l Optical glass By www.freepatentsonline.com Published On :: Tue, 19 May 2015 08:00:00 EDT Provided is an optical glass that has desired optical properties, superior resistance to devitrification, and superior mass productivity. An optical glass is made of a SiO2—Nb2O5—TiO2-based glass having a refractive index (nd) of 1.75 to 1.95 and an Abbe's number (νd) of 15 to 35 and has an operation temperature range (ΔT=(temperature at 100.5 poise)−(liquidus temperature)) of 20° C. or more. The optical glass preferably contains, in percent by mass, 15% to 45% SiO2, 15% to 40% (but excluding 40%) Nb2O5 and 1% to 30% TiO2 as glass components. Full Article
l Dielectric composition and ceramic electronic component including the same By www.freepatentsonline.com Published On :: Tue, 19 May 2015 08:00:00 EDT There is provided a dielectric composition including: a base powder including BaTiO3; a first accessory component including a content (x1) of 0.1 to 1.0 at % of an oxide or a carbonate including transition metals, based on 100 moles of the base powder; a second accessory component including a content (y) of 0.01 to 3.0 at % of oxide or carbonate including a fixed valence acceptor element, based on 100 moles of the base powder; a third accessory component including an oxide or a carbonate including a Ce element (content of z at %) and at least one rare earth element (content of w at %); and a fourth accessory component including a sintering aid, wherein 0.01≦z≦x1+4y and 0.01≦z+w≦x1+4y based on 100 moles of the base powder. Full Article
l Optical glass, optical element, and method for manufacturing optical glass By www.freepatentsonline.com Published On :: Tue, 26 May 2015 08:00:00 EDT An optical glass including B3+, La3+ and Nb5+ as cationic components constituting the glass, wherein the optical glass satisfies the following expressions represented in cation percentages: 10 cat. %≦B3+≦50 cat. %;40 cat. %≦La3+≦65 cat. %;0 cat. %≦Nb5+≦40 cat. %;80 cat. %≦(total amount of B3++La3++Nb5+)≦100 cat. %; and0 cat. %≦Si4+≦10 cat. %;0 cat. %≦Ge4+≦5 cat. %;0 cat. %≦Mg2+≦5 cat. %;0 cat. %≦Ba2+≦10 cat. %;0 cat. %≦Ca2+≦10 cat. %;0 cat. %≦Sr2+≦10 cat. %;0 cat. %≦Zn2+≦20 cat. %;0 cat. %≦W6+≦5 cat. %;0 cat. %≦Zr4+≦5 cat. %;0 cat. %≦Ti4+≦5 cat. %;0 cat. %≦Bi3+≦5 cat. %;0 cat. %≦Ta5+≦10 cat. %;0 cat. %≦(total amount of Y3++Gd3+)≦20 cat. %; and0 cat. %≦(total amount of Yb3++Lu3+)≦10 cat. %. Full Article
l Method of toughening alumina By www.freepatentsonline.com Published On :: Tue, 26 May 2015 08:00:00 EDT The present application is directed to a zirconia toughened alumina body and process for making the body. The process involves combining tetragonally stabilized ZrO2 nanoparticles, Mg(OH)2 particles and alumina powder into a mixture. All particles of the mixture are milled, formed into a green compact and then sintered. The final composition of the body includes α-Al2O3 toughened with 0.5 to 2.5 weight percent ZrO2 in a stabilized tetragonal form and 0.03 to 0.10 weight percent MgO. The composition results in an Al2O3 body with a density less than 4.0 g/cc and strength greater than 50 kpsi. Full Article
l Shaped or unshaped refractory or kiln furniture composition By www.freepatentsonline.com Published On :: Tue, 26 May 2015 08:00:00 EDT The present description relates to a refractory composition including 70 weight percent to 98 weight percent particulate refractory material and 2 weight percent to 30 weight percent of a binder phase including reactive filler and a binder, the binder phase substantially includes solely reactive andalusite as reactive filler. Full Article
l Powder comprising stabilized zirconia granules and a binder having Tg of 25C or lower By www.freepatentsonline.com Published On :: Tue, 24 Nov 2015 08:00:00 EST The invention relates to a granulated powder intended, in particular, for the production of ceramic sintered parts, said powder having the following chemical weight composition, based on dry matter, namely: a zirconia stabiliser selected from the group containing Y2O3, Sc2O3, MgO, CaO, CeO2, and mixtures thereof, the weight content of stabiliser, based on the total zirconia and stabiliser content, being between 2% and 20% and the MgO+CaO content being less than 5% based on the total zirconia and stabiliser content; at least 1% of a first binder having a glass transition temperature less than or equal to 25° C.; 0-4% of an additional binder having a glass transition temperature greater than 25° C.; 5-50% alumina; 0-4% of a temporary additive different from the first binder and the additional binder, the total content of the first binder, the additional binder and the temporary additive being less than 9%; less than 2% impurities; and ZrO2 to make up 100%. According to the invention, the median diameter D50 of the powder is between 80 and 130 μm, the percentile D99.5 is less than 500 μm and the relative density of the granules is between 30% and 60%. Full Article
