id

Trinamool moves ECI against State BJP president, misuse of Central forces

The Trinamool Congress delegation also expressed dissatisfaction that the Election Commissioners were not available to meet the party delegation at ECI headquarters




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Halide-free and metal-free allylic thiolation/selenation of P(O)H compounds with sulfur/selenium and allylic alcohols

Green Chem., 2024, 26,10886-10892
DOI: 10.1039/D4GC03960B, Paper
Longzhi Zhu, Weiwei Luo, Furong Guo, Lin Chen, Ying Tang, Biquan Xiong, Yu Liu, Ke-Wen Tang, Renhua Qiu
A halide- and metal-free method for forming C–S/Se–P(O) bonds using allylic alcohols, P(O)H compounds, and elemental sulfur/selenium is reported, eliminating the need for toxic, odorous, and moisture-sensitive starting materials.
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What to do with polyurethane waste? The environmental potential of chemically recycling polyurethane rigid foam

Green Chem., 2024, 26,10893-10906
DOI: 10.1039/D4GC02594F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Martin Pillich, Johannes Schilling, Luca Bosetti, André Bardow
The environmental potential guides through the maze of chemical recycling of polyurethane rigid foams highlighting promising options.
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Self-supported FeCoNiCuP high-entropy alloy nanosheet arrays for efficient glycerol oxidation and hydrogen evolution in seawater electrolytes

Green Chem., 2024, 26,10921-10928
DOI: 10.1039/D4GC02517B, Paper
Leyang Song, Chaoqun Ma, Peidong Shi, Xiaojuan Zhu, Kaiyu Qu, Lijie Zhu, Qipeng Lu, An-Liang Wang
Self-supported FeCoNiCuP high entropy alloy nanosheet arrays electrocatalyst was developed for highly efficient glycerol oxidation to formate and hydrogen evolution in seawater electrolytes.
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Feasibility and sustainability of emerging CCU pathways for formic acid production

Green Chem., 2024, 26,10982-10995
DOI: 10.1039/D4GC02507E, Paper
Tesfalem Aregawi Atsbha, Ha-Jun Yoon, Ali Cherif, Chul-Jin Lee
The thermo-catalytic pathway can be a competitive alternative to the conventional pathway. CO2 source and electricity source highly affected the GWI for the thermo-catalytic pathway and electrochemical reduction pathway respectively.
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Solid phase peptide synthesis using side-chain unprotected arginine and histidine with Oxyma Pure/TBEC in green solvents

Green Chem., 2024, 26,10929-10939
DOI: 10.1039/D4GC03209H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tommaso Fantoni, Andrea Orlandin, Ilaria Di Stefano, Marco Macis, Alessandra Tolomelli, Antonio Ricci, Walter Cabri, Lucia Ferrazzano
Oxyma Pure/TBEC coupling protocol in green solid phase peptide synthesis (GSPPS) eliminates protective groups on Arg and His, enhancing atom economy and reducing impurities during cleavage. The technology was extended to side-chain-free Tyr and Trp.
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Light-driven ultrafast dual C–C cleavage and coupling of dihydroxyacetone into high-purity carbon monoxide and ethylene glycol

Green Chem., 2024, 26,10859-10866
DOI: 10.1039/D4GC04180A, Paper
Fanhao Kong, Hongru Zhou, Zhiwei Chen, Zhaolin Dou, Min Wang
Reforming of biomass-based dihydroxyacetone to produce high-purity CO and ethylene glycol is achieved via a distinctive photochemical process under ambient conditions.
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Evaluation on the recovery of lignin from basic [Ch][Lys] systems using low-cost alcohols as anti-solvents under acid-free conditions

Green Chem., 2024, 26,10950-10959
DOI: 10.1039/D4GC03898C, Paper
Yichen Liu, Wanting Zhao, Qizhen Luo, Jipeng Yan, Jian Sun
An acid-free, high efficiency, and mild method of precipitating and separating lignin from basic ionic liquids (BIL) such as choline lysinate ([Ch][Lys]) by using alchohols (such as tert-butanol) as anti--solvents.
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Straightforward solid-phase modification of TiO2 with propylphosphonic acid via manual grinding and shaker mixing: enhancing modification degree by thermal control while improving atom economy

