorized manner from the Bhavnagar Municipal Corporation.




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Ahd Covid-19 waste peaked to 8,422kg in 1 day

On March 24, when the lockdown was imposed, the total biomedical Covid waste incinerated in Ahmedabad that day was 82kg. The waste was mainly from the initial admissions at SVP Hospital,




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Palghar workers stuck in Guj wait to return home

Hundreds of brick kiln workers and their families from Dahanu and Talasari talukas stranded in Gujarat since the lockdown began, are waiting to return to their homes.




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Ahmedabad lockdown: Today's updates

Amid prevalent chaos and uncertainty over access to the essential services and commodities during the lockdown, we bring you the latest updates from your city.




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Resource Showcase: JSTOR

JSTOR provides access to more than 12 million academic journal articles, books, and primary sources in 75 disciplines. During the Covid-19 crisis, JSTOR are providing expanded access to more than 35,000 additional eBook titles. Learn how to do research using JSTOR Learn how to teach remotely with JSTOR See what other resources the library has for your subject




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Resource Showcase: Daily Mirror Historical Archive

The archive features more than 800,000 pages of brand-new, full text searchable, scans of the complete run of the Mirror from 1903-2000, including the Sunday Mirror. This is one of many e-resources we currently have on trial. You can see the complete list and gain access via our trial e-resources page. Please remember to leave feedback – your opinions help shape our collections. See what other newspapers and news services are available via Durham University Library and Collections




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Simplifying levulinic acid conversion towards a sustainable biomass valorisation

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04306C, Paper
Chiara Defilippi, Daily Rodríguez-Padrón, Rafael Luque, Cristina Giordano
In the range of biomass valorisation, hydroconversion of levulinic acid (one of the products of the hydrolysis of lignocellulosic biomass) was tested for the first time using nanosized Ni3N and Ni0 catalysts, with very promising results alongside high stability.
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One-pot hydrodeoxygenation of biomass furan derivatives into decane under mild conditions over Pd/C combined with phosphotungstic acid

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00428F, Paper
Song Li, Long Yan, Qiying Liu, Jianguo Liu, Qiyu Liu, Wei Fan, Xuelai Zhao, Xinghua Zhang, Chenguang Wang, Longlong Ma, Qi Zhang
One-pot hydrodeoxygenation of δ-furfurylidenelevulinic acid over Pd/C combined with phosphotungstic acid through successive hydrogenolysis and HDO of furans and lactones.
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Water Effects in the Heterogeneous Catalytic Valorization of Levulinic Acid into γ-Valerolactone and its Derivatives

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01082K, Critical Review
Rengui Weng, Zhihao Yu, Jian Xiong, Xuebin Lu
Levulinic acid (LA), which has been hailed as a versatile biomass-derived platform molecular, typically occupy a core position in the cellulosic biorefinery system. The heterogeneous catalytic valorization of LA for...
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Methylation-triggered fractionation of lignocellulosic biomass to afford cellulose-, hemicellulose-, and lignin-based functional polymers via click chemistry

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00451K, Paper
Kentaro Miki, Hiroshi Kamitakahara, Arata Yoshinaga, Yuki Tobimatsu, Toshiyuki Takano
This paper reports a new concept for the biorefinery of lignocellulosic biomass where the derivatisation and fractionation of lignocellulose are accomplished at the same time.
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Ni-Based Heterogeneous Catalysts for the Transformation of Fatty Acids into Higher Yields of O-Free Hydrocarbons

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00853B, Paper
Diego Valencia, Citlalli Zenteno, Diana Gomora-Herrera, María Teresa Gómez-Pérez, Jorge Aburto
A series of novel catalytic materials were synthesized by changing the chemical compounds in the impregnation solutions. A rigid, aromatic and bidentate molecule 1,10-phenanthroline (PhN) was used as a ligand...
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Photocatalyst-free visible light promoted E → Z isomerization of alkenes

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04303A, Communication
Jianbin Xu, Na Liu, Haiping Lv, Chixian He, Zining Liu, Xianfu Shen, Feixiang Cheng, Baomin Fan
A photocatalyst-free, simple and green method of visible light driven photocatalytic E to Z isomerization of alkenes has been developed.
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Thermophilic bio-electro CO2 recycling into organic compounds