l Process for removing oxygenate from an olefin stream By www.freepatentsonline.com Published On :: Tue, 21 Apr 2015 08:00:00 EDT The present invention provides a process for removing oxygenate from an olefin stream comprising oxygenate, comprising providing to an oxygenate recovery zone the olefin stream comprising oxygenate and a solvent comprising ethanol, treating the olefin stream comprising oxygenate with the solvent, and retrieving from the oxygenate recovery zone at least one oxygenate-depleted olefinic product stream comprising olefin and a spent solvent comprising at least part of the oxygenate. Full Article
l Separation of components from a multi-component hydrocarbon stream which includes ethylene By www.freepatentsonline.com Published On :: Tue, 28 Apr 2015 08:00:00 EDT A process to separate a multi-component hydrocarbon stream which includes ethylene and other components with at least some of the components being present in a number of phases, is provided. The process includes in a first flash stage, flashing the multi-component hydrocarbon stream, from an elevated pressure and temperature to a pressure in the range of 10-18 bar(a), producing a first ethylene-containing vapor stream at a pressure in the range of 10-18 bar(a) and a multi-phase stream which includes some ethylene. In a second flash stage, the multi-phase stream is flashed to a pressure of less than 6 bar(a), producing a second vapor stream at a pressure of less than 6 bar(a) and a bottoms stream. The first ethylene-containing vapor stream is removed from the first flash stage, the second vapor stream is removed from the second flash stage and the bottoms stream is removed from the second flash stage. Full Article
l Catalyst composition and process for oligomerization of ethylene By www.freepatentsonline.com Published On :: Tue, 28 Apr 2015 08:00:00 EDT The present invention relates to a catalyst composition for oligomerization of ethylene, comprising a chromium compound; a ligand of the general structure R1R2P—N(R3)—P(R4)—N(R5)—H, wherein R1, R2, R3, R4 and R5 are independently selected from halogen, amino, trimethylsilyl, C1-C10-alkyl, aryl and substituted aryl; a modifier containing organic or inorganic halide; and an activator or co-catalyst; and a process for oligomerization utilizing that catalyst. Full Article
l Lubricant composition for an internal combustion engine and method for lubricating an internal combustion engine By www.freepatentsonline.com Published On :: Tue, 05 May 2015 08:00:00 EDT A lubricating oil composition for an internal combustion engine contains: a base oil including a component (A) of a polyalphaolefin having a kinematic viscosity at 100 degrees C. of 5.5 mm2/s or less, a CCS viscosity at −35 degrees C. of 3000 mPa·s or less and a NOACK of 12 mass % or less and a component (B) of a mineral oil having a viscosity index of 120 or more; and polyisobutylene having a mass average molecular weight of 500,000 or more. A content of the composition (A) is 25 mass % or more of a total amount of a lubricating oil. Full Article
l Lubricant composition for an internal combustion engine and method for lubricating an internal combustion engine By www.freepatentsonline.com Published On :: Tue, 05 May 2015 08:00:00 EDT A lubricating oil composition for an internal combustion engine contains a component (A) of a polyalphaolefin having a kinematic viscosity at 100 degrees C. of 5.5 mm2/s or less, a CCS viscosity at −35 degrees C. of 3000 mPA·s or less and a NOACK of 12 mass % or less, and a component (B) of a mineral oil having a viscosity index of 120 or more. The component (A) is contained at a content of 10 mass % or more of a total amount of the composition. Full Article
l High temperature platformer By www.freepatentsonline.com Published On :: Tue, 05 May 2015 08:00:00 EDT An apparatus for reforming a hydrocarbon stream is presented. The apparatus involves changing the design of reformers and associated equipment to allow for increasing the processing temperatures in the reformers and heaters. The reformers are operated under different conditions to utilize advantages in the equilibriums, but require modifications to prevent increasing thermal cracking and to prevent increases in coking. Full Article
l Method for producing p-xylene and/or p-tolualdehyde By www.freepatentsonline.com Published On :: Tue, 05 May 2015 08:00:00 EDT Disclosed is a method for producing p-xylene and/or p-tolualdehyde with high yield through a short process using biomass resource-derived substances as raw materials. The method for producing p-xylene and/or p-tolualdehyde of the present invention comprises: a cyclization step of producing 4-methyl-3-cyclohexenecarboxaldehyde from isoprene and acrolein; and an aromatization step of producing p-xylene and/or p-tolualdehyde from 4-methyl-3-cyclohexenecarboxaldehyde by gas-phase flow reaction using a catalyst(s). Full Article
