ter Influence of weakly coordinating anions binding to the hexa-tert-butyl dysprosocenium cation By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02713B, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Sophie C. Corner, Gemma K. Gransbury, David P. MillsWe present the synthesis and characterisation of two dysprosium metallocene complexes with bound weakly coordinating anions. Despite their similarity these complexes exhibit vastly different effective energy barriers to magnetic reversal.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter The preparation of CuM/SiO2 (M=Bi, Mg, Mn) catalysts applied in ethynylation of formaldehyde for 1,4‑butynediol synthesis: the positive interface effect of CuO and Bi2O3 By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02616K, PaperJiali Chen, Guihua Yang, Feng Gao, Rui WangThe ethynylation of formaldehyde reaction catalyzed by Cu-based catalysts is an important synthesis method for 1,4-butynediol relating to high value-added chemicals. In this work, a series of CuM/SiO2 ( M=Bi,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter A highly sensitive ratiometric optical thermometer based on Sr2MgWO6 double perovskite doped with Dy3+ exploiting thermally coupled and uncoupled levels By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02940B, PaperThi Hong Quan Vu, Bartosz Bondzior, Dagmara Stefanska, Shovan Dan, Przemysław Jacek DereńThe increasing demand for highly sensitive optical thermometers operating within a wide temperature range necessitates the development of new phosphors. In this work, the potential of temperature sensing performance of...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Stable homogeneous silver(I) catalysts for the highly efficient cycloaddition of azides onto terminal alkynes in water By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02825B, CommunicationMeysam Kakavand, Anna Kozakiewicz, Abdollah NeshatTo develop stable and efficient silver(I) catalysts and evaluate the role of sulfur and phosphorus donor ligands in the catalytic cycloaddition of selected organic azides and alkynes (AAC), a series...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Co-doping regulation on Ni-based electrocatalysts to adjust the selectivity of oxygen reduction reaction for Zn–air batteries and H2O2 production By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17819-17828DOI: 10.1039/D4DT01625D, PaperSonghan Hu, Kai Wang, Xinxin Xu, Qiang WangTwo Ni-based electrocatalysts with different ORR selectivity were synthesized from a NiMOF, which show promising prospects in Zn–air batteries and H2O2 production.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Excited-state intramolecular proton transfer (ESIPT) active interwoven polycatenated coordination polymer for selective detection of Al3+ and Ag+ ions along with water detection in less polar solvents By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18003-18012DOI: 10.1039/D4DT02285H, PaperAnupam Maiti, Rakesh Kumar, Bidyadhar Mahato, Debajyoti GhoshalAn ESIPT active coordination polymer is successfully synthesized, exhibiting ESIPT induced blue shift for Al3+ ions and ESIPT-off for Ag+ ions. The material can also detect polar water, dimethylformamide and methanol in less polar organic solvents.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Metal–organic framework-derived Se-blended ZrO2 with a nitrogen-doped carbon heterostructure for electrocatalytic overall water splitting By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17918-17933DOI: 10.1039/D4DT02542C, PaperKrishnendu M. Nair, Pavithra Shankar, Selvaraju ThangaveluElectrocatalytic overall water splitting is achieved with ease at 1.58 V together with exciting stability over 48 h.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Construction of oxygen-rich vacancies and heterojunctions coupled with different morphologies of CeO2/mesoporous TiO2 framework structures for efficient photocatalytic CO2 reduction performance By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17963-17975DOI: 10.1039/D4DT02014F, PaperMorigejile Liu, Guangmei Jiang, Zaiwang Zhao, Ying Shi, Siqin ZhaoConstruction of oxygen-rich vacancies and heterojunction-coupled CeO2/mesoporous TiO2 framework structures with different morphologies and efficient photocatalytic CO2 reduction performance.