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ter Advances, opportunities, and challenges in methods for interrogating the structure activity relationships of natural products By pubs.rsc.org Published On :: Nat. Prod. Rep., 2024, 41,1543-1578DOI: 10.1039/D4NP00009A, Review Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Christine Mae F. Ancajas, Abiodun S. Oyedele, Caitlin M. Butt, Allison S. WalkerThis review highlights methods for studying structure activity relationships of natural products and proposes that these methods are complementary and could be used to build an iterative computational-experimental workflow.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Estimating the extent of adulteration of the popular herbs black cohosh, echinacea, elder berry, ginkgo, and turmeric – its challenges and limitations By pubs.rsc.org Published On :: Nat. Prod. Rep., 2024, 41,1604-1621DOI: 10.1039/D4NP00014E, Review Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Nilüfer Orhan, Stefan Gafner, Mark BlumenthalThis review article focuses on the challenges and limitations of estimating the prevalence of adulteration in preparations made from black cohosh, echinacea, elder berry, ginkgo, and turmeric.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Volatile organic compounds (VOCs) in terrestrial extreme environments: implications for life detection beyond Earth By pubs.rsc.org Published On :: Nat. Prod. Rep., 2024, Advance ArticleDOI: 10.1039/D4NP00037D, Review Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Claire A. Batty, Victoria K. Pearson, Karen Olsson-Francis, Geraint MorganThis review highlights how discovering and analysing VOCs in extreme environments on Earth can help identify biosignatures and unravel complex patterns in metabolic data that could help identify life on other planetary bodies.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Siccanin-related drimane meroterpenoids: biological activities and synthesis By pubs.rsc.org Published On :: Nat. Prod. Rep., 2024, Advance ArticleDOI: 10.1039/D4NP00025K, Review ArticleShengxin Sun, Xia Wang, Nvdan Hu, Shiqi Fu, Shengkun LiThis review describes the isolation, structural characteristics, bioactivities and divergent synthetic strategies of siccanin-related drimane meroterpenoids.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Efficient catalysis of Knoevenagel condensation by 1D copper-containing heteropolyoxoniobate at room temperature By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,1993-1997DOI: 10.1039/D4QI00260A, Research ArticleYa-Kun Zuo, Yan-Ru Li, Yan-Qiong Sun, Xin-Xiong Li, Cai Sun, Shou-Tian ZhengA 1D copper-containing organic–inorganic hybrid heteropolyoxoniobate catalyst for efficient catalysis of Knoevenagel condensation at room temperature.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Defect-engineered WSxSe2−x nanocrystals anchored on selenized polyacrylonitrile fibers toward high-performance sodium/potassium-ion batteries with a wide working temperature range By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2164-2177DOI: 10.1039/D3QI02640J, Research ArticleFuyu Xiao, Jingran Zhang, Weiming Zhou, Yixing Fang, Xiaotong He, Wenbin Lai, Chuyuan Lin, Mingyang Ge, Haosen Fan, Qingrong Qian, Mingdeng Wei, Qinghua Chen, Lingxing ZengWSSe-Se@PAN was fabricated by the electrospinning route combined with selenization treatment. It exhibited a wide working temperature range for SIB/PIB applications.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Te doped 1T/2H-MoSe2 nanosheets with rich defects as advanced anode materials for high-rate sodium ion half/full batteries By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2017-2028DOI: 10.1039/D4QI00259H, Research ArticleZhiqi Li, Jiawen Yan, Qiming Li, Ao Xu, Jianchao Sun, Yijing Wang, Xiaoyu Zhang, Xueqin Sun, Fuyi Jiang, Yanli ZhouMoSe2 with a two-dimensional layer-like structure has been considered a promising anode material for sodium-ion batteries (SIBs) on account of its high capacity and rich reserves on Earth.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Electron-deficient Co modulated by the construction of heterojunctions Co@NC boosts the electroreduction of nitrate to ammonia By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2144-2151DOI: 10.1039/D4QI00110A, Research ArticleBo Zhang, Fengshou Yu, Yaohua Hong, Yuzhuo Zhou, Yaheng Wang, Shaobo Zhang, Lu-Hua ZhangFormation of electron-deficient Co by the construction of heterojunctions to promote the electroreduction of nitrate to ammonia.