l Method and apparatus for preparing fuel components from crude tall oil By www.freepatentsonline.com Published On :: Tue, 05 May 2015 08:00:00 EDT A method for preparing fuel components from crude tall oil. Feedstock containing tall oil including unsaturated fatty acids is introduced to a catalytic hydrodeoxygenation to convert unsaturated fatty acids, rosin acids and sterols to fuel components. Crude tall oil is purified in a purification by washing the crude tall oil with washing liquid and separating the purified crude tall oil from the washing liquid. The purified crude tall oil is introduced directly to the catalytic hydrodeoxygenation as a purified crude tall oil feedstock. An additional feedstock may be supplied to the catalytic hydrodeoxygenation. Full Article
l Integrated hydrogenation/dehydrogenation reactor in a catalytic reforming process configuration for improved aromatics production By www.freepatentsonline.com Published On :: Tue, 05 May 2015 08:00:00 EDT A process for reforming hydrocarbons is presented. The process involves applying process controls over the reaction temperatures to preferentially convert a portion of the hydrocarbon stream to generate an intermediate stream, which will further react with reduced endothermicity. The intermediate stream is then processed at a higher temperature, where a second reforming reactor is operated under substantially isothermal conditions. Full Article
l Initial hydrotreating of naphthenes with subsequent high temperature reforming By www.freepatentsonline.com Published On :: Tue, 05 May 2015 08:00:00 EDT A process for the production of aromatics through the reforming of a hydrocarbon stream is presented. The process utilizes the differences in properties of components within the hydrocarbon stream to increase the energy efficiency. The differences in the reactions of different hydrocarbon components in the conversion to aromatics allows for different treatments of the different components to reduce the energy used in reforming process. Full Article
l Co-current catalyst flow with feed for fractionated feed recombined and sent to high temperature reforming reactors By www.freepatentsonline.com Published On :: Tue, 05 May 2015 08:00:00 EDT A process is presented for the increasing the yields of aromatics from reforming a hydrocarbon feedstream. The process includes splitting a naphtha feedstream into a light hydrocarbon stream, and a heavier stream having a relatively rich concentration of naphthenes. The heavy stream is reformed to convert the naphthenes to aromatics and the resulting product stream is further reformed with the light hydrocarbon stream to increase the aromatics yields. The catalyst is passed through the reactors in a sequential manner. Full Article
l Process for producing olefins By www.freepatentsonline.com Published On :: Tue, 05 May 2015 08:00:00 EDT The present invention discloses a process for producing olefins from petroleum saturated hydrocarbons. The process of the present invention comprises: contacting a preheated petroleum saturated hydrocarbons feedstock with a dehydrogenation catalyst in a dehydrogenation reaction zone of a reaction system to obtain a petroleum hydrocarbon stream containing unsaturated hydrocarbon compounds, in which the dehydrogenation reaction has a conversion rate of at least 20%; and contacting the obtained petroleum hydrocarbon stream containing the unsaturated hydrocarbon compounds with olefins cracking catalyst in an olefin cracking zone of the reaction system to obtain a product stream containing olefins with a reduced number of carbon atoms. Full Article
l Method for controlling 2-phenyl isomer content of linear alkylbenzene and catalyst used in the method By www.freepatentsonline.com Published On :: Tue, 05 May 2015 08:00:00 EDT A method for controlling 2-isomer content in linear alkylbenzene obtained by alkylating benzene with olefins and catalyst used in the method. Full Article
l Catalysts, processes for preparing the catalysts, and processes for transalkylating aromatic hydrocarbon compounds By www.freepatentsonline.com Published On :: Tue, 05 May 2015 08:00:00 EDT A catalyst comprising an aluminosilicate zeolite having an MOR framework type, an acidic MFI molecular sieve component having a Si/Al2 molar ratio of less than 80, a metal component comprising one or more elements selected from groups VIB, VIIB, VIII, and IVA, an inorganic oxide binder, and a fluoride component. Full Article