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Direct O2 mediated oxidation of a Ni(II)N3O structural model complex for the active site of nickel acireductone dioxygenase (Ni-ARD): characterization, biomimetic reactivity, and enzymatic implications By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17852-17863DOI: 10.1039/D4DT02538E, PaperKelsey E. Kirsch, Mary E. Little, Thomas R. Cundari, Emily El-Shaer, Georgia Barone, Vincent M. Lynch, Santiago A. ToledoA structural and functional biomimetic Ni(II)N3O complex, capable of O2 mediated dioxygenase like C–C bond cleavage, via a putative high-valent Ni intermediate.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Three organic–inorganic polyoxoniobate-based compounds modified with Cu(II) amine complexes: synthesis, characterization, and catalytic studies for oxidation of styrene By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17880-17892DOI: 10.1039/D4DT02544J, PaperZhi-Cheng Duan, Guanghua Li, Ke-Chang Li, Xiao-Bing CuiThree novel organic–inorganic polyoxoniobate-based compounds modified with Cu(II) amine complexes were synthesized under hydrothermal conditions. Additionally, the catalytic efficacy of these compounds in the oxidation of styrene was investigated.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Coinage metal(I) clusters supported by a 1,10-phenanthroline-phosphine: orange-to-NIR phosphorescence, metallophilic interactions and enhanced cytotoxicity By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18027-18036DOI: 10.1039/D4DT02642J, PaperAlexander V. Artem'ev, Maria P. Davydova, Lyubov S. Klyushova, Evgeniy H. Sadykov, Mariana I. Rakhmanova, Taisiya S. SukhikhBased on 2-(diphenylphosphino)-1,10-phenanthroline, a series of small metal(I) clusters, exhibiting orange to NIR phosphorescence and strong dose-dependent cytotoxicity.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter An acidity-triggered aggregation nanoplatform based on degradable mesoporous organosilica nanoparticles for precise drug delivery and phototherapy of focal bacterial infection By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17893-17901DOI: 10.1039/D4DT02111H, PaperYunhan Huang, Wei Guo, Xinyu Wang, Jingrui Chang, Bo LuAn acidity-triggered aggregation antibacterial nanoplatform based on biodegradable mesoporous organic silica nanoparticles, is reported. It enables precise drug release and spatial accuracy for photodynamic therapy and photothermal therapy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter A bioinspired water oxidation catalyst that is ∼1/10th as active as the photosystem II oxygen evolving center at pH 7: a study of activity and stability factors By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17783-17788DOI: 10.1039/D4DT02336F, CommunicationDanijel Boskovic, Richard Terrett, Matthew Longhurst, Sabeel Basheer, Alireza Ariafard, Pawel Wagner, Ronald J. Pace, Rob Stranger, Gerhard F. SwiegersCa-doped birnessite MnOx on liquid crystalline reduced graphene oxide exhibits unprecedented performance for an abiological catalyst at pH 7, including a very low onset overpotential of 0.52 V and high activity per unit area at 0.56 V overpotential.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter The effect of second coordination sphere interactions on the magnetic anisotropy of transition metals By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02873B, PaperSofie S. Leiszner, Mauro Perfetti, Emil Damgaard-Møller, Yu-Sheng Chen, Bo B. IversenBy investigating second coordination sphere effects on the magnetic anisotropy of a Co(II) single molecule magnet (SMM), we aim to clarify their role in magneto-structural correlations to enhance the performance of transition metal SMMs.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Heats of formation on the way from B2H6 to B20H16: thermochemical consequences of multicenter bonding in ab initio and DFT methods By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02589J, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jindřich Fanfrlík, Jan Řezáč, Drahomír Hnyk, Josef HolubThe objective of this study is to evaluate the effectiveness of various computational methods in reproducing the experimental heats of formation of boron hydrides using the atomization energy approach.