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[ASAP] Photochemical Oxidation Specific to Distorted Aromatic Amines Providing <italic toggle="yes">ortho</italic>-Diketones

Organic Letters
DOI: 10.1021/acs.orglett.0c01190




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[ASAP] Synthesis of Stable, High-SOMO Zwitterionic Radicals: Enabling Intermolecular Electron Transfer between Naphthalenediimides

Organic Letters
DOI: 10.1021/acs.orglett.0c01263




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[ASAP] Visible-Light-Induced Palladium-Catalyzed Intermolecular Narasaka–Heck Reaction at Room Temperature

Organic Letters
DOI: 10.1021/acs.orglett.0c01267




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[ASAP] Chiral Binaphthyl Box-Copper-Catalyzed Enantioselective Tandem Michael–Ketalization Annulations for Optically Active Aryl and Heteroaryl Fused Bicyclicnonanes

Organic Letters
DOI: 10.1021/acs.orglett.0c01221




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[ASAP] Acylation of Aryl Halides and a-Bromo Acetates with Aldehydes Enabled by Nickel/TBADT Cocatalysis

Organic Letters
DOI: 10.1021/acs.orglett.0c01121




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[ASAP] Pd-Catalyzed Regiodivergent Synthesis of Diverse Oxindoles Enabled by the Versatile Heck Reaction of Carbamoyl Chlorides

Organic Letters
DOI: 10.1021/acs.orglett.0c01197




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[ASAP] Carbocation versus Carbene Controlled Chemoselectivity: DFT Study on Gold- and Silver-Catalyzed Alkylation/Cyclopropanation of Indoles with Vinyl Diazoesters

Organic Letters
DOI: 10.1021/acs.orglett.0c01476




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[ASAP] K<sub>2</sub>S as Sulfur Source and DMSO as Carbon Source for the Synthesis of 2-Unsubstituted Benzothiazoles

Organic Letters
DOI: 10.1021/acs.orglett.0c00994




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[ASAP] Palladium-Catalyzed Cascade Decarboxylative Amination/6-<italic toggle="yes">endo-dig</italic> Benzannulation of <italic toggle="yes">o</italic>-Alkynylarylketones with <italic toggle="yes"&g

Organic Letters
DOI: 10.1021/acs.orglett.0c01183




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[ASAP] DNA Compatible Intermolecular Wittig Olefination for the Construction of a, ß-Unsaturated Carbonyl Compounds

Organic Letters
DOI: 10.1021/acs.orglett.0c01215




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[ASAP] Selective Synthesis of Secondary Alkylboronates: Markovnikov-Selective Hydroboration of Vinylarenes with Bis(pinacolato)diboron Catalyzed by a Nickel Pincer Complex

Organic Letters
DOI: 10.1021/acs.orglett.0c01416




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[ASAP] Catalytic, Enantioselective C2-Functionalization of 3-Aminobenzofurans Using N-Heterocyclic Carbenes

Organic Letters
DOI: 10.1021/acs.orglett.0c01112




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[ASAP] Stereoselective Asymmetric Synthesis of Pyrrolidines with Vicinal Stereocenters Using a Memory of Chirality-Assisted Intramolecular S<sub>N</sub>2' Reaction

Organic Letters
DOI: 10.1021/acs.orglett.0c01307




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[ASAP] Enantioselective Copper-Catalyzed Remote C(sp<sup>3</sup>)–H Alkynylation of Linear Primary Sulfonamides

Organic Letters
DOI: 10.1021/acs.orglett.0c01325




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[ASAP] Nickel(II)-Catalyzed Addition of Aryl-, Alkenyl-, and Alkylboronic Acids to Alkenylazaarenes

Organic Letters
DOI: 10.1021/acs.orglett.0c01425




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[ASAP] Sequential Visible-Light and <italic toggle="yes">N</italic>-Heterocyclic Carbene Catalysis: Stereoselective Synthesis of Tetrahydropyrano[2,3-<italic toggle="yes">b</italic>]indoles

Organic Letters
DOI: 10.1021/acs.orglett.0c01447




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[ASAP] Synthesis of Spiroisoxazolines via an Oximation/Dearomatization Cascade under Air

Organic Letters
DOI: 10.1021/acs.orglett.0c01429




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[ASAP] Columnar Organization of Carbo[5]helicene Directed by Peripheral Steric Perturbation

