Chem. Commun., 2020, 56,4894-4897
DOI: 10.1039/D0CC01532F, Communication

Qi Wu, Xian Liu, Yeshuang Du, Chunlin Teng, Fei Liang
A first example of monovalent-metal-based hybrid halides [N(CH₃)₄]MCl₂ (M = Ga⁺, In⁺) with zero-dimensional configuration containing unprecedented linear [GaCl₂]/[InCl₂] units have been designed and synthesized.
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Chem. Commun., 2020, 56,4886-4889
DOI: 10.1039/D0CC00327A, Communication

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Jing Lai, Jun Zhang, Zuowei Li, Yao Xiao, Weibo Hua, Zhenguo Wu, Yanxiao Chen, Yanjun Zhong, Wei Xiang, Xiaodong Guo
A splitting of two O3 phases, rather than the often observed O1 phases in the conventional LiCoO₂ electrode, was discovered in the LiNi_0.85Co_0.10Mn_0.05O₂ at high-voltage region (>4.6 V) by in situ high-resolution synchrotron radiation diffraction.
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Chem. Commun., 2020, 56,4906-4909
DOI: 10.1039/D0CC00548G, Communication

Xiaozhou Ma, Elizaveta A. Suturina, Mathieu Rouzières, Fabrice Wilhelm, Andrei Rogalev, Rodolphe Clérac, Pierre Dechambenoit
Ligand-based successive reductions in a heteroleptic Cr(III) complex give rise to intended extremely strong metal–radical magnetic interactions.
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Chem. Commun., 2020, 56,4942-4945
DOI: 10.1039/D0CC01086C, Communication

Chao Jiang, Yan Huang, Ting He, Peng Huang, Jing Lin
A colorimetric/fluorescence/photoacoustic triple read-out detection of prostate specific antigen (PSA) was developed by using a silica coated Au@Ag core–shell nanorod (denoted Au@Ag@SiO₂) based enzyme-linked immunosorbent assay (ELISA) system.
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Chem. Commun., 2020, 56,4914-4917
DOI: 10.1039/D0CC01456G, Communication

Turki Alkathiri, Nripen Dhar, Azmira Jannat, Nitu Syed, Md Mohiuddin, Manal M. Y. A. Alsaif, Robi S. Datta, Kibret A. Messalea, Bao Yue Zhang, Muhammad Waqas Khan, Aaron Elbourne, Naresh Pillai, Jian Zhen Ou, Ali Zavabeti, Torben Daeneke
The library of two-dimensional materials is limited since many transition metal compounds are not stratified and can thus not be easily isolated as nanosheets. Liquid metal-based synthesis provides a new approach to overcome this limitation.
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Chem. Commun., 2020, 56,4870-4873
DOI: 10.1039/D0CC00230E, Communication

Bing Han, Tianbo Li, Junying Zhang, Chaobin Zeng, Hiroaki Matsumoto, Yang Su, Botao Qiao, Tao Zhang
Rh₁/CeO₂ SAC is highly active for CO oxidation, which exhibits a high TOF of 0.41 s⁻¹via the Mars–van Krevelen mechanism.
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Chem. Commun., 2020, 56,4874-4877
DOI: 10.1039/D0CC00943A, Communication

Jugal Kishore Rai Deka, Biswajit Sahariah, Kalpita Baruah, Arun Kumar Bar, Bani Kanta Sarma
Unusual N(amide)⋯C–X noncovalent carbon bonding interactions stabilize the trans–cis (t–c) amide bond rotamers of N-methyl-N,N'-diacylhydrazines over the expected trans–trans (t–t) rotamers in solution.
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Chem. Commun., 2020, 56,4946-4949
DOI: 10.1039/D0CC01444C, Communication

Qiuping Xie, Delong Hou, Jinming Chang, Zhou Xu, Qi Zeng, Zhonghui Wang, Yi Chen
A supramolecular strategy as efficient as temperature that enabled facile control over collagen fibrillogenesis under physiological conditions was reported.
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Chem. Commun., 2020, 56,4882-4885
DOI: 10.1039/D0CC01429J, Communication

