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METHODS FOR INCREASING SENSITIVITY OF DETECTION AND/OR QUANTIFICATION OF NEGATIVELY CHARGED ANALYTES

The present technology provides methods for increasing sensitivity of detection and/or quantification of a negatively charged analyte, e.g., an oligonucleotide, using an analytical system that comprises liquid chromatography and mass spectrometry. The methods comprise passing an acidic solution through the analytical system, i.e., through a fluidic path from the mobile phase reservoir to the detector to remove or displace, at least in part, metal ions adsorbed to charged sites in the fluidic path.




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SCINTILLATOR CONFIGURATIONS AND METHODS FOR FABRICATING THE SAME

A scintillator block is presented. The scintillator block includes at least one scintillator having an isotropic volume. Furthermore, the scintillator block includes a laser-generated three-dimensional pattern positioned within the isotropic volume of the at least one scintillator, where the laser-generated three-dimensional pattern is configured to modify one or more optical properties within the isotropic volume of the at least one scintillator, and where the three-dimensional pattern varies along one or more of a depth, a width, and an angular orientation of the at least one scintillator.




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LINEAR-RESPONSE NANOCRYSTAL SCINTILLATORS AND METHODS OF USING THE SAME

Systems and devices incorporating radiation detection, and techniques and materials for improved radiation detection are provided that involve a nano-scintillator exhibiting a linear luminescent emission response to stimulating electromagnetic radiation. The nano-scintillator can include at least one nanocrystal comprising a rare earth element, a lanthanide dopant, and a spectator dopant, wherein the nanocrystal exhibits a linear luminescent emission response to stimulating electromagnetic radiation of wavelengths less than 100 nm. As one example, the nanocrystal is [Y2-xO3; Eux, Liy], where x is 0.05 to 0.1 and y is 0.1 to 0.16, and has an average nanoparticle size of 40 to 70 nm. These nanocrystals can be fabricated through a glycine combustion method.




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SLOW NEUTRON CONVERSION BODY AND SLOW NEUTRON DETECTOR

The present application, pertaining to the field of slow neutron detection, relates to a slow neutron converter and a slow neutron detector. The slow neutron converter includes a substrate, the substrate including a plurality of holes extending along a first direction and insulating walls between the plurality of holes, wherein the plurality of holes are through holes. The slow neutron converter further includes a boron layer at least covering an exposed surface of the plurality of holes. The slow neutron converter and the slow neutron detector having the slow neutron converter according to the present disclosure are capable of maintaining a high slow neutron detection efficiency. In addition, the manufacturing complexity and manufacturing cost of the detector are reduced, and thus the effective, convenient and low-cost slow neutron detection is achieved.




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Gamma-Ray Detectors For Downhole Applications

Methods and related systems are described for gamma-ray detection. A gamma-ray detector is made depending on its properties and how those properties are affected by the data analysis. Desirable properties for a downhole detector include; high temperature operation, reliable/robust packaging, good resolution, high countrate capability, high density, high Z, low radioactive background, low neutron cross-section, high light output, single decay time, efficiency, linearity, size availability, etc. Since no single detector has the optimum of all these properties, a downhole tool design preferably picks the best combination of these in existing detectors, which will optimize the performance of the measurement in the required environment and live with the remaining non-optimum properties. A preferable detector choice is one where the required measurement precision (logging speed) is obtained for all of the required inelastic elements and/or minimization of unwanted background signals that complicate the data analysis.




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Electronic Devices Having Infrared-Transparent Window Coatings

An electronic device may have a display with a cover layer. A light-based component such as an infrared-light proximity sensor or other infrared-light-based component may be aligned with a window in the display cover layer. The window may block visible light and transmit infrared light. A coating in the window may include a thin-film filter formed from a stack of inorganic dielectric layers. The thin-film filter may block visible light and transmit infrared light. The coating may also include at least one layer of material such as a semiconductor material that absorbs visible light and that passes infrared light. This material may be interposed between the thin-film filter and the display cover layer. Antireflection properties and color adjustment properties may be provided using thin-film layers between the thin-film filter and the display cover layer.




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DISPLAY DEVICE

A display device comprising a first image display device comprising a light guide plate, a dimmer, and a light control device. The light control device is configured to identify a start time of change in quantity of light received by the display device, and control transmissivity of the dimmer based on quantity of light received by the display device, after a predetermined amount of time after the start time has elapsed.




