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Highly efficient exciplex-based OLEDs incorporating a novel electron donor

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Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00116C, Research Article
Qi-Sheng Tian, Xiang-Dong Zhu, Liang-Sheng Liao
A high performance green exciplex OLED comprising a novel electron donor DEX with an acceptor PO-T2T can reach an EQEmax of 11.2%, and a red phosphorescent OLED incorporating the green exciplex forming co-host achieves an EQEmax of 24.5%.
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Near-infrared electron acceptors with fused nonacyclic molecular backbones for nonfullerene organic solar cells

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Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QM00754G, Research Article
Jianquan Zhang, Yunke Li, Zhengxing Peng, Fujin Bai, Lik-Kuen Ma, Harald Ade, Zhengke Li, He Yan
Two strong electron-donating moieties were fused into the molecular backbone of small molecular acceptors showing dramatically extended absorption beyond 900 nm.
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Efficient near-infrared photosensitizer with aggregation-induced emission characteristics for mitochondria-targeted and image-guided photodynamic cancer therapy

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Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00170H, Research Article
Hanxiao Yang, Jiabao Zhuang, Nan Li, Yue Li, Shiyu Zhu, Jiaxin Hao, Jiayao Xin, Na Zhao
A highly efficient near-infrared photosensitizer with aggregation-induced emission characteristics was developed for mitochondria-targeted and image-guided photodynamic cancer therapy.
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Oxygen Vacancy Induced Superior Visible-light-driven Photo-catalytic Performance in BiOCl Homojunction

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Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00187B, Research Article
Si-Ying Niu, Ruoyu Zhang, Chongfeng Guo
The photocatalytic performance of semiconductor can be enhanced by expanding the spectral response and accelerating the photo-induced charge separation. Introduction of oxygen vacancies and construction of homo-junction in BiOCl were...
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Each phenyl group performs its own functions on luminescence: phenyl substituted effect in tetraphenylpyrazine

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Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00098A, Research Article
Haozhong Wu, Xiaojuan Song, Bing Zhang, Zhiming Wang, Tian Zhang, Anjun Qin, Ben Zhong Tang
Three phenyl groups of TPP derivatives affect the luminescence process in various modes. TPPs show AIE thanks to the ortho substituted groups, while meta and para groups can modulate their luminescence in different extents.
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Lithium bis(oxalate)borate additive in electrolyte to improve Li-rich layered oxide cathode materials

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Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00094A, Research Article
Zi Xiao, Jiuding Liu, Guilan Fan, Meng Yu, Junxiang Liu, Xinglong Gou, Mingjian Yuan, Fangyi Cheng
Lithium-rich layered oxides (LLO), as the most attractive cathode materials for high-energy lithium-ion batteries (LIBs), are plagued by poor cyclability due to structural and electrode/electrolyte interface instability. Herein, we report...
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Single-crystalline CoFe nanoparticles encapsulated in N-doped carbon nanotubes as a bifunctional catalyst for water splitting

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Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00126K, Research Article
Xiaojun Zeng, Myeong Je Jang, Sung Mook Choi, Hyun-Seok Cho, Chang-Hee Kim, Nosang Vincent Myung, Yadong Yin
We utilize a simple heat-treatment process to synthesize single-crystalline CoFe alloy nanoparticles encapsulated in N-doped carbon nanotubes, which exhibit excellent catalytic activity and superior stability towards overall water splitting.
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Electrical stability study of polymer-based organic transistors in ambient air using an active semiconducting/insulating polyblend-based pseudo-bilayer

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Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00048E, Research Article
Bo-Ren Lin, Horng-Long Cheng, Hung-Han Lin, Fu-Chiao Wu, Jia-Hui Lin, Wei-Yang Chou, Jrjeng Ruan, Yu-Wu Wang
Polymeric transistors with unexpected nondecaying features even in ambient air are fabricated based on a P3HT/PMMA pseudo-bilayer with microphase separation morphology.
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Polydopamine sacrificial layer mediated SiOx/C@C yolk@shell structure for durable lithium storage

