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Transesterification or polymerization? Reaction mechanism and kinetics of 2-(diethylamino)ethyl methacrylate with methanol and the competitive effect on free-radical polymerization

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00406J, Paper
Judith Cabello-Romero, Román Torres-Lubián, Javier Francisco Enríquez-Medrano, Adrián Ochoa-Terán, Jesús Jara-Cortés, Iván Zapata-González
Transesterification of 2-(diethylamino)ethyl methacrylate (DEAEMA) with methanol leads to the formation of methyl methacrylate (MMA) and amino alcohol. This reaction significantly affects DEAEMA polymerization giving rise to poly(DEAEMA-co-MMA).
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Removal of gaseous Hg0 by Cl-loaded carbonaceous material prepared from rice husk

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00414K, Paper
Naoto Tsubouchi, Momone Yoshizawa, Javzandogole Bud, Yuuki Mochizuki
The main objective of this study was to investigate the removal of gaseous Hg0 from the residue obtained during the chlorination of rice husk char to recover silica.
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Sugar additive with a halogen group enabling a highly reversible and dendrite-free Zn anode

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00366G, Paper
Weihao Xu, Xipo Ma, Pengbo Lyu, Zhenren Gao, Chunshuang Yan, Chade Lv
Sucralose, a weakly polar sugar electrolyte additive containing halogen elements, enables a highly reversible and dendrite-free Zn anode.
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Ammonia Decomposition over Low-loading Ruthenium Catalyst Achieved through “Adiabatic” Plasma Reactor

React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00509K, Paper
Minhazur Rahman Shawon, Chinwendu Umeojiakor, Anthony Griffin, Jeffrey S. Aguinaga, Jiachun Wu, Derek Patton, Zhe Qiang, Hossein Toghiani, Yizhi Xiang
Electrified catalytic processes for ammonia (NH3) decomposition have been considered as essential technologies for distributed COx-free hydrogen production. Here we show that efficient NH3 decomposition can be achieved over low-loading...
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Preparation of modified humic acid/TiO2/P(AA-co-AM) nanocomposite hydrogels with enhanced dye adsorption and photocatalysis

Soft Matter, 2024, 20,2937-2954
DOI: 10.1039/D3SM01749D, Paper
Xuankun Gong, Amatjan Sawut, Rena Simayi, Ziyue Wang, Yurou Feng
A novel composite hydrogel with exceptional adsorption and photocatalytic properties was synthesized using modified coal-based humic acid (HA-C), modified titanium dioxide (TiO2) nanoparticles, acrylic acid (AA), and acrylamide (AM) as precursors.
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Self-adhesion of uncrosslinked poly(butadiene-co-acrylonitrile), i.e. nitrile rubber, an inhomogeneous and associative polymer

Soft Matter, 2024, 20,2978-2985
DOI: 10.1039/D3SM01630G, Paper
Valentine Hervio, Annie Brûlet, Costantino Creton, Gabriel E. Sanoja
The precursor of NBR, poly(acrylonitrile-co-butadiene), experiences thermodynamic forces for self-assembly and kinetic barriers for processing. We introduce three strategies to overcome such barriers and enable polymer self-adhesion in the bulk.
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Analysis of the adhesive secreting cells of Arion subfuscus: insights into the role of microgels in a tough, fast-setting hydrogel glue

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00071D, Paper
Andrew M. Smith, Patrick Flammang
A model for the rapid setting of a gastropod hydrogel adhesive. Cross-linked microgels mix with microscopic packets of polysaccharides; these flow onto surfaces until the packets rupture, joining the microgels together.
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Adsorption of semiflexible wormlike polymers to a bar and their double-chain complex formation

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00188E, Paper
Open Access
A. N. Semenov, I. A. Nyrkova
The quantitative transfer matrix approach and scaling arguments in terms of trains, loops, tails and supertrains allowed us to characterize the main regimes of semiflexible chain adsorption on a bar and double-chain complex formation.
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Hydrogen bonding enhanced drug–polymer interaction for efficient drug loading and delivery

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00003J, Communication
Xiaotian Qu, Junran Li, Yishu Yu, Jie Yang
A carrier design strategy of hydrogen bonding enhanced drug–carrier interaction is developed to prepare a polymeric nanomedicine with high drug loading content and superb loading efficiency as well as tunable nanostructures.
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Self-healing polyacrylates based on dynamic disulfide and quadruple hydrogen bonds