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Protective Device and Laser Raman Safety Inspection Apparatus Comprising the Same

Embodiments of the present invention provide a protective device including a sliding door and a housing, together forming a closed space, wherein, a guide rail is provided on the housing, and the sliding door is slidable along the guide rail to open or close the closed space. In addition, embodiments of the present invention also provide a laser Raman safety inspection apparatus including the abovementioned protective device.




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CONTROL SYSTEM AND METHOD FOR LITHOGRAPHY APPARATUS

A method for initializing a first operation in a first module at a first start time value in a first time base, the method comprising generating a clock signal, generating a second time base in the first module based on the clock signal, determining a second sync value in the second time base, determining a first sync value in the first time base corresponding to a second sync value in the second time base, determining a start trigger value in the second time base based on the first sync value and the start time value in the first time base, and initializing the first operation in the first module based on the start trigger value and a current value of the second time base in the first module.




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METHOD OF FABRICATING AN INTEGRATED CIRCUIT WITH A PATTERN DENSITY-OUTLIER-TREATMENT FOR OPTIMIZED PATTERN DENSITY UNIFORMITY

The present disclosure provides one embodiment of an IC method. First pattern densities (PDs) of a plurality of templates of an IC design layout are received. Then a high PD outlier template and a low PD outlier template from the plurality of templates are identified. The high PD outlier template is split into multiple subsets of template and each subset of template carries a portion of PD of the high PD outlier template. A PD uniformity (PDU) optimization is performed to the low PD outlier template and multiple individual exposure processes are applied by using respective subset of templates.




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Monitoring Liquid Chromatography Elution to Determine When to Perform a Lockmass Calibration

A method of mass spectrometry is disclosed that comprises acquiring mass spectral data during a single experimental run or acquisition of a mass spectrometer and determining a first time T during the single experimental run or acquisition for calibrating the mass spectrometer. The step of determining the first time T further comprises determining a time when the mass spectral data being acquired during the single experimental run or acquisition is equal to or below a threshold. The mass spectrometer is then calibrated by introducing calibrant or lockmass ions at the first time T.




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ACTIVE STABILIZATION OF ION TRAP RADIOFREQUENCY POTENTIALS

Disclosed are improved methods and structures for actively stabilizing the oscillation frequency of a trapped ion by noninvasively sampling and rectifying the high voltage RF potential at circuit locations between a step-up transformer and a vacuum feedthrough leading to the ion trap electrodes. We use this sampled/rectified signal in a feedback loop to regulate the RF input amplitude to the circuit. By employing techniques and structures according to the present disclosure we are advantageously able to stabilize a 1 MHz trapped ion oscillation frequency to




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SUPERCONDUCTING NANOWIRE AVALANCHE PHOTODETECTORS WITH REDUCED CURRENT CROWDING

Superconducting nanowire avalanche photodetectors (SNAPs) have using meandering nanowires to detect incident photons. When a superconducting nanowire absorbs a photon, it switches from a superconducting state to a resistive state, producing a change in voltage that can be measured across the nanowire. A SNAP may include multiple nanowires in order to increase the fill factor of the SNAP's active area and the SNAP's detection efficiency. But using multiple meandering nanowires to achieve high fill-factor in SNAPs can lead to current crowding at bends in the nanowires. This current crowding degrades SNAP performance by decreasing the switching current, which the current at which the nanowire transitions from a superconducting state to a resistive state. Fortunately, staggering the bends in the nanowires reduces current crowding, increasing the nanowire switching current, which in turn increases the SNAP dynamic range.




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Methods and Apparatus for Backside Integrated Circuit High Frequency Signal Radiation, Reception and Interconnects

In an example arrangement an apparatus includes a semiconductor substrate having a front side surface including circuitry and a backside surface opposing the front side surface; a plurality of metal conductors formed over a front side surface of the semiconductor substrate; at least one cavity opening etched in a backside surface of the semiconductor substrate; and a radiator formed in a portion of the metal conductors and configured to radiate signals through the cavity opening in the backside surface. Methods and additional apparatus arrangements are also disclosed.




