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Color Tuning in Ca3-xMx(PO4)2: Eu2+ (M = Sr, Ba) Phosphors via Cation Substitution

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01130D, Paper
Huiling Zhang, Dengwen Yuan, Xiaoyun Mi, Xiuling Liu, Jun Lin
A series of Ca3-xMx(PO4)2: Eu2+ (M = Sr, Ba) phosphors were prepared via high-temperature solid-state reaction process. The X-ray diffraction and Rietveld refinements were used to verify the incorporations of...
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Multicolor tunable luminescence and energy transfer of core-shell structured SiO2@Gd2O3 microspheres co-activated with Dy3+/Eu3+ under single UV excitation

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00735H, Paper
Jie Chen, Yixin Gao, Haifeng Jiang, Yan Liu, Zhaohui Jin
Optimizing structure and varing doped ions are two main strategies to obtain excellent luminescence performance. Spherical morphology is considered to be the most ideal phosphor structure due to the least...
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The role of the excited state dynamic of the antenna ligand in the Lanthanide sensitization mechanism

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01132K, Paper
María Joaquina Beltrán Leiva, Eduardo Solis Céspedes, Dayan Paez-Hernandez
A fragmentation scheme combined with a series of theoretical approximations like TD-DFT, and multiconfigurational CASSCF/NEVPT2 methods, have been used to describe the photophysical phenomena associated with the antenna effect and...
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Influence of Eu valence in the optical activity of BaTiO3 decorated with CaF2 synthesized by microwave-assisted hydrothermal method

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01321H, Paper
Tatiane Strelow Lilge, Adriano Borges Andrade, Claudiane dos Santos Bezerra, Giordano Frederico da Cunha Bispo, Zélia Soares Macedo, Mario Lucio Lúcio Moreira, Mário Ernesto Giroldo Valerio
Inorganic hybrid materials are promising applications in absorbers and photon harvesting of solar irradiation, such as DSSC cell photoanodes. Moreover, the investigation of the interaction between the photoanode constituent materials...
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Probing the limits of linker substitution in aluminum MOFs through water vapor sorption studies: Mixed-MOF instead of mixed-linker CAU-23 and MIL-160 materials

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01044H, Paper
Carsten Schlüsener, Dustin Nils Jordan, Mergime Xhinovci, Tobie J. Matemb Ma Ntep, Alexa Schmitz, Beatriz Giesen, Christoph Janiak
We report the systematic study on the possibility of forming mixed-linker MOFs spanning between the aluminum metal-organic frameworks CAU-23 and MIL-160 with their 2,5-thiophenedicarboxylate (TDC) and 2,5 furandicarboxylate (FDC) linkers,...
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Luminescent organic dyes containing a phenanthro[9,10-D]imidazole core and [Ir(N^C)(N^N)]+ complexes based on the cyclometalating and diimine ligands of this type

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00568A, Paper
Anastasia I. Solomatina, Kirill M. Kuznetsov, Vladislav V. Gurzhiy, Vladimir V. Pavlovskiy, Vitaly V. Porsev, Robert A. Evarestov, Sergey P. Tunik
New N^N and N^C luminescent ligands with solvatochromic behavior and their iridium complexes were synthesized, characterized and investigated.
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MnO2 flowery nanocomposites for efficient and fast removal of mercury(II) from aqueous solution: a facile strategy and mechanistic interpretation

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01054E, Paper
Sankar Das, Arnab Samanta, Kanika Kole, Gautam Gangopadhyay, Subhra Jana
MnO2 flowery nanocomposites were explored as a novel and cost effective nanoadsorbent for the fast and efficient extraction of toxic inorganic contaminants from aqueous solution.
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Three diphosphates, α-Li2Na2P2O7, Li8Pb3Ba(P2O7)4 and Li7Rb(P2O7)2: influences of co-substitution on the crystal structure

