Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00163E, Paper

Yueyang Zhang, Greg G. Goss
The presence of microplastics in the environment and their potential effects on the health of organisms are a subject of great concern.
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00230E, Paper

Tao Jiang, Carlo Alberto Amadei, Na Gou, Yishan Lin, Jiaqi Lan, Chad D. Vecitis, April Z. Gu
Single-walled carbon nanotubes (SWCNTs) have caused increasing public concerns associated with their potential toxicological effects. This study demonstrated that the physicochemical properties of SWCNTs have impacts on their toxicological effects.
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/D0EN00284D, Paper

Fanqing Meng, wei Ma, Yinglong Wang, Zhaoyou Zhu, zhen chen, gung Lu
The elimination of antibiotics by piezo-catalysis method has recently drawn great attention for its benefits in engineering application. However, the risk assessment of the target antibiotics and its degradation intermediates...
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00219D, Paper

Zheng-Zhe Zhang, Yu Zhang, Ya-Fei Cheng, Ren-Cun Jin
The risks of metallic nanoparticles (MNPs) in anammox have attracted increasing attention; however, how sulfidation, an important environmental transformation process, affects their toxicity potential is unclear.
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00214C, Paper

Li Lu, Min Huang, Yuxiong Huang, Philippe F.-X. Corvini, Rong Ji, Lijuan Zhao
Mn₃O₄ nanoenzymes boost endogenous antioxidants in, and enhance resistance of, the cucumber (Cucumis sativus) plant subjected to salinity stress.
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/C9EN01366K, Paper

Peirui Liu, Jianfeng Zhou, Ting Wang, Cecilia Yu, Yu Hong, Xing Xie
Locally enhanced electric field treatment (LEEFT) has been considered as a novel and promising technology for efficient microorganism inactivation in recent years. Previous studies were primarily conducted on bacteria and...
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/C9EN01300H, Paper

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Adam Davis, Fatima Nasser, Jamie R Lead, Zongbo Shi
The pH within the gastrointestinal (GI) tract of zooplankton regulates the bioavailability of nutrients and inorganic toxins (metals, nanoparticles) and the breakdown of ingested food. However, measuring the spatial distribution...
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Environ. Sci.: Nano, 2020, Advance Article
DOI: 10.1039/D0EN00075B, Paper

Jaroslav Semerád, Jan Filip, Alena Ševců, Miroslav Brumovský, Nhung H. A. Nguyen, Jiří Mikšíček, Tomáš Lederer, Alena Filipová, Jana Boháčková, Tomáš Cajthaml
This work describes an important, environmentally relevant phenomenon of metal nanoparticle aging in relation to the toxicity of nanomaterials; in this case, sulfidated nanoscale zero-valent materials intended for remediation purposes.
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Environ. Sci.: Nano, 2020, Accepted Manuscript
DOI: 10.1039/C9EN01360A, Paper

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Richard Zepp, Emmanuel Ruggiero, Brad Acrey, Mary J. B. J. B. Davis, Changseok Han, Hsin-Se Hsieh, Klaus Vilsmeier, Wendel Wohlleben, Endalkachew Sahle-Demessie
In recent years, an increasing number of polymeric composites incorporating nanomaterials (NMs) have reached the market. Such nano-enabled products (NEPs) present enhanced performance through improved mechanical, thermal, UV protection, electrical,...
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00404A, Communication

Xinrui He, Jian Zhao, Zeqing Tan, Jiaxin Zhao, Xiao Cheng, Chuanjian Zhou
Chalcone single crystals with distinctively different emission color and photoinduced mechanical response are designed and fabricated via fine-tuning the donor substituents.
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CrystEngComm, 2020, 22,2756-2765
DOI: 10.1039/C9CE01885A, Paper

Yaser Balmohammadi, Hamid Reza Khavasi, S. Shahab Naghavi
There is a common perception by the scientific community that a halogen-involving interaction forms when the distance between the donor atom and the acceptor atom is less than the sum of their van der Waals (vdW) radii.
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CrystEngComm, 2020, 22,2700-2704
DOI: 10.1039/D0CE00133C, Communication