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MULTI-CHANNEL PARALLEL OPTICAL TRANSCEIVER MODULE

The present disclosure provides a multi-channel parallel optical transceiver module. The disclosed optical transceiver module/device may include a shell body and a circuit board located in the shell body, and an optical emitter base soldered to a first end of the circuit board. A notch located on the base, for engaging the first end of the circuit board, and the optical emitter base engaged with the first end of the circuit board may be soldered to two sides of the circuit board. The optical emitters may be disposed in parallel on the base, and separated from each other by a block. A lens and a laser may be disposed at a first side of each of the optical emitters that is adjacent to the circuit board, and an optical monitor may be disposed on a second end of the circuit board adjacent to the laser.




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SOLID-STATE IMAGING DEVICE

A solid-state imaging device includes a detector, a count value storage, and a reader. The detector includes an avalanche amplification type light receiving element that detects a photon, and a resetter that resets an output potential of the light receiving element, and outputs a digital signal that indicates the presence or absence of incidence of a photon on the light receiving element. The count value storage performs counting by converting the digital signal output from the detector to an analog voltage, and stores the result of counting as a count value. The reader outputs an analog signal indicating the count value.




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High lubricity fuel reformulation to increase mileage and reduce emissions

A fuel additive imparting high lubricity to gasoline and diesel fuels while concurrently increasing miles and reducing emissions. The fuel additive is formed of a plurality of individual components having individual and a combined synergistic effect along with components increasing fuel lubricity which are mixed with a liquid fuel-soluble carrier and added to the fuel supply of internal combustion engines.




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Method for controlling and optimizing the manufacture of gasoline blendstocks for blending with an alcohol as an oxygenate

A method for manufacturing an oxygenated gasoline-blend by blending a hydrocarbon Basestock for Oxygenate Blending (BOB) with an alcohol such as ethanol to a required octane specification first blends the BOB to an octane number, (RON+MON)/2 based on the octane sensitivity (RON−MON) of the BOB and the proportion of alcohol to be added to the BOB, such that when the BOB is blended with the specification proportion of alcohol to form the oxygenated gasoline blend, this blend will have the required octane specification. The blending of the BOB with the alcohol will typically be done at a location remote from that where the BOB is blended, e.g. at the product distribution terminal after being transported from the refinery by pipeline or tank car.




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Suspended solids separation systems and methods

A method that includes clarifying a thin stillage product in a mechanical processor to produce a fine suspended solids stream and a clarified thin stillage is provided. The method further includes providing the thin stillage product and the clarified thin stillage, separately or in a combined stream, to one or more evaporators to produce one or more reduced suspended solids streams, each stream having a reduced amount of suspended solids and a lower viscosity as compared to process streams having a comparable total solids content but containing a higher amount of suspended solids. The method can further included further processing of one or more of the reduced suspended solids streams to produce a bio-oil product.




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Organism co-culture in the production of biofuels

This invention provides co-cultures of photosynthetic microorganisms and biofuel producing microorganisms. In certain embodiments, polysaccharide-producing, photosynthetic microorganisms are microalgae having frustules provide a substrate on which biofuel-producing microorganisms can grow. In other embodiments, the photosynthetic microorganisms produce a lipid and the non-photosynthetic microorganisms produce a solvent in which the lipid is soluble.




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Alkoxylated quaternary ammonium salts and fuels containing them

A fuel additive and its preparation for a engine, a fuel containing the additive, a fuel additive concentrate, a method for improving performance of fuel injectors and a method for cleaning fuel injectors for an engine. The fuel additive includes a quaternary ammonium salt derived from a reaction of a hydrocarbyl substituted anhydride, a tertiary amine and a hydroxyl-containing epoxide, wherein the tertiary amine is devoid of primary and secondary amino groups.




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Remote additive application

The present disclosure is directed to the application of additives to a feed material at a location remote from an industrial facility using the feed material.




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Pre-burning, dry process methodology and systems for enhancing mettallurgical solid fuel properties

Measurements are taken of moisture, BTU/lb (British Thermal Units per pound), ash, forms of sulfur, volatile material, grindability, and absorption properties of any of a wide variety of mine-run solid fuels. Using that information, a dry electromagnetic process technology has been developed that can be controlled and monitored to selectively alter and enhance metallurgical solid fuel properties. Specific changes include altering the mechanical structure and chemical composition of solid fuels such as coal, coal coke or petroleum coke, increasing the BTU/lb to optimum levels, decreasing all forms of sulfur, and decreasing ash, while maintaining the BTU/lb of the fuels. A new family of solid fuel designer coals not found in nature can be produced via these methods and apparatus.