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00320D, Paper
Open Access
Laura Rovira-Alsina, Elisabet Perona-Vico, Lluís Bañeras, Jesús Colprim, M. Dolors Balaguer, Sebastià Puig
Many industrial combustion processes produce carbon dioxide (CO2) at high temperature, which may be electrically recycled into valuable chemicals using microorganisms as catalysts.
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Solvent-free hydrogenation of levulinic acid to γ-valerolactone using a Shvo catalyst precursor: optimization, thermodynamic insights, and life cycle assessment

Green Chem., 2020, 22,2443-2458
DOI: 10.1039/C9GC02088H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christian A. M. R. van Slagmaat, Marie A. F. Delgove, Jules Stouten, Lukas Morick, Yvonne van der Meer, Katrien V. Bernaerts, Stefaan M. A. De Wildeman
We studied the solvent-free hydrogenation of levulinic acid to γ-valerolactone with the Shvo catalyst involving comparative catalysis, DFT, and LCA.
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Insights into pressure tunable reaction rates for electrochemical reduction of CO2 in organic electrolytes

Green Chem., 2020, 22,2434-2442
DOI: 10.1039/D0GC00013B, Paper
Charles I. Shaughnessy, David J. Sconyers, Hyun-Jin Lee, Bala Subramaniam, James D. Blakemore, Kevin C. Leonard
Modeling and simulation reveal the mechanistic basis for the pressure-tunable rates of CO2 reduction at elevated pressures of CO2.
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Dioxomolybdenum complex as an efficient and cheap catalyst for the reductive depolymerization of plastic waste into value-added compounds and fuels

Green Chem., 2020, 22,2419-2425
DOI: 10.1039/C9GC04206G, Paper
Beatriz F. S. Nunes, M. Conceição Oliveira, Ana C. Fernandes
Several types of PCL, PLA, PDO, PET and PBT plastic waste were efficiently converted into value-added compounds and fuels catalyzed by MoO2Cl2(H2O)2.
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Sustainability by design: automated nanoscale 2,3,4-trisubstituted quinazoline diversity

Green Chem., 2020, 22,2459-2467
DOI: 10.1039/D0GC00363H, Paper
Open Access
Mojgan Hadian, Shabnam Shaabani, Pravin Patil, Svitlana V. Shishkina, Harry Böltz, Alexander Dömling
Automated, one step, nanoscale synthesis of 2,3,4-trisubstituted quinazoline derivatives using positive pressure facilitated dispensing to access a very large chemical space exemplified by more than 1000 compounds.
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Novel insights into biomass delignification with acidic deep eutectic solvents: a mechanistic study of β-O-4 ether bond cleavage and the role of the halide counterion in the catalytic performance

Green Chem., 2020, 22,2474-2487
DOI: 10.1039/C9GC02569C, Paper
André M. da Costa Lopes, José R. B. Gomes, João A. P. Coutinho, Armando J. D. Silvestre
The potentiality of acidic deep eutectic solvents for β-O-4 ether bond cleavage is herein demonstrated from a mechanistic point of view.
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Efficient base-free oxidation of monosaccharide into sugar acid under mild conditions using hierarchical porous carbon supported gold catalysts

Green Chem., 2020, 22,2588-2597
DOI: 10.1039/C9GC04333K, Paper
Xintong Meng, Zengyong Li, Di Li, Yiming Huang, Jiaojiao Ma, Chuanfu Liu, Xinwen Peng
The highly selective synthesis of D-xylonic acid and D-gluconic acid from monosaccharide catalyzed by Au/NC-3 under base-free aerobic oxidation conditions.
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Fabrication of highly proton-conductive chitosan whole-bio-membrane materials functionalized with adenine and adenosine monophosphate

Green Chem., 2020, 22,2426-2433
DOI: 10.1039/C9GC04104D, Paper
Guanglei Zhao, Yuanyuan Chen, Xiao-Feng Li, Sihan Zhang, Yuanqiu Situ
A successful strategy to prepare novel proton-conductive chitosan membrane biomaterials functionalized with adenine and adenosine monophosphate via a one-pot grafting procedure.
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Upgrading 1-butanol to unsaturated, carbonyl and aromatic compounds: a new synthesis approach to produce important organic building blocks