Ukyo Yamashita, Nobuto Yoshinari, Rapheepraew Sodkhomkhum, Natthaya Meundaeng, Takumi Konno
Anion-controlled formation of hydrogen-bonded metallosupramolecular helices from a Rh^III₄Zn^II₄ polycarboxylate is reported.
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CrystEngComm, 2020, 22,2849-2858
DOI: 10.1039/D0CE00024H, Paper

T. V. M. Sreekanth, P. C. Nagajyothi, K. C. Devarayapalli, J. Shim, K. Yoo
A ZnCo₂O₄ electrocatalyst for the efficient MOR and ORR.
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CrystEngComm, 2020, 22,2728-2742
DOI: 10.1039/C9CE01972C, Paper

Marc Robin, Stanislas Von Euw, Guillaume Renaudin, Sandrine Gomes, Jean-Marc Krafft, Nadine Nassif, Thierry Azaïs, Guylène Costentin
Monitoring apatite formation through in situ RAMAN and ex situ ssNMR spectroscopy.
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CrystEngComm, 2020, 22,2709-2717
DOI: 10.1039/C9CE01966A, Paper

Xiaojuan Bai, Boxuan Sun, Xuyu Wang, Tianshuo Zhang, Qiang Hao, Bing-Jie Ni, Ruilong Zong, Ziyang Zhang, Xiaoran Zhang, Haiyan Li
The mechanism of the photocatalytic reaction of defective ZnO systems was determined.
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CrystEngComm, 2020, 22,2866-2872
DOI: 10.1039/D0CE00096E, Paper

Andrei V. Churakov, Dmitry A. Grishanov, Alexander G. Medvedev, Alexey A. Mikhaylov, Mikhail V. Vener, Mger A. Navasardyan, Tatiana A. Tripol'skaya, Ovadia Lev, Petr V. Prikhodchenko
2-Aminobenzimidazole peroxosolvate – the third H₂O₂ crystalline adduct stabilized with the maximum possible number of hydrogen bonds formed by one hydrogen peroxide molecule.
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CrystEngComm, 2020, 22,2837-2844
DOI: 10.1039/D0CE00238K, Paper

Xinfang Liu, Liyong Du, Rongfang Li, Ningning Ma, Mengdi You, Xun Feng
Isostructural Ln-CPs (1-Eu and 2-Tb) show almost the same high detection ability for Fe³⁺ and different detection abilities for aniline. The detection difference was studied through PXRD, UV-vis, luminescence lifetimes and Hirshfeld surface analysis.
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CrystEngComm, 2020, 22,2743-2755
DOI: 10.1039/D0CE00064G, Paper

Bowen Sun, Hui Wang, Jiakun Wu, Yanling Geng, Jixiang Xu, Yaowei Wang, Yanyan Li, Haifeng Lin, Lei Wang
Unique ZnS@CdS@Cd_0.5Zn_0.5S-MoS₂ hollow nanospheres with abundant active sites and enhanced light-harvesting and charge separation demonstrate efficient H₂ evolution from visible-light-driven water-splitting.
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CrystEngComm, 2020, 22,2827-2836
DOI: 10.1039/D0CE00171F, Paper

Binghui Xu, Xin Dai, Qingke Tan, Yuan Wei, Gonggang Liu, Guanglei Wu
In this work, a nano-sized goethite and zinc oxide hetero-structure (FeOOH@ZnO) dispersed on reduced graphene oxide (RGO) sheets was synthesized for the first time to construct a ternary composite (FeOOH@ZnO/RGO) via a stepped graphene oxide (GO) deoxygenation process.
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CrystEngComm, 2020, 22,2859-2865
DOI: 10.1039/D0CE00119H, Paper