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00257A, Paper
Longjin Du, Yuting Zhong, Linying Zhao, Chengzhen Hu, Liang Shen, Yuping Yang, Jiang Zhong
Herein, a self-healing polyacrylate system was successfully prepared by introducing crosslinking agents containing disulfide bonds and monomers capable of forming quadruple hydrogen bonds through free radical copolymerization.
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Multiple physical crosslinked highly adhesive and conductive hydrogels for human motion and electrophysiological signal monitoring

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00195H, Paper
Qirui Wu, Anbang Chen, Yidan Xu, Songjiu Han, Jiayu Zhang, Yujia Chen, Jianren Hang, Xiaoxiang Yang, Lunhui Guan
Ionic conducting hydrogel (ICHgel) was synthesized by doping fumed SiO2, which exhibited superior stretchability, conductivity, and adhesiveness, making it a promising bridge for effective communication between electronic devices and human tissues.
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Bacteria–surface interactions: role of impacting bacteria-laden droplets

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00196F, Paper
Sudip Shyam, Sirshendu Misra, Surjyasish Mitra, Sushanta K. Mitra
Impact-induced transformation of bacteria from a viable to a dormant mode.
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Softness matters: effects of compression on the behavior of adsorbed microgels at interfaces

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00235K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yuri Gerelli, Fabrizio Camerin, Steffen Bochenek, Maximilian M. Schmidt, Armando Maestro, Walter Richtering, Emanuela Zaccarelli, Andrea Scotti
As lateral compression is applied, microgel particles with different softness exhibit distinct behaviours. Hard microgels (green particles) are pushed away from the air–water interface, whereas soft ones (orange particles) are less deformed.
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Lock-Key Microfluidics: Simulating Nematic Colloid Advection along Wavy-Walled Channels

Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D3SM01536J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Karolina Wamsler, Louise C Head, Tyler Nathan Shendruk
Liquid crystalline media mediate interactions between suspended particles and confining geometries, which not only has potential to guide patterning and bottom-up colloidal assembly, but can also control colloidal migration in...
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Angle-resolved optical spectroscopy of photonic cellulose nanocrystal films reveals the influence of additives on the mechanism of kinetic arrest

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00155A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Thomas G. Parton, Richard M. Parker, Sonja Osbild, Silvia Vignolini, Bruno Frka-Petesic
Photonic films produced by cellulose nanocrystal self-assembly offer a sustainable source of colouration. Their angular optical response reveals the suspension conditions at kinetic arrest and how common additives affect this liquid–solid transition.
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The sweetest polymer nanoparticles: opportunities ahead for glycogen in nanomedicine

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00261J, Perspective
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Quinn A. Besford
Glycogen is a biomaterial nanoparticle composed of sugar. In this perspective, the opportunities of glycogen in nanomedicine going forward is discussed.
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Switchable origami adhesives

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00082J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Wathsala M. A. Jayawardana, Theresa Elder, Timothy Twohig, Andrew B. Croll
Creating a reusable adhesive that can hold objects on a wall and can yet be easily removed without causing damage has been a goal for researchers in the adhesives community for many years.
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Flexible hydrogels connecting adhesion and wetting

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00022F, Paper
A-Reum Kim, Surjyasish Mitra, Sudip Shyam, Boxin Zhao, Sushanta K. Mitra
Soft, flexible hydrogels enable researchers to connect two discrete regimes: liquid wetting to contact adhesion in solids.
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Effect of equilibration time on the structural gradient in the vertical direction for bicontinuous microemulsions in Winsor-III and -IV systems

Soft Matter, 2024, Advance Article
DOI: 10.1039/D3SM01741A, Paper
Douglas G. Hayes, Brian A. Barth, Sai Venkatesh Pingali
Both equilibration time and the transfer of Winsor-III microemulsion systems from one container to another affect the structure of the bicontinuous phase in the vertical direction.
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Spontaneous oscillation of an active filament under viscosity gradients

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00095A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zhaorong Liu, Youchuang Chao, Zhijun Zheng, Lailai Zhu
We investigate the effects of uniform viscosity gradients on the spontaneous oscillations of an elastic, active filament in viscous fluids.
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Synthesis and characterization of TiO2/hydrochar matrix composites for enhanced ammonia degradation

RSC Adv., 2024, 14,12131-12141
DOI: 10.1039/D4RA00671B, Paper
Open Access
Ling Zhao, Jiaxing Sun, Shuang E., Kuichuan Sheng, Kaiying Wang, Ximing Zhang
Development of a one-pot method for synthesizing TiO2/hydrochar matrix composites.
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A prediction model for CO2/CO adsorption performance on binary alloys based on machine learning