Green Chem., 2024, 26,10907-10920
DOI: 10.1039/D4GC03330B, Paper
Open Access
Kaimin Zhang, Jinxin Wang, Nick Gys, Elien Derveaux, Nahal Ghanemnia, Wouter Marchal, Peter Adriaensens, Vera Meynen
The straightforward manual grinding method achieves controllable grafting of organophosphonic acid onto TiO2, demonstrating its atom economy and greenness.
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Research progress on photocatalytic, electrocatalytic and photoelectrocatalytic selective oxidation of 5-hydroxymethylfurfural

Green Chem., 2024, 26,10739-10773
DOI: 10.1039/D4GC03597F, Critical Review
Yang An, Tao Lei, Weiyi Jiang, Huan Pang
This paper summarizes the latest research progress in selective photocatalytic, electrocatalytic, and photoelectrocatalytic oxidation of HMF, along with the reaction mechanisms, advantages, and challenges faced during selective HMF oxidation.
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Synthesis of axially chiral thiourea by NHC-catalyzed desymmetrizative amidation

Green Chem., 2024, 26,10940-10949
DOI: 10.1039/D4GC03113J, Paper
Yingtao Wu, Xin Guan, Kehan Jiao, Huaqiu Zhao, Mingrui Li, Jiaqiong Sun, Guangfan Zheng, Qian Zhang
NHC-catalyzed desymmetrization amidation of biaryl dialdehydes has been developed for NH-free axially chiral thiourea. Sequential kinetic resolution enhances the chirality induction of the desymmetrization strategy, expanding the applicable scope.
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Lipase-entrapped colloidosomes with light-responsive wettability for efficient and recyclable Pickering interfacial biocatalysis

Green Chem., 2024, 26,10824-10828
DOI: 10.1039/D4GC03982C, Communication
Dingyi Yang, Qi Zeng, Kaiwen Tan, Haoyue Hou, Xingyuan Fang, Chenlong Guo, Hao Yuan, Tao Meng
We prepared lipase-entrapped TiO2 colloidosomes with excellent recyclability for light-responsive Pickering interfacial biocatalysis, providing a green, recyclable and efficient Pickering interfacial biocatalysis platform.
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Metal-free photoinduced-radical hydrocyclization of 2-isocyanides: a unified synthetic approach to facilely assemble diverse N-heteroarenes

Green Chem., 2024, 26,10804-10810
DOI: 10.1039/D4GC03774J, Communication
Ziyi Wang, Haonan Wei, Jinrong Du, Zhijun Zuo
We present an efficient and sustainable protocol for the photoinduced-radical hydrocyclization of isocyanides, providing a united route to assemble diverse α-unsubstituted N-heteroarenes.
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Electrochemistry-enabled Rh-catalyzed regioselective [4 + 1] and [4 + 2] cycloaddition of benzoic acid with alkynyl esters/amides

Green Chem., 2024, 26,10996-11002
DOI: 10.1039/D4GC03753G, Paper
Wei-Jung Chiu, Chung-Ming Sun
The reaction of benzoic acids with alkynyl esters/amides in the presence of a Rh-catalyst and AcOH as an additive to give phthalides by [4 + 1] annulation. In contrast, the additive NaOAc exclusively affords isocoumarins through the [4 + 2] pathway.
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Electroreductive deuteration of N-propynylamides to enamides

Green Chem., 2024, 26,10975-10981
DOI: 10.1039/D4GC03790A, Paper
Qiansong Gao, Mingchun Wang, Lianyou Zheng, Lingling Shi, Cheng Wu, He Li, Jinbao Xiang
A migratory reductive deuteration of terminal alkynes to access enamides with more than 3 deuteriums incorporated per molecule was realized.
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Light-induced isomerization of quinoline-N-oxide derivatives through Zn-catalysis: a photochemical approach for synthesizing 2-quinolinone derivatives

Green Chem., 2024, 26,10818-10823
DOI: 10.1039/D4GC03226H, Communication
Xiaoqiang Yu, Sana Yang, Ning Yan, Yukang Fu, Yang Li, Wanhui Wang, Ming Bao
The light-induced Zn-catalyzed isomerization of quinoline-N-oxides proceeded smoothly to afford 2-quinolinone derivatives via intramolecular hydrogen and oxygen transfer.
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Controllable tertiary amine-promoted photoactivation metal-free carbonylation of aryl sulfonium salts to aryl carboxylic acid derivatives