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Combination of dimensional reduction and active site addition strategies for preparing unique {RE9}-cluster-based MOFs: efficient CO2 fixation and Knoevenagel condensation By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2071-2080DOI: 10.1039/D3QI02527F, Research ArticleYing Zhao, Dan Wu, Yidan Qiao, Guo-Ping Yang, Lu-Fang Ma, Yao-Yu WangA series of 2D {RE9}-cluster-based rare-earth MOFs were built by dimensional reduction and active site addition strategies. They exhibit excellent catalytic activity in CO2 fixation and Knoevenagel condensation under mild conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Reasonable regulation of flexible sulfur-based bifunctional catalytic electrodes for efficient seawater splitting By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2152-2163DOI: 10.1039/D3QI02575F, Research ArticleFengjing Lei, Xunwei Ma, Xinyun Shao, Ziyan Fang, Yuqin Wang, Weiju HaoAn iron-regulated three-dimensional nano-conical, economical, and flexible Fe-NiS@HA electrode exhibiting high intrinsic activity is prepared by gentle one-step electroless plating for efficient, durable hydrogen production in alkaline seawater.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Synthesis and characterization of a CsPbCl3 perovskite doped with Nd3+: structural, optical, and energy transfer properties By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00171K, Research ArticleMariusz Stefanski, Bartosz Bondzior, Adam Basinski, Maciej Ptak, Bibo Lou, Chong-Geng MaThe levels of Nd3+ in CsPbCl3 lie below the top of the host's VB. Consequently, Nd3+ luminescence is not observed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Sodium ion pre-intercalation regulates the electron density and structural stability of vanadium oxide nanowires for Ca–ion batteries By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00218K, Research ArticleHuajie Feng, Yize Wang, Wenda Qiu, Zixi Liu, Yaping Tao, Xihong LuBenefiting from the abundant resource, low cost, and high operating potential, calcium–ion batteries (CIBs) have attracted great attention as emerging energy storage devices over lithium-based systems.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Tailoring two magic number Au13 nanoclusters with N-containing diphosphine ligands: a classical icosahedral core vs. an unprecedented UFO- shaped core By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00334A, Research ArticleJing Liu, Jia-Chuan Liu, Hai-Ling Wang, Pei-Yu Liao, Jian-Hua Jia, Ming-Liang TongTwo magic number Au13 nanoclusters were tailored using two N-containing multidentate phosphine ligands with a classical icosahedral core and an unprecedented “UFO”-shaped polyhedral core, respectively.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Adhesion, stability, structural and electronic properties of perovskite/BaWO4 heterostructures: first-principles and experimental characterizations By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00231H, Research ArticleYao Guo, Shiding Zhang, Zhaoyu Zhang, Yuanbin Xue, Jianxin Li, Haixiang Song, Yuhua Wang, Qing ShenThe interfacial behavior and mechanism of the CsPbBr3/BaWO4 and MAPbBr3/BaWO4 heterostructures have been extensively investigated by a combined first-principles and experimental analysis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Pb3.5GeS4Br3: the first phase-matching thiogermanate halide infrared nonlinear optical material By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00293H, Research ArticleJiazheng Zhou, Hongshan Wang, Junjie Liu, Xin Su, Yu Chu, Jiale Qu, Xiangzhan JiangPb3.5GeS4Br3 is the first phase-matching thiogermanate halide infrared nonlinear optical material.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Effects of weak intramolecular interactions and distortions from trigonal prismatic coordination on the magnetic properties of zero-field Co(II) single-ion magnets By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D3QI02507A, Research ArticleBen Zhang, Yang Zhou, Hao-Yi Huang, Xiao-Le Zhang, Yi Xiang, Yanbo Shi, Chennan Zhang, Aihua Yuan, Xingwei Cai, Lei Chen, Yi-Quan Zhang, Zhao-Bo HuThe change of counter anions significantly affects the environment around Co(II) ions, leading to two zero-field single-ion magnets possessing different uniaxial anisotropies and dynamic magnetic properties.