Green Chem., 2020, 22,2365-2369
DOI: 10.1039/D0GC00254B, Communication
Jorge Mora Vargas, Luiz Henrique Tofaneli Morelato, Julieth Orduna Ortega, Mauricio Boscolo, Gustavo Metzker
Conversion of 1-butanol into added-value organic building blocks was achieved using fixed-bed flow reactor and Cu-based catalyst at 550 and 600 °C with and without methanol as addictive.
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Visible-light-induced photocatalyst-free C-3 functionalization of indoles with diethyl bromomalonate

Green Chem., 2020, 22,2543-2548
DOI: 10.1039/D0GC00292E, Paper
Guangmiao Gu, Mengmeng Huang, Jung Keun Kim, Jianye Zhang, Yabo Li, Yangjie Wu
A visible-light-induced and XB-promoted green approach to construct α-indolyl diethyl malonates was developed.
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Reusable, homogeneous water soluble photoredox catalyzed oxidative dehydrogenation of N-heterocycles in a biphasic system: application to the synthesis of biologically active natural products

Green Chem., 2020, 22,2575-2587
DOI: 10.1039/D0GC00569J, Paper
S. Srinath, R. Abinaya, Arun Prasanth, M. Mariappan, R. Sridhar, B. Baskar
Herein, a simple and efficient method for the oxidative dehydrogenation (ODH) of tetrahydro-β-carbolines, indolines and (iso)quinolines is described using a reusable, homogeneous cobalt-phthalocyanine photoredox catalyst in a biphasic medium.
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Base-mediated benzannulation of α-cyanocrotonates with ynones: facile synthesis of benzonitriles and fluorenes

Green Chem., 2020, 22,2370-2374
DOI: 10.1039/D0GC00608D, Communication
Maneesh Kumar Reddy Singam, Attunuri Nagireddy, Sridhar Reddy Maddi
Benzonitriles and cyanofluorenes have been rapidly obtained via the [3 + 3] benzannulation of readily available alkynones and α-cyanocrotonates using KOtBu as the only reagent and EtOH (and CO2) is the only by-product.
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One-pot synthesis of 1,3-butanediol by 1,4-anhydroerythritol hydrogenolysis over a tungsten-modified platinum on silica catalyst

Green Chem., 2020, 22,2375-2380
DOI: 10.1039/D0GC00244E, Communication
Lujie Liu, Takehiro Asano, Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige
Chemical production of 1,3-butanediol from biomass-derived compounds was first reported by 1,4-anhydroerythritol hydrogenolysis over a Pt–WOx/SiO2 catalyst.
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Using dialkyl amide via forming hydrophobic deep eutectic solvents to separate citric acid from fermentation broth

Green Chem., 2020, 22,2526-2533
DOI: 10.1039/C9GC04401A, Paper
Lijuan Liu, Qifeng Wei, Yong Zhou, Xiulian Ren
The separation of citric acids was realized by utilizing hydrophobic deep eutectic solvents (DESs), which were formed by using N,N-dibutylacetamide as a hydrogen acceptor and citric acid as the hydrogen bond.
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An entirely solvent-free photooxygenation of olefins under continuous flow conditions

Green Chem., 2020, 22,2359-2364
DOI: 10.1039/D0GC00436G, Communication
Patrick Bayer, Axel Jacobi von Wangelin
Photooxygenations of alkenes with singlet oxygen have been performed under solvent-free conditions in a flow reactor under VIS irradiation. The reaction operates at very high substrate/sensitizer ratios and enables high space–time yields.
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Double-metal cyanide as an acid and hydrogenation catalyst for the highly selective ring-rearrangement of biomass-derived furfuryl alcohol to cyclopentenone compounds

