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[ASAP] Update to Our Reader, Reviewer, and Author Communities—April 2020

Organometallics
DOI: 10.1021/acs.organomet.0c00266




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[ASAP] Synthesis, Characterization, and Catalytic Reactivity of {CoNO}<sup>8</sup> PCP Pincer Complexes

Organometallics
DOI: 10.1021/acs.organomet.0c00167




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[ASAP] Catalytic C–H Bond Alkylation of Azoles with Alkyl Halides Mediated by Nickel(II) Complexes of Phenanthridine-Based <italic toggle="yes">N</italic>^<italic toggle="yes">N</italic><sup><italic tog

Organometallics
DOI: 10.1021/acs.organomet.0c00161




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[ASAP] Transformation of a Norbornadiene Unit to Ethylenylcyclopentene Requiring Cooperation between Boron and Rhodium Centers

Organometallics
DOI: 10.1021/acs.organomet.0c00155




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[ASAP] NHC-Palladium(II) Mononuclear and Binuclear Complexes Containing Phenylene-Bridged Bis(thione) Ligands: Synthesis, Characterization, and Catalytic Activities

Organometallics
DOI: 10.1021/acs.organomet.0c00091




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[ASAP] C–F Bond Activation of a Perfluorinated Ligand Leading to Nucleophilic Fluorination of an Organic Electrophile

Organometallics
DOI: 10.1021/acs.organomet.0c00176




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[ASAP] Spatial Recognition Within Terpenes: Redox and H-bond Promoted Linkage Isomerizations and the Selective Binding of Complex Alkenes

Organometallics
DOI: 10.1021/acs.organomet.0c00151




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[ASAP] Linkage Isomerism in Dinuclear Al and Ga Organometallic Complexes: Structural and Reactivity Consequences

Organometallics
DOI: 10.1021/acs.organomet.0c00096




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[ASAP] Electrosynthetic Route to Cyclopentadienyl Rhenium Hydride Complexes Enabled by Electrochemical Investigations of their Redox-Induced Formation

Organometallics
DOI: 10.1021/acs.organomet.0c00049




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[ASAP] A Stiboranyl Platinum Triflate Complex as an Electrophilic Catalyst

Organometallics
DOI: 10.1021/acs.organomet.0c00193




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[ASAP] Synthesis and Characterization of an Oxo-Centered Homotrimetallic Uranium(IV)–Cyclobutadienyl Dianion Complex

Organometallics
DOI: 10.1021/acs.organomet.0c00104




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[ASAP] Development of Quinoline-Derived Chiral Diaminocarbene Ligands and Their Transition Metal Complexes: Synthesis, Structural Characterization, and Catalytic Properties

Organometallics
DOI: 10.1021/acs.organomet.0c00141




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[ASAP] Synthesis and Characterization of Tungsten Alkylidene and Alkylidyne Complexes Featuring a New Carbazole-Based Rigid Trianionic ONO<sup>3–</sup> Pincer-Type Ligand

Organometallics
DOI: 10.1021/acs.organomet.0c00150




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[ASAP] Heteroleptic ß-Ketoiminate Magnesium Catalysts for the Ring-Opening Polymerization of Lactide

Organometallics
DOI: 10.1021/acs.organomet.0c00168




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[ASAP] Use of Ligand Steric Properties to Control the Thermodynamics and Kinetics of Oxidative Addition and Reductive Elimination with Pincer-Ligated Rh Complexes

Organometallics
DOI: 10.1021/acs.organomet.0c00122




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[ASAP] Catalytic Dimerization of Alkynes via C–H Bond Cleavage by a Platinum–Silylene Complex

Organometallics
DOI: 10.1021/acs.organomet.0c00195




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[ASAP] Synthesis, Structures, and Electronic Properties of O- and S-Heterocyclic Carbene Complexes of Iridium, Copper, Silver, and Gold

Organometallics
DOI: 10.1021/acs.organomet.0c00066




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No word in Rail Budget on track conversion in Tripura:Minister

have sought clarification on plans of converting the meter gauge railway lines into broad gauge:Transport minister Manik Dey




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Celebrities on KickStarter

This weeks show is kindly supported by Insites: ConfShop — A unique one day event for web workers focused on openness, sharing and learning taking place in London on Friday July 5th. Tickets are limited to 100 and are available for £125.