Shangqing Qu, Yonggang Wang, Yu Xiao, Yujie Yuan, Shengyi Li, Jikun Chen, Lidong Zhao, Zhiguo Xia, Jing Zhao
We report for the first time the discovery of reversible n–p conduction type switching in a chalcogenide, NaCu₅S₃, without structural transition.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02645J, Communication

Jiwei Wang, Licheng Zhan, Gendi Wang, Yin Wei, Min Shi, Jun Zhang
Oxidative addition of Pd/Au vinylene species with iodobenzene reveals the effect of a strong metallophilic Pd⋯Au interaction on phenyl transmetalation from Pd^IV to Au^I, which allows subsequent reductive elimination of LAuI at Pd and Au.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02140G, Communication

Kosuke Nakamoto, Naoko Abe, Genichiro Tsuji, Yasuaki Kimura, Fumiaki Tomoike, Yoshihiro Shimizu, Hiroshi Abe
Circular RNA without a stop codon enables rolling circle translation. we carried out one-pot chemical synthesis of circular RNA from RNA fragments. The synthesized circular RNAs acted as translation templates, despite the presence of unnatural phosphoramidate linkages.
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02176H, Communication

Haobo Sun, Yunliang Qiu, Yajie Lu, Jinming Kong, Xueji Zhang
In this paper, an ultrasensitive, highly selective and green electrochemical biosensor for quantifying DNA sequences (aM DNA) based on MnTBAP catalyst for AGET ATRP reaction is proposed. For the first...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02300K, Communication

ZHILONG LI, Vincent Gandon, Christophe Bour
Styrene derivatives can be easily synthesized from vinyl triflates and arenes under mild reaction conditions, using [Li][Al(OC(CF₃)₃)₄] as a catalyst and LiHMDS as a base. This transformation is likely to...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02001J, Feature Article

Kui Yang, Zhihua Zhang, Jie Du, Wei Li, Zhichao Pei
Owing to its spatiotemporal selectivity and noninvasive nature, photodynamic therapy (PDT) has become a promising approach for the treatment of cancer. However, the non-targeting capability and the accompanying side effects...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00478B, Communication

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Glenn Wright, Chaoyi Yao, Tom Moody, A. P. De Silva
Molecular AND logic gates 1, 3, 5 and 7, which are designed according to principles of photoinduced electron transfer (PET) switching, respond to co-existing Candida antarctica lipase B and H+...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00564A, Communication

Tianshu Chen, Xin Fu, Qianqian Zhang, Dongsheng Mao, Yuchen Song, Chang Feng, Xiaoli Zhu
We have designed a DNA logic gate that can integrate multiple biomarkers recognition with signal amplification to perform accurate and and sensitive analysis of circulating tumor cells (CTCs). It also...
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02029J, Communication

M. T. Jeena, Seokyoung Lee, Ayan Kumar Barui, Seongeon Jin, Yuri Cho, Suk-Won Hwang, Sehoon Kim, Ja-Hyoung Ryu
The design of peptide-based therapeutics is generally based on the replacement of L-amino acids with D-isomers to obtain improved therapeutic efficiency.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01505A, Communication

Jian-Xin Wang, Yi-Shuai Yu, Li-Ya Niu, Bo Zou, Kai Wang, Qing-Zheng Yang
Difluoroboron β-diketonate complexes that manifested temperature-dependent emission wavelength are reported.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01785J, Communication

Ying Zang, Jiangwei Zhang, Rui Wang, Zhao-Di Wang, Yandi Zhu, Xiaoyan Ren, Shunfang Li, Xi-Yan Dong, Shuang-Quan Zang
We evaluate photocatalytic H₂ generation of three Cu-based coordination polymers, a record-high rate of 57.64 mmol g⁻¹ h⁻¹ for Cu–MIM, and reveal that the excellent performances are due to the synergies of the inter-chain double-site Cu atoms.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01856B, Communication