l Method for producing olefin By www.freepatentsonline.com Published On :: Tue, 05 May 2015 08:00:00 EDT The present invention provides a method for producing an olefin from a carboxylic acid having a β-hydrogen atom or an anhydride thereof in the presene of a catalyst containing at least one metal element selected from metals of Group 8, Group 9 and Group 10 and bromine element at a reaction temperature of 120° C. to 270° C. Full Article
l Methods for removing weakly basic nitrogen compounds from a hydrocarbon stream using basic molecular sieves By www.freepatentsonline.com Published On :: Tue, 05 May 2015 08:00:00 EDT Disclosed is a method for removing weakly basic nitrogen compounds from a hydrocarbon feed stream by contacting the hydrocarbon feed stream with a basic catalyst to convert a portion of the weakly basic nitrogen compounds to basic nitrogen compounds. The method also includes contacting the hydrocarbon feed stream with an acidic adsorbent to adsorb the basic nitrogen compounds from the stream. The hydrocarbon feed stream comprises an aromatic compound and a weakly basic nitrogen compound. Full Article
l System and process for flushing residual fluid from transfer lines in simulated moving bed adsorption By www.freepatentsonline.com Published On :: Tue, 05 May 2015 08:00:00 EDT A process according to various approaches includes flushing an intermediate transfer line between a raffinate stream transfer line and a desorbent stream transfer line away from the adsorptive separation chamber to remove residual fluid including desorbent from intermediate transfer line. The process may include directing the residual fluid flushed from the intermediate transfer line to a recycle stream to introduce the residual fluid into the adsorptive separation chamber. Full Article
l Method for increasing thermal stability of a fuel composition using a solid phosphoric acid catalyst By www.freepatentsonline.com Published On :: Tue, 12 May 2015 08:00:00 EDT This invention relates to a method for increasing thermal stability of fuel, as well as in reducing nitrogen content and/or enhancing color quality of the fuel. According to the method, a fuel feedstock can be treated with a solid phosphoric acid catalyst under appropriate catalyst conditions, e.g., to increase the thermal stability of the fuel feedstock. Preferably, the fuel feedstock can be treated with the solid phosphoric acid catalyst at a ratio of catalyst mass within a contact zone to a mass flow rate of feedstock through the zone of at least about 18 minutes to increase the thermal stability of the fuel feedstock, along with reducing nitrogen content and/or enhancing color quality. Full Article
l Demulsifying of hydrocarbon feeds By www.freepatentsonline.com Published On :: Tue, 12 May 2015 08:00:00 EDT In various aspects, the invention provides for processing a hydrocarbon feed having hydrocarbon and emulsified aqueous components demulsifying into hydrocarbon and aqueous phases over an initial demulsification time, with an active agent to form a treated feed. The active agent has an active agent solubility in the hydrocarbon component and in the aqueous component, the aqueous component has an aqueous component solubility in the hydrocarbon component. The active agent solubility in the hydrocarbon component is greater than the aqueous component solubility in the hydrocarbon component. The active agent solubility in the aqueous component is greater than the active agent solubility in the hydrocarbon component. The active agent solubility in the aqueous component is greater than the active agent solubility in the hydrocarbon component. A treated demulsified hydrocarbon phase separates from the active agent and the aqueous component in a modified demulsification time that is shorter than the initial demulsification time. Full Article
l Integrated hydrogenation/dehydrogenation reactor in a platforming process By www.freepatentsonline.com Published On :: Tue, 12 May 2015 08:00:00 EDT A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and partially processing each feedstream in separate reactors. The processing includes passing the light stream to a combination hydrogenation/dehydrogenation reactor. The process reduces the energy by reducing the endothermic properties of intermediate reformed process streams. Full Article