In this episode we tell you about our new “studio”, discuss the route to inner nirvana (no really), the “problem” of celebrities on KickStarter and ask whether Ghost is the future of blogging as we know it.

Thanks again to Insites: ConfShop for supporting this weeks episode.




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The Joys &#038; Perils of Remote Working

In a change to the announced billing, an impromptu early morning phone call made us think a chat about remote working might be in order. As many of us fight the January blues, and inevitable bout of illness that the new year often brings, it felt a timely opportunity to discuss the good, and the bad, aspects of working from a distance.

Topics we discuss include:

  • How does working remotely affect us?
  • What we both like and dislike about it
  • How much real work you achieve per day
  • The importance of “banter”
  • Is the reality like the dream?
  • A typical day for remote working?
  • Do we put extra pressure on ourselves to output more as we are not in the office?
  • How to feel part of the company you work for

And finally for those Nabaztag doubters out there you can read the full history of the internet enabled rabbit on Wikipedia!

Five Simple Steps Giveaway

To be in with a chance of winning one of the two sets of Five Simple Step’s Pocket Guide Collection 3 all you have to do it answer one of the following two questions correctly. Kieran’s decision will be final (he’s a harsh judge):

  1. Q: What was Matthew Lillard’s handle in the cult-classic 1995 film Hackers?
  2. Q: In the same year Sandra Bullock played a Systems Analyst in the film The Net. During the course of the film her identity is changed by cyber criminals but what is the name they gave her?

To enter just send a tweet to @backtofrontshow with your answer. We’ll announce winners on the next episode.




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Back Stories with Marc Thiele

Welcome to Back Stories — a new series of one on one interviews hosted by Keir Whitaker (one-half of the team behind The Back to Front Show).

Each episode, unlike the usual show, will come in at 30 minutes and will attempt to delve into the interesting lives of people working in the web, design, tech, publishing, and creative industries.

In this first episode, Keir chats with Marc Thiele — long-time friend and the man behind the Beyond Tellerrand series of web conferences. There’s plenty of ground covered including the early 8 bit days, Flash, events, and more.

Marc Online




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Back Stories with Craig Lockwood

Welcome to the second episode of Back Stories — a new series of one on one interviews hosted by Keir Whitaker (one-half of the team behind The Back to Front Show).

In this episode, Keir is joined by Craig Lockwood — long time friend of the show and the man behind endeavours including software, events, co-working spaces, and more. In this very open and honest account of his work and life, Craig shares his experiences of working in the web and tech industry.

Craig Online




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Back Stories with Kurt Elster

In this episode of Back Stories, Keir chats with Kurt Elster — founder of ecommerce agency Ethercycle, host of the popular Ecommerce Hacks Weekly video series, author of Ecommerce Bootcamp, and the host of The Unofficial Shopify Podcast.

Topics include the benefits of the “peacock” jacket, naming your company, specialisation, automating inbound leads, productised consulting, and much more.

Kurt Online




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Back Stories with Oliver Lindberg

In this episode of Back Stories, Keir chats with Oliver Lindberg— founder of the new Pixel Pioneers web conference series and all round content guru. Topics covered include how to find speakers for your conference, the role of a good editor, how to improve your writing skills, and how to pitch to an editor.

Oliver Online




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Muppetry &amp; other Stories

Happy 2018! Eschewing a long-standing tradition of not actually releasing shows we are kicking off the year as we mean to go on (for now) with a brand spanking new edition!

Join us for 50 glorious high fidelity minutes (true for one of us) and celebrate five years of the show. We don’t dwell too long on our golden non-award winning archive and go on to indulge in some chat, review a book, have a moan about Kickstarter projects, and for once don’t end on dog tech!




