ter Synergy of prediction rule and total synthesis in solving the stereochemical puzzle of eucalactam B By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01777C, Research ArticleChenqi Wang, Junyang Liu, Tao YeThe absolute configurations of the fungal-derived reduced polyketide eucalactam B were initially predicted using the “Biochemistry-based rule” and later confirmed through its first successful total synthesis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter I2-Promoted oxidative annulation of three different amines to access diverse biheteroaryls By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01801J, Research ArticleGuangping Fan, Penghui Cao, Fang Bai, Yanyan Yin, Xueyan Hou, Yani Liu, Zhenzhen Xing, Yanhui Wang, Tangqiang Sun, Qinghe GaoAn I2-promoted oxidative annulation of three different amines enables the assembly of nonsymmetrical 2,2'-biquinolines and related bis-azines through a [4π + 2σ] annulation reaction.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Facile one-pot synthesis of novel imidates as multifunctional organic fluorescent materials By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01628A, Research ArticleFeng-Ting Liu, Shuo Wang, Yong-Shun Chen, Jun-Ying Miao, Bao-Xiang Zhao, Zhao-Min LinA novel one-pot synthesis of multifunctional organic fluorescent imidates from quinolinium salt derivatives, nitrosoarenes and alcohols was presented. This method had a wide substrate scope and excellent isolated yields.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter General ppm-level Pd-catalysed asymmetric diarylalkyne hydrosilylation to access structurally diverse Si-stereogenic vinylsilanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01698J, Research ArticleHeng Xu, Han-Xiao Yu, An-Jiu Wen, Fang-Ying Ling, Fei Ye, Li Li, Fuk Yee Kwong, Li-Wen XuThe first example of enantioselective Pd-catalyzed hydrosilylation of symmetric and asymmetric diarylalkynes to access novel Si-stereogenic vinylsilanes with excellent ee and a high TON is realized under mild reaction conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Stereoselective access to furan-fused [5.5.0] bicyclic heterocycles enabled by gold-catalyzed asymmetric [8 + 4] cycloaddition By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01841A, Research ArticleXunhua Wang, Jianhua Wang, Xiaoxun LiA gold-catalyzed asymmetric [8 + 4] cycloaddition was developed to afford highly functionalized furan/pyrrole-fused [5.5.0] polycyclic heterocycles with good diastereo- and enantioselectivity.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Total synthesis of spiro Ganoderma meroterpenoids spiroapplanatumines B, D, F, and H By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6333-6339DOI: 10.1039/D4QO01147C, Research ArticleJia-Hao Zhang, Wen-Cai Luo, Wen-Tao Chen, Yu-Tao He, Ya-Jian HuThe first total synthesis of spiroapplanatumines B, D, F, and H as well as the possibly undiscovered natural product spiroapplanatumine R has been achieved.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Iridium/palladium dual photocatalysis for oxidative decarboxylative esterification of alcohols using α-keto acids By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6367-6379DOI: 10.1039/D4QO01452A, Research ArticleSubal Mondal, Soumya Mondal, Debabrata Halder, Siba P. Midya, Ankan Paul, Pradyut GhoshHerein, we report an unprecedented oxidative decarboxylative C–O cross-coupling reaction for the esterification of feedstock α-keto carboxylic acids and alcohols under mild conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Structure determination of difficult-to-crystallize organic molecules by co-crystallization of a phosphorylated macrocycle By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6358-6366DOI: 10.1039/D4QO01498G, Research ArticleHeng Li, Zhijin Li, Juli Jiang, Chen Lin, Leyong WangThis work reported that 37 different difficult-to-crystallize guest molecules were co-crystallized with the host macrocycle F[3]A1-[P(O)Ph]3 at room temperature, and the molecular structures of the guests could be determined by SCXRD.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Theoretical insights into Pd-catalyzed dual γ-1,1-C(sp3)–H activation of aliphatic carboxylic acids: mechanistic pathways, substituent influence on product selectivity, diastereoselectivity, and additive effects By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6393-6410DOI: 10.1039/D4QO01451K, Research ArticleJiaoyang Liu, Li-juan Huang, Zeang Sun, Juan LiDFT calculations were employed to explore the detailed reaction mechanism and the origins of the experimentally observed product, regio-, and diastereoselectivities in the Pd-catalyzed dual-γ-1,1-C(sp3)–H activation of aliphatic carboxylic acids.