Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01856B, Communication

Miantai Ye, Wei Hu, Meng He, Chenchen Li, Shuyang Zhai, Zhihong Liu, Yanying Wang, Huijuan Zhang, Chunya Li
A near-infrared two-photon fluorescent probe for selective detection and deep-depth imaging of NO helps to discover the relationship between NO and resistance to antitumor drugs.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01876G, Communication

Meng Yu, Da Xie, Rahul T. Kadakia, Weiran Wang, Emily L. Que
A Tm(III) complex displays an “off–on” ¹⁹F NMR/MRI response to Zn(II) upon tuning the chemical exchange rate.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01619E, Communication

Huang Zhou, Shaoyun Duan, Ji Huang, Fengjiao He
An ultrasensitive electrochemical biosensor was developed based on RCA and multipedal DNA walking strategy for the assay of 16S rRNA gene, and it has great application potential in food safety, environmental monitoring, and disease diagnosis.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01934H, Communication

Lishan Li, Songbo Cui, An Hu, Wei Zhang, Yiwen Li, Nianchen Zhou, Zhengbiao Zhang, Xiulin Zhu
Several kinds of novel azobenzene-containing tubular polymersomes were fabricated via self-assembly, and their shape could be tuned precisely by changing the chemical structure, self-assembly condition and external stimuli.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01517B, Communication

Weiyuan Ding, Hongquan Yu, Yu Tang, Zhuxin Li, Bijiao Liu, Dechong Liu, Yuyu Wang, Shu hong Liu, Hong Zhao, Daniel Mandler
A Fe–NC catalyst containing carbon nanotubes, mesopores and macropores with a measurable 3D framework structure was prepared by electrospinning.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01659D, Communication

Xin Yue, Ming Hu, Xingyi He, Shuang Wu, Jin-Heng Li
An unprecedented indium-promoted three-component 1,3,4-trifunctionalization cascade of 1,3-enynes with sulfinates and tert-butyl nitrite for producing 5-sulfonylisoxazoles via [3+2] annulation is reported.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01438A, Feature Article

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Pablo Ríos, Amor Rodríguez, Salvador Conejero
Well-defined electrophilic or low-electron count platinum complexes are very versatile catalysts for a variety of chemical transformations.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01756F, Communication

Pernille Rose Jensen, Sebastian Meier
Structures and rates in the catalytic cycle of carbohydrate dehydration by Lewis acidic salt are determined through the systematic use of complementary NMR approaches.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01250E, Communication

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

G. Ferrand-Drake del Castillo, R. L. N. Hailes, Z. Adali-Kaya, T. Robson, Andreas Dahlin
A new and generic method for protein capture-release by polyelectrolyte brushes and pH control.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02550J, Communication

Hao Zeng, Chuanle Zhu, Chi Liu, Yingying Cai, Fulin Chen, Huanfeng Jiang
The three component hydroxyletherification and hydroxylazidation reactions of (trifluoromethyl)alkenes are reported, providing various useful α-trifluoromethyl β-heteroatom substituted tertiary alcohols in high yields.
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01951H, Communication

Lu Sun, Qiao Zhao, Xinli Liu, Yongchun Pan, Yanfeng Gao, Jingjing Yang, Yuzhen Wang, Yujun Song
Here, we propose an amplification strategy of enzyme-mimicking accelerated signal enhancement integrated with triple-channel volumetric bar-chart chip for visually multiplexed quantitation of telomerase activity. This platform was used for evaluating...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02520H, Communication

Emily Lythell, Reynier Suardiaz, Philip Hinchliffe, Chonnikan Hanpaibool, Surawit Visitsatthawong, Sofia Oliveira, Eric Lang, Panida Surawatanawong, Vannajan Sanghiran Lee, Thanyada Rungrotmongkol, Natalie Fey, James Spencer, Adrian John Mulholland
MCR (mobile colistin resistance) enzymes catalyse phosphoethanolamine (PEA) addition to bacterial lipid A, threatening the “last-resort” antibiotic colistin. Molecular dynamics and density functional theory simulations indicate that monozinc MCR supports...
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02108C, Communication