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IIEBM - Learning experience for gen-next leaders

If you are an aspiring management student, you might have been storming your head after reading about all the academic rigour and jam-packed schedules that o...




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Resource Showcase: Trial e-resources

British Online Archives: Providing access to over 80 collections of primary resources, the website hosts over 3 million records drawn from both private and public archives. These records are organised thematically, covering 1,000 years of world history, from politics and warfare to slavery and medicine. This is one of many e-resources we currently have on trial. You can see the complete list and gain access via our trial e-resources page. Please remember to leave feedback – your opinions help shape our collections.




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Resource Showcase: Trial e-resources

IBISWorld: A leading global provider of industry research and analysis. With over 6000 granular reports across 5 geographies, IBISWorld supports curriculum and course development, student assignments and projects, careers counselling/employability, entrepreneurship and new business start-up preparation. This is one of many e-resources we currently have on trial. You can see the complete list and gain access via our trial e-resources page. Please remember to leave feedback – your opinions help shape our collections.




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Resource Showcase: Daily Mirror Historical Archive

The archive features more than 800,000 pages of brand-new, full text searchable, scans of the complete run of the Mirror from 1903-2000, including the Sunday Mirror. This is one of many e-resources we currently have on trial. You can see the complete list and gain access via our trial e-resources page. Please remember to leave feedback – your opinions help shape our collections. See what other newspapers and news services are available via Durham University Library and Collections




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Simplifying levulinic acid conversion towards a sustainable biomass valorisation

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04306C, Paper
Chiara Defilippi, Daily Rodríguez-Padrón, Rafael Luque, Cristina Giordano
In the range of biomass valorisation, hydroconversion of levulinic acid (one of the products of the hydrolysis of lignocellulosic biomass) was tested for the first time using nanosized Ni3N and Ni0 catalysts, with very promising results alongside high stability.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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One-pot hydrodeoxygenation of biomass furan derivatives into decane under mild conditions over Pd/C combined with phosphotungstic acid

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00428F, Paper
Song Li, Long Yan, Qiying Liu, Jianguo Liu, Qiyu Liu, Wei Fan, Xuelai Zhao, Xinghua Zhang, Chenguang Wang, Longlong Ma, Qi Zhang
One-pot hydrodeoxygenation of δ-furfurylidenelevulinic acid over Pd/C combined with phosphotungstic acid through successive hydrogenolysis and HDO of furans and lactones.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Water Effects in the Heterogeneous Catalytic Valorization of Levulinic Acid into γ-Valerolactone and its Derivatives

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01082K, Critical Review
Rengui Weng, Zhihao Yu, Jian Xiong, Xuebin Lu
Levulinic acid (LA), which has been hailed as a versatile biomass-derived platform molecular, typically occupy a core position in the cellulosic biorefinery system. The heterogeneous catalytic valorization of LA for...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Methylation-triggered fractionation of lignocellulosic biomass to afford cellulose-, hemicellulose-, and lignin-based functional polymers via click chemistry

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00451K, Paper
Kentaro Miki, Hiroshi Kamitakahara, Arata Yoshinaga, Yuki Tobimatsu, Toshiyuki Takano
This paper reports a new concept for the biorefinery of lignocellulosic biomass where the derivatisation and fractionation of lignocellulose are accomplished at the same time.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Photocatalyst-free visible light promoted E → Z isomerization of alkenes

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04303A, Communication
Jianbin Xu, Na Liu, Haiping Lv, Chixian He, Zining Liu, Xianfu Shen, Feixiang Cheng, Baomin Fan
A photocatalyst-free, simple and green method of visible light driven photocatalytic E to Z isomerization of alkenes has been developed.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Eco-friendly and sustainable synthesis of biocompatible nanomaterials for diagnostic imaging: current challenges and future perspectives

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00734J, Critical Review
Ghazaleh Jamalipour Soufi, Siavash Iravani
Current advancements, important challenges and future perspectives of biocompatible nanomaterials for diagnostic imaging are discussed as well as their greener synthesis.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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New biobased-zwitterionic ionic liquids: efficiency and biocompatibility for the development of sustainable biorefinery processes