Ines E. Collings, Paul J. Saines, Mirko Mikolasek, Tiziana Boffa Ballaran, Michael Hanfland
Effects of A-site and M-site substitutions on the structural properties of perovskite dimethylammonium iron formate.
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CrystEngComm, 2020, 22,2817-2826
DOI: 10.1039/D0CE00070A, Paper

Florbela Pereira
Machine learning algorithms were explored for the prediction of the crystallization propensity based on molecular descriptors and fingerprints generated from 2D chemical structures and 3D chemical structures optimized with empirical methods.
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00113A, Paper

Mohd Nazri Abd Rahman, Yusnizam Yusuf, Afiq Anuar, Mohamad Raqif Mahat, Narong Chanlek, Noor Azrina Talik, Muhammad I. M. Abdul Khudus, Norzaini Zainal, Wan Haliza Abd Majid, Ahmad Shuhaimi
An atomically flat covering with a dense and crack-free surface of aluminium nitride films was successfully deposited on a sapphire-(0 0 0 1) substrate through a pulsed atomic-layer epitaxy technique via horizontal metalorganic chemical vapour deposition.
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00416B, Communication

Takumi Kusakawa, Takayuki Goto, Akiko Hori
Expanded π-conjugated coordination complexes, [M(L²)₂] (M = Cu²⁺, Pd²⁺, Pt²⁺; L² = dinaphthoylmethanido⁻), were prepared and their unique electron contributions and electrophile/nucleophile characteristics were found due to the supramolecular associations.
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00317D, Paper

Zhen-Li Yang, Jian Qin, Jun- Qing Yang , Jianguo Zhang
Research on novel energetic coordination polymers (ECPs) is becoming increasingly important for energetic materials, numerous ECPs were reported and found to be potential energetic materials. In this study, 4,5-dicarboxylic-1,2,3-triazolean was...
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00255K, Paper

Yunhao Zang, Jinying Wang, Jianfeng Gu, Jiangying Qu, Feng Gao
Herein, a mesoporogen-free, and steam-assisted route is proposed to synthesize highly crystalline hierarchical HZSM-5 using Stöber silica spheres as the precursor. The effect of crystallization time on the morphology and...
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00269K, Paper

Selma Piranej, Michael A. W. Shelhart Sayers, Gregory J. Deye, Sergey N. Maximoff, Jonathan P. Hopwood, Haejun Park, Jean G. Slavsky, Jacob Ciszek
Reactivity trends for molecular solids cannot be explained exclusively through topochemical phenomenon (i.e. diffusivity, reaction cavities) or electronic structure of the molecules. As an example of this class, Diels-Alder reactions...
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00294A, Paper

Chih-Tung Yang, Xiang-Kai Yang, Ji-Hong Hu, Wei-Te Lee, Tsun-Ren Chen, Chih-Chieh Wang, Jhy-Der Chen
Two extended metal chains based on linear tetracopper units are reported, in which the bromide complex undergoes reversible structural transformation and luminescence change.
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00347F, Paper

Yu Feng, Erwei Du, Shijing Gong, Ke Yu, Xiaofan Chen, Ziqiang Zhu
The MoS2@VS2 micro-nano composite was synthesized via a two-step hydrothermal method. The field emission properties of MoS2@VS2 micro-nano composite were investigated for the first time. The finger-like VS2 has a...
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE90057E, Correction

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Chenglan Zhao, Yuqian Jiang, Shunfei Liang, Fang Gao, Li Xie, Lingyun Chen
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00526F, Paper

Shuang Zhao, Baiqi Shao, Yang Feng, Senwen Yuan, Langping Dong, Liang Zhang, Hongpeng You
A novel synthesis strategy of porous/hollow YVO₄ submicro-ellipsoids with multicolor emissions has been developed based on the high structural matching of LYH and YVO₄.
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00297F, Paper

Zhihui Hu, Zhi Chen, Juntong Huang, Mingge Yan, Meng Zhang, Lei Zhang, Xibao Li, Zhijun Feng
3C-SiC nanowires with nanosheets were synthesized via a direct reaction of Si vapor (from solid silicon) and SiO vapor (from silicon and silicon dioxide) with graphene nanosheets at 1500 °C without any additional metal catalyst.
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE90053B, Editorial