RSC Adv., 2024, 14,12235-12246
DOI: 10.1039/D4RA00710G, Paper
Open Access
Xiaofeng Cao, Wenjia Luo, Huimin Liu
Machine-learning models were constructed to accurately predict CO2 and CO adsorption affinity on a wide range of binary alloying.
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Synthesis and study of antibiofilm and antivirulence properties of flavonol analogues generated by palladium catalyzed ligand free Suzuki–Miyaura coupling against Pseudomonas aeruginosa PAO1

RSC Adv., 2024, 14,12278-12293
DOI: 10.1039/D3RA08617H, Paper
Open Access
Anjitha Theres Benny, Masthan Thamim, Prakhar Srivastava, Sindoora Suresh, Krishnan Thirumoorthy, Loganathan Rangasamy, Karthikeyan S., Nalini Easwaran, Ethiraj Kannatt Radhakrishnan
An overview on the mechanism of Pseudomonas aeruginosa PAO1 biofilm inhibition by Suzuki–Miyaura coupled flavonols.
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Reusable magnetic mixture of CuFe2O4–Fe2O3 and TiO2 for photocatalytic degradation of pesticides in water

RSC Adv., 2024, 14,12337-12348
DOI: 10.1039/D4RA00094C, Paper
Open Access
Dmytro Danilian, Franziska Maria Bundrück, Arvo Kikas, Tanel Käämbre, Hugo Mändar, Sandro Lehner, Alexander Gogos, Jekaterina Kozlova, Mati Kook, Valter Kiisk, Joosep Link, Raivo Stern, Angela Ivask, Vambola Kisand, Rainer Pärna
Mixture of TiO2-P25 and magnetic CuFe2O4–Fe2O3 nanocomposites improves photocatalytic water treatment and enables easy catalyst recovery, effectively degrading pollutants like 2,4-D.
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Kinetic and reactivity of gas-phase reaction of acyclic dienes with hydroxyl radical in the 273–318 K temperature range

RSC Adv., 2024, 14,12303-12312
DOI: 10.1039/D3RA08750F, Paper
Open Access
Chenyang Xue, Xinmiao Xu, Han Lyu, Yunfeng Li, Yangang Ren, Jinhe Wang, Yujing Mu, Abdelwahid Mellouki, Zongzheng Yang
The relative position of two CC on the acyclic dienes could determine its reactivity. The number and type of alkyl group and the number of addition sites on diene could also strongly affect its reactivity toward OH radical.
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Synthesis of different types of nano-hydroxyapatites for efficient photocatalytic degradation of textile dye (Congo red): a crystallographic characterization

RSC Adv., 2024, 14,11570-11583
DOI: 10.1039/D3RA08527A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Md. Kawsar, Md. Sahadat Hossain, Sumaya Tabassum, Newaz Mohammed Bahadur, Samina Ahmed
Exploration of the crystallographic parameters of various nano-hydroxyapatites for enhanced photocatalytic degradation of Congo red dye.
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Progress of research on the bonding-strength improvement of two-layer adhesive-free flexible copper-clad laminates

RSC Adv., 2024, 14,12372-12385
DOI: 10.1039/D4RA01408A, Review Article
Open Access
Wanqi Tang, Yuxi Liu, Xianghai Jing, Jinsong Hou, Qianfeng Zhang, Chongguang Jian
Bond strength of two-layer adhesive-free flexible copper-clad laminate is an important factor that directly affects the stability and reliability of electronic devices.
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Quantitative analysis of the illegal addition of Atenolol in Panax notoginseng based on NIR–MIR spectral data fusion and calibration transfer

RSC Adv., 2024, 14,12428-12437
DOI: 10.1039/D3RA08183D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jie Du, Zhengwei Huang, Chun Li, Ling Jiang
To address the issue of the common illegal addition of Atenolol in Panax notoginseng, we propose an approach that realizes multivariate calibration transfer between different particle sizes based on spectral data fusion.
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Gamma-irradiated stibnite thin films set a remarkable benchmark performance for photoelectrochemical water splitting