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC01002B, Paper
Gaël Huet, Monica Araya-Farias, Ranim Alayoubi, Sylvain Laclef, Benjamin Bouvier, Isabelle Gosselin, Christine Cézard, Romain Roulard, Matthieu Courty, Caroline Hadad, Eric Husson, Catherine Sarazin, Albert Nguyen Van Nhien
A combination of experiments and modeling reveals the influence of alkyl chain lengths in biobased ZILs on the biocompatibility towards various microorganisms.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of amorphous Geobacter-manganese oxide biohybrid as efficient water oxidation catalysts

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9GC04353E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shafeer Kalathil, Krishna Katuri, Pascal Saikaly
The development of low cost and efficient oxygen evolution reaction (OER) catalyst has paramount importance to meet future sustainable energy demand. Nature’s photosynthetic machinery deploy manganese-based complex in photosystem II...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Ga/ZSM-5 catalyst improves hydrocarbon yields and increases alkene selectivity during catalytic fast pyrolysis of biomass with co-fed hydrogen

Green Chem., 2020, 22,2403-2418
DOI: 10.1039/C9GC03408K, Paper
Kristiina Iisa, Yeonjoon Kim, Kellene A. Orton, David J. Robichaud, Rui Katahira, Michael J. Watson, Evan C. Wegener, Mark R. Nimlos, Joshua A. Schaidle, Calvin Mukarakate, Seonah Kim
An integrated experimental and computational study to understand the catalytic upgrading of biomass vapors into high yield of alkenes.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Dioxomolybdenum complex as an efficient and cheap catalyst for the reductive depolymerization of plastic waste into value-added compounds and fuels

Green Chem., 2020, 22,2419-2425
DOI: 10.1039/C9GC04206G, Paper
Beatriz F. S. Nunes, M. Conceição Oliveira, Ana C. Fernandes
Several types of PCL, PLA, PDO, PET and PBT plastic waste were efficiently converted into value-added compounds and fuels catalyzed by MoO2Cl2(H2O)2.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Sustainability by design: automated nanoscale 2,3,4-trisubstituted quinazoline diversity

Green Chem., 2020, 22,2459-2467
DOI: 10.1039/D0GC00363H, Paper
Open Access
Mojgan Hadian, Shabnam Shaabani, Pravin Patil, Svitlana V. Shishkina, Harry Böltz, Alexander Dömling
Automated, one step, nanoscale synthesis of 2,3,4-trisubstituted quinazoline derivatives using positive pressure facilitated dispensing to access a very large chemical space exemplified by more than 1000 compounds.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Novel insights into biomass delignification with acidic deep eutectic solvents: a mechanistic study of β-O-4 ether bond cleavage and the role of the halide counterion in the catalytic performance

Green Chem., 2020, 22,2474-2487
DOI: 10.1039/C9GC02569C, Paper
André M. da Costa Lopes, José R. B. Gomes, João A. P. Coutinho, Armando J. D. Silvestre
The potentiality of acidic deep eutectic solvents for β-O-4 ether bond cleavage is herein demonstrated from a mechanistic point of view.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Efficient base-free oxidation of monosaccharide into sugar acid under mild conditions using hierarchical porous carbon supported gold catalysts

Green Chem., 2020, 22,2588-2597
DOI: 10.1039/C9GC04333K, Paper
Xintong Meng, Zengyong Li, Di Li, Yiming Huang, Jiaojiao Ma, Chuanfu Liu, Xinwen Peng
The highly selective synthesis of D-xylonic acid and D-gluconic acid from monosaccharide catalyzed by Au/NC-3 under base-free aerobic oxidation conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of bioderived polycarbonates with adjustable molecular weights catalyzed by phenolic-derived ionic liquids

