Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02385D, Review Article

Jiayu Li, Ertai Na, Xudong Liang, Qihua Liang, Meihong Fan, Hui Chen, Guodong Li, Xiaoxin Zou
With the development of science and technology, the demand for reliable and efficient gas sensors in various applications, ranging from environmental monitoring to industrial safety, is increasing. In particular, MOS...
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01824A, Research Article

Qianyi Chen, Zhenjie Lun, Dongdan Chen, Yongsheng Sun, Puxian Xiong, Siyun Li, Shanhui Xu, Zhongmin Yang
A defect engineering strategy mediated by the structural cationic substitution is proposed and experimentally demonstrated for ultra-broadband emission in a garnet Y₃Sc₂Al₃O₁₂:B³⁺ phosphor.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02149E, Research Article

Jing-Ning Lv, Na Lin, Jia-Yi Zhang, Yu-Meng Liu, Li-Chuang Niu, Jie Shi, Xiao-Wu Lei, Zhi-Wei Chen
A cuprous hybrid halide with high efficient photoluminescence and anti-water stability was prepared by reasonably selecting a hydrophobic organic cation, which allows this halide as a high-performance scintillator for X-ray imaging.
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02070G, Research Article

Bei An, Xiaoqian Li, Yuan Lin, Fanfan Shang, Huijie He, Hairui Cai, Xiaoxiao Zeng, Weitong Wang, Shengchun Yang, Bin Wang
Oxygen evolution reaction (OER) plays a crucial role as the anode reaction of electrolytic water in various applications. To date, it is still a great challenge to develop highly active...
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02314E, Research Article

Xinwen Dou, Mingyue Liu, Tian Cao, Chan Wang, Yingjie Zhang, Yuhang Jia, Qiang Ju, Zhenlan Fang
Effects of four kinds of post-treatment strategies on the structures, morphologies, and electrochemical behaviors of MOF derivatives are systematically investigated for the first time.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02182G, Research Article

Haiyan He, Yue Lan, Jinlong Qin, Quanguo Jiang, Lu Yang, Jian Zhang, Huajie Huang
An in situ soft-chemistry approach is adopted for fabricating 3D porous rhodium–copper alloy nanoflowers stereoassembled on ultrathin Ti₃C₂T_x lamellas, which are able to serve as highly-efficient electrocatalysts toward alkaline methanol oxidation.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01947D, Research Article

Hyeonggeun Choi, Seunghwan Jo, Ki Hoon Shin, HeeYoung Lim, Liting Zhang, Keon Beom Lee, Young-Woo Lee, Jung Inn Sohn
A charge valence state and surface-electronegativity-modulated NiMoCuCo composite is proposed as an active and durable alkaline hydrogen evolution reaction electrocatalyst with moderated hydroxide adsorption energy.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01996B, Research Article

Alexander V. Artem'ev, Maxim I. Rogovoy, Ilia M. Odud, Maria P. Davydova, Marianna I. Rakhmanova, Pavel A. Petrov, Valery K. Brel, Oleg I. Artushin, Konstantin A. Brylev, Denis G. Samsonenko, Alexey S. Berezin, Dmitry E. Gorbunov, Nina P. Gritsan
Tetraphosphine-carbene Cu(I), Ag(I) and Au(I) complexes, synthesized via a symmetry-based design strategy, exhibit cyan to yellow TADF with excellent quantum yields (58–89%) and reduced lifetimes.
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02230K, Research Article

Yifei Li, Senyao Meng, Ping Wang, Miao He, Jiasai Yao, Cheng Yang, Fangzhou Mo, Jiang Li, Zhenxing Li
The crystal facet of CeO2 is crucial in governing the catalytic performance. However, studies on the relationship between the photocatalytic oxidation performance of CeO2 and its crystal facets are scarce....
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Inorg. Chem. Front., 2024, 11,7860-7871
DOI: 10.1039/D4QI00404C, Research Article

Shalu Atri, Vipul Vilas Kusumkar, Süleyman İnan, Maros Gregor, Tomas Roch, Maria Caplovicova, Michal Galambos, Eva Viglasova, Gustav Plesch, Martin Motola, Olivier Monfort
The potential activity of Fe₃O₄ decorated MXenes in the removal of highly toxic ¹³³Ba and ¹³⁷Cs using a radioactive indicator method.
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Inorg. Chem. Front., 2024, 11,7793-7802
DOI: 10.1039/D4QI00970C, Research Article