Green Chem., 2020, 22,2549-2557
DOI: 10.1039/C9GC04432A, Paper
Xiang Li, Qiang Deng, Lian Yu, Rui Gao, Zhikun Tong, Chenxi Lu, Jun Wang, Zheling Zeng, Ji-Jun Zou, Shuguang Deng
Herein, novel green synthetic routes to 4-hydroxy-2-cyclopentenone (HCP) and 2-cyclopentenone (CPE) from biomass-derived furfuryl alcohol via double-metal cyanide catalysis are proposed.
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Visible Light-Induced Aerobic Oxidation of Diarylalkynes to -Diketones Catalyzed by Copper-superoxo at Room Temperature

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00975J, Communication
Vaibhav Pramod Charpe, Arunachalam Sagadevan, Kuo Chu Hwang
We have developed the visible light induced simple copper(II) chloride catalyzed the oxidation of diarylacetylenes to -diketones by molecular oxygen at room temperature. The in-situ generated copper(II)-superoxo complex is a...
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Computer-aided Nanotoxicology: Risk Assessment of Metal Oxide Nanoparticles via nano-QSAR

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00933D, Paper
Jiakai Cao, Yong Pan, Yanting Jiang, Ronghua Qi, Beilei Yuan, Zhenhua Jia, Juncheng Jiang, Qingsheng Wang
Since the applications of nanomaterials have been expanded to serve as a therapeutic methodology, the cytotoxicity accompanying with the nanomaterials drew lots of attention during the therapeutic process. It is...
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Photocatalytic transfer hydrogenolysis of aromatic ketones using alcohols

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00732C, Paper
Hongji Li, Zhuyan Gao, Lijun Lei, Huifang Liu, Jianyu Han, Feng Hong, Nengchao Luo, Feng Wang
A mild method of photocatalytic deoxygenation of aromatic ketones to alkyl arenes was developed, which utilized alcohols as the green hydrogen donor. No hydrogen evolution during this transformation suggested a...
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Boron-doped CuO nanobundles for electroreduction of carbon dioxide to ethylene

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00730G, Communication
Qiang Wan, Jianling Zhang, Bingxing Zhang, Dongxing Tan, Lei Yao, Lirong Zheng, Fanyu Zhang, Lifei Liu, Xiuyan Cheng, Buxing Han
Herein, we synthesize B-doped CuO nanobundles for electrocatalytic CO2 reduction. Ethylene is the only multi-carbon product and a maximum ethylene faradaic efficiency (FE) of 58.4% can be achieved at −1.1 V (versus the reversible hydrogen electrode).
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One-step catalytic amination of naphthalene to naphthylamine with exceptional yield

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00633E, Communication
Fang Hao, Xin Wang, Linfang Huang, Wei Xiong, Pingle Liu, Hean Luo
This is the first time to synthesize naphthylamine from one-step naphthalene amination by vanadium catalysts with high yield under mild condition. It could obtain ∼70% yield of naphthylamine, with major product of valuable 1,5-diaminonaphthalene.
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Achieving visible light-driven hydrogen evolution at positive bias with a hybrid copper–iron oxide|TiO2-cobaloxime photocathode

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00979B, Paper
C. Tapia, E. Bellet-Amalric, D. Aldakov, F. Boudoire, K. Sivula, L. Cagnon, V. Artero
H2 is an environmentally-friendly fuel that would allow for a circular economy but its sustainable production from solar energy and water using stable, efficient and scalable Earth-abundant materials, remains a challenge.
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Ethyl lactate participated three-component dehydrogenative reactions: biomass feedstock in diversity oriented quinoline synthesis

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00738B, Communication
Lu Yang, Jie-Ping Wan
Ethyl lactate participated three-component dehydrogenative reactions: biomass feedstock in diversity oriented quinoline synthesis
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Photocatalytic Hydrogen Atom Transfer: the Philosopher’s Stone for Late-Stage Functionalization?

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01035A, Tutorial Review
Luca Capaldo, Lorenzo Lafayette Quadri, Davide Ravelli
An overview about the potentialities of photocatalytic Hydrogen Atom Transfer (HAT) for the Late-Stage Functionalization (LSF) of complex molecules is offered. The examined approach allows the smooth homolytic cleavage of...
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Development and validation of an ecofriendly HPLC-DAD method for the determination of oleuropein and its applicability to several matrices: olive oil, olive leaf extracts and nanostructured lipid carriers.