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04502E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jiajun Zhang, Le-Cheng Wang, Yuanrui Wang, Xiao-Feng Wu
This paper describes a new method for the activation of aryl radicals via EDA complexes without metals and photosensitizers for carbonylation with various nucleophilic reagents under visible light.
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Flow electrosynthesis of phosphinamides and phosphoramidates through P–N coupling

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04450A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tribani Boruah, Ren Ishizeki, Alberto Roldan, Rebecca L. Melen, Thomas Wirth
A robust flow electrochemical method for P–N and P–O oxidative coupling under mild conditions has been developed. Cyclic voltammetry (CV) was employed to investigate the redox behaviour of reactants.
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Continuous-flow Synthesis of Cyclic Carbonates with Polymer-supported Imidazolium-based Ionic Liquid (Im-PSIL) Catalysts

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04499A, Communication
Open Access
Zhibo Yu, Haruro Ishitani, Shu Kobayashi
Carbon dioxide (CO2), a major greenhouse gas emitted through human activities, represents a valuable carbon source for chemical production. However, maximizing its efficiency requires novel methods for CO2 conversion that...
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Green synthesis of N-sulfonyl amidine using a CuI-incorporated CoFe2O4 nano-catalyst in aqueous medium

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04033C, Paper
Samrat Charaimuria, Prodeep Phukan
A magnetically separable nanocatalyst has been developed by the incorporation of CuI on the functionalized surface of cobalt ferrite nanoparticles for the synthesis of N-sulfonyl amidines in aqueous medium at ambient temperature.
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Single-layer 2D supramolecular-organic-framework-supported polyoxometalates: efficient selective oxidation of toluene in seawater under sunlight

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04480K, Paper
Xin-Long Ni, Yan Fan, Yi Luo, Xu Luo
Performing organic reactions in water, in particular in seawater under sunlight, is a desirable objective in chemistry because both are the most abundant and cheapest resources on earth. Herein, we...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Green dipolar aprotic solvents for the dynamic polycondensation of high-performance polyimide membranes

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04279D, Paper
Open Access
E. San José, M. R. de la Viuda, F. J. Carmona, C. Soto, L. Palacio, P. Prádanos, A. Hernández, A. Tena
Guidelines for the evaluation of green solvents were revisited and integrated into a decision diagram. GVL, Cyrene™, DMC, NOP, DEC, DMI, GBL, NBP, Rhodiasolv® PolarClean, and DMSO showed the potential to substitute hazardous polar aprotic solvents.
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(B,P,Co,Fe)-Ni Modified on Nanowood for Boosting Seawater Urea Electro-Oxidation

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC05156D, Paper
Hongjiao Chen, Kewei Zhang, Yanzhi Xia, Jian Li, Bin Hui
Coupling urea oxidation reaction (UOR) and hydrogen evolution reaction (HER) in seawater is desirable to produce sustainable and green hydrogen due to the reduced energy consumption. However, developing high-performance UOR/HER...
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Toward safer and more sustainable by design biocatalytic amide-bond coupling

Green Chem., 2024, 26,11147-11163
DOI: 10.1039/D4GC03665D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Elisabeth Söderberg, Kerstin von Borries, Ulf Norinder, Mark Petchey, Ganapathy Ranjani, Swapnil Chavan, Hanna Holmquist, Magnus Johansson, Ian Cotgreave, Martin A. Hayes, Peter Fantke, Per-Olof Syrén
We describe an exploratory approach to a concept of safer and more sustainable by design in biocatalytic amide bond synthesis.
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Scaling up clean production of biomass-derived organic acids as a step towards the realization of dual carbon goals: a review

Green Chem., 2024, 26,11061-11082
DOI: 10.1039/D4GC03829K, Tutorial Review
Zulfiqar Ali, Jiliang Ma, Runcang Sun
Biomass-derived organic acid for green and sustainable future.
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A spatially integrated electrochemical–thermal tandem reaction for continuous mild synthesis of propylene oxide

Green Chem., 2024, 26,11206-11215
DOI: 10.1039/D4GC03455D, Paper
Yuefeng Qiu, Peng Jiang, Wenkai Ye, Jiahao Hu, Bin Zhang, Tuo Ji, Liwen Mu, Xin Feng, Xiaohua Lu, Jiahua Zhu
A spatially integrated electrochemical–thermal tandem reaction generates propylene oxide at 1 atm using hydrogen, oxygen, and propylene as feedstock.
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Photocatalytic acylation of lysine screened using a microfluidic-based chemical robotic system