Organic Letters
DOI: 10.1021/acs.orglett.0c01421




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[ASAP] Oxidative Coupling of Aldehydes with Alcohol for the Synthesis of Esters Promoted by Polystyrene-Supported N-Heterocyclic Carbene: Unraveling the Solvent Effect on the Catalyst Behavior Using NMR Relaxation

Organic Letters
DOI: 10.1021/acs.orglett.0c01188




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[ASAP] Copper-Mediated DNA-Compatible One-Pot Click Reactions of Alkynes with Aryl Borates and TMS-N<sub>3</sub>

Organic Letters
DOI: 10.1021/acs.orglett.0c01219




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[ASAP] Photoredox Catalysis toward 2-Sulfenylindole Synthesis through a Radical Cascade Process

Organic Letters
DOI: 10.1021/acs.orglett.0c01297




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[ASAP] A General One-Pot Protocol for Hindered <italic toggle="yes">N</italic>-Alkyl Azaheterocycles from Tertiary Carboxylic Acids

Organic Letters
DOI: 10.1021/acs.orglett.0c01254




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[ASAP] Palladium-Catalyzed Regio- and Stereoselective Cross-Coupling of Vinylethylene Carbonates with Ketimine Esters to Generate (<italic toggle="yes">Z</italic>)-Tri- and Tetra-substituted Allylic Amino Acid Derivatives

Organic Letters
DOI: 10.1021/acs.orglett.0c01211




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[ASAP] Nickel-Catalyzed Formal Aminocarbonylation of Secondary Benzyl Chlorides with Isocyanides

Organic Letters
DOI: 10.1021/acs.orglett.0c01284




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[ASAP] Rh(I)-Catalyzed C6-Selective Decarbonylative Alkylation of 2-Pyridones with Alkyl Carboxylic Acids and Anhydrides

Organic Letters
DOI: 10.1021/acs.orglett.0c01277




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Beyond Cedarville: Why Do Pastors Keep Getting Rehired After Abuse?

Victims’ advocates caution institutions against plans to “restore” fallen leaders.

Update (May 1): Cedarville University president Thomas White has been placed on administration leave by the school’s board of trustees. A week after Anthony Moore was fired by White over “additional information related to [his] past,” the board announced it will commission an independent investigation of Moore and an audit of his hiring.

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Another case of a leader with an abusive past moving from one evangelical institution to another has intensified scrutiny on Christian hiring practices and responses to abuse.

In ministry contexts, the desire to keep fallen leaders out of positions where they might again abuse their authority is sometimes met with another perspective—a hope that a redemptive and forgiving God would allow people to be restored to leadership. Both victims’ advocates and community members worry that administrators weighing those considerations at Cedarville University made the wrong call.

In 2017, Cedarville welcomed Anthony Moore six months after he was fired from the lead pastor position of The Village Church’s Fort Worth campus. President Thomas White wrote that he offered to shepherd Moore through a five-year plan of restoration at the conservative Baptist school while he taught theology, helped coach basketball, and served as a special advisor on diversity.

CT spoke with four current and former Cedarville professors who said they knew Moore had made a “mistake” related to same-sex attraction and technology, based on White’s introduction and Moore’s own telling. Some assumed pornography or an online relationship. They had no idea that he had reportedly filmed a subordinate at his previous church in the shower. The revelation, detailed by multiple ...

Continue reading...




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After SAT and ACT Cancel, Registrations Soar for Classical Education Exam

An alternative college admissions test, used by some Christian schools, draws a record 50,000 students.

The Classic Learning Test (CLT), a niche college entrance exam aspiring to bring a sense of virtue to standardized tests, saw a 1,000 percent increase in registrations over its short history when the SAT and ACT canceled testing for the remainder of the school year due to COVID-19.

“Because we are able to administer the test remotely, we’re kind of the only game in town,” said Jeremy Tate, who created the CLT four years ago amid a renaissance in Classical education, including among Christians.

At its first administration in June 2016, 47 students took the CLT. With the bump in registration, 50,000 students will take its suite of tests—the CLT, and the CLT-8 and CLT-10, designed for lower grades—during the 2019-2020 academic year. That’s more than double last year’s total.

Though not a Christian company, CLT references figures including John Henry Newman and C. S. Lewis in its promotional materials and stresses the moral, formational dimension to education. The exam has been popular among classical Christian schools, which educate over 40,000 students in the US, and homeschoolers, who make up about 40 percent of CLT test-takers.