Miantai Ye, Wei Hu, Meng He, Chenchen Li, Shuyang Zhai, Zhihong Liu, Yanying Wang, Huijuan Zhang, Chunya Li
A near-infrared two-photon fluorescent probe for selective detection and deep-depth imaging of NO helps to discover the relationship between NO and resistance to antitumor drugs.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01619E, Communication

Huang Zhou, Shaoyun Duan, Ji Huang, Fengjiao He
An ultrasensitive electrochemical biosensor was developed based on RCA and multipedal DNA walking strategy for the assay of 16S rRNA gene, and it has great application potential in food safety, environmental monitoring, and disease diagnosis.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01934H, Communication

Lishan Li, Songbo Cui, An Hu, Wei Zhang, Yiwen Li, Nianchen Zhou, Zhengbiao Zhang, Xiulin Zhu
Several kinds of novel azobenzene-containing tubular polymersomes were fabricated via self-assembly, and their shape could be tuned precisely by changing the chemical structure, self-assembly condition and external stimuli.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01930E, Communication

Yanfei Qin, Lingjing Chen, Gui Chen, Zhenguo Guo, Lei Wang, Hongbo Fan, Marc Robert, Tai-Chu Lau
[Fe(qnpy)(H₂O)₂]²⁺ is a highly efficient and robust catalyst for visible-light-driven reduction of CO₂ to CO, with a TON for CO of up to 14 095 and selectivity of 98% using Ru(phen)₃Cl₂ as photosensitizer and BIH as sacrificial reductant.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01517B, Communication

Weiyuan Ding, Hongquan Yu, Yu Tang, Zhuxin Li, Bijiao Liu, Dechong Liu, Yuyu Wang, Shu hong Liu, Hong Zhao, Daniel Mandler
A Fe–NC catalyst containing carbon nanotubes, mesopores and macropores with a measurable 3D framework structure was prepared by electrospinning.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01659D, Communication

Xin Yue, Ming Hu, Xingyi He, Shuang Wu, Jin-Heng Li
An unprecedented indium-promoted three-component 1,3,4-trifunctionalization cascade of 1,3-enynes with sulfinates and tert-butyl nitrite for producing 5-sulfonylisoxazoles via [3+2] annulation is reported.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01438A, Feature Article

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Pablo Ríos, Amor Rodríguez, Salvador Conejero
Well-defined electrophilic or low-electron count platinum complexes are very versatile catalysts for a variety of chemical transformations.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01756F, Communication

Pernille Rose Jensen, Sebastian Meier
Structures and rates in the catalytic cycle of carbohydrate dehydration by Lewis acidic salt are determined through the systematic use of complementary NMR approaches.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01936D, Communication

Yunfei Fan, Yahang Xie, Zhen Zhao, Yang Zhao, Rui Yu, Xiang-yang Liu, Youhui Lin, Changxu Lin
A wettability read-out strategy for an aptasensor is setup with a bilayer surface. It targets on methamphetamine and uses hydrophobicity reduction as the signal induced by recognition by the supporting aptamer layer.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02550J, Communication

Hao Zeng, Chuanle Zhu, Chi Liu, Yingying Cai, Fulin Chen, Huanfeng Jiang
The three component hydroxyletherification and hydroxylazidation reactions of (trifluoromethyl)alkenes are reported, providing various useful α-trifluoromethyl β-heteroatom substituted tertiary alcohols in high yields.
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01951H, Communication

Lu Sun, Qiao Zhao, Xinli Liu, Yongchun Pan, Yanfeng Gao, Jingjing Yang, Yuzhen Wang, Yujun Song
Here, we propose an amplification strategy of enzyme-mimicking accelerated signal enhancement integrated with triple-channel volumetric bar-chart chip for visually multiplexed quantitation of telomerase activity. This platform was used for evaluating...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02520H, Communication