l Process to make alpha olefins from ethanol By www.freepatentsonline.com Published On :: Tue, 12 May 2015 08:00:00 EDT The present invention relates to a process to make alpha olefins comprising: dehydrating ethanol to recover an ethylene stream,introducing said ethylene stream into an oligomerization zone containing an oligomerization catalyst and into contact with said oligomerization catalyst,operating said oligomerization zone at conditions effective to produce an effluent consisting essentially of 1-butene, 1-hexene, optionally heavier alpha olefins and unconverted ethylene if any,introducing the above effluent into a fractionation zone to recover a stream consisting essentially of 1-butene, a stream consisting essentially of 1-hexene, optionally a stream consisting essentially of heavier alpha olefins and an optional ethylene stream. In an advantageous embodiment the 1-hexene or at least one heavier alpha olefins, if any, are isomerized to an internal olefin and subsequently transformed by metathesis with the aid of additional ethylene into different alpha-olefins with even or odd number of carbons. By way of example 1-hexene is isomerized into 2-hexene and by methathesis with ethylene converted to 1-pentene and propylene.In another embodiment the oligomerization zone is only a dimerization zone and butene is produced. 1-butene is isomerized to 2-butene and sent to a methathesis zone in the presence of ethylene to be converted to propylene. In said embodiment the dehydration catalyst is selected in the group consisting of a crystalline silicate having a ratio Si/Al of at least about 100, a dealuminated crystalline silicate, and a phosphorus modified zeolite. Full Article
l Selective oligomerization of isobutene By www.freepatentsonline.com Published On :: Tue, 12 May 2015 08:00:00 EDT A process for oligomerizing isobutene comprises contacting a feedstock comprising isobutene with a catalyst comprising a MCM-22 family molecular sieve under conditions effective to oligomerize the isobutene, wherein said conditions including a temperature from about 45° C. to less than 140° C. The isobutene may be a component of a hydrocarbon feedstock containing at least one additional C4 alkene. In certain aspects, isobutene oligomers are separated from a first effluent of the oligomerization to produce a second effluent comprising at least one n-butene. The second effluent can be contacted with an alkylation catalyst to produce sec-butylbenzene. Full Article
l Methods for removing weakly basic nitrogen compounds from a hydrocarbon stream using acidic clay By www.freepatentsonline.com Published On :: Tue, 12 May 2015 08:00:00 EDT Disclosed is a method for removing weakly basic nitrogen compounds from a hydrocarbon feed stream by contacting the hydrocarbon feed stream with acidic clay to produce a hydrocarbon effluent stream having a lower weakly basic nitrogen compound content relative to the hydrocarbon feed stream. The hydrocarbon feed stream comprises an aromatic compound and a weakly basic nitrogen compound. Full Article
l High octane unleaded aviation gasoline By www.freepatentsonline.com Published On :: Tue, 19 May 2015 08:00:00 EDT High octane unleaded aviation fuel compositions having high aromatics content and a CHN content of at least 97.2 wt %, less than 2.8 wt % of oxygen content, a T10 of at most 75° C., T40 of at least 75° C., a T50 of at most 105° C., a T90 of at most 135° C., a final boiling point of less than 190° C., an adjusted heat of combustion of at least 43.5 MJ/kg, a vapor pressure in the range of 38 to 49 kPa, freezing point is less than −58° C. is provided. Full Article
l Biomass feed system including gas assist By www.freepatentsonline.com Published On :: Tue, 19 May 2015 08:00:00 EDT An improved biomass feed system and processes for transporting biomass to downstream processing locations are disclosed. The system uses a pressurized gas to assist in the transporting of the biomass to the conversion reactor. Full Article
l Integrated hydrogenation/dehydrogenation reactor in a platforming process By www.freepatentsonline.com Published On :: Tue, 19 May 2015 08:00:00 EDT A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and partially processing each feedstream in separate reactors. The processing includes passing the light stream to a combination hydrogenation/dehydrogenation reactor. The process reduces the energy by reducing the endothermic properties of intermediate reformed process streams. Full Article
l Oligomerisation of olefinic compounds in the presence of an activated oligomerisation catalyst By www.freepatentsonline.com Published On :: Tue, 19 May 2015 08:00:00 EDT This invention relates to the oligomerization of olefinic compounds in the presence of an activated oligomerization catalyst. The invention also extends to a particular manner for providing an activated oligomerization catalyst. According to the present invention, there is provided a process for producing an oligomeric product by the oligomerization of at least one olefinic compound, the process including (a) providing an activated oligomerization catalyst by combining, in any order, iii) a source of chromium, ιv) a ligating compound of the formula (R1)mX1(Y)X2(R2)n wherein X1 and X2 are independently an atom selected from the group consisting of nitrogen, phosphorus, arsenic, antimony, bismuth, oxygen, sulphur and selenium or said atom oxidized by S, Se, N or O where the valence of X1 