Yong Liu, Juanjuan Li, Wei Zhang
A liquid metal-assisted exfoliation strategy is developed for synthesizing two-dimensional polydopamine nanosheets.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC90201B, Correction

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Cheng-Ying Chan, Chao-Hung Chang, Hsing-Yu Tuan
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02620D, Communication

Ruoyu Fan, Zhi Hu, Chun Chen, Xiaoguang Zhu, Haimin Zhang, Yunxia Zhang, Huijun Zhao, Guozhong Wang
ZIF-8 was employed as template to synthesize HD-Ni/N-CMS containing highly dispersed Ni at atomic-level anchored on N-doped carbon molecular sieve for vanillin hydrodeoxygenation. The ZIF-8 structure was inherited and Ni-N...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/C9CC09589F, Communication

Pei-Qin Liao, Ningyu Huang, Hai He, Hao Li, Xiao-Ming Chen
Herein, we report a metal-organic framework featuring a binuclear copper unit, showing extraordinarily high catalytic activity (102.8 mmol g-1 h-1) for photodriven hydrogen generation, which is attributed to the synergistic...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01833C, Communication

Hyeon Jin Park, Chang Wook Song, Sourav Sarkar, Yong Woong Jun, Ye Jin Reo, Mingchong Dai, Kyo Han Ahn
Near-infrared-emitting hemicyanine dyes are widely used in activatable fluorescent probes for various biological analytes, which fact, on the contrary, poses a chemical stability issue along with photoinstability as shown here...
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Chem. Commun., 2020, 56,5058-5061
DOI: 10.1039/D0CC00641F, Communication

Xiao-Yue Chen, Xiao-Xue Nie, Yichen Wu, Peng Wang
Using thianthrene S-oxide (TTSO) as a transient mediator, para-arylation and alkenylation of mono-substituted arenes have been demonstrated via a para-selective thianthrenation/Pd-catalyzed thio-Suzuki–Miyaura coupling sequence under mild conditions.
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Chem. Commun., 2020, 56,5010-5013
DOI: 10.1039/C9CC09869K, Communication

Binbin Huang, Chao Yang, Jia Zhou, Wujiong Xia
This study presents a straightforward protocol for approaching N-sulphonylamidines via an electricity-driven, iodine-mediated cross dehydrogenative condensation (CDC) between sulphonamides and tertiary amines.
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Chem. Commun., 2020, 56,5054-5057
DOI: 10.1039/D0CC01188F, Communication

Suman Pradhan, Sandeep Patel, Indranil Chatterjee
Aromatic amines and (hetero)arenes, such as indoles and pyrroles, are regioselectively sulfinylated under mild aerobic conditions using nitrosoarenes as a redox-catalyst.
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Chem. Commun., 2020, 56,5022-5025
DOI: 10.1039/D0CC01005G, Communication

Ganesh S. Ghotekar, Sachin R. Shirsath, Aslam C. Shaikh, M. Muthukrishnan
An expedient one-pot synthesis of carbocyclic spiro[5.5]undeca-1,4-dien-3-ones via 1,6-conjugate addition initiated formal [4+2] annulation sequences by employing p-quinone methides and sulfonyl allenols.
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Chem. Commun., 2020, 56,5006-5009
DOI: 10.1039/D0CC01197E, Communication

Wenhuai Feng, Chengxi Zhang, Jun-Xing Zhong, Liming Ding, Wu-Qiang Wu
Anchoring of amine ligands with different alkyl chain lengths on perovskites mitigates non-radiative charge recombination in perovskite solar cells.
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Chem. Commun., 2020, 56,5042-5045
DOI: 10.1039/D0CC01219J, Communication

Lingling Tao, Zhe Sun, Lei Chen, Mao Liang, Song Xue
The combination of a zinc stannate photoanode and cobalt complex electrolyte in DSCs yields an impressive power conversion efficiency of 8.1%.
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Chem. Commun., 2020, 56,5030-5033
DOI: 10.1039/D0CC00768D, Communication