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Cobalt-catalyzed enantioselective reductive addition of ketimine with cyclopropyl chloride to construct chiral amino esters bearing cyclopropyl fragments By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6311-6318DOI: 10.1039/D4QO01474J, Research ArticleJiangtao Hu, Tingting Xia, Xianqing Wu, Hongrui Feng, Jingping Qu, Yifeng ChenCo-catalyzed asymmetric reductive addition of ketimine with cyclopropyl chloride has been realized to access diverse chiral amino esters bearing cyclopropyl fragments with broad functional group tolerance and excellent enantioselectivities.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Recent advances in asymmetric synthesis of chiral benzoheterocycles via Earth-abundant metal catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6534-6557DOI: 10.1039/D4QO01686F, Review ArticleJinhui Cai, Wenting Zhang, Usman Muhammad, Weishuang Li, Yanjun XieThis review mainly focus on the assembly of chiral benzoheterocycles, such as dihydrobenzofurans, chromans, indolines, tetrahydroquinolines, etc., via Earth-abundant metal-catalyzed (Cu, Fe, Ni, and Ti) asymmetric synthesis in the last few decades.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter LiTMP-LiBr complex-induced lateral lithiation and cross ester condensation: direct access to isocoumarins from 2-methoxy o-toluate esters By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01678E, Research Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Mintu Rehman, Sajib Daimary, Rasajna Madhusudhana, Rajendar GoretiLiTMP-LiBr complex promotes cross-ester coupling of 2-methoxy o-toluate esters to directly yield isocoumarin is demonstrated. Method applied to many natural product precursors including synthesis of (+)- and (−)-lunatinins.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Regio- and stereoselective azidation of activated N-allenamides: an entry to α, β, γ and δ-amido-azides By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01802H, Research ArticleDorian Schutz, Maxime Hourtoule, Laurence MieschA totally controlled regiodivergent azidation of activated N-allenamides is described, offering a broad range of diverse functionalized amido-azide derivatives.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Catalyst-free C–H methylation of heteroarenes enabled by electron donor–acceptor complex photoactivation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01309C, Research ArticleJiayang Wang, Baoer Shao, Haixia Ge, Huiyu Xue, Xiangyuan Ding, Yuqi Li, Peiyao ShengA visible-light-induced direct C–H methylation of heterocycles (including quinoxalinones, pyrazinones, quinolinones and coumarins) with methylamines via EDA complex photoactivation was developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter A Stereoselective Organocatalyzed C-Glycosylation of Indole: Implications of Acceptor-Catalyst-Donor Interaction By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01873G, Research ArticleLihuang Xie, Wenchao Liu, Zhenbo Guo, Qinbo Jiao, Xiaomin Shen, Tianfei Liu, Chunfa XuA stereoselective pyridinium hexafluorophosphate-catalyzed C-glycosylation of indole is presented, featuring the plausible formation of a catalyst-acceptor complex and a crucial H-bond between the indole N-H and the oxygen at C6...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Stereocontrolled synthesis of heterocycles from unactivated alkynes by photoredox/nickel dual-catalyzed cyclization By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01627K, Research ArticleBo-Rong Leng, Feng Yang, Jin-Lian Bai, Yu-Wen Huang, Qing-Quan Liu, Ping Wei, De-Cai Wang, Yi-Long ZhuWe report a nickel/photoredox dual catalysis method for synthesizing heterocyclics from unactivated alkynes and aryl iodides, offering a direct, selective, and green alternative to traditional synthesis with potential in medicinal chemistry.