and/or X2 allows for such oxidation, Y is a linking group between X1 and X2 which linking group contains at least one nitrogen atom which is directly bonded to X1 or X2, m and n are independently 0, 1 or a larger integer, and R1 and R2 are independently hydrogen, a hydrocarbyl group, an organoheteryl group or a heterohydrocarbyl group, and the respective R1 groups are the same or different when m>1, and the respective R2 groups are the same or different when n>1, in) a catalyst activator which is an organoboron compound including a cation and a non-coordinating anion of the general formula [(R10)xL*-H]+[B(R20)4]− wherein L* is an atom selected from the group consisting of N, S and P, the cation [(R10)x L*-H]* is a Bronsted acid, x is an integer 1, 2 or 3, each R10 is the same or different when x is 2 or 3 and each is a —H, hydrocarbyl group or a heterohydrocarbyl group, provided that at least one of R10 comprises at least 6 carbon atoms and provided further that the total number of carbon atoms in (R10)x collectively is greater than 12, R20 independently at each occurrence is selected from the group consisting of hydride, dialkylamido, halide, alkoxide, aryloxide, hydrocarbyl, halosubstituted-hydrocarbyl radicals, halosubstituted-alkoxide, halosubstituted-aryloxide and a halosubstituted aromatic ring moiety with at least one halide substituent on the aromatic ring, and vi) an aliphatic solvent, and (b) contacting the at least one olefinic compound with the activated oligomerization catalyst to produce an oligomeric product. Full Article
l Use of phosphorus modified molecular sieves in conversion of organics to olefins By www.freepatentsonline.com Published On :: Tue, 19 May 2015 08:00:00 EDT A method of making light olefins in a combined XTO (organics to olefins) and OCP (olefins cracking) process, from an oxygen-containing, halogenide-containing, or sulphur-containing organic feedstock contacted with a catalyst in a first reactor to convert the feedstock into a reactor effluent comprising light olefins and a heavy hydrocarbon fraction; separating the light olefins from the heavy hydrocarbon fraction, then contacting the heavy hydrocarbon fraction in a second reactor with a catalyst to convert a portion of the heavy hydrocarbons into light olefins; wherein the catalyst is a zeolite selected among a H+ or NH4+—form of MFI, MEL, FER, MOR, or clinoptilolite; modifying the zeolite by adding from 0.05 to 7 wt % of phosphorous to the zeolite, and an optional washing and/or drying in either order, then calcination. In an embodiment, the initial zeolite Si:Al atomic ratio of at least one catalyst is 100 or less. Full Article
l Co-processing of biomass and synthetic polymer based materials in a pyrolysis conversion process By www.freepatentsonline.com Published On :: Tue, 26 May 2015 08:00:00 EDT Disclosed is a process for biomass conversion which includes co-processing the biomass with thermoplastic and non-thermoplastic polymer based materials in a catalytic pyrolysis reactor to convert such to liquid hydrocarbons; wherein hydrogen atoms originating with the polymer materials can remove oxygen from oxygenated hydrocarbons produced in the conversion of the biomass in the reactor. Full Article
l Catalyst for metathesis of ethylene and 2-butene and/or double bond isomerization By www.freepatentsonline.com Published On :: Tue, 26 May 2015 08:00:00 EDT A process for the double-bond isomerization of olefins is disclosed. The process may include contacting a fluid stream comprising olefins with a fixed bed comprising an activated basic metal oxide isomerization catalyst to convert at least a portion of the olefin to its isomer. The isomerization catalysts disclosed herein may have a reduced cycle to cycle deactivation as compared to conventional catalysts, thus maintaining higher activity over the complete catalyst life cycle. Full Article
l Z-selective ring-closing metathesis reactions By www.freepatentsonline.com Published On :: Tue, 07 Jul 2015 08:00:00 EDT The present invention relates generally to olefin metathesis. In some embodiments, the present invention provides methods for Z-selective ring-closing metathesis. Full Article
l Spin-transfer torque magnetic random access memory (STTMRAM) with perpendicular laminated free layer By www.freepatentsonline.com Published On :: Tue, 05 May 2015 08:00:00 EDT A perpendicular spin-transfer torque magnetic random access memory (STTMRAM) element includes a fixed layer having a magnetization that is substantially fixed in one direction and a barrier layer formed on top of the fixed layer and a free layer. The free layer has a number of alternating laminates, each laminate being made of a magnetic layer and an insulating layer. The magnetic layer is switchable and formed on top of the barrier layer. The free layer is capable of switching its magnetization to a parallel or an anti-parallel state relative to the magnetization of the fixed layer during a write operation when bidirectional electric current is applied across the STTMRAM element. Magnetic layers of the laminates are ferromagnetically coupled to switch together as a single domain during the write operation and the magnetization of the fixed and free layers and the magnetic layers of the laminates have perpendicular anisotropy. Full Article