So far, 178 colleges and universities in the US accept the exam, mostly Catholic and Protestant schools. For other institutions, the CLT can serve as a supplemental assessment.

The College Board and ACT Inc., the companies that administer the SAT and ACT, respectively, have canceled or postponed in-person testing until the fall, leading many colleges to make the admissions exams an optional part of their applications. In 2018, around 2 million students took the SAT and 1.9 million took the ACT.

While some registrants may turn to the CLT this year for the convenience ...

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Died: Darrin Patrick, Who Used His Fall and Restoration to Help Struggling Pastors

(UPDATED) The St. Louis pastor spoke up about the difficulties faced by leaders and critiqued “celebrity culture” in ministry.

Darrin Patrick, a megachurch pastor, author, and speaker, has died.

Patrick was a teaching pastor at Seacoast Church, a multi-site megachurch based in Mount Pleasant, South Carolina, and the founding pastor of the Journey Church in St. Louis, where he lived.

In a Friday evening update, Seacoast Church stated: “Darrin was target shooting with a friend at the time of his death. An official cause of death has not been released but it appears to be a self-inflicted gunshot wound. No foul play is suspected.”

Patrick’s unexpected death came as a shock to friends and colleagues. Robby Gallaty, pastor of Long Hollow Baptist, in Hendersonville, Tennessee, said that Patrick was scheduled to speak at his church next weekend.

“I just talked to him Tuesday and Wednesday,” said Gallaty. “This is the second close friend I have lost in a year.”

Gallaty first met Patrick in 2015 and had invited him to speak the following year at a men’s ministry event at Long Hollow. Just before the event, he said, Patrick called and said he was leaving the ministry.

At the time, Patrick had been a rising star among Reformed evangelical circles and was serving as vice-president of the Acts 29 church planting network. He was fired from Journey for what church elders called misconduct including “inappropriate meetings, conversations, and phone calls with two women” and an abuse of power.

Despite Patrick’s fall from ministry, the two stayed friends. Patrick admitted his faults and got counseling. He went through a restoration process that lasted 26 months, according to a 2019 blog interview posted at Christianity Today. He returned to the ministry as a preacher but not as a senior pastor of a church. ...

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LG Chem share price falls nearly 2% after deadly gas leak in India

The leak was brought under control after being discovered by a maintenance worker on the night shift at the LG Polymers plant, outside the east coast city of Visakhapatnam, in India`s southern Andhra Pradesh state, according to a company spokesman.




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Elon Musk delays release of Tesla's Roadster sports car

Tesla Inc Chief Executive Elon Musk said in a podcast interview released on Thursday that the company`s planned Roadster sports car would take a backseat to the development of other vehicle models.




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IndiGo Airlines to cut salary for senior employees from May

The company will also put in place a leave without pay program for the months of May, June and July




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Ratan Tata invests in 17-year-old kid's pharma start-up Generic Aadhaar

Generic Aadhaar supplies quality generic drugs from reputed manufacturers at up to 80 per cent lesser cost and other medicines 20-30 per cent cheaper.




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Invest Rs 10,000 and earn Rs 30,000 per month by starting pickle making business

For pickle making business you will be required to obtain a license. 




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Markets end higher, Sensex closes above 31,600

The BSE Sensex jumped 199.32 points or 0.63 per cent to close at 31,642.70. On the other hand, the NSE Nifty rose 52.45 points, or 0.57 per cent, to settle at 9,251.50.




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Service charges for Post office savings a/c, issue of duplicate passport and more

Here are some details of service charges that the Post Office charges you.




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Dharmendra Pradhan hints at new gas policy, says low oil prices no answer

Pradhan also said that India favours reasonable prices that give some space to the producer countries.




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Nitin Gadkari asks traders to take loan in dollars, keep their balance sheets clean

The Union minister also offered them some remedies that are likely to earn money and will help them in increasing their business.




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Franklin Templeton issues apology to SEBI, says top executive's remark 'taken out of context'

Franklin Templeton Mutual Fund on Friday said it is making every effort to ensure an orderly and equitable exit to all investors affected by closure of six debt schemes, a day after it was asked by regulator sebi to focus on returning investors' money at the earliest.




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Free market and the reel world

Theatre owners need not fear OTT platforms and resort to protectionism. They can continue to be relevant even as tech disrupts




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An area of darkness

Power sector needs liquidity relief in Covid times



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