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Probing Intersystem Crossing in Multi-brominated Eumelanin through Transient Absorption and Surface Hopping Dynamics By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01832J, Research Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kavya Vinod, Lukhmanul Hakeem K., Diana Thomas, Pallavi Panthakkal Das, Mahesh HariharanAchieving intersystem crossing (ISC) through structural tuning in biological systems is an evolving area for therapeutic and materials research. Eumelanin, a natural pigment, offers huge potential for bio-inspired material design,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Rh-Catalysed Hydroacyloxylation of Cyclopropenes: Regio- and Diastereoselective Synthesis of Acyloxycyclopropanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01810A, Research ArticleÁngel Manu Martínez, Gema Domínguez, Ines Alonso, Marta Palaín, Javier Perez-CastellsCyclopropyl carboxylates are essential building blocks in biological and medicinal chemistry. However, their accessibility is severely limited by the need to pre-synthesise highly reactive cyclopropane derivatives. Herein, we report an...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Intermolecular Defluorinative 1,2-Diamination of Fluoroalkenyl Iodides with Sulfonamides: Synthesis of Acyclic and Cyclic Fluorinated 1,2-Enediamines By pubs.rsc.org Published On :: Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01913J, Research ArticleXue-Qiang Chu, Yu-Lan Chen, Chi Zhang, Xue-Ying Huang, Yu Ding, Danhua Ge, Zhi-Liang ShenAlkene diamination represents one of the most straightforward strategies for 1,2-diamine derivatives synthesis. However, transition-metal-free 1,2-diamination of fluoroalkenes has been less studied. Here we report an intermolecular defluorinative vicinal diamination...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Woman arrested after kidnap attempt in Koti Government Maternity Hospital By www.thehindu.com Published On :: Thu, 07 Nov 2024 18:41:29 +0530 The accused was a habitual offender and had made a vain bid on Tuesday night, before being caught by the hospital staff and police on Wednesday Full Article Telangana
ter Moneylenders push family to end life, man his daughter die, wife survives By www.thehindu.com Published On :: Thu, 07 Nov 2024 21:07:01 +0530 Head of the family was being harassed and intimidated by two Nizamabad-based moneylenders Full Article Telangana
ter Mother-daughter duo to showcase Andhra Natyam and Perini Tandavam in Hyderabad By www.thehindu.com Published On :: Fri, 08 Nov 2024 15:20:10 +0530 Duvvuri Vathsalendra redefines tradition by mastering Perini Thandavam and sharing its power on stage with her daughter Abhimanika Full Article Entertainment
ter Hyderabad man loses ₹1.73 lakh trying to get 0% interest loan on insurance policy worth ₹10 lakh By www.thehindu.com Published On :: Fri, 08 Nov 2024 18:29:42 +0530 Full Article Telangana
ter Home guard injured after engineering student attempts to flee vehicle checking in Panjagutta By www.thehindu.com Published On :: Fri, 08 Nov 2024 21:27:50 +0530 Full Article Telangana
ter HMWS&SB website taken down after reported hacking By www.thehindu.com Published On :: Sat, 09 Nov 2024 13:52:43 +0530 Hyderabad Water Board website down for maintenance after redirection to unauthorised sites, no impact on regular services Full Article Hyderabad
ter Varun Tej: ‘Matka’ entertains but does not glorify the gambler By www.thehindu.com Published On :: Sat, 09 Nov 2024 16:33:00 +0530 Actor Varun Tej discusses his new Telugu film ‘Matka’, a fictional tale inspired by Ratan Khatri, set in Visakhapatnam of the 1960s and 70s Full Article Movies
ter Man, friend killed in car-bus collision after attending sister’s wedding reception By www.thehindu.com Published On :: Sun, 10 Nov 2024 19:10:31 +0530 Full Article Telangana
ter Minister Ponnam Prabhakar urges caste associations to support ongoing comprehensive survey in Telangana By www.thehindu.com Published On :: Sun, 10 Nov 2024 23:47:20 +0530 Full Article Telangana
ter Nodal officers appointed for the caste survey in Greater Hyderabad By www.thehindu.com Published On :: Mon, 11 Nov 2024 20:44:47 +0530 Full Article Telangana
ter Telangana to repair 9,000 km of roads using advanced technology: Minister Komatireddy By www.thehindu.com Published On :: Tue, 12 Nov 2024 00:43:54 +0530 Full Article Telangana
ter Three schoolgirls in Telangana tribal school hospitalised after suspected food poisoning, one critical By www.thehindu.com Published On :: Tue, 12 Nov 2024 19:20:20 +0530 The girls, aged between 13 and 16, suffered acute gastroenteritis, dehydration, and kidney-related complications Full Article Telangana
ter Letters to the Editor dated June 24, 2024 By www.thehindubusinessline.com Published On :: Mon, 24 Jun 2024 21:22:29 +0530 Full Article Letters
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