RSC Adv., 2024, 14,12475-12495
DOI: 10.1039/D4RA01382D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Adel Chihi
The study sets out to show the positive impact of sulfur vacancy engineering on the structural, morphological, optical, electrical, and photoelectrochemical (PEC) properties of Sb2S3 films synthesized using the spin coating technique.
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Synergistic effects of β-NaFeO2 ferrite nanoparticles for photocatalytic degradation, antibacterial, and antioxidant applications

RSC Adv., 2024, 14,12513-12527
DOI: 10.1039/D4RA02430C, Paper
Open Access
Tahira Jabeen, Muhammad Shahid Khan, Sana Javaid, Waqar Azeem, Rabia Ayoub, Martin Motola
Detailed antibacterial mechanism using by synthesized β-NaFeO2.
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Visible light mediated iron-catalyzed addition of oxamic acids to imines

RSC Adv., 2024, 14,12528-12532
DOI: 10.1039/D4RA02258K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Margaux Badufle, Frédéric Robert, Yannick Landais
Oxamic acids where shown to add to imines, providing a broad range of α-aminoacid amides in generally good yields.
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Electrochemical oxidative radical cascade cyclization of dienes and diselenides towards the synthesis of seleno-benzazepines

RSC Adv., 2024, 14,12556-12560
DOI: 10.1039/D4RA01914H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ling Hu, Jingyi Zhang, Minghan Li, Yulin Feng, Fangling Lu
An electrochemical approach to access seleno-benzazepines through an oxidative radical cascade cyclization of dienes with diselenides under metal-free, external oxidant-free and base-free conditions.
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Amplification of photocatalytic degradation of antibiotics (amoxicillin, ciprofloxacin) by sodium doping in nano-crystallite hydroxyapatite

RSC Adv., 2024, 14,12386-12396
DOI: 10.1039/D4RA00126E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sakabe Tarannum, Md. Sahadat Hossain, Muhammad Shahriar Bashar, Newaz Mohammed Bahadur, Samina Ahmed
Sodium-doped hydroxyapatite (Na_HAp) was synthesized for the enhanced photocatalytic degradation of amoxicillin and ciprofloxacin.
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Thermally modified nanocrystalline snail shell adsorbent for methylene blue sequestration: equilibrium, kinetic, thermodynamic, artificial intelligence, and DFT studies

RSC Adv., 2024, 14,12703-12719
DOI: 10.1039/D4RA01074D, Paper
Open Access
Abisoye Abidemi Adaramaja, Abayomi Bamisaye, Shakirudeen Modupe Abati, Kayode Adesina Adegoke, Morenike Oluwabunmi Adesina, Ayodeji Rapheal Ige, Oluwatobi Adeleke, Mopelola Abidemi Idowu, Abel Kolawole Oyebamiji, Olugbenga Solomon Bello
The quest for an efficient and sustainable adsorbent material that can effectively remove harmful and hazardous dyes from industrial effluent has become more intense. Thermally modified nanocrystalline snail shell is a new biosorbent for removing methylene blue dye from contaminated wastewater.
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Application of cold-adapted microbial agents in soil contaminate remediation: biodegradation mechanisms, case studies, and safety assessments

RSC Adv., 2024, 14,12720-12734
DOI: 10.1039/D4RA01510J, Review Article
Open Access
Jiaxin Li, Yujuan Wen, Zheng Fang, Wenqi Yang, Xiaoming Song
Analyzed the microorganisms cold-adapted mechanism, and summarized the degradation pathway of nitro-aromatic compounds. Evaluated safety of microbial agents according to the existing application restoration cases under freeze-thaw cycles condition.
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Insight into the probability of ethoxy(pentafluoro)cyclotriphosphazene (PFPN) as the functional electrolyte additive in lithium–sulfur batteries

RSC Adv., 2024, 14,12754-12761
DOI: 10.1039/D3RA08379A, Paper
Open Access
Ning Li, Yu Zhang, Shun Zhang, Lu Shi, Jie-Yu Zhang, Ke-Meng Song, Jin-Chun Li, Fang-Lei Zeng
Enhancing the flame retardancy of electrolytes and the stability of lithium anodes is of great significance to improve the safety performance of lithium–sulfur (Li–S) batteries.
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Treatment of carbon electrodes with Ti3C2Tx MXene coating and thermal method for vanadium redox flow batteries: a comparative study