Xin Xu, Zhongyi Wang, Qingkun Kong, Siping Liu, Ruiling Zhang, Xiaojing Liu, Keli Han
Metastable 1D β-Cs₃Cu₂Br₅ synthesized by rapid cooling could be stabilized by Ag⁺. Ag-alloyed samples exhibit tunable emission from blue-greenish to yellow, which is attributed to different degrees of lattice distortion regulated by Ag⁺.
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Inorg. Chem. Front., 2024, 11,7803-7811
DOI: 10.1039/D4QI01846J, Research Article

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Aarón Terán, Francesca Fasulo, Giarita Ferraro, Ana Edilia Sánchez-Peláez, Santiago Herrero, Michele Pavone, Ana Belén Muñoz-García, Antonello Merlino
The reactivity of [Ru₂Cl(D-p-CNPhF)(O₂CCH₃)₃]_n (D-p-CNPhF⁻ = N,N'-bis(4-cyanophenyl)formamidinate) with the model protein RNase A has been investigated by X-ray crystallography and Quantum Chemistry.
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Inorg. Chem. Front., 2024, 11,7872-7885
DOI: 10.1039/D4QI01874E, Research Article

Open Access

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Gaia Urciuoli, Francesco Zaccaria, Cristiano Zuccaccia, Roberta Cipullo, Peter H. M. Budzelaar, Leonardo Tensi, Antonio Vittoria, Christian Ehm, Alceo Macchioni, Vincenzo Busico
The stability and reactivity of {[iBu₂(L)Al]₂(μ-H)}⁺[B(C₆F₅)₄]⁻ (AlHAl), recently identified as a promising cocatalyst for olefin polymerization, can be modulated by varying the structure of the neutral N-donor (L).
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Inorg. Chem. Front., 2024, 11,7930-7935
DOI: 10.1039/D4QI01965B, Research Article

Dipanwita Palit, Debasish Manna
TET enzymes play a key role in epigenetic regulation by oxidizing 5-methylcytosine, impacting gene expression and DNA methylation. Here, we report a chemical model of the TET enzyme which selectively and catalytically oxidize 5-hydroxymethylcytosine.
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Inorg. Chem. Front., 2024, 11,7966-7978
DOI: 10.1039/D4QI02373K, Research Article

Pawel J. Bonarek, Mikolaj Zychowicz, Jan Rzepiela, Michal Liberka, Sebastian Baś, Jakub J. Zakrzewski, Szymon Chorazy
Dysprosium(III) single-molecule magnets are bridged within a coordination polymer by Pt(II)-cyanido metalloligands serving as their temperature sensors.
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Inorg. Chem. Front., 2024, 11,8003-8015
DOI: 10.1039/D4QI02005G, Research Article

Jiawei Liu, Xin Liu, Chunhui Dai, Chao Zeng, Sajjad Ali, Mohamed Bououdina, Yushuai Jia
Bi₂MoO₆ catalysts doped by monovalence Cu with self-adapting O vacancies (Ov) are prepared. The optimal Bi₂MoO₆–10% Cu exhibits an outstanding CO evolution rate of 11.40 μmol g⁻¹ h⁻¹, about 6 times higher than that of Bi₂MoO₆ (1.94 μmol g⁻¹ h⁻¹).
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Inorg. Chem. Front., 2024, 11,7979-7990
DOI: 10.1039/D4QI01904K, Research Article

Bao Ke, Hui Peng, Yongqi Yang, Chengzhi Yang, Shangfei Yao, Arfan Bukhtiar, Qilin Wei, Jialong Zhao, Bingsuo Zou
Here, we report a new NIR emitter of Sb³⁺-doped tin(IV)-based metal halides via coordination structure modulation, which can exhibit bright broadband NIR emission under blue light excitation with a PLQY of 33.2%.
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Inorg. Chem. Front., 2024, 11,8130-8138
DOI: 10.1039/D4QI02088J, Research Article

Bei-Bei Zhang, Wen-Ye Gao, Wei Xu, Liang Ma, Wenlong Liu, Ru-Ling Tang, Sheng-Ping Guo
The acentric Ce(IV) fluoride NH₄Ce₃F₁₃ is systematically studied, exhibiting the strong SHG effect (1.2 × KDP) and high LIDTs (39 × AGS). It also possesses the largest band gap among NLO materials containing Ce(IV).
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Inorg. Chem. Front., 2024, 11,8078-8092
DOI: 10.1039/D4QI01704H, Research Article