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01070G, Paper
Ming Wen, Cong Hu, Hongping Wu, Zhihua Yang, Xiaohong Wu, Shilie Pan
We reported the synthesis, structure, characterization and first-principles calculations of diphosphates, α-Li2Na2P2O7, Li8Pb3Ba(P2O7)4 and Li7Rb(P2O7)2, and studied the influences of co-substitution on the crystal structure.
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Influence of magnetic dilution on relaxation processes in a solid solution comprising tetrahedral Co/ZnII complexes

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01058H, Paper
Magdalena Ceglarska, Olaf Stefańczyk, Shin-ichi Ohkoshi, Anna M. Majcher-Fitas
Dilution with diamagnetic species in a SIM solid solution leads to an increase in relaxation times at low temperatures and monotonously reduces the probability of quantum tunneling of magnetization and the direct process.
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Dehydrogenation of amines in aryl-amine functionalized pincer-like nitrogen-donor redox non-innocent ligands via ligand reduction on a Ni(II) template

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00466A, Paper
Manas Khatua, Bappaditya Goswami, Subhas Samanta
A Ni(II)-template directed dehydrogenative imine formation reaction via ligand reduction leading to the formation of new pincer-like azo imine ligands is described.
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Recent advances in coordination-driven polymeric gel materials: design and applications

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00863J, Frontier
Papri Sutar, Tapas Kumar Maji
In this article, we reviewed recent advances in coordination-driven polymeric gels and highlighted their design and applications in various fields.
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Amorphous Ni–Fe–Se hollow nanospheres electrodeposited on nickel foam as a highly active and bifunctional catalyst for alkaline water splitting

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/C9DT04755G, Paper
Xuerui Yi, Xiaobo He, Fengxiang Yin, Biaohua Chen, Guoru Li, Huaqiang Yin
The electrodeposition of amorphous Ni–Fe–Se hollow nanospheres as a highly efficient bifunctional catalyst for the sustainable production of hydrogen.
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Metal–metal bond formation of triplatinum cores with a silver(I) ion affording a heptanuclear cluster bearing four Pt–Ag bonds

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01227K, Communication
Natsuki Yabune, Hiroshi Nakajima, Takanori Nishioka
A triplatinum complex with chelating NHC ligands reacts with Ag(I) and affords a heptanuclear cluster bearing four Ag–Pt bonds.
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Selenotungstates incorporating organophosphonate ligands and metal ions: synthesis, characterization, magnetism and catalytic efficiency in Knoevenagel condensation reaction

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00444H, Paper
Jingyang Niu, Hui Kong, Peipei He, Zongfei Yang, Qiaofei Xu, Jiawei Wang, Ran Ban, Pengtao Ma, Jingping Wang
Three sandwich-type TM-containing (TM = transition metal) organophosphonate-based polyoxotungstate clusters, [TM(H2O)4(SeW6O21)2{Co(OOCCH2NCH2PO3)2}3]12– (TM = Co, Ni), have been successfully synthesized, which is the first reported TMs-containing organophosphonate-based selenotungstates. They were structurally...
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Luminescent lanthanide complexes with a pyridine-bis(carboxamide)-bithiophene sensitizer showing wavelength-dependent singlet oxygen generation

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01034K, Paper
Katherine R. Johnson, Sebastian B. Vittardi, Manuel A. Gracia-Nava, Jeffrey J. Rack, Ana de Bettencourt-Dias
A new pyridine-bis(carboxamide)-based ligand with a bithiophene pendant, 2Tcbx, was synthesized.
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Amorphous Co-doped MoSex Effectively Enhances Photocatalysis in Visible Light

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01295E, Paper
Rui Feng, Rong Wu, Yuncheng Cao, Xiaolin Guo, Xu Ma
Molybdenum selenide has great potential for degradation of water pollutants，but its performance is limited by the active sites and recombination of photogenerated electron-hole pairs. In this study, amorphous Co-doped MoSex...
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Amide and ester derivatives of chlorido[4-carboxy-1,2-disalicylideneaminobenzene]iron(III) as necroptosis and ferroptosis inducers