Green Chem., 2024, 26,11238-11248
DOI: 10.1039/D4GC03562C, Paper
Zhanfeng Hou, Chuan Wan, Heming Jiang, Yuena Wang, Yun Xing, Jinpeng Wang, Zhihong Liu, Xiaochun Guo, Yuhao An, Wei Han, Rui Wang, Xinhao Zhang, Feng Yin, Zigang Li
In our work, we contribute to the photoredox catalytic lysine acylation in proteins and peptides. The optimal reaction conditions were obtained using a high-throughput microfluidic-based chemical robotic system and GPR model.
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Thermodynamically stable synthesis of high entropy alloys and efficiently catalyzed oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid under base-free conditions

Green Chem., 2024, 26,11316-11327
DOI: 10.1039/D4GC04186K, Paper
Guangqiang Lv, Shan Liu, Xiaoyan Chen, Mengxin Chen, Yanjuan Wu, Yuji Gao, Shuai Wang, Furong Tao, Jingui Wang, Liwei Niu
In a completely non-alkaline aqueous system, a high-entropy alloy catalyst composed of FeCoNiCuGaPt activates O2 and H2O molecules to form hydroxyl radicals (˙OH) and efficiently oxidizes 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid.
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A paired alkaline electrolyzer for furfural oxidation and hydrogen evolution over noble metal-free NiFe/Ni and Co/MXene catalysts

Green Chem., 2024, 26,11351-11363
DOI: 10.1039/D4GC04447A, Paper
Open Access
Xiaopeng Liu, Mohammad Albloushi, Michael Galvin, Connor W. Schroeder, Yue Wu, Wenzhen Li
A paired alkaline electrolyzer with non-noble metal catalysts was developed, demonstrating higher performances of furfural oxidation on NiFe/Ni foam at the anode and hydrogen evolution on Co/MXene at the cathode under practical current densities.
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Recent advances in N-formylation reaction for the chemical recycling of carbon dioxide

Green Chem., 2024, 26,11106-11124
DOI: 10.1039/D4GC04094E, Tutorial Review
Qiang Yuan, Xiao Cai, Weiping Ding, Yan Zhu
The homogeneous and heterogeneous catalyst systems applied in N-formylation reaction of amines and CO2 reaction from both homogeneous and heterogeneous systems are summarized.
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Augmentation of Pd-catalysed oxidative C–H/C–H carbonylation through alternating current electrosynthesis

Green Chem., 2024, 26,11177-11181
DOI: 10.1039/D4GC04569F, Paper
Haoran Li, Jiaqi Peng, Li Zeng, Linpu Zhou, Muhammad Shabbir, Feiran Xiao, Jiaxin Yuan, Hong Yi, Aiwen Lei
Unsymmetrical-waveform AC electrolysis facilitates Pd-catalysed oxidative C–H/C–H carbonylation. This methodology highlights the substantial benefits conferred by Pd-catalysed conversions in comparison to traditional DC electrolysis.
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Formaldehyde dehydrogenase SzFaldDH: an indispensable bridge for relaying CO2 bioactivation and conversion

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC03745F, Communication
Boxia Guo, Xiuling Ji, Yaju Xue, Yuhong Huang
A novel formaldehyde dehydrogenase with outstanding reductive activity and kinetic properties was discovered for CO2 bioactivation and conversion.
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CdS/Mg–Fe layered double hydroxide: a versatile heterogeneous photocatalyst for the acylation of indoles with α-keto acids

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC05239K, Paper
Jun-Bo Wang, Tong Yue, Ling Xu, Zhi-Qiang Hao, Zhan-Hui Zhang
The composite CdS/Mg–Fe layered double hydroxide was constructed and confirmed as an efficient recyclable heterogeneous photocatalyst for C-3 acylation of indoles with α-keto acids under light irradiation at room temperature.
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Bio-derived solvent-based automated dispersive liquid–liquid microextraction for pretreatment of diamide insecticides in environmental water samples

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04467C, Paper
Jin Liu, Yuxin Wang, Rui Song, Yukun Yang, Li Li, Xu Jing
The automatic dispersive liquid–liquid microextraction based on bio-derived solvents achieved great environmental greenness, high-throughput operation, and low human error compared to the present sample pretreatment methods for diamide insecticides.
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Ball milling-promoting difunctionalization of alkynyl sulfonium salts with sulfinic acids towards (Z)-1,2-disulfonylethenes