Zhengzheng Xu, Yanjiao Li, Shiqi Li, Yingying Chen, Majid Farahmandjou, Guoxiu Wang, Hongxun Yang, Hao Tian
A facile and general strategy is developed for constructing graphene aerogels with in situ encapsulated bimetallic selenide heterostructure materials exhibiting high rate-capabilities and long cycling stabilities in sodium-ion batteries.
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Inorg. Chem. Front., 2024, 11,7898-7909
DOI: 10.1039/D4QI01765J, Research Article

Open Access

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Huayun Shi, Guy J. Clarkson, Peter J. Sadler
The photochemotherapeutic activity of diazido Pt(IV) complexes towards bladder cancer, a common cancer with expensive treatment, has been tuned via modification of trans N-heterocyclic ligands, to give a candidate for preclinical development.
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Inorg. Chem. Front., 2024, 11,7921-7929
DOI: 10.1039/D4QI01818D, Research Article

Miriam Abán, J. Marco Cuenca, Irene Embid, Alba de Toro, Pilar Gómez-Sal, Ernesto de Jesús, Marta Valencia, Cristina G. Yebra
[CpIr(CO)H₂] efficiently catalyses formic acid dehydrogenation, forming in situ from pyridyl-triazole pre-catalysts [Cp*Ir(k²-NN)(Cl)][OTf]. Neat formic acid is dehydrogenated with a TON of up to 26876 and a TOF exceeding 10700 h⁻¹.
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Inorg. Chem. Front., 2024, 11,7843-7852
DOI: 10.1039/D4QI02234C, Research Article

Chenxu Li, Abudukadi Tudi, Huanhuan Cheng, Qingyu Liu, Zhihua Yang, Shilie Pan
High-throughput screening of 222 hydroxyborates identified three as promising short-wavelength ultraviolet nonlinear optical. with phase-matching second harmonic generation capacity extending to the solar blind region (200–280 nm).
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Inorg. Chem. Front., 2024, 11,8110-8122
DOI: 10.1039/D4QI01934B, Research Article

Hongbo Zhou, Xuan Hao, Jiexin Guan, Yilin Deng, Zi Wei, Yashu Liu, Guoxing Zhu
The 2,2'-bpy coordination shells surrounding the Ni/Fe active sites of NiFe(2,2'-bpy)_n@CNT materials effectively boost OER catalysis.
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Inorg. Chem. Front., 2024, 11,8101-8109
DOI: 10.1039/D4QI01796J, Research Article

Yong-Zheng Zhang, Xin-Dan Zhang, Yan-Kai Zhang, Fu-Tian Wang, Longlong Geng, Hui Hu, Zhen Li, Da-Shuai Zhang, Hongliang Huang, Xiuling Zhang
A novel mixed-ligand metal–organic framework, featuring naphthalene rings in its secondary linker, exhibits exceptional benzene adsorption and separation capacities.
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Inorg. Chem. Front., 2024, 11,8139-8145
DOI: 10.1039/D4QI02061H, Research Article

Nan Li, Lujiao Mao, Yuting Fu, Haoran Wang, Yuchang Shen, Xuemei Zhou, Qipeng Li, Jinjie Qian
This study demonstrates a new approach for Ru-anchoring CoOF-1-derived porous Ru-Co₃O₄ nanomaterials with high activity and durability, showcasing great potential in the field of practical energy storage and conversion.
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Inorg. Chem. Front., 2024, 11,8146-8146
DOI: 10.1039/D4QI90072C, Correction

Open Access

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Ru-Ling Tang, Gang-Xiang Liu, Wen-Dong Yao, Li-Nan Zhang, Wenlong Liu, Sheng-Ping Guo
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Inorg. Chem. Front., 2024, 11,8147-8147
DOI: 10.1039/D4QI90073A, Correction

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Maddalena Paolillo, Giarita Ferraro, Irene Cipollone, Eugenio Garribba, Maria Monti, Antonello Merlino
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02333A, Research Article

Weiwei Bao, Mameng Yang, Taotao Ai, Jie Han, Zhifeng Deng, Xiangyu Zou, Peng Jiang, Junjun Zhang
The oxygen-containing anion formed by electrooxidation and leaching on the electrode surface can effectively improve the catalytic activity of UOR and provide an accurate way for the energy saving hydrogen production assisted by urea.
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02372B, Research Article

Guo-guo Zhang, Pengtao Qiu, Jiaxin Kang, Zhiwei Lu, An-qi Zhu, Xiaohu Yu, Xuenian Chen
Solid-state potassium metal batteries have increasingly gained attention as promising alternatives in large-scale energy storage due to their safety and low cost. However, these batteries usually suffer from a lack...
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02143F, Research Article

