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Unsaturated coordination modulation and enlarged pore size in nanoflower-like metal organic frameworks for enhanced lithium–oxygen battery performance

J. Mater. Chem. A, 2024, 12,30591-30600
DOI: 10.1039/D4TA06346E, Paper
Lingwen Zhao, Juanjuan Feng, Adeel Abbas, Hao Sun, Chunlei Wang, Hongchao Wang
Unsaturated coordination modulation alters the discharge path and increased pore size accelerates ion exchange and oxygen transport, synergistically improving the electrochemical performance of LOBs.
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Multifunctional characteristics of a one-dimensional bimetallic oxyhydroxide nanorod-coupled polyaniline interface for accelerated water and urea electrolysis

J. Mater. Chem. A, 2024, 12,30743-30756
DOI: 10.1039/D4TA05082G, Paper
Niranjanmurthi Lingappan, Sandhiya Lakshmanan, Wonoh Lee
Designing an efficient and durable electrocatalyst is central to hydrogen production technologies such as hydrogen evolution reaction, oxygen evolution reaction, and urea oxidation reaction.
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Recyclable microcellular rubber foams with superior photothermal performance via constructing Fe3+ heterodentate coordination between epoxidized natural rubber and polyaniline

J. Mater. Chem. A, 2024, 12,30486-30497
DOI: 10.1039/D4TA06543C, Paper
Jingyi Zhu, Yukun Chen, Patrick C. Lee, Shuidong Zhang
Developing recyclable microcellular rubber foams with excellent photothermal conversion ability can reduce resource waste and harvest solar energy to alleviate environmental pollution and the energy crisis simultaneously.
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Synthesis of a Cu@ZnO1−x/Al2O3 catalyst with high-density ZnO1−x–Cu interfacial sites for enhanced CO2 hydrogenation to methanol

J. Mater. Chem. A, 2024, 12,30692-30706
DOI: 10.1039/D4TA05801A, Paper
Yunshuo Wu, Haiqiang Wang, Zhongbiao Wu
The development of catalysts with high-density interfacial sites is crucial for enhancing catalytic performance.
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Lewis acid sites and flexible active centers synergistically boost efficient electrochemical ammonia synthesis

J. Mater. Chem. A, 2024, 12,30476-30485
DOI: 10.1039/D4TA04884A, Paper
Li-Bo Chen, Tong-Hui Wang, Xing-You Lang, Qing Jiang
The Lewis acid sites enhance N2 adsorption and activation, while the flexible active center facilitates hydrogenation and NH4+ formation, regenerating the catalyst.
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Sulfur-doped g-C3N4/V2C MXene Schottky junctions for superior photocatalytic H2 evolution

J. Mater. Chem. A, 2024, 12,30429-30441
DOI: 10.1039/D4TA05929H, Paper
Haitao Wang, Jipeng Fan, Jing Zou, Yujie Zheng, Dingsheng Wang, Jizhou Jiang
An advanced sulfur-doped g-C3N4/V2C MXene (SCN/V2C) Schottky junction HER photocatalyst was prepared via vacuum ball milling and subsequent annealing.
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Exploring reaction mechanisms for CO2 reduction on carbides

J. Mater. Chem. A, 2024, 12,30340-30350
DOI: 10.1039/D4TA05592F, Paper
Naveed Ashraf, Atef Iqbal, Younes Abghoui
The electrocatalytic conversion of carbon dioxide (CO2) into valuable fuels offers immense promise in pursuing sustainable energy solutions.
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Sodium storage performance of a high entropy sulfide anode with reduced volume expansion

J. Mater. Chem. A, 2024, 12,30629-30641
DOI: 10.1039/D4TA05122J, Paper
Jianping Ma, Jinyi Guo, Weizheng Li, Xiaohan Yang, Chengde Huang
The introduction of a high-entropy structure into multi-metal sulfides has successfully mitigated volume expansion during the cycling process of sodium-ion batteries!
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Controlling CO2 flux in a CO2-permeable membrane with a H2O driving force

J. Mater. Chem. A, 2024, 12,30821-30830
DOI: 10.1039/D4TA05021E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jacqueline A. Penn, Wenting Hu, Ian S. Metcalfe, Greg A. Mutch
A H2O driving force in the opposite direction to CO2 permeation exerts control over CO2 flux in a molten-salt membrane fabricated using hydroxides.
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Dual solar-driven hydrogen evolution and alcohol oxidation with CdS quantum dot-sensitized photocatalysts prepared by the SILAR methodology