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00168F, Paper
Daniel Baecker, Benjamin N. Ma, Jessica Sagasser, Lukas Schultz, Carina Hörschläger, Maria Weinreich, Lucy Steiner, Brigitte Kircher, Ronald Gust
Amide and ester derivatives of chlorido[4-carboxy-1,2-disalicylideneaminobenzene]iron(III) were synthesized and characterized as necroptosis and ferroptosis inducers using the acute myeloid leukemia cell line HL-60.
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Reactive metallocene cations as sensitive indicators of gas-phase oxygen and water

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00798F, Paper
Anuj Joshi, Sofia Donnecke, Ori Granot, Dongju Shin, Scott Collins, Irina Paci, J. Scott McIndoe
Gas-phase oxidation of air-sensitive organometallic compounds does not proceed to a significant extent in mass spectrometric analysis unless a vacant coordination site is generated, making nitrogen generators a suitable source of desolvation gas.
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Heat-resistant Pb(II)-based X-ray scintillating metal-organic frameworks for sensitive dosage detection via the aggregation-induced luminescent chromophore

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00974A, Communication
Jian Lu, Shuai-Hua Wang, Yan Li, Wen-Fei Wang, Cai Sun, Pei-Xin Li, Fa-Kun Zheng, Guo-Cong Guo
The synergy of unusual X-aggregation induced luminescent chromophores and heavy Pb(II) ions has facilitated excellent X-ray scintillation of two structurally similar Pb-SMOFs, which are heat-resistant due to solvent-free lattices. Owing...
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High Pressure and Elastic properties of a Guanidinium -formate Hybrid Perovskite

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/C9DT04805G, Paper
Hong-Qiang Gao, Chao Li, Lin-Sui Li, Wen-Juan Wei, Yu-hui Tan, Yun Zhi Tang
The high pressure and elastic properties in a hybrid ABX3-type perovskite, [C(NH2)3][Cd(HCOO)3] (CdGF), based on the A-site guest molecular is revealed via combining the high-pressure synchrotron X-ray diffraction experiments with...
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Spin-frustration with two quasi-degenerated spin states of a copper(II) heptanuclear complex obtained from an amino acid ligand

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/C9DT04501E, Paper
Catiúcia Rodrigues Marcelino Oliveira Matos, Henrique Silva Jr, Dayenny D’Amato, Guilherme Guedes, Glaucio Braga Ferreira, Odivaldo Cambraia Alves, Filipe Barra de Almeida, Sergio Pinheiro, Acácio Souza, Flavio Garcia, Célia Machado Ronconi
The Cu(II) heptanuclear complex (Cu7atac) was synthesised using the hydrated amino acid ligand 2-(5-amino-1H-1,2,4-triazol-3-yl)acetic acid (Hatac.H2O). Single crystal X-ray diffraction analysis revealed a μ3-hydroxo bridged Cu(II) heptanuclear complex, consisting of...
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Photophysical, photodynamical, redox properties and BSA-interactions of novel isomeric tetra-cationic peripheral palladium(II)-bipyridyl porphyrins

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01063D, Paper
Fabiano S Santos, Carolina H. da Silveira, Fabio Souza Nunes, Daniele Ferreira, Henrique Victória, Klaus Krambrock, Otávio Augusto Chaves, Fabiano Severo Rodembusch, Bernardo Almeida Iglesias
New isomeric tetra-cationic porphyrins containing peripheral [Pd(bpy)Cl]+ units attached at pyridyl substituents were synthetized and fully characterized. The porphyrins present an intense Soret band located in the blue spectral region...
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Impacts of hydrogen bonding interactions with Np(V/VI)O2Cl4 complexes: vibrational spectroscopy, redox behavior, and computational analysis