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Modulating Mn self-reduction and multimodal luminescence in CaSb2O6 through La3+ doping for quadruple-mode dynamic anti-counterfeiting and optical temperature sensing applications By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00493K, Research ArticleFenzhong Long, Lu Xie, Jiawei Fu, Kaian Shan, Huihui Fei, Xinmin ZhangThe co-doping La3+strategy was employed to modulate Mn self-reduction and multimodal luminescence in CaS2O6:Mn. CaS2O6:Mn has potential application in optical anti-counterfeiting and high-sensitivity temperature sensing applications.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter NH3 plasma-etching-derived porous N-doped carbon nanotubes with FeP nanoparticles and intrinsic carbon defects for boosting oxygen reduction in rechargeable Zn–air batteries By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00182F, Research ArticleBing Chen, Minjie Zhou, Na Zhang, Xianglin Deng, HaiHua YangThe formation of intrinsic carbon defects and phase engineered FeP nanoparticles regulated by NH3 plasma etching significantly enhanced the oxygen reduction reaction performance of N-doped carbon nanotubes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Controlling the structural and adsorption features of polyoxovanadate-based metal–organic clusters by adjustable template effect By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00254G, Research ArticleYan-Hu Wang, Ke-Wei Tong, Chao-Qin Chen, Jing Du, Guo-Ping Yang, Peng YangAn adjustable template effect was employed to activate the evolution of polyoxovanadate-based metal–organic clusters, resulting in unprecedented structural archetypes as well as customized dye and iodine adsorption features.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Discovery of excellent ultraviolet nonlinear optical materials in chlorates and bromates with highly stereochemically active lone pairs By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00462K, Research ArticleChun-Li Hu, Qian-Qian Chen, Fang Kong, Jiang-Gao MaoThe long-neglected stereochemically active lone pair groups ClO3− and BrO3− are demonstrated to be important UV NLO functional motifs based on the fact that AClO3 and ABrO3 possess high SHG effects and short λPM and are promising UV NLO materials.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Near-infrared-photoinduced metamagnet based on a layered cyanido-bridged Co–W assembly with π–π interactions By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00511B, Research Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kazuki Nakamura, Koji Nakabayashi, Shota Kobayashi, Shin-ichi OhkoshiA cyanido-bridged Co–W assembly with π–π interactions showed a thermal phase transition and a photo–induced metamagnetism based on a charge transfer–induced spin transition.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Integrating multiple regulatory strategies: phase, morphology and interface engineering to construct a hierarchical Ni2P–MoS2/rGO heterostructure catalyst for efficient oxygen reduction reaction By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00262H, Research ArticleXinyi Wang, Jing Jin, Zeyuan Gao, Li Hou, Xiwen Tao, Jing Wang, Yueqi Zhao, Faming GaoTwo-dimensional (2D) molybdenum disulfide (MoS2) with a large surface area and unique electronic properties has emerged as a promising noble metal-free catalyst for electrochemical energy storage/conversion applications.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Efficient doped and non-doped light-emitting diodes based on a TADF-emitting Cu4Br4 cluster By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00210E, Research ArticleXin Lu, Shao-Jie Wu, Ya-Shu Wang, Shan-Yue Wei, Lingyi Meng, Xi-He Huang, Xu-Lin Chen, Can-Zhong LuA sublimable Cu4Br4 cluster, chelated by bidentate N^P ligands with a donor–acceptor configuration, realizes highly efficient doped and non-doped cluster light-emitting diodes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Hysteretic magnetism–dielectricity switching in 2D Hofmann type spin-crossover compounds By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D3QI02660D, Research ArticleNian-Tao Yao, Meng-Jia Shang, Han-Han Lu, Qiang Liu, Wen Wen, Shi-Hui Zhang, Liang Zhao, Hiroki Oshio, Yin-Shan Meng, Tao LiuTwo 2D Hofmann type compounds {Fe(3,4-bpt)2[M(CN)4]} were synthesized. They showed reversible switching in magnetism, dielectricity, and thermochromism actuated by the spin transition of Fe(II).To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Porphyrin-based MOFs for photocatalysis in water: advancements in solar fuels generation and pollutants degradation By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2212-2245DOI: 