J. Mater. Chem. A, 2024, 12,30885-30891
DOI: 10.1039/D4TA03559C, Paper
Vasilis Nikolaou, Deborah Romito, Clément Maheu, Jonathan Hamon, Eric Gautron, Florian Massuyeau, Pierre-Emmanuel Petit, Stéphane Jobic, Fabrice Odobel
The first use of the successive ionic layer adsorption and reaction (SILAR) method to grow CdS quantum dots on TiO2 nanoparticles, achieving efficient photocatalytic alcohol oxidation and H2 evolution without catalysts or sacrificial donors.
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Design and construction of porphyrin box-based metal–organic frameworks with hierarchical superstructures for efficient energy transfer and photooxidation

J. Mater. Chem. A, 2024, 12,30685-30691
DOI: 10.1039/D4TA05576D, Paper
Qian Xu, Peng Zhang, Yuanyuan Sun, Jishi Chen, Chuantao Hou, Zonghua Wang
A porphyrin box-based MOF with hierarchical superstructures was synthesized, exhibiting enhanced performance in singlet oxygen-mediated photooxidation.
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A sustainable redox-mediated pathway for improved transition metal organic framework activation and CO2 uptake performance

J. Mater. Chem. A, 2024, 12,30454-30464
DOI: 10.1039/D4TA02526A, Paper
Taylor Jade Self, Jiabin Niu, Wen Liu, Chaobin He, Mei Chee Tan
Sustainable substitutions in MOF fabrication and processing can confidently be made by employing redox engineering for synergistic valency and defect constitution, based on application, without sacrificing active site functionality.
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Tailoring the electrocatalytic properties of novel microwave synthesized CuNd(2−x)GdxO4 nanoparticles for efficient total water splitting in alkaline media

J. Mater. Chem. A, 2024, 12,30850-30861
DOI: 10.1039/D4TA05919K, Paper
Anto Priyanka E, Sreenivasan Nagappan, J. Judith Vijaya, Angappan Sankaramahalingam, Subrata Kundu
CuNd(2−x)GdxO4 nanoparticles synthesized via microwave method as efficient OER and HER catalysts require low overpotentials exhibiting remarkable stability. Gd doping enhances charge transfer leading to optimized electrocatalysis.
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Interfacial charge transfer modulation in laser-synthesized catalysts for efficient oxygen evolution

J. Mater. Chem. A, 2024, 12,30269-30278
DOI: 10.1039/D4TA06794K, Paper
Dong Hyeon Lee, Rahul Kerkar, Deepak Arumugam, Jayaraman Theerthagiri, Shankar Ramasamy, Soorathep Kheawhom, Myong Yong Choi
This study introduces a NiFe LDH-based catalyst via pulsed laser irradiation in liquids and microwave methods, achieving superior oxygen evolution performance. In situ electrode casting optimizes the catalyst for water-splitting applications.
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Ultrahigh energy storage in multilayer BiFeO3–BaTiO3–NaTaO3 relaxor ferroelectric ceramics

J. Mater. Chem. A, 2024, 12,30642-30654
DOI: 10.1039/D4TA04324C, Paper
Rhys Montecillo, R. R. Chien, Cheng-Sao Chen, Po-Hsien Wu, Chi-Shun Tu, Kuei-Chih Feng
The rising challenge of high-density electric energy storage has accelerated the research of electric energy-storage capacitors due to their high power density and voltage resistance, excellent temperature stability, and environmental friendliness.
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Smart fabrics with liquid metal reinforced PU/CNT/MXene multilayer structures for constructing multifunctional sensors and wearable electronics

J. Mater. Chem. A, 2024, 12,30872-30884
DOI: 10.1039/D4TA05266H, Paper
Haijiao Lin, Hui Wang, Yongguang Yang, Yuxuan Zhang, Ling Li, Youwei Zhao, Wenming Zhang
Smart fabrics with liquid metal reinforced PU/CNT/MXene multilayer structures for constructing multifunctional sensors and wearable electronics.
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Achieving the selectivity of the oxygen reduction reaction by regulating electron spin states and active centers on Fe–Mn–N6–C dual-atom catalysts

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06650B, Paper
Shiyao Li, Honghao Chen, Yue Qiu, Chengxing Cui, Wenhui Zhong, Jun Jiang
As the first attempt to reveal the intrinsic relationship between electron spins and catalytic selectivity, this work offers new insights into the rational design of efficient transition metal atom-dispersed catalysts through spin regulation.
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Dually encapsulated LiMn0.6Fe0.4PO4 architecture with MXenes and amorphous carbon to achieve high-performance and ultra-stable lithium batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06323F, Paper
Yang Song, Haidong Zhong, Tingting Hu, Qizhi Chen, Lei Shi, Jun Du, Changyuan Tao, Qian Zhang
An LMFP@MXene@C cathode material was fabricated by electrostatic adsorption and in situ graphitization, providing optimized Li+ transmission and a stable structure featuring ultrahigh average capacity and cycle stability.
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A doubly interpenetrated perylene diimide-based zirconium metal–organic framework for selective oxidation of sulfides powered by blue light