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Process to obtain diesel from vegetable and animal oils through a hydrotreatment with short residence time and byproducts obtained from it

A method for obtaining diesel fuel from vegetable or animal oils through the addition of hydrogen in the presence of catalysts under suitable temperature and pressure conditions is described. The method is different from other similar methods in that it involves the use of space velocities of between 5.1 h-1 and 9 h-1, thereby enabling a reduction in the size of the reactor and in hydrogen consumption, as well as lowering construction and operating costs. The invention also relates to the products obtained using said method, which have demonstrated that in additions, even below 10%, they improve the performance of diesel engines, thereby lowering fuel consumption.




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Process for drying material and dryer for use in the process

A process of drying moisture containing material having a tendency to create dust when dried, said process including the steps of providing said material in a heated chamber having a steam containing atmosphere at a temperature above the dewpoint of the steam, recirculating a hot gas including a portion of the steam through said chamber in order to evaporate moisture from the material to a predetermined level of dryness.




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Transparent gel candle base

The present invention relates to transparent gel candle bases that may be used as a base material of transparent candles, to the transparent candles made therefrom, and to methods of making such candle bases and candles. The transparent gel candle bases of the present invention include a hydrocarbon oil and a gelling agent comprising dibutyl lauroyl glutamide and dibutyl ethylhexanoyl glutamide.




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Fuel compositions and methods for making same

This invention relates to low sulfur marine/bunker fuel compositions and methods of making same. Contrary to conventional marine/bunker fuel compositions/methods, the inventive lower sulfur compositions/methods focus on use of mostly uncracked components, such as (cat feed) hydrotreated gasoils, and/or can also have reduced contents of residual components.




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Quality certification of oxygenated gasoline

A method for controlling the manufacture and certification of an oxygenated gasoline product is carried out by manufacturing a gasoline Basestock for Oxygenate Blending (BOB) at a refinery site in accordance with an empirical relationship, valid for at that site under typical manufacturing conditions, between (i) a property value of the BOB stream such as octane as determined by an on-site online process analyzer and (ii) the corresponding instantaneous value or FPAPV property value as determined by the test method mandated by the product specification for the final gasoline stream when blended with the required proportion of oxygenate. The quality of fit of this empirical relationship is calculated according to the standard deviation of the residuals of the relationship and a confidence level is fixed so that the final oxygenated gasoline formulated with the BOB will meet the required property specification when measured by the test method mandated by the specification. The final oxygenated gasoline blend is certified as having a property value conforming to the required specification based on the predicted property value for the finished gasoline.




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Method for contemporaneously dimerizing and hydrating a feed having butene

Methods for producing alcohols and oligomers contemporaneously from a hydrocarbon feed containing mixed butenes using an acid based catalyst are provided. Additionally, methods for producing fuel compositions having alcohols and oligomers prepared from mixed olefins are also provided as embodiments of the present invention. In certain embodiments, the catalyst can include a dual phase catalyst system that includes a water soluble acid catalyst and a solid acid catalyst.




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Systems and methods for producing engineered fuel feedstocks with reduced chlorine content

Systems and methods for producing engineered fuels from municipal solid waste material are described herein. In some embodiments, a method includes combining a first waste stream that includes at least one of hard plastic, soft plastic and mixed plastic with a sorbent and increasing the temperature of the combined first waste stream and sorbent to a temperature of at least about 200° C. The method further includes combining the thermally treated first waste stream and sorbent with a second waste stream that includes fiber, and compressing the combined first waste stream, sorbent, and second waste stream to form a densified engineered fuel feedstock.




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Apparatus for upgrading coal and method of using same

An apparatus for upgrading coal comprising a baffle tower, inlet and exhaust plenums, and one or more cooling augers. The baffle tower comprises a plurality of alternating rows of inverted v-shaped inlet and outlet baffles. The inlet and outlet plenums are affixed to side walls of the baffle tower. Process gas enters the baffle tower from the inlet plenum via baffle holes in the side wall and dries the coal in the baffle tower. Process exhaust gas exits the baffle tower into the exhaust plenum via baffle holes in a different side wall of the baffle tower. Coal that enters the baffle tower descends by gravity downward through the baffle tower and enters a cooling auger, where the dried coal from the baffle tower is mixed with non-dried coal. A method of using the apparatus described above to upgrade coal.