We would like to take this opportunity to highlight the Outstanding Reviewers for CrystEngComm in 2019, as selected by the editorial team for their significant contribution to the journal.
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00204F, Paper

Zhi-Ping Shi, Guo-Bin Ren, Ming-Hui Qi, Zhong Li, Xiaoyong Xu
Based on reported isomorphism of Azoxystrobin (AZO) solvates, five novel AZO solvates, including dimethyl succinate solvate (AZO-DMS), ethyl butyrate solvate (AZO-EB), thiophene solvate (AZO-TP), furan solvate (AZO-FN), and 1,2-diethoxyethane solvate...
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00386G, Paper

Jinxin Huang, Zongqi Wang, Bing Teng, Hong Liu, Xixi Zheng, Shaohua Ji
A series of K(D_xH_1-x)₂PO₄ (DKDP) crystals with different saturating temperature and deuteration levels were grown by point-seed rapid growth method. The correlation between deuterium segregation coefficient and temperature and deuterium...
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00214C, Paper

João P. P. Copetti, Paulo R. S. Salbego, Tainára Orlando, Jéssica M. L. Rosa, Gabriela F. Fiss, João P. G. de Oliveira, Mário L. A. A. Vasconcellos, Nilo Zanatta, Helio G. Bonacorso, Marcos A. P. Martins
The crystallization mechanisms of a series of fourteen 7-chloro-4-substituted-quinolines were proposed based on a retrocrystallization approach using the supramolecular cluster as demarcation.
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00417K, Paper

Weidong Hou, Jia Yang, Haiming Xu, Dongya Li, Zhongwei Zou, Dongsheng Xia
Nymphaea-like BiOCl with oxygen vacancies (OVs) was successfully prepared by adjusting the pH of the precursor and using aspartic acid as surfactant. The as-fabricated samples were investigated by XRD, SEM,...
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CrystEngComm, 2020, 22,2904-2913
DOI: 10.1039/C9CE01157A, Paper

Edurne S. Larrea, Roberto Fernández de Luis, Arkaitz Fidalgo-Marijuan, Eva M. Maya, Marta Iglesias, Maria I. Arriortua
The versatility of CuBTC (HKUST-1) MOF materials to be functionalized to improve their catalytic activity performance was evaluated. CuBTC@IL catalysts are selective for the cycloaddition of CO₂ to epoxides, giving rise to value-added products.
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CrystEngComm, 2020, 22,2970-2977
DOI: 10.1039/D0CE00251H, Paper

Prasanata Kumar Bhaumik, Abhisek Banerjee, Tamal Dutta, Sudipta Chatterjee, Antonio Frontera, Shouvik Chattopadhyay
The ethoxy groups have a dual effect in hindering the attack of the pseudo-halides on the nickel(II) centre and also in stabilizing the complex by intra-molecular interactions.
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CrystEngComm, 2020, 22,2978-2989
DOI: 10.1039/D0CE00106F, Paper

Utsav Garg, Yasser Azim, Aranya Kar, Chullikkattil P. Pradeep
Revisit of acid–aminopyrimidine synthons to explore the robustness in presence of linear hetrotetramer and heterotrimer synthon.
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CrystEngComm, 2020, 22,2919-2925
DOI: 10.1039/D0CE00067A, Paper

Kohei Yoshiyama, Masae Mori, Manabu Hagiwara, Shinobu Fujihara
The effect of the size and morphology of piezoelectric BiFeO₃ particles on the performance of BiFeO₃–PDMS composite generators is revealed.
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CrystEngComm, 2020, 22,2990-2997
DOI: 10.1039/D0CE00112K, Paper

Yan-Kai Li, Yu-Ge Wang, Cui-Liu Fu, You-Liang Zhu, Zhan-Wei Li, Zhao-Yan Sun
The crystallization transformation from form II to form I in PB-1/CNT materials is mainly influenced by the lamellar thickness.
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CrystEngComm, 2020, 22,3070-3078
DOI: 10.1039/D0CE00075B, Paper