Green Chem., 2020, 22,2488-2497
DOI: 10.1039/D0GC00493F, Paper
Wei Qian, Lei Liu, Zengliang Zhang, Qian Su, Weizhen Zhao, Weiguo Cheng, Li Dong, Zifeng Yang, Ruibing Bai, Fei Xu, Yanqiang Zhang, Suojiang Zhang
Phenolic ionic liquid structure can be designed readily to control the molecular weight of isosorbide-derived polycarbonates.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Fabrication of highly proton-conductive chitosan whole-bio-membrane materials functionalized with adenine and adenosine monophosphate

Green Chem., 2020, 22,2426-2433
DOI: 10.1039/C9GC04104D, Paper
Guanglei Zhao, Yuanyuan Chen, Xiao-Feng Li, Sihan Zhang, Yuanqiu Situ
A successful strategy to prepare novel proton-conductive chitosan membrane biomaterials functionalized with adenine and adenosine monophosphate via a one-pot grafting procedure.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A non-phosgene process for bioderived polycarbonate with high molecular weight and advanced property profile synthesized using amino acid ionic liquids as catalysts

Green Chem., 2020, 22,2534-2542
DOI: 10.1039/D0GC00265H, Paper
Zhencai Zhang, Fei Xu, Yaqin Zhang, Chenhao Li, Hongyan He, Zifeng Yang, Zengxi Li
Bio-based polycarbonate with high molecular weight and advanced property profile was synthesized using amino acid ionic liquids as catalysts.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Solvent-free and montmorillonite K10-catalyzed domino reactions for the synthesis of pyrazoles with alkynylester as a dual synthon

Green Chem., 2020, 22,2388-2393
DOI: 10.1039/D0GC00162G, Communication
Sesuraj Babiola Annes, Rajendhiran Saritha, Saravanan Subramanian, Bhaskaran Shankar, Subburethinam Ramesh
A highly regioselective, solvent-free and montmorillonite K10 clay-catalyzed domino process with an unprecedented C–C bond formation reaction is described for the synthesis of new class of tri-substituted and di-substituted pyrazole derivatives.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Base-mediated benzannulation of α-cyanocrotonates with ynones: facile synthesis of benzonitriles and fluorenes

Green Chem., 2020, 22,2370-2374
DOI: 10.1039/D0GC00608D, Communication
Maneesh Kumar Reddy Singam, Attunuri Nagireddy, Sridhar Reddy Maddi
Benzonitriles and cyanofluorenes have been rapidly obtained via the [3 + 3] benzannulation of readily available alkynones and α-cyanocrotonates using KOtBu as the only reagent and EtOH (and CO2) is the only by-product.
The content of this RSS Feed (c) The Royal Society of Chemistry




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One-pot synthesis of 1,3-butanediol by 1,4-anhydroerythritol hydrogenolysis over a tungsten-modified platinum on silica catalyst

Green Chem., 2020, 22,2375-2380
DOI: 10.1039/D0GC00244E, Communication
Lujie Liu, Takehiro Asano, Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige
Chemical production of 1,3-butanediol from biomass-derived compounds was first reported by 1,4-anhydroerythritol hydrogenolysis over a Pt–WOx/SiO2 catalyst.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Iridium-catalyzed orthogonal and regioselective synthesis of triazole disulfides in aqueous media under mild conditions

Green Chem., 2020, 22,2394-2398
DOI: 10.1039/D0GC00555J, Communication
Ming Li, Nan Zheng, Junhao Li, Yubin Zheng, Wangze Song
Triazole disulfides were prepared in water or biological media under mild conditions by orthogonal and regioselective Ir-catalyzed reactions.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Using dialkyl amide via forming hydrophobic deep eutectic solvents to separate citric acid from fermentation broth

Green Chem., 2020, 22,2526-2533
DOI: 10.1039/C9GC04401A, Paper
Lijuan Liu, Qifeng Wei, Yong Zhou, Xiulian Ren
The separation of citric acids was realized by utilizing hydrophobic deep eutectic solvents (DESs), which were formed by using N,N-dibutylacetamide as a hydrogen acceptor and citric acid as the hydrogen bond.
The content of this RSS Feed (c) The Royal Society of Chemistry