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Methods of producing coal and fertilizers from fermentation residues

The present invention concerns a process for producing synthetic coal and aqueous liquid plant fertilizing solution products from a fermentation residue such as is left over from the corn based process of producing ethanol. The synthetic coal has a high heat value commensurate with naturally occurring coals and is lower in ash and sulfur content and thus has value as a clean burning energy source. The aqueous fertilizer includes commercially useful amounts of phosphorous, potassium and nitrogen in solution. The process of the invention is also energy efficient in that the products produced thereby involve the use of substantially less energy as compared to the traditional methods of processing fermentation residues in the corn based ethanol production industry.




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Process for production of biodiesel

A multi-stage reactor system for preparing biodiesel is used to increase efficiency and yield and reduce impurities. A three-stage transesterification reaction for preparing biodiesel can include one high-shear cavitation reactor and two low-shear cavitation reactors, preferably in series, and optionally one or more separation vessels for removing waste and recycling triglyceride feedstock, catalyst and alcohol to the high-shear cavitation reactor.




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Reusable heater in a package

A heater in a housing with an opening. The heater reacts with oxygen to produce heat and upon consumption of the oxygen, the heating reaction stops and can be restarted at a later point in time upon the introduction of additional oxygen and is used in a package for heating pre-moistened substrates such as sanitary wipes, and the like.




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Bio-oil production method

The invention relates to methods for the conversion of lignocellulosic matter into fuel products. More specifically, the invention relates to methods for the generation of a bio-oil product from specific component(s) of lignocellulosic matter.




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Device for preparing bio-oil, system for preparing bio-oil and method for preparing bio-oil using the same

A device for preparing bio-oil, a system for preparing bio-oil and a method for preparing bio-oil using the same are provided. Biomass is supplied to an inclined portion of a reactor, and high-temperature hot sand is supplied to an upper side of the biomass supplied to the inclined portion. Then, a heater heats the inclined portion. Thus, the fast pyrolysis performance of the biomass can be enhanced, thereby increasing the yield of bio-oil. Also, combustion gas produced from the heater is supplied to the interior of the reactor, so that the interior of the reactor can be simply formed under a nonoxidizing atmosphere. Accordingly, the device for preparing bio-oil can be manufactured into a very simple structure.




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Biphenyl benzyl ether marker compounds for liquid hydrocarbons and other fuels and oils

A compound having formula (I) wherein G represents at least one substituent selected from the group consisting of C1-C12 alkyl and C1-C12 alkoxy.




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Bisphenol A compounds as markers for liquid hydrocarbons and other fuels and oils

A method for marking a petroleum hydrocarbon or a liquid biologically derived fuel by adding at least one compound having formula (I), wherein R1 and R2 independently represent hydrogen or C1-C4 alkyl groups, and G represents hydrogen or at least one substituent selected from the group consisting of C1-C18 alkyl and C1-C18 alkoxy.




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Use of 1,1-diethoxyethane for increasing knocking resistance of automotive gasoline

The present invention relates to the use of 1,1-diethoxyethane for increasing the knocking resistance of low-boiling gasoline with an initial boiling point (IBP) of 80° C. to 120° C. by at least 40 units (Research Octane Number).




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Method for producing solid fuel and solid fuel produced by the method

Modified solid fuel manufacturing method and modified solid fuels manufactured using the manufacturing method. When solid fuels are manufactured by crushing low grade coal, mixing the crushed low grade coal with solvent oil to prepare a slurry, heating the slurry to at least the boiling point of water to evaporate moisture included in the slurry, separating the solvent oil from the slurry to produce charcoal dust and compression compacting said charcoal dust, by heating the slurry to at least the boiling point of water, the non-volatile components included in the low grade coal are extracted with the solvent oil, the outer surface of the low grade coal and the internal surfaces of the pores are coated with the extracted non-volatile components, and the content of heavy oil added from the outside will be less than 0.5 mass % relative to the solid fuel after drying.




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Process for upgrading low rank carbonaceous material

A process for upgrading brown coal having a first water content including subjecting the brown coal to a conditioning step which includes heating the brown coal to a first temperature to produce a conditioned brown coal having a second water content which is lower than the first water content; attritioning the conditioned brown coal to enable water to be released from the microstructure of the brown coal and thereby producing an admixture of the brown coal and released water; forming aggregates of the admixture; drying the aggregates to produce upgraded brown coal having a third water content which is lower than the second water content.