Yucheng Hao, Yang Pan, Yuan Lin, Linbo He, Guangjie Ge, Yu Ruan, Haida Zhou, Yang Xue, Kisan Koirala
Three novel highly porous aluminophosphates were synthesized through mild hydrothermal methods. Interestingly, among them, α-NaAlPO₄(OH) is polar and exhibits moderate nonlinear optical properties with a short cutoff edge.
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CrystEngComm, 2020, 22,2953-2963
DOI: 10.1039/D0CE00268B, Paper

Chenglan Zhao, Yuqian Jiang, Shunfei Liang, Fang Gao, Li Xie, Lingyun Chen
2D porous nickel oxalate thin sheets constructed by ultrathin nanosheets were first synthesized by using a simple hydrothermal method. The resulting porous thin sheets exhibited superior supercapacitor performance.
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CrystEngComm, 2020, 22,2884-2888
DOI: 10.1039/D0CE00305K, Communication

Mei-li Qi, Shengkun Yao, Xiao-Cun Liu, Xiaoning Wang, Fengkun Cui
Well-defined carbonated hydroxyapatite microspheres assembled from nanosheets were synthesized by a Na₂EDTA-assisted hydrothermal homogeneous precipitation route.
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00341G, Paper

Yue Qi, Ou Sun, Yanyan Zhou, Yuan Yao, Zhenyu Cheng, Ting Gao, Hongfeng Li
Due to the effect of the combination of the rigid structure and synergistic interactions of two ligands on energy transfer, the Cd–Ln complexes show excellent NIR luminescence properties with the QYs reaching 0.34% for Nd³⁺ and 2.13% for Yb³⁺.
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CrystEngComm, 2020, Advance Article
DOI: 10.1039/D0CE00253D, Paper

Yini Mao, Li Jiang, Pengfei Xian, Qiongfen Fu, Shanshan Hu, Jun Yang
Pure hexagonal phase KSc(MoO₄)₂ crystals with a hexagonal block shape were successfully synthesized via a one-step hydrothermal method.
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CrystEngComm, 2020, 22,2964-2969
DOI: 10.1039/D0CE00221F, Paper

Masahide Tominaga, Kosuke Mizuno, Haruka Yamamoto, Tadashi Hyodo, Kentaro Yamaguchi
Crystallization of a diimide-based macrocycle having adamantane parts and several cyclic ethers in chloroform provided inclusion crystals, where both guests were cooperatively accommodated within inner spaces between the macrocycles.
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CrystEngComm, 2020, 22,2998-3004
DOI: 10.1039/D0CE00039F, Paper

Ruirui Wang, Haili Wang, Juan Wang, Feifei Bai, Yue Ma, Licun Li, Qinglun Wang, Bin Zhao, Peng Cheng
For the isomorphic tetranuclear 3d–4f compounds constructed by [M(CN)₆]³⁻ linking Ln^III-Schiff-base units, the diamagnetic Co^III ions in the system could suppress QTM effectively and obtain a field-induced SMMs behavior.
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CrystEngComm, 2020, 22,3005-3019
DOI: 10.1039/D0CE00125B, Paper

Ipsita Mondal, Tanmoy Basak, Snehasis Banerjee, Shouvik Chattopadhyay
A reduced Schiff base used as a fluorescence chemo-sensor for selective detection of zinc(II). Strong fluorescence behaviors of two zinc(II) complexes are correlated with the presence of a rigid hydrogen-bonded network in their solid state structure.
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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00435A, Paper

Pengpeng Lei, Ran An, Chengyu Li, Jing Feng, Hongjie Zhang
Bismuth-based nanoparticles, especially NaBiF4, have attracted extensive attention as hosts of lanthanides (Ln3+) ions and other luminescent ions in recent years. However, controllable synthesis of NaBiF4 nanoparticles remains a challenge....
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