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06294A, Paper
Chao Wei, Ming Lu, Jing-Jing Li, Ze-Jiu Diao, Guoliang Liu, Xiao-Qin Liu, Lin-Bing Sun
A doubly interpenetrated perylene diimide-based zirconium metal–organic framework is developed as a heterogeneous photocatalyst for selective photocatalytic oxidation of organic sulfides powered by blue light.
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Oxygen-defective ruthenium oxide as an efficient and durable electrocatalyst for acidic oxygen evolution reaction

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06592A, Paper
Jingwei Wang, Lejuan Cai, Zhipeng Yu, Hao Tan, Xinyi Xiang, Kaiyang Xu, Yang Chao, Sitaramanjaneya Mouli Thalluri, Fei Lin, Haoliang Huang, Chenyue Zhang, Yang Zhao, Wenlong Wang, Lifeng Liu
Proton exchange membrane water electrolysis (PEMWE) is considered a promising technology for green hydrogen production in combination with renewable energy. However, the high cost and particularly the scarcity of iridium...
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Enhanced oxygen exchange kinetics and long-term stability of Ruddlesden-Popper phase Pr4Ni3O10+δ cathode for solid oxide fuel cells

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01845A, Paper
Saim Saher, Affaq Qamar, Chou Yong Tan, Singh Ramesh, Walied Alfraidi
This research explores the intricacies of oxygen exchange kinetics in Pr4Ni3O10+δ (PNO), aiming to assess its potential as a viable cathode material for solid oxide fuel cell applications. Utilizing a...
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Scalable Synthesis of N–Doped Graphene–Oxide–Supported FeCo(OH)x Nanosheets for Efficient Co–Doped Fe3O4 Nanoparticle-Based Oxygen Reduction Reaction Electrocatalysis

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06684G, Paper
Open Access
Sunglun Kwon, Jong Hyeon Lee
Developing efficient and cost-effective materials is crucial for advancing electrochemical oxygen reduction reaction (ORR). This study presents a synthesis route for high-performance spinel Fe and Co oxide nanoparticles on N-doped...
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A π–d conjugated metal–organic framework decorated on a MXene-carbon nanofiber as a self-standing electrode for flexible supercapacitors

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06232A, Paper
Zahir Abbas, Shaikh M. Mobin
A c-MOF is grown on MX-CNF, which was prepared via electrospining method. Furthermore, it utilized for flexible supercapcitors with different flexibility angles.
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Regulating oxygen redox reactions in lithium-rich materials via an Al2O3-doped ZnO layer for enhanced stability and performance

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06843B, Paper
Xinyu Cheng, Yuke Wang, Jia Lu, Wangqi Dai, Huanhao Lei, Jinning Zuo, Hong Li, Zhengwen Fu
An ultrathin Al2O3-doped ZnO (AZO) layer on LRM regulates oxygen redox by suppressing anion migration and inhibiting surface oxygen oxidation, enhancing cycling performance.
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Retraction: Thermally reduced graphene oxide/polymelamine formaldehyde nanocomposite as a high specific capacitance electrochemical supercapacitor electrode

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA90211D, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ali A. Ensafi, Hossein A. Alinajafi, B. Rezaei
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Advancing Paper-Based Sensors with MXenes and MOFs: Exploring the Cutting-Edge Innovations

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06561A, Review Article
Sepehr Larijani, Atefeh Zarepour, Arezoo Khosravi, Siavash Iravani, Mahnaz Eskandari, Ali Zarrabi
MXenes and metal-organic frameworks (MOFs) are emerging as promising materials for integration into paper-based sensors (PSs), offering unique properties that can enhance sensor performance in various applications. MXenes, with their...
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Electrochemical PET recycling to formate through ethylene glycol oxidation on Ni-Co-S nanosheet arrays

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA07156E, Paper
Yi Ma, Luming Li, Jialing Tang, Zongkun Hu, Yong Zhang, Ning Jian, Huan Ge, Jun Zhao, Andreu Cabot, Junshan Li
Plastics have become an integral part of modern society due to their excellent mechanical properties, lightweight, chemical stability and low cost. However, their continuous production and use worldwide have resulted...
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Long-lasting, flexible and fully bioresorbable AZ31–tungsten batteries for transient, biodegradable electronics