l Integrated microelectronic package temperature sensor By www.freepatentsonline.com Published On :: Tue, 12 May 2015 08:00:00 EDT Temperatures in microelectronic integrated circuit packages and components may be measured in situ using carbon nanotube networks. An array of carbon nanotubes strung between upstanding structures may be used to measure local temperature. Because of the carbon nanotubes, a highly accurate temperature measurement may be achieved. In some cases, the carbon nanotubes and the upstanding structures may be secured to a substrate that is subsequently attached to a microelectronic package. Full Article
l Semiconductor nanoparticles and method for producing same By www.freepatentsonline.com Published On :: Tue, 12 May 2015 08:00:00 EDT Copper(II) acetate, zinc(II) acetate, and tin(IV) acetate are weighed so that the total amount of metal ions is 2.0×10−4 mol and the molar ratio of ions is Cu:Zn:Sn=2:1:1, and 2.0 cm3 of oleylamine is added to prepare a mixed solution. Apart from this, 1.0 cm3 of oleylamine is added to 2.0×10−4 mol of sulfur powder to prepare a mixed solution. These mixed solutions are separately heated at 60° C. and mixed at room temperature. The pressure in a test tube is reduced, followed by nitrogen filling. The test tube is heated at 240° C. for 30 minutes and then allowed to stand until room temperature. The resultant product is separated into a supernatant and precipitates by centrifugal separation. The separated supernatant is filtered, methanol is added to produce precipitates. The precipitates are dissolved by adding chloroform to prepare a semiconductor nanoparticle solution. Full Article
l Fluorescent nanoscopy device and method By www.freepatentsonline.com Published On :: Tue, 12 May 2015 08:00:00 EDT A method for analysis of an object dyed with fluorescent coloring agents. Separately fluorescing visible molecules or nanoparticles are periodically formed in different object parts, the laser produces the oscillation thereof which is sufficient for recording the non-overlapping images of the molecules or nanoparticles and for decoloring already recorded fluorescent molecules, wherein tens of thousands of pictures of recorded individual molecule or nanoparticle images, in the form of stains having a diameter on the order of a fluorescent light wavelength multiplied by a microscope amplification, are processed by a computer for searching the coordinates of the stain centers and building the object image according to millions of calculated stain center co-ordinates corresponding to the co-ordinates of the individual fluorescent molecules or nanoparticles. Two-dimensional and three-dimensional images are provided for proteins, nucleic acids and lipids with different coloring agents. Full Article
l Nanoparticles for drug delivery to the central nervous system By www.freepatentsonline.com Published On :: Tue, 12 May 2015 08:00:00 EDT The present disclosure relates to compositions and methods for producing nanoparticles to provide relatively more rapid delivery of such particles across the blood-brain barrier. The nanoparticles may be formed from bis-quaternary pyridinium-aldoxime salts that may also be of a specific polymorphic structure and which may be formed in either hydrophobic or hydrophilic type liquid media. In addition, the nanoparticle for transport across the blood-brain barrier may comprise a polymeric resin encapsulating a bis-quaternary pyridinium-2-aldoxime salt. Full Article
l Metal silicate nanosheets, methods of making metal silicate nanosheets, and methods of use By www.freepatentsonline.com Published On :: Tue, 12 May 2015 08:00:00 EDT Embodiments of the present disclosure relate to the preparation of colloidal dispersions or suspensions of inorganic materials with nano-sized and nano-structured morphologies, preferably the nanosheet form, compositions produced by this method, and the like. Full Article