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Device and method for controlling the conversion of biomass to biofuel

Embodiments presented herein describe an apparatus and method to control the conversion of carbonaceous materials, particularly biomass and those biomass resources, into a high performance solid fuel. This method, and the apparatus described as the means to accomplish this method, provides a process having a control system that enables the system to produce a fuel of uniform quality, even with a change in biomass supply.




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Polytetrahydrobenzoxazines and bistetrahydrobenzoxazines and use thereof as a fuel additive or lubricant additive

Polytetrahydrobenzoxazines and bistetrahydrobenzoxazines, obtainable by (A) reacting at least one diamine of the formula H2N-A-NH2 with a C1- to C12-aldehyde and a C1- to C8-alkanol at 20 to 80° C. with elimination and removal of water, (B) reacting the condensation product from (A) with a phenol which bears a long-chain substituent at 30 to 120° C., and optionally (C) heating the reaction product from (B) to 125 to 280° C. The resulting polytetrahydrobenzoxazines and bistetrahydrobenzoxazines are suitable as fuel or lubricant additives, especially as detergent additives for diesel fuels.




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Methods for converting motor oil into fuel

Methods for converting petroleum based oil into fuel generally include forming a conversion mixture of an alcohol and a base, and adding the conversion mixture to petroleum based oil, such as used motor oil, to form a reaction mixture. The methods can also include adding a high nitrate compound and an amino acid to the reaction mixture and ozonizing the reaction mixture. The result of the methods can include a three phase system in which the bottom phase is asphalt oil, the middle phase is diesel fuel or jet fuel, and the top phase is sulfuric acid. The three phases can be separated to obtain the final diesel fuel or jet fuel product.




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Fuel composition containing a hydrocarbyl-substituted succinimide

The present disclosure is directed to a middle distillate fuel composition comprising a friction modifying effective amount of a hydrocarbyl-substituted succinimide derived from maleic anhydride, polyisobutylene and ammonia; and a middle distillate fuel. A method for modifying friction in a compression engine comprising providing to the engine the disclosed fuel composition is also disclosed. Moreover, there is disclosed a method for improving fuel mileage.




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Tritylated ethers

A compound having formula (Ph3C)mAr(OR)n, wherein Ph represents a phenyl group, Ar is an aromatic ring system having from six to twenty carbon atoms, R is C1-C18 alkyl or C7-C12 aralkyl, m is one or two, and n is an integer from one to four.




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Two-stage reactor and process for conversion of solid biomass material

A two-stage reactor is disclosed for the conversion of solid particulate biomass material. The reactor is designed to maximize conversion of the solid biomass material, while limiting excess cracking of primary reaction products. The two-stage reactor comprises a first stage reactor, in which solid biomass material is thermally pyrolyzed to primary reaction products. The primary reaction products are catalytically converted in a second stage reactor.




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Fuel compositions

Use in a gas oil fuel composition, which preferably comprises a Fischer-Tropsch derived fuel, of a compound according to formula (I): wherein: R1 to R4 are each independently hydrogen or a C1-10 alkyl group, where such alkyl groups may be the same as or different from one another; and X is a nitrogen- or oxygen-containing group, for the purpose of reducing the cetane number of said fuel composition; preparation of such a fuel composition; and operating a fuel consuming system.




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Alkanolamides and their use as fuel additives

The present invention relates to alkanolamide-containing compositions, and more particularly to alkanolamide-containing compositions formed by the reaction of a fatty acid and diethanolamine (DEA) which contain low levels of undesirable by-products. Such compositions are particularly suitable for use as fuel additives.




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Gasoline fuel composition for improved performance in fuel injected engines

A method for improving performance of fuel injectors, and a method for cleaning fuel injectors for an internal combustion engine. The methods include operating the engine on a fuel composition comprising a major amount of fuel and from about 1 to about 200 ppm by weight based on a total weight of the fuel of a reaction product of (i) a hydrocarbyl substituted compound containing at least one tertiary amino group and (ii) a halogen substituted C2-C8 carboxylic acid, ester, amide, or salt thereof, wherein the reaction product as made is substantially devoid of free anion species.