Tongzheng Zhang, Zhaohui Huang, Guanshun Xie, Le Liao, Changqiang Yu, Xiuqiang Xie, Nan Zhang
La/Ni-MOF with oxygen vacancies and regulated electronic structures is prepared and exhibits enhanced visible-light photocatalytic activity for CO₂-to-CO conversion.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02325K, Research Article

Weijie Fang, Chaofan Liu, Jiang Wu, Weikai Fan, Le Chen, Zaiguo Fu, Lin Peng, Ping He, Jia Lin, Zhongwei Chen
The moss-like amorphous CoB/crystalline CeO₂ heterojunction nanosheets synthesized in this study have excellent OER activity and stability.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02350A, Research Article

Zongyi Wang, Jiuli Chang, Zhiyong Gao
Nitrate–methanol co-electrolysis by the pairwise cathodic NO₃RR and anodic MOR is a viable way to coproduce ammonia (NH₃) and formate via gentle, sustainable and energy-saving “E-refining” and “E-reforming” means.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02451F, Review Article

Chunwen Sun
The progress of nanoengineering of electrodes fabricated by various methods for SOFCs operating at low and intermediate temperatures is reviewed. Future research directions on nanoengineering of cathodes for next-generation SOFCs are also provided.
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI01916D, Research Article

Jinggao Wu, Canyu Zhong, Xiaofan Chen, Jing Huang
Li3V2(PO4)3 (LVP)-coated with N and S co-doped carbon (NSC) is investigated by DFT calculation, suggesting that NSC significantly enhances electronic conductivity and lowers Li+ migration energy barrier in comparison to...
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02228A, Review Article

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Zongsu Han, Joshua Rushlow, Yihao Yang, Jiatong Huo, Wei Shi, Hong-Cai Zhou
Lithium extraction attracts great attention due to the rising demand for batteries, but faces challenges related to low natural abundance and environmental concerns. MOFs show promise in lithium extraction, benefitting from customizable structures.
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02262A, Research Article

Tamara A. Bazhenova, Vyacheslav Kopotkov, Denis V. Korchagin, Elena Yureva, Michael V. Zhidkov, Alexey I Dmitriev, Ilya Yakushev, N. N. Efimov, Konstantin Andreevich Babeshkin, Vladimir Sergeevich Mironov, Eduard B. Yagubskii
A series of three new seven-coordinate pentagonal-bipyramidal (PBPY-7) Dy(III) complexes [Dy(L^CH3)(Cy₃PO)₂]ClO₄∙CH₃CN (1), [Dy(L^2(t-Bu))(Ph₃PO)₂]ClO₄∙0.63C₂H₅OH (2), [Dy(L^OCH3)(Ph₃PO)₂]ClO₄∙2H₂O (3) including various chelating pentadentate ligands with a [N₃O₂]²⁻ binding node in the equatorial plane,...
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02449D, Review Article

Ping Zhang, Yongchong Yu, Reyila Tuerhong, Xinyu Du, Keyi Chai, Xiaoping Su, Qiong Su, Shujuan Meng, Lijuan Han
The conventional synthetic ammonia industry is characterized by its high energy consumption, necessitating the exploration of a new environmentally sustainable method for NH3 synthesis. A prospective alternative to the Haber-Bosch...
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02422B, Research Article

Gengxin Wu, Yong-Kang Zhu, Dongxia Li, Jia-Rui Wu, Yan Wang, Zhiquan Zhang, Ying-Wei Yang
Engineering ideal functional coordination polymers (CPs) via post-synthetic modification has emerged as a powerful synthetic strategy to achieve desirable functionalities and superior properties. In this work, we report a versatile...
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Lab Chip, 2024, 24,1965-1976
DOI: 10.1039/D3LC01007D, Paper

Wei-Jen Soong, Chih-Hung Wang, Chihchen Chen, Gwo-Bin Lee
We devised an innovative method for automated sorting of extracellular vesicles (EVs) employing optically-induced dielectrophoresis on an integrated microfluidic chip. EVs of three distinct size categories could be isolated in 1 h at a purity of 86%.
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Lab Chip, 2024, 24,2049-2057
DOI: 10.1039/D3LC00707C, Paper

Open Access

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Fumiaki Yokoyama, André Kling, Petra S. Dittrich
A microdevice with narrow winding channels is introduced to trap and culture single bacterial cells. It is used to study growth patterns of the cells and to monitor secretion of extracellular vesicles under treatment with an antibiotic drug.
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Lab Chip, 2024, 24,1957-1964
DOI: 10.1039/D3LC01014G, Paper