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00848F, Paper
Mikaela M. Pyrch, Jennifer L. Bjorklund, James M. Williams, Daniel L. Parr IV, Sara E. Mason, Johna Leddy, Tori Z. Forbes
Crystallization of neptunyl(V) tetrachlorides over neptunyl(VI) species occurs simultaneously with charge assisted hydrogen bonding in our solid state materials, which we explored by DFT calculations, cyclic voltammograms, and Raman spectroscopy.
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The differential magnetic relaxation behaviours of slightly distorted triangular dodecahedral dysprosium analogues in a type of cyano-bridged 3d–4f zig-zag chain compounds

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00990C, Paper
An-Qi Xue, Yang-Yu Liu, Jia-Xin Li, Yan Zhang, Yin-Shan Meng, Wen-Hua Zhu, Yi-Quan Zhang, Hao-Ling Sun, Fei Wang, Guan-Xia Qiu, Lu-Yu Liang, Xiang Wang, Song Gao
Differential magnetic properties were observed for triangular dodecahedral dysprosium analogues in a type of cyano-bridged 3d–4f zig-zag chain compound.
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A Review: Recent Advances in Preparations and Applications of Heteroatom-Doped Carbon Quantum Dots

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01004A, Perspective
Xiaoli Kou, Shicui Jiang, Soo-Jin Park, Long-Yue Meng
Carbon quantum dots (CQDs) are widely used in optoelectronic catalysis, biological imaging, and ion probes owing to their low toxicity, stable photoluminescence, and ease of chemical modification. However, the low...
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Highly cytotoxic gold(I)-phosphane dithiocarbamate complexes trigger an ER stress-dependent immune response in ovarian cancer cells

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01411G, Paper
Hai Van Le, Maria Babak, Muhammad Ali Ehsan, Mohammad Altaf , Lisa Reichert, Artem Gushchin, Wee Han Ang, Anvarhusein Isab
Ovarian cancer is a highly aggressive disease which is treated by surgery and platinum chemotherapy. However, a significant proportion of treated patients develop resistance to platinum treatment resulting in tumor...
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Platinum Complexes of a Boron-Rich Diphosphine Ligand

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00963F, Paper
Marcus W. Drover, Eric G Bowes, Maeve C Dufour, Lindsay Lesperance-Nantau
Herein, we describe the preparation, characterization, and reactivity of two PtIIbis-hydrocarbyl complexes containing the 1,2-bis(di(3-dicyclohexylboraneyl)propylphosphino)ethane (P2BCy4) ligand. These scaffolds are readily accessed from four-fold hydroboration of 1,2-bis(diallylphosphino)ethane PtII precursors....
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Dual-fixations of europium cation and TEMPO species on metal-organic frameworks for aerobic oxidation of alcohols

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01324B, Paper
Seongwoo Kim, Jooyeon Lee, Sungeun Jeoung, Hoi Ri Moon, Min Kim
The efficient and selective aerobic oxidation of alcohols has been investigated with judicious combinations of europium-incorporated and/or TEMPO ((2,2,6,6-tetramethylpiperidin-1-yl)oxyl)-functionalized zirconium-based porous metal-organic frameworks (MOFs). Although MOFs are well-known catalytic platform...
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Sequenced cooking that really works

By www.berkshirepublishing.com
Published On :: Wed, 25 Sep 2019 20:55:55 +0000

I went to a talk by a cookbook author who said she’d figured out a system for efficient home cooking: big pots of beans and soup, dishes that could be frozen and reheated. The concepts would have been obvious to any old-fashioned cook, and they are good, practical concepts. But her specific advice was so

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What is a “third place,” and do you have one?