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Asymmetric triply bridged lanthanide binuclear clusters with distinctly different magnetic behaviors By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02652G, CommunicationYue Yang, Yu-Xia Wang, Yu-Zhe Lei, Peng ChengIsomorphic binuclear clusters Gd and Dy with antiferromagnetic and ferromagnetic couplings are separately exhibiting single-molecule magnetic behavior and strong magnetocaloric entropy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter Recent Advances in Syntheses and Emerging Applications of 2D Borophene based Nanomaterials with a Focus on Supercapacitors By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02573C, FrontierPrashanta Pal, Mahasweta NandiTwo dimensional (2D) nanosheet of boron i.e. borophene, triggered interest in progressive research as a result of the vast field of opportunities to explore, from its innovative synthetic techniques to...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ter It's all in the interpretation By www.thehindubusinessline.com Published On :: Sun, 25 Aug 2013 16:22:29 +0530 Full Article S Madhavan
ter Troubled waters By www.thehindu.com Published On :: Sun, 11 Aug 2024 02:14:00 +0530 The good and bad aspects of the rains Full Article Open Page
ter The heart of the matter By www.thehindu.com Published On :: Sun, 29 Sep 2024 03:25:00 +0530 On World Heart Day, September 29, random thoughts on keeping the ticker ticking Full Article Open Page
ter The City of Literature By www.thehindu.com Published On :: Sun, 29 Sep 2024 04:00:00 +0530 Kozhikode’s history has deep literary roots Full Article Open Page
ter A lie and its deleterious effects By www.thehindu.com Published On :: Sun, 13 Oct 2024 03:23:00 +0530 Lying often results in guilt, anxiety, or the fear of being caught Full Article Open Page
ter Heavy fog affects 21 flights at Kempegowda International Airport in Devanahalli in Bengaluru By www.thehindu.com Published On :: Sun, 10 Nov 2024 09:46:15 +0530 There were more than 15 delays, and six flights diverted Full Article Bengaluru
ter Dalit family assaulted for entering temple in Arakalgud village By www.thehindu.com Published On :: Sun, 10 Nov 2024 21:15:39 +0530 Full Article Karnataka
ter Siddaramaiah, Shivakumar term PM’s allegations of raising ₹700 cr. to fund Maharashtra polls as a ‘lie’ By www.thehindu.com Published On :: Sun, 10 Nov 2024 21:32:57 +0530 Full Article Karnataka
ter Cheluvarayaswamy accuses HDK of collecting ₹1,000 cr. from steel industries to fund elections; JD(S) terms it a strategy to divert attention from ‘excise scam’ By www.thehindu.com Published On :: Mon, 11 Nov 2024 04:25:28 +0530 After Prime Minister Narendra Modi accused the Congress government of collecting ₹700 crore from excise sources to fund the Maharashtra elections, it was the turn of N. Cheluvarayaswamy Full Article Karnataka
ter B.S. Yediyurappa says he will respond to allegations of corruption after bypolls By www.thehindu.com Published On :: Mon, 11 Nov 2024 07:00:00 +0530 Full Article Karnataka
ter Karnataka Minister Zameer Ahmed Khan kicks up another row with ‘racist’ remark about Union Minister H.D. Kumaraswamy By www.thehindu.com Published On :: Mon, 11 Nov 2024 16:39:36 +0530 The Housing Minister is already facing flak for the wakf controversy that has snowballed into a big issue in Karnataka Full Article Karnataka
ter Karnataka Ministers seek action against Union Minister Pralhad Joshi for ‘agent’ comment on retired high court judge Michael D’Cunha By www.thehindu.com Published On :: Mon, 11 Nov 2024 17:14:22 +0530 The two Ministers told the Governor that Mr. Joshi made a deliberate attempt to politicise and taint a constitutionally sanctioned inquiry, betraying public trust in the process Full Article Karnataka
ter BJP MLA B.P. Yatnal walks out of event after crowd objects to political speech over mention of Waqf land row By www.thehindu.com Published On :: Mon, 11 Nov 2024 18:33:09 +0530 Mr. Yatnal raised the issue of waqf during an Allammaprabhu temple event Full Article Karnataka
ter Sahitya Sammelana: ₹50 lakh set aside for drinking water supply By www.thehindu.com Published On :: Mon, 11 Nov 2024 20:07:11 +0530 Full Article Karnataka
ter Tribals seek internal reservation, FRA implementation By www.thehindu.com Published On :: Mon, 11 Nov 2024 22:54:32 +0530 A memorandum will be submitted to Chief Minister Siddaramaiah during his visit to H.D. Kote on Tuesday Full Article Karnataka