l Composite material, method for producing the same, and apparatus for producing the same By www.freepatentsonline.com Published On :: Tue, 12 May 2015 08:00:00 EDT Disclosed is a composite material wherein adhesion between a silicon surface and a plating material is enhanced. A method and an apparatus for producing the composite material are also disclosed. The method for producing a composite material comprises a dispersion/allocation step wherein the surface of a silicon substrate (102), which is a matrix provided with a silicon layer at least as the outermost layer, is immersed into a first solution containing gold (Au) ions, so that particulate or island-shaped gold (Au) serving as a first metal and substituted with a part of the silicon layer are dispersed/allocated on the matrix surface, and a plating step wherein the silicon substrate (102) is immersed into a second solution (24), which contains a reducing agent to which gold (Au) exhibits catalyst activity and metal ions which can be reduced by the reducing agent, so that the surface of the silicon substrate (102) is covered with the metal or an alloy of the metal (108) which is formed by autocatalytic electroless plating using gold (Au) as a starting point. Full Article
l Negative active material, method of preparing the same, and lithium battery including the same By www.freepatentsonline.com Published On :: Tue, 12 May 2015 08:00:00 EDT Provided are a negative active material, a method of preparing the same, and a lithium battery including the negative active material. The negative active material includes a carbonaceous core that has a sulfur content of about 10 ppm to 900 ppm; and an amorphous carbon layer continuously formed on a surface of the carbonaceous core, wherein the carbonaceous core has a crystalloid plate structure, and a crystallite size measured from a full width at half maximum of the peak with respect to the surface (002) of about 10 nm to about 45 nm in an X-ray diffraction spectrum of the carbonaceous core. The lithium battery including a negative electrode including the negative active material has improved capacity characteristics and ring lifetime characteristics. Full Article
l Sensor for biomolecules By www.freepatentsonline.com Published On :: Tue, 12 May 2015 08:00:00 EDT A sensor for biomolecules includes a silicon fin comprising undoped silicon; a source region adjacent to the silicon fin, the source region comprising heavily doped silicon; a drain region adjacent to the silicon fin, the drain region comprising heavily doped silicon of a doping type that is the same doping type as that of the source region; and a layer of a gate dielectric covering an exterior portion of the silicon fin between the source region and the drain region, the gate dielectric comprising a plurality of antibodies, the plurality of antibodies configured to bind with the biomolecules, such that a drain current flowing between the source region and the drain region varies when the biomolecules bind with the antibodies. Full Article
l Method of fabricating Ag-doped Te-based nano-material and memory device using the same By www.freepatentsonline.com Published On :: Tue, 12 May 2015 08:00:00 EDT A nano-ionic memory device is provided. The memory device includes a substrate, a chemically inactive lower electrode provided on the substrate, a solid electrolyte layer provided on the lower electrode and including a silver (Ag)-doped telluride (Te)-based nano-material, and an oxidizable upper electrode provided on the electrolyte layer. Full Article
l Nanostructure, optical device including the same, and methods of manufacturing the nanostructure and the optical device By www.freepatentsonline.com Published On :: Tue, 12 May 2015 08:00:00 EDT A nanostructure, an optical device including the nanostructure, and methods of manufacturing the nanostructure and the optical device. A method of manufacturing a nanostructure may include forming a block copolymer template layer and a precursor pattern of metal coupled to the block copolymer template layer on a graphene layer, and forming a metal nanopattern on the graphene layer by removing the block copolymer template layer and reducing the precursor pattern. Full Article
l Solid ganaxolone compositions and methods for the making and use thereof By www.freepatentsonline.com Published On :: Tue, 12 May 2015 08:00:00 EDT In certain embodiments, the invention is directed to composition comprising stable particles comprising ganaxolone, wherein the volume weighted median diameter (D50) of the particles is from about 50 nm to about 500 nm. Full Article
l Silica-supported oligomeric hybrid materials By www.freepatentsonline.com Published On :: Tue, 12 May 2015 08:00:00 EDT A particle-polymer hybrid material can include: a substance having the structure of Formula 1 Z(Y-FP)m, wherein Z is a particle smaller than 1 mm; m is an integer; Y is a linker including a silicon atom linked to the particle; FP is a functionalized polymer having: a first structure derived from a first norbornene compound linked to the Y; and one or more repeating units linked to the first structure, each unit being derived from a second norbornene compound and having a functional group. Full Article