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04895D, Paper
Li-Hua Yang, Bei Li, Lin Chen, Wen-Shi Yao, Han-Yue Peng, Sha Peng, Long-Yong Xie
A simple ball milling-mediated disulfonylation of alkynyl sulfonium salts with sulfinic acids for the stereoselective synthesis of various (Z)-1,2-disulfonylethenes has been developed under catalyst-, additive- and solvent-free conditions.
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EtOH-mediated cascade C(sp3)–H alkylation via aromatization-driven [1,6]-hydride transfer: green and divergent synthesis of spirocyclic azepino[4,3,2-cd]indoles

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04534C, Paper
Yao-Bin Shen, Qian-Hao Zhuang, Xiao-Lin Wang, Xiao-De An, Bin Qiu, Tiesheng Shi, Jian Xiao
Unprecedented EtOH-mediated cascade C(sp3)–H alkylation reactions of 4-dialkylamino-indole-3-carbaldehydes have been realized for the green and divergent synthesis of spirocyclic azepino[4,3,2-cd]indole derivatives.
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Comparison of microbial strains as candidate hosts and genetic reservoirs for the valorization of lignin streams

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC03876B, Paper
Open Access
Rebecca A. Wilkes, Andrew J. Borchert, Valentina E. Garcia, Gina M. Geiselman, Sarah Liu, Adam M. Guss, Joshua K. Michener, Daniel R. Noguera, Eiji Masai, John M. Gladden, John Ralph, Gregg T. Beckham
Comparison of microbial strains for tolerance to and catabolism of lignin stream constituents toward evaluating microbial hosts for lignin bioconversion.
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High-efficient green catalytic conversion for waste CS2 by non-noble metal cage-based MOFs: An access to high-valued thiazolidine-2-thione

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04541F, Paper
Wenyu Ding, Xinyu Tang, Sheng Jin, Zhao Li, Dongwei Xu, Xiaomin Kang, Zhiliang Liu
Green and effective disposal of Carbon disulfide (CS2) waste into high-valued chemicals under mild conditions is meaningful and challenging. Herein, a novel 3D cluster-based metal-organic framework (MOF) {(Me2NH2)2[Co3(µ3-O)(XN)(BDC)3]∙4DMF∙5MeOH}n (compound 1)...
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Idhayakkani (1975)

Star Cast: M.G. Ramachandran, Radha Saluja, Rajasulochana, R.S. Manohar, Pandari Bai, S.V. Ramadas, ‘Vennira Aadai’ Nirmala, V. Gopalakrishnan, V.S. Raghavan, ‘Thengai’ Srinivasan, ‘Isari’ Velan, ‘Kavartchi Villain’ K. Kannan, Rathna, S. Leela S.V. Subbaiah, Vishwaprasad Kanakadurga




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Is Thursday the new Friday?

A look at films being released a day earlier than usual




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Royal Challengers ride on Kohli’s brilliance

Gayle and de Villiers too join the party in making Kolkata Knight Riders's challenging total seem small




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Raina returns as Lions hope to roar against Knight Riders

Half of Gujarat Lions worries will be taken care of if the dazzling opening combo of Dwayne Smith and Brendon McCullum fires.



  • Indian Premier League

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Skipper Raina guides Lions ‘home’

Dwayne Smith’s stingy spell restricts Kolkata Knight Riders to its lowest score of this season.



  • Indian Premier League

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Nair's confidence earns Delhi 6-wicket win

And Delhi Daredevils stay afloat to fight another day, after Karun Nair held his own on a day of hot and cold fielding, after Sunrisers set them 158.



  • Indian Premier League

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Pune vs Punjab: Cellar-dwellers battle to avoid wooden spoon



  • Indian Premier League

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It’s win or go home for Knight Riders



  • Indian Premier League

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Kolkata Knight Riders books play-offs berth



  • Indian Premier League

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Can Sunrisers tame the marauding Knight Riders?

Injuries to key players a concern for both teams; the winner will meet the loser of Qualifier 1 for a place in the final



  • Indian Premier League

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Sunrisers eliminate Knight Riders

Bowlers do the trick once again for the Hyderabad team, setting up a meeting with Lions



  • Indian Premier League

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The rise and rise of David Warner



  • Indian Premier League