Yu Zhang, Tao Peng, Yu Ge, Mengda Li, Chendi Li, Jiyu Xi, Zixi Li, Zewen Wei, Yuntao Hu
Stratified delivery into specific retinal layers was realized by a flexible electrode array that exhibited high compatibility with surgical procedures.
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Lab Chip, 2024, 24,2017-2024
DOI: 10.1039/D3LC01050C, Paper

Samantha Bourg, Karol Rakotozandriny, Ivan T. Lucas, Emmanuel Letavernier, Christian Bonhomme, Florence Babonneau, Ali Abou-Hassan
The successful formation of a carbonated apatite coating inside a micrometer channel is described, which was used to investigate its role on the formation of calcium oxalate crystals in the context of kidney stones.
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Lab Chip, 2024, 24,1918-1929
DOI: 10.1039/D3LC00793F, Paper

Lauren M. Delong, Colby E. Witt, Madison Pennell, Ashley E. Ross
Here, we have developed a 3D printed microfluidic device capable of oxygen gradient formation within intestinal tissue slices ex vivo. The device is open-welled and compatible with external electrochemical recording during tissue analysis.
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Lab Chip, 2024, 24,2122-2134
DOI: 10.1039/D3LC00945A, Paper

Meiying Zhao, Ye Tao, Wenshang Guo, Zhenyou Ge, Hanqing Hu, Ying Yan, Chaoxia Zou, Guiyu Wang, Yukun Ren
A multifunctional flexible magnetic drive gripper is synthetically designed to achieve active steering and carry out operations on different targets in a constrained environment by changing the external magnetic field.
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Lab Chip, 2024, 24,1887-1902
DOI: 10.1039/D3LC00507K, Paper

Open Access

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Chu-Chun Liang, Po-Yen Chen, Nien-Che Liu, I-Chi Lee
A 3D neural spheroid-based system with an interstitial level of flow for simulating the brain microenvironment toward a dynamic amyloid-β induced neuronal toxic model was established. A real-time impedance recording was used to monitor the neural network formation and disconnection.
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Lab Chip, 2024, 24,2069-2079
DOI: 10.1039/D3LC00830D, Paper

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Chaeeun Lee, Sumit Kumar, Juhee Park, Yongjun Choi, Elizabeth Maria Clarissa, Yoon-Kyoung Cho
Tonicity-induced cargo loading into extracellular vesicles (EVs) is achieved through controlled membrane permeability, ensuring cargo incorporation without causing damage to the EV membrane.
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Lab Chip, 2024, 24,1867-1874
DOI: 10.1039/D3LC00796K, Perspective

Open Access

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Umut A. Gurkan, David K. Wood, Dorn Carranza, Luke H. Herbertson, Scott L. Diamond, E. Du, Suvajyoti Guha, Jorge Di Paola, Patrick C. Hines, Ian Papautsky, Sergey S. Shevkoplyas, Nathan J. Sniadecki, Vamsee K. Pamula, Prithu Sundd, Asif Rizwan, Pankaj Qasba, Wilbur A. Lam
In this perspective article, we present the state of the microfluidic field regarding current limitations and propose future directions and new approaches for the field to advance lab-on-a-chip technologies closer to translation and clinical use.
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Lab Chip, 2024, 24,2176-2192
DOI: 10.1039/D3LC00912B, Paper

Open Access

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Priscilla Delgado, C. Alessandra Luna, Anjana Dissanayaka, Oluwamayokun Oshinowo, Jesse J. Waggoner, Sara Schley, Todd Fernandez, David R. Myers
This activity enables students to construct geometrically complex microfluidics at their desk with no specialized equipment. It can be easily transported, and helped students significantly improve their understanding of miniaturization science.
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Lab Chip, 2024, 24,2193-2201
DOI: 10.1039/D3LC00979C, Paper

Bingbing Zhang, Jinxin Fu, Maohua Du, Kai Jin, Qi Huang, Jiahao Li, Dongping Wang, Siyi Hu, Jinhua Li, Hanbin Ma
Advancing active-matrix digital microfluidics through polar coordinates for precise concentration gradients. Demonstrated with chip photography, concentration gradient solution demo, and efficiency comparison.
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Lab Chip, 2024, 24,2280-2286
DOI: 10.1039/D3LC00822C, Paper

Mingwei Zhao, Jing Yang, Zhenqing Li, Yuan Zeng, Chunxian Tao, Bo Dai, Dawei Zhang, Yoshinori Yamaguchi
Concentration gradient generation and mixed combinations of multiple solutions are of great value in the field of biomedical research.
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