RSC Adv., 2024, 14,12807-12816
DOI: 10.1039/D4RA01380H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kavin Teenakul, Sayed Ali Ahmad Alem, Ritambhara Gond, Anupma Thakur, Babak Anasori, Amirreza Khataee
Treatment of carbon papers with Ti3C2Tx MXene solution for vanadium redox flow batteries.
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Novel supramolecular luminescent metallogels containing Tb(III) and Eu(III) ions with benzene-1,3,5-tricarboxylic acid gelator: advancing semiconductor applications in microelectronic devices

RSC Adv., 2024, 14,12829-12840
DOI: 10.1039/D3RA07903A, Paper
Open Access
Subhendu Dhibar, Aiswarya Mohan, Kripasindhu Karmakar, Bijnaneswar Mondal, Arpita Roy, Saranya Babu, Parul Garg, Pradip Ruidas, Subham Bhattacharjee, Sanjay Roy, Ashok Bera, Soumya Jyoti Ray, Padmanabhan Predeep, Bidyut Saha
Supramolecular metallogels with Tb(III)- and Eu(III)-ions, formed using benzene-1,3,5-tricarboxylic acid, display remarkable stability at room temperature. They hold promise for use in electronics, notably as reliable ambient Schottky barrier diodes.
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Carbon dots–cadmium sulfide quantum dots nanocomposite for ‘on–off’ fluorescence sensing of chromium(VI) ions

RSC Adv., 2024, 14,12923-12934
DOI: 10.1039/D4RA00436A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Anisha B. Patil, Pooja L. Chaudhary, Parag V. Adhyapak
This work involves fluorescent probe which is composed of carbon dots (CD) and cadmium sulfide quantum dots (CdS QD) for the sensitive and selective fluorescence detection of chromium(VI) ions.
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Rational design of a lysosome-targeted fluorescent probe for monitoring the generation of hydroxyl radicals in ferroptosis pathways

RSC Adv., 2024, 14,12864-12872
DOI: 10.1039/D4RA00562G, Paper
Open Access
Lili Zhong, Datian Fu, Jin Xu, Linyan Tan, Haimei Wu, Min Wang
A novel hydrocyanine-based turn-on fluorescence probe HCy-Lyso, with excellent lysosome-targeting ability and ˙OH-responsive efficiency, has been applied for monitoring the variation in lysosomal ˙OH levels during ferroptosis.
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Wet adhesive hydrogels based on niobium carbide for experimental research of oral mucosal impairment

RSC Adv., 2024, 14,12935-12946
DOI: 10.1039/D4RA01352B, Paper
Open Access
Jiayuan Chen, Junyu Ren, Yingjie Wu, Narisu Hu, Fang Zhao, Lin Zhang
Illustration of the mechanism of NbC/TA–GelMA hydrogel with multifunctional properties for potential application in oral mucosal impairment.
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Correction: Photocatalytic degradation of drugs and dyes using a machine learning approach

RSC Adv., 2024, 14,12983-12983
DOI: 10.1039/D4RA90045F, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ganesan Anandhi, M. Iyapparaja
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Efficient dye adsorption of mesoporous activated carbon from bamboo parenchyma cells by phosphoric acid activation

RSC Adv., 2024, 14,12873-12882
DOI: 10.1039/D4RA01652A, Paper
Open Access
Yuxuan Yao, Haifeng Zuo, Yijing Liu, Shenghua Pang, Liuqian Lan, Futi Yao, Yongyi Wu, Zhigao Liu
In this study, mesoporous activated carbon was prepared from bamboo parenchyma cells for MB removal from water.
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Mesoporous degradable chitosan-based monoliths: synthesis and applications toward water purification

Mol. Syst. Des. Eng., 2024, 9,399-408
DOI: 10.1039/D3ME00180F, Paper
Jyoti Devi Katiyar, Subrata Chattopadhyay
A synthetic strategy is presented for the preparation of degradable chitosan based functional porous polymer monoliths with tunable surface area, which are capable to efficiently remove multiple pollutants from water.
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Biobased copoly(acetal-triazole)s with tunable degradable properties

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00005F, Paper
Joseph C. Daniels, Guery Saenz, Colleen N. Scott
Enhanced degradation of acetal-containing polymers in environmental conditions.
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A taste of forest food and adivasi tradition

Visit Bhopoli village in Palghar district of Maharashtra to de-stress from urban pressures and to go back to nature




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Infy rallies behind Padukone Academy




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Helping anganwadis recover




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Pelican paradise at Uppalapadu

How a bird habitat in AP is being protected and developed, thanks to the passion of a self-taught ornithologist




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Women at the wheel: Azad Foundation’s ‘by women, for women’ cab service is driving change