10.1039/D3QI01996A, Review Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Fangbing Liu, Irene Rincón, Herme G. Baldoví, Amarajothi Dhakshinamoorthy, Patricia Horcajada, Sara Rojas, Sergio Navalón, Alexandra FateevaThis review highlights the recent advances in the photocatalytic applications of porphyrin-based MOFs in aqueous environments for solar fuel generation and water remediation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Selenium doping induced phase transformation and interlayer expansion boost the zinc storage performance of molybdenum disulfide By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2272-2280DOI: 10.1039/D4QI00344F, Research ArticleMengfan Niu, Wenli Xin, Lei Zhang, Min Yang, Yaheng Geng, Xilin Xiao, Hui Zhang, Zhiqiang ZhuThis work synthesized Se-doped MoS2 nanosheets as a cathode for aqueous zinc-ion batteries, and they exhibited largely improved electrochemical performance owing to their high content of the 1T phase (64%) and expanded interlayer spacing (0.65 nm).The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Deciphering the active species and reaction mechanism in water oxidation catalyzed by a copper complex with redox-active ligands By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2365-2372DOI: 10.1039/D4QI00163J, Research ArticleQing Fan, Cong Yang, Mengdi Li, Chen Wang, Guixia Wang, Xiangfei Kong, Qiping ZhuThis theoretical study unveils active species and the reaction mechanism in electrochemical water oxidation catalyzed by a copper complex with redox-active ligands.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Ultrathin 2D–2D NiFe LDH/MOF heterojunction nanosheets: an efficient oxygen evolution reaction catalyst for water oxidation By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2489-2497DOI: 10.1039/D4QI00090K, Research ArticleHaoran Yin, Shibiao Su, Di Yao, Lixia Wang, Xinqiang Liu, Tayirjan Taylor Isimjan, Xiulin Yang, Dandan CaiAn ultrathin NiFe LDH/MOF catalyst is grown on carbon paper by an in situ self-dissociation–assembly strategy. Studies reveal that the strong electronic interaction between Fe and Ni species with rich active sites results in good OER and OWS performance.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Electrochemical conversion of 5-hydroxymethylfurfural over CuNi bimetallic catalysts: the synergistic effect of interfacial active sites By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2479-2488DOI: 10.1039/D4QI00145A, Research ArticleYiwei Zhao, Chao Zhang, Shuangxi Xing, Zuhang Jin, Tingting XiaoECO of HMF to FDCA and ECR to BHMF with high yield have been studied on CuNi-based bimetallic catalysts. The presence of the Cu–O–Ni interfacial area was beneficial for promoting the catalytic performance in ECO.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Perovskite photoinitiated RAFT-mediated polymerization-induced self-assembly for organic–inorganic hybrid nanomaterials By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2471-2478DOI: 10.1039/D4QI00233D, Research ArticleBingfeng Shi, Wanchao Hu, Shiyi Li, Zhinan Xia, Changli LüAn efficient strategy is proposed to construct PQD/polymer organic–inorganic nanohybrids by PET-RAFT polymerization-mediated PISA and the nanohybrid assemblies can maintain excellent luminescence originating from PQDs with enhanced stability.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter sp2–sp cross-carbanion coupling at a rare-earth center leading to the formation of carbon–carbon double bonds By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2312-2318DOI: 10.1039/D4QI00178H, Research ArticleZhengqi Chai, Ze-Jie Lv, Wei Liu, Jinxiao Yang, Junnian Wei, Wen-Xiong ZhangThe reaction of rare-earth azametallacyclopentadienes with terminal alkynes provides rare-earth metallacycles with cumulated double bonds in three steps: alkynyl C–H bond activation, sp2–sp cross-carbanion coupling and subsequent isomerization.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter N-heterocyclic carbene-stabilized Cu9 clusters with combined thermally activated delayed fluorescence and phosphorescence By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2498-2507DOI: 10.1039/D4QI00160E, Research ArticleLin-Mei Zhang, Mo Xie, Hui-Zhi Wei, Shang-Fu Yuan, Dong-Sheng Li, Tao WuTwo NHC-stabilized Cu9 clusters showcase both TADF and direct phosphorescence in thermal equilibrium. The combined harvesting mechanism arises from the simultaneous presence of a small ΔE(S1 − T1) gap and relatively strong spin–orbit coupling.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