Emily Lythell, Reynier Suardiaz, Philip Hinchliffe, Chonnikan Hanpaibool, Surawit Visitsatthawong, Sofia Oliveira, Eric Lang, Panida Surawatanawong, Vannajan Sanghiran Lee, Thanyada Rungrotmongkol, Natalie Fey, James Spencer, Adrian John Mulholland
MCR (mobile colistin resistance) enzymes catalyse phosphoethanolamine (PEA) addition to bacterial lipid A, threatening the “last-resort” antibiotic colistin. Molecular dynamics and density functional theory simulations indicate that monozinc MCR supports...
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02108C, Communication

Yong Liu, Juanjuan Li, Wei Zhang
A liquid metal-assisted exfoliation strategy is developed for synthesizing two-dimensional polydopamine nanosheets.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC90201B, Correction

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Cheng-Ying Chan, Chao-Hung Chang, Hsing-Yu Tuan
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02620D, Communication

Ruoyu Fan, Zhi Hu, Chun Chen, Xiaoguang Zhu, Haimin Zhang, Yunxia Zhang, Huijun Zhao, Guozhong Wang
ZIF-8 was employed as template to synthesize HD-Ni/N-CMS containing highly dispersed Ni at atomic-level anchored on N-doped carbon molecular sieve for vanillin hydrodeoxygenation. The ZIF-8 structure was inherited and Ni-N...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/C9CC09589F, Communication

Pei-Qin Liao, Ningyu Huang, Hai He, Hao Li, Xiao-Ming Chen
Herein, we report a metal-organic framework featuring a binuclear copper unit, showing extraordinarily high catalytic activity (102.8 mmol g-1 h-1) for photodriven hydrogen generation, which is attributed to the synergistic...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01833C, Communication

Hyeon Jin Park, Chang Wook Song, Sourav Sarkar, Yong Woong Jun, Ye Jin Reo, Mingchong Dai, Kyo Han Ahn
Near-infrared-emitting hemicyanine dyes are widely used in activatable fluorescent probes for various biological analytes, which fact, on the contrary, poses a chemical stability issue along with photoinstability as shown here...
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Chem. Commun., 2020, 56,4994-4997
DOI: 10.1039/D0CC00011F, Communication

Jonathan A. Kephart, Zachary Hecht, Brooke N. Livesay, Indrani Bhowmick, Matthew P. Shores, V. Codrina Popescu, Navamoney Arulsamy, Elliott B. Hulley
Aerobic oxidation of (tmeda)Fe(CH₂^tBu)₂ in toluene or THF solution leads to the self-assembly of a magic-sized all-ferrous oxide cluster containing the Fe₉O₆ subunit and bearing organometallic and diamine ligands.
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Chem. Commun., 2020, 56,4998-5001
DOI: 10.1039/D0CC00049C, Communication

Fang Xian, Jiedong Li, Zhenglin Hu, Qian Zhou, Chen Wang, Chenglong Lu, Zhongyi Zhang, Shanmu Dong, Chunbo Mou, Guanglei Cui
We adopted a SN based deep eutectic electrolyte with the SN as the only solvent and found that the high-state Co ion could be reduced by the SN solvent on the interface of the LiCoO₂ electrode, causing a reverse phase change of the LiCoO₂.
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Chem. Commun., 2020, 56,5058-5061
DOI: 10.1039/D0CC00641F, Communication

Xiao-Yue Chen, Xiao-Xue Nie, Yichen Wu, Peng Wang
Using thianthrene S-oxide (TTSO) as a transient mediator, para-arylation and alkenylation of mono-substituted arenes have been demonstrated via a para-selective thianthrenation/Pd-catalyzed thio-Suzuki–Miyaura coupling sequence under mild conditions.
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Chem. Commun., 2020, 56,5010-5013
DOI: 10.1039/C9CC09869K, Communication

Binbin Huang, Chao Yang, Jia Zhou, Wujiong Xia
This study presents a straightforward protocol for approaching N-sulphonylamidines via an electricity-driven, iodine-mediated cross dehydrogenative condensation (CDC) between sulphonamides and tertiary amines.
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Chem. Commun., 2020, 56,5054-5057
DOI: 10.1039/D0CC01188F, Communication