ter Karnataka School Examination and Assessment Board directs students from unauthorised schools not to register for SSLC exam this year By www.thehindu.com Published On :: Mon, 11 Nov 2024 23:28:30 +0530 Full Article Karnataka
ter Chief Minister Siddaramaiah has no moral right to seek resignation of Prime Minister Narendra Modi, says Union Minister By www.thehindu.com Published On :: Tue, 12 Nov 2024 07:00:00 +0530 Pralhad Joshi was responding to a challenge by Mr. Siddaramaiah to the PM to prove charges of corruption in Karnataka or resign. Full Article Karnataka
ter I apologise if my remark about H.D. Kumaraswamy has hurt JD(S) workers: Karnataka Housing Minister B Z Zameer Ahmed Khan By www.thehindu.com Published On :: Tue, 12 Nov 2024 16:22:44 +0530 Housing Minister’s remarks about colour of skin of Union Minister H. D. Kumaraswamy had drawn criticism from BJP and JD(S) Full Article Karnataka
ter Sandur bypolls: Ballari Deputy Commissioner appeals to voters to exercise franchise By www.thehindu.com Published On :: Tue, 12 Nov 2024 19:36:30 +0530 Full Article Karnataka
ter Movement of suspected Maoists in Chikkamagaluru: Jayapura police register case, seize three rifles By www.thehindu.com Published On :: Tue, 12 Nov 2024 21:04:31 +0530 Full Article Karnataka
ter Don’t reduce quantum of advance, Minister Shivanand Patil tells NABARD By www.thehindu.com Published On :: Tue, 12 Nov 2024 21:15:47 +0530 Full Article Karnataka
ter Karnataka byelections: All set for polling today after weeks of high-decibel campaign By www.thehindu.com Published On :: Tue, 12 Nov 2024 21:33:21 +0530 Though the results have little consequence in the number game for the government, the stakes are high for individual leaders Full Article Karnataka
ter EPL PIX: United thrash Leicester By www.rediff.com Published On :: IMAGES from the English Premier League matches played on Sunday. Full Article
ter Integrated motivational interviewing and cognitive behavioral therapy (ICBT) [electronic resource] : a practitioners guide / Joseph Hyde, Maria Torres, Win Turner, R. Lyle Cooper. By darius.uleth.ca Published On :: Hoboken, New Jersey : John Wiley & Sons, Inc., [2024] Full Article
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ter Over nine crore voters to decide Maha's fate on Nov 20 By www.newkerala.com Published On :: Wed, 16 Oct 2024 12:40:02 +0530 Full Article
ter Boozers beware: Maharashtra orders sophisticated surveillance of 'watering holes' By www.newkerala.com Published On :: Wed, 16 Oct 2024 22:38:02 +0530 Full Article
ter Chennai Grandmasters 2024: Arjun in sole lead after fourth round By www.thehindu.com Published On :: Sat, 09 Nov 2024 05:22:00 +0530 Vidit Gujrathi, who drew with Maxime Vachier-Lagrave, is yet to win too. He’s had two losses, followed by two draws. Full Article Sport
ter Samson says support from captain Suryakumar, coach Gambhir helped him overcome doubt over his ability after failures By www.thehindu.com Published On :: Sat, 09 Nov 2024 11:15:43 +0530 “I received a lot of phone calls from Gautam bhai and Surya, telling me what to work on,” says the Kerala batter, after his century against South Africa Full Article Cricket
ter Mourinho gets one-match ban and fined after Turkish tirade By www.thehindu.com Published On :: Sat, 09 Nov 2024 14:02:06 +0530 Jose Mourinho fined and banned for criticising Turkish soccer, questioning officials, and unsportsmanlike conduct towards fans Full Article Football
ter IND vs SA second T20I: India needs top-order to bat better against South Africa By www.thehindu.com Published On :: Sat, 09 Nov 2024 15:21:15 +0530 India need to address lack of runs from other key batters to ensure that the burden doesn't fall too heavily on their in-form keeper-batter. Full Article Cricket
ter Manipur beats Bengal; Uttar Pradesh qualifies for quarterfinals By www.thehindu.com Published On :: Sat, 09 Nov 2024 21:22:20 +0530 Full Article Hockey
ter Kiran George's Korea Masters run ends in semifinals with loss to Kunlavut By www.thehindu.com Published On :: Sun, 10 Nov 2024 06:23:18 +0530 Kiran George, who trains at the Prakash Padukone Badminton Academy (PPBA), had earlier registered a fine win over fifth seed Takuma Obayashi of Japan in the quarterfinals Full Article Sport