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00965B, Paper
Amaia Huguet-Casquero, Tania Belen Lopez-Mendez, Eusebio Gainza, Jose Luis Pedraz
Oleuropein is a natural ingredient largely used in nutritional supplements. This study reports on the development, validation and application of an HPLC method based on UV-vis detection for determining oleuropein...
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Transparent, flexible and recyclable nanopaper-based touch sensors fabricated via inkjet-printing

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00658K, Paper
Hao Ling, Ruwei Chen, Quanbo Huang, Feng Shen, Yuyuan Wang, Xiaohui Wang
Using an eco-friendly PEDOT:PSS ink formula, a transparent and flexible nanopaper-based touch sensor was fabricated via inkjet-printing.
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MOFs come up to scratch: an environmentally benign route to oxidative [4 + 2] cycloaddition on maleimides solely via MOFs in water

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00619J, Paper
Masoumeh Abbasnia, Mehdi Sheykhan, Mona Bahmani, Parvaneh Taghizadeh
The first Diels–Alder reaction of vinyl arenes with ene systems catalyzed by MOFs is reported.
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Scalable synthesis and polymerisation of a β-angelica lactone derived monomer

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00338G, Paper
Open Access
Andrea Dell'Acqua, Bernhard M. Stadler, Sarah Kirchhecker, Sergey Tin, Johannes G. de Vries
A new bio-based norbornene polymer was prepared starting from β-angelica lactone, prepared in a sustainable and scalable manner from the platform chemical levulinic acid. The new material displays transparency comparable to petrochemical-derived polynorbornene.
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Yb(OTf)3 and Visible Light Relay Catalyzed [3+2] Cycloaddition/[3,3]-Rearrangement/[4+2] Cycloaddition in One Pot to Prepare Oxazonine-Fused Endoperoxides

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00929F, Paper
Xiao-Pan Ma, Cai-Mei Nong, Yu-Feng Liang, Pei-Pei Xu, Xiu-Yun GUO, Cui Liang, Chengxue Pan, Gui-Fa SU, Dong-Liang Mo
We report a relay catalysis for the highly stereoselective synthesis of densely substituted oxazonine-fused endoperoxides in good yields. This domino reaction is based on a Yb(OTf)3 and visible light promoted...
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CO2-switchable non-Newtonian fluids

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00877J, Paper
Xiang Hao, Zejian Leng, Hairong Wang, Feng Peng, Qiang Yan
We report a new class of CO2-regulated non-Newtonian polymeric fluids that can switch between shear thinning and shear thickening states.
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Clean synthesis of linear and star amphiphilic poly(ε-caprolactone)-block-poly(ethyl ethylene phosphonate) block copolymers: assessing self-assembly and surface activity

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00819B, Paper
Payal Baheti, Timo Rheinberger, Olinda Gimello, Cécile Bouilhac, Frederik R. Wurm, Patrick Lacroix-Desmazes, Steven M. Howdle
Synthesis by ROP of star-like amphiphilic block copolymer surfactants composed of PCL hydrophobic segments and poly(phosphonate) as biodegradable segments.
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Metal-catalysed selective transfer hydrogenation of α,β-unsaturated carbonyl compounds to allylic alcohols

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00855A, Critical Review
Ronald Alvaro Alvaro Farrar Tobar, Andrea Dell'Acqua, Sergey Tin, Johannes G. de Vries
Allylic alcohols are highly important compounds which are used in a variety of processes. They can be obtained from α,β-unsaturated carbonyl compounds via stoichiometric or catalytic reductions. Catalytic transfer hydrogenation...
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Molecular engineering low-surface energy membranes by grafting perfluoro-tert-butoxy chains containing fluorous silica aerogels

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00593B, Paper
Vicki Man-Wai Yim, Angel See-Wing Lo, Bhaskar Jyoti Deka, Jiaxin Guo, Jehad A. Kharraz, István T. Horváth, Alicia Kyoungjin An
Environmentally benign fluorous aerogels have been synthesized and electrospun on commercial PVDF membrane imparting superhydrophobicity and enabling the membrane undergo a stable, non-wetting 10-day DCMD operation with 0.1 mM SDS and 3.5% NaCl feed.
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