Suman Pradhan, Sandeep Patel, Indranil Chatterjee
Aromatic amines and (hetero)arenes, such as indoles and pyrroles, are regioselectively sulfinylated under mild aerobic conditions using nitrosoarenes as a redox-catalyst.
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Chem. Commun., 2020, 56,5022-5025
DOI: 10.1039/D0CC01005G, Communication

Ganesh S. Ghotekar, Sachin R. Shirsath, Aslam C. Shaikh, M. Muthukrishnan
An expedient one-pot synthesis of carbocyclic spiro[5.5]undeca-1,4-dien-3-ones via 1,6-conjugate addition initiated formal [4+2] annulation sequences by employing p-quinone methides and sulfonyl allenols.
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Chem. Commun., 2020, 56,5006-5009
DOI: 10.1039/D0CC01197E, Communication

Wenhuai Feng, Chengxi Zhang, Jun-Xing Zhong, Liming Ding, Wu-Qiang Wu
Anchoring of amine ligands with different alkyl chain lengths on perovskites mitigates non-radiative charge recombination in perovskite solar cells.
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Chem. Commun., 2020, 56,5042-5045
DOI: 10.1039/D0CC01219J, Communication

Lingling Tao, Zhe Sun, Lei Chen, Mao Liang, Song Xue
The combination of a zinc stannate photoanode and cobalt complex electrolyte in DSCs yields an impressive power conversion efficiency of 8.1%.
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Chem. Commun., 2020, 56,5030-5033
DOI: 10.1039/D0CC00768D, Communication

Xin Yu, Yang Yang, Wufang Yang, Xungai Wang, Xin Liu, Feng Zhou, Yan Zhao
Organic solvents that possess affinity towards both polar monomers and hydrophobic PDMS play a “driving” role in the diffusion of polar monomers into the subsurface of the PDMS substrate.
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Chem. Commun., 2020, 56,5034-5037
DOI: 10.1039/D0CC01796E, Communication

Fatimat O. Badmus, Joshua A. Malone, Frank R. Fronczek, Rendy Kartika
An expedient synthesis of highly substituted tetrahydrobenzofuran via an unsymmetrical silyloxyallyl cation is reported.
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Chem. Commun., 2020, 56,4990-4993
DOI: 10.1039/D0CC01488E, Communication

Dan Guo, Huayu Chen, Hanmin Tian, Shuxin Ouyang, Jianbo Wang, Jun Lv
A strategy involving modulating the intermediate layer of an electrode was developed to promote the electrocatalysis kinetics of the electrode and therefore enhance its performance.
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Chem. Commun., 2020, 56,5046-5049
DOI: 10.1039/C9CC09563B, Communication

Kostadin V. Petrov, Laura Paltrinieri, Lukasz Poltorak, Louis C. P. M. de Smet, Ernst J. R. Sudhölter
A novel ion separation methodology using a cation-exchange membrane modified with iron oxide nanoparticles (Fe₃O₄ NPs) coated with polyhexamethylene guanidine (PHMG) is proposed.
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Chem. Commun., 2020, 56,5002-5005
DOI: 10.1039/D0CC01720E, Communication

Jiang-Ling Shi, Yuankai Wang, Zixuan Wang, Bowen Dou, Jianbo Wang
Ring-opening iodination or bromination of unstrained cycloalkanols with NaI or NaBr and PhI(OAc)₂ under visible light irradiation is developed.
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Chem. Commun., 2020, 56,5038-5041
DOI: 10.1039/D0CC01316A, Communication

Ruzhang Liu, Zhen Wei, Juan Wang, Yongmei Liu, Huaiguo Xue
Pt-catalyzed hydrosilylation of equilibrating allylic azides provides 3-azidopropansilanes with high chemoselectivity, regioselectivity, and excellent functional group tolerance.
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