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06222A, Paper
Open Access
Gwan-Jin Ko, Tae-Min Jang, Daiha Shin, Heeseok Kang, Seung Min Yang, Sungkeun Han, Rajaram Kaveti, Chan-Hwi Eom, So Jeong Choi, Won Bae Han, Woon-Hong Yeo, Amay J. Bandodkar, Jiung Cho, Suk-Won Hwang
An eco-friendly, fully biodegradable magnesium alloy (AZ31)–tungsten (W) battery exhibits enhanced stability and corrosion resistance. The integration of alginate-based elastic electrolytes demonstrates a fully biodegradable solid-state battery.
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Flexible multifunctional MXene@Ag nanowires/cotton fabric inspired by transport of nutrients by roots for electromagnetic shielding, infrared stealth, Joule/solar heating and flame retardancy

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06712F, Paper
Jiatong Yan, Meimei Chen, Rui Tan, Chuanxi Lin, Shan Jiang, Weijie Wang, Songyue Pan, Hongyan Xiao, Erhui Ren, Ronghui Guo
With the rapid development of 5G intelligent detection technology, electromagnetic shielding/infrared stealth fabrics with Joule/solar heating performance can meet the needs of wearable electronic devices for multi-application scenarios.
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Monte Carlo simulations on temperature-dependent microstructure evolution of relaxor ferroelectric polymers

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06242F, Paper
Tong Guan, Quan-Ao He, Shuang Chen
Poly(vinylidene fluoride-trifluoroethylene) [P(VDF-TrFE)] relaxor ferroelectrics have drawn a lot of attention nowadays due to their excellent multifunctionality and extensive applications. However, the microstructures behind their relaxor behaviors have not been...
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High-throughput Screening of Mechanically Interlocked Catenane Metal Complexes for Enhanced Electrocatalytic Activity

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06497F, Paper
Mohsen Tamtaji, William A. Goddard III, Guanhua Chen
Metal complexes have been thoroughly investigated for a wide range of electrochemical reactions. However, mechanically interlocked molecular machines (MIM) have not been investigated for electrochemistry through a systematic high throughput...
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Ternary NiFeCo-Glycerolate Catalysts: Rational Design for Improved Oxygen Evolution Reaction Efficiency

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06455K, Paper
Irlan Santos Lima, Josué M. Gonçalves, Lúcio Angnes
Catalysts capable of overcoming the bottleneck of water splitting, known as the oxygen evolution reaction (OER), are indispensable to the expansion of renewable energy systems. Thus, we report the synthesis...
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Brock Purdy is over the arm fatigue he experienced last season after surgery

49ers quarterback Brock Purdy underwent surgery to repair a torn ulnar collateral ligament in his right elbow during the 2023 offseason.




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Dolphins claim ex-Seahawks LB Tyrel Dodson after surprising release in Seattle

The Seahawks released Tyrel Dodson, their leading tackler this season, on Monday.




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Joe Mixon primed for a huge game vs. Cowboys

Yahoo fantasy analyst Andy Behrens explains why fantasy managers should roll with the Houston RB in Week 11.




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With Jordan Mailata expected back, Eagles release Jack Driscoll

In a sign that Jordan Mailata is likely ready to return to action, the Eagles on Tuesday released veteran backup offensive lineman Jack Driscoll.




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With Jordan Mailata expected back, Eagles release Jack Stoll

The Eagles on Tuesday released veteran tight end Jack Stoll, presumably to create a spot on the 53-man roster for Jordan Mailata.




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Niners CB Deommodore Lenoir agrees to five-year, $92 million extension, per report

One of the NFL's best slot cornerbacks got paid.




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Report: 49ers, CB Deommodore Lenoir agree to five-year, $92 million extension

Lenoir is in the final year of his rookie deal and was scheduled to become a free agent in March.




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Report: Lenoir, 49ers agree to five-year, $92M contract extension

Cornerback Deommodore Lenoir and the San Francisco 49ers reportedly have agreed to a five-year contract extension worth $92 million.




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Why timing worked for Lenoir, 49ers to get extension done now

Matt Maiocco explains why the timing was perfect for 49ers cornerback Deommodore Lenoir and San Francisco to finalize a contract extension now.




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Source: Lenoir, 49ers agree to five-year contract extension

Cornerback Deommodore Lenoir and the San Francisco 49ers have agreed to a five-year contract extension, a source told NBC Sports Bay Area's Matt Maiocco.




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Berlin launches official bid campaign to host an NFL game the next five seasons

NFL Commissioner Roger Goodell all but said this week that the league will play a game in Berlin next season.




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Players Review Box24 Casino Play Games Online

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Peculiarities Of Choosing a Extreme Casino

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