By www.berkshirepublishing.com
Published On :: Fri, 01 Nov 2019 11:05:34 +0000

The term “happy place” is not in the Oxford English Dictionary (though “happy slap” is), but I’ve been hearing the term a lot. There’s even a new shop in Great Barrington called HappyPlace Berkshires. I first dismissed it as therapeutic slang, but discovered that the concept actually goes back to the Greeks: a utopia is

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First Look at the T S Eliot – Emily Hale Letters (podcast)

By www.berkshirepublishing.com
Published On :: Wed, 15 Jan 2020 00:36:24 +0000

In what one scholar called “the literary event of the decade,” on 2 January 2020, Princeton University Library opened up more than 1,100 letters that the Nobel-Prize-winning poet T.S. Eliot wrote over the course of three decades to an American speech professor and amateur actress named Emily Hale. The day became even more

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Do exclusionary rules ensure a fair trial?: a comparative perspective on evidentiary rules / Sabine Gless, Thomas Richter, editors

By library.mit.edu
Published On :: Sun, 21 Jul 2019 09:24:23 EDT

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Our selfish tax laws: toward tax reform that mirrors our better selves / Anthony C. Infanti

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Dewey Library - KF6289.I49 2018


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The World Bank policy for projects on international waterways: an historical and legal analysis / Salman M.A. Salman

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

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Real estate finance in a nutshell / Vada Waters Lindsey, Associate Professor of Law, Marquette University Law School

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Rotch Library - KF695.Z9 L56 2018


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Many nations under many gods: public land management and American Indian sacred sites / Todd Allin Morman

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Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Rotch Library - KF5605.M67 2018


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Free speech in the digital age/ Edited By Susan J. Brison And Katharine Gelber

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Dewey Library - K3254.F73 2019


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Decarcerating America: from mass punishment to public health / edited by Ernest Drucker

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Dewey Library - KF9730.D43 2018


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Contempt: a memoir of the Clinton investigation / Ken Starr

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Dewey Library - KF5076.C57 S72 2018


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No property in man: slavery and antislavery at the nation's founding / Sean Wilentz

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Hayden Library - KF4545.S5 W59 2018


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Networked press freedom: creating infrastructures for a public right to hear / Mike Ananny

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Dewey Library - K3255.A958 2018


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Separate: the story of Plessy v. Ferguson, and America's journey from slavery to segregation / Steve Luxenberg

By library.mit.edu
Published On :: Sun, 4 Aug 2019 10:22:43 EDT

Hayden Library - KF223.P56 L88 2019


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Gender quotas in South America's big three: national and subnational impacts / Adriana Piatti-Crocker, Gregory D. Schmidt, and Clara Araujo

By library.mit.edu
Published On :: Sun, 4 Aug 2019 10:22:43 EDT

Dewey Library - KH136.W64 P53 2017


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Winning together: the natural resource negotiation playbook / Bruno Verdini Trejo

By library.mit.edu
Published On :: Sun, 4 Aug 2019 10:22:43 EDT

Dewey Library - KZ6047.V47 2017


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Strategic indeterminacy in the law / David Lanius

By library.mit.edu
Published On :: Sun, 4 Aug 2019 10:22:43 EDT

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Authors, users, and pirates: copyright law and subjectivity / James Meese

By library.mit.edu
Published On :: Sun, 4 Aug 2019 10:22:43 EDT

Dewey Library - K1420.5.M44 2018


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Armed conflict and forcible displacement: individual rights under international law / edited by Elena Katselli Proukaki

By library.mit.edu
Published On :: Sun, 4 Aug 2019 10:22:43 EDT

Dewey Library - KZ6530.A75 2018


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Punishing atrocities through a fair trial: international criminal law from Nuremberg to the age of global terrorism / Jonathan Hafetz

By library.mit.edu
Published On :: Sun, 11 Aug 2019 10:25:18 EDT

Dewey Library - KZ7050.H34 2018


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From slaves to prisoners of war: the Ottoman Empire, Russia, and international law / Will Smiley

By library.mit.edu
Published On :: Sun, 11 Aug 2019 10:25:18 EDT

Dewey Library - KZ6495.S63 2018


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Regulatory counter-terrorism: a critical appraisal of proactive global governance / Nathanael Tilahun Ali

By library.mit.edu
Published On :: Sun, 11 Aug 2019 10:25:18 EDT

Dewey Library - KZ7220.A9565 2018


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