Xin Yu, Yang Yang, Wufang Yang, Xungai Wang, Xin Liu, Feng Zhou, Yan Zhao
Organic solvents that possess affinity towards both polar monomers and hydrophobic PDMS play a “driving” role in the diffusion of polar monomers into the subsurface of the PDMS substrate.
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Chem. Commun., 2020, 56,5014-5017
DOI: 10.1039/D0CC01643H, Communication

Lixia Zhang, Zhenhua Li, Zhijun Chen
A curli fluorescent light-up probe called bromophenol blue, which binds to curli via recognizing CsgA.
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Chem. Commun., 2020, 56,5026-5029
DOI: 10.1039/D0CC01339K, Communication

Ignacio Rosa-Pardo, Carla Casadevall, Luciana Schmidt, Miguel Claros, Raquel E. Galian, Julio Lloret-Fillol, Julia Pérez-Prieto
The cooperative action between the CsPbBr₃ surface and capping makes the photoredox homo-/cross-coupling of benzyl bromides under mild conditions possible.
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Chem. Commun., 2020, 56,4990-4993
DOI: 10.1039/D0CC01488E, Communication

Dan Guo, Huayu Chen, Hanmin Tian, Shuxin Ouyang, Jianbo Wang, Jun Lv
A strategy involving modulating the intermediate layer of an electrode was developed to promote the electrocatalysis kinetics of the electrode and therefore enhance its performance.
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Chem. Commun., 2020, 56,5002-5005
DOI: 10.1039/D0CC01720E, Communication

Jiang-Ling Shi, Yuankai Wang, Zixuan Wang, Bowen Dou, Jianbo Wang
Ring-opening iodination or bromination of unstrained cycloalkanols with NaI or NaBr and PhI(OAc)₂ under visible light irradiation is developed.
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Chem. Commun., 2020, 56,4986-4989
DOI: 10.1039/D0CC01557A, Communication

Jordan P. Hooker, Florian Feist, Laura Delafresnaye, Federica Cavalli, Leonie Barner, Christopher Barner-Kowollik
Polymer particles are synthesized using a photo-active ortho-methyl benzaldehyde with a terminal alkyne for cross-linking. The reactive 1,4-dihydronaphthalene at every cross-linking point undergoes aromatisation to a fluorescent naphthalene upon exposure to acid.
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Chem. Commun., 2020, 56,4970-4981
DOI: 10.1039/D0CC00841A, Highlight

Gilles Berger, Pierre Frangville, Franck Meyer
This review highlights recent developments of halogen bonding in materials and biological sciences with a short discussion on the nature of the interaction.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01331E, Communication

Jun Li, Ke Yi, Yanli Lei, Zhihe Qing, Zhen Zou, Yuedong Zhang, Haiyan Sun, Ronghua Yang
In this work, an Al centre-powered graphitic nanozyme (Fe/Al-GNE) was developed for chemodynamic cancer therapy, which afforded pH-independent catalytic activity and high reaction kinetics.
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02214D, Communication

Rong Fu, Junying Zhang, Shaojie Liu, Xing-Dong XU, Shengyu Feng
Reticulated copolymer hosts pillar[5]arene crosslinked with poly(dimethylsiloxane) (PDMS) were synthesized for the facile construction of double network crosslinked elastomer upon noncovalently cross-linking with tetraphenyethylene (TPE)-based tetratopic guests through host-guest interactions....
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00536C, Communication

Xiang Hao, ZeJian Leng, Dan Sun, Feng Peng, Akram Yasin
We herein report a 12-armed photo-responsive supramolecular star centered by a pillar[6]arene-coated M6L12 metal-organic polyhedron (MOP) via core-first approach.
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01332C, Communication

Yuichiro Kobayashi, Kenji Kohara, Yusuke Kiuchi, Hiroki Onoda, Osami Shoji, Hiroyasu Yamaguchi
We prepared enzyme immobilized hydrogels and investigated the effects of the cross-linking density and polymer properties on their oxidation reaction rate. The oxidation rate of enzyme immobilized hydrogels increased as...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02164D, Communication

María José Dávila-Rodríguez, Thales Souza Freire, Erik Lindahl, Ignez Caracelli, Júlio Zukerman-Schpector, Ran Friedman
Drug resistance is a serious problem in cancer, viral, bacterial, fungal and parasitic diseases. Examination of crystal structures of protein-drug complexes is often not enough to explain why a certain...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01999B, Communication

Tong Sun, Yingying Su, Houjing Liu, Hongjie Song, Yi Lv
In this study, more 〖SO〗_4^( ∙-) and strong intrinsic chemiluminescence (CL) can be achieved through activating sulphite (〖SO〗_3^( 2-)) with ferrous ions (Fe2+) on the WS2 nanosheets with the thickness...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00176G, Communication

Yaqun Dong, Jin-Tao Yu, Song Sun, Jiang Cheng
A rhodium(III)-catalyzed ortho- C−H functionalization of sulfoxonium ylides followed by intramolecular annulation reactions with quinones is described, where the carbonyl in sulfoxonium ylides served as a chelation group. This protocol...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01906B, Communication

Amina Benchohra, Christophe Méthivier, david kreher, Jessem Landoulsi, rodrigue lescouezec
Electrospray ionization (EI) deposition is proven efficient in obtaining monolayers of a polymetallic charge transfer complex onto gold surfaces. The molecule’s integrity is monitored by PM-IRRAS and XPS. This approach...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02671A, Communication

Shweta P. Yelgaonkar, Daniyal Kiani, Jonas Baltrusaitis, Len R MacGillivray
Salt cocrystals with components that assemble by hydrogen bonds and aromatic anion-molecule stacks (π(−)−π stacks) are reported. U-shaped bipyridines and an isocoumarin carboxylic acid self-assemble to form 5-, 6-, and...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02437F, Communication

Xiaohong Yang, Lian Wu, Aipeng Li, Lidan Ye, Jiahai Zhou, Hongwei Yu
Combinatorial modulation of inter- and intra-subunit interactions on decameric D-fructose-6-phosphate aldolase A (FSAA) generated a triple-site variant I31T/Q59T/I195Q FSAA with 27 to 278-fold activity improvement towards target heteroaromatic aldehydes. X-ray...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02851G, Communication

Sheuli Sasmal, Soumya Kumar Sinha, Goutam Kumar Lahiri, Debrabrata Maiti
A meta selective C‒H nitration of phenol derivatives have been developed using a Ru-catalyzed σ-activation strategy. Cu(NO3)2.3H2O has been employed as the nitrating source while Ru3(CO)12 was found to be...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02329A, Communication

Lijian Zhang, Fei Ma, Ao Qi, Lulu Liu, Junjie Zhang, Simin Xu, Qisheng Zhong, Yusen Chen, Chun-yang Zhang, Chun Cai
We report for the first time the integration of ultra-high-pressure liquid chromatography-tandem mass spectrometry with machine learning for identifying fatty acid metabolite biomarkers of ischemic stroke. Especially, we develop an...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01854F, Communication

Indrani Bhowmick, David Washburn Shaffer, Jenny Y Yang, Matthew Shores
We report the first example of field-induced single molecule magnet (SMM) behaviour in a square-planar S = ½ Co(II) pincer complex [(P^NN^NP)CoBr]Br (2). The related five-coordinate complexes [(P^CN^CP)CoBr₂] (1) and...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02506B, Communication

Takehiro Hirao, Yoshiki Iwabe, Naoyuki Hisano, Takeharu HAINO
Chiral biscalixarenes and a C60-appended polyphenylacetylene have been synthesized. The chiral biscalixarene encapsulated the C60 unit of the phenylpolyacetylene, which induced the preferred helicity of the polyacetylene.
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