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Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00120A, Research Article
Yuanyuan Zhang, Guangwu Hu, Qiang Yu, Zhenhui Liu, Chang Yu, Longsheng Wu, Liang Zhou, Liqiang Mai
Yolk@shell structured SiOx/C@C has been constructed through a polydopamine sacrificial layer mediated strategy, and the SiOx/C@C displays high specific capacity and durable cyclability in lithium storage.
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Aromatic imide/amide-based organic small-molecule emitters for organic light-emitting diodes

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Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00084A, Review Article
Yuanyuan Qin, Guoping Li, Ting Qi, Hui Huang
Aromatic imide/amide-based organic small molecules as emitters in organic light-emitting diodes have caught increasing attention. This study summarized their advances in terms of device performance and molecular design rules over the past 20 years.
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Multicationic AIEgens for unimolecular photodynamic theranostics and two-photon fluorescence bioimaging

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Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00119H, Research Article
Yuting Gao, Haoke Zhang, Zhenyan He, Fang Fang, Chao Wang, Kanghua Zeng, Shangbang Gao, Fanling Meng, Liang Luo, Ben Zhong Tang
This work reports multicationic AIEgens for unimolecular photodynamic theranostics, and an investigation of the relationship between their structures and activities, including PDT performance, 2-photon bioimaging, and self-reporting characteristics.
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AIEgen based polymorphs with solvent regulated crystal-to-crystal switch properties

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Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00154F, Research Article
Liming Lai, Bing Fang, Wenyu Cheng, Pengyu Li, Yantu Zhang, Meizhen Yin
An AIEgen with tunable polymorphism-dependent emission and solvent regulated crystal-to-crystal switch properties is reported. Our study has provided insight into the relationship between molecular stacking and emission properties.
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One-pot quaternization of dual-responsive poly(vinyl alcohol) with AIEgens for pH-switchable imaging and killing of bacteria

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Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00014K, Research Article
Jin Wang, Meng Gao, Zhong-Kai Cui, Yong-Guang Jia, Sa Liu, Kai-Feng Chen, Xiaohui Chen, Yiqing Zhang, Zhou Fang, Yunhua Chen, Kaojin Wang, Huatang Zhang, Lin Wang, Li Ren
Dual-responsive poly(vinyl alcohol) derivatives bearing AIEgens and quaternary ammonium moieties were prepared through a facile one-pot quaternization for the pH-switchable imaging and killing of bacteria.
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Fluoro-alkyl substituted isothianaphthene bisimides as stable n-type semiconductors

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Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00137F, Research Article
Xiaolong Chen, Dongwei Zhang, Yaowu He, Muhammad Umair Ali, Yuting Wu, Changbin Zhao, Peiheng Wu, Chaoyi Yan, Fred Wudl, Hong Meng
Two fluoro-alkyl substituted isothianaphthene bisimide materials with high solubility and their applications in stable n-type OTFTs are demonstrated.
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Novel cathode buffer layer of Al(acac)3 enables efficient, large area and stable semi-transparent organic solar cells

By pubs.rsc.org
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Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00198H, Research Article
Yiming Bai, Chunyan Zhao, Rongkang Shi, Jun Wang, Fuzhi Wang, Tasawar Hayat, Ahmed Alsaedi, Zhan'ao Tan
Electrode buffer layer plays a more crucial in semi-transparent organic solar cells (ST-OSCs) than that of the opaque devices due to the additional requirements of the average visible transmittance (AVT)...
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Boosting the piezocatalytic performance towards degradation of organic pollutant of Bi2WO6 nanosheets

By pubs.rsc.org
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Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00179A, Research Article
Aize Hao, Xueer Ning, Yali Cao, Jing Xie, Dianzen Jia
The novel piezocatalyst of Bi2WO6 nanosheets (BWO NS) are successfully synthesized by a simple, green and harmless solid-state chemistry method. The BWO NS present excellent piezocatalytic activity in contrast with...
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Zeolite-confined carbon dots: tuning thermally activated delayed fluorescence emission via energy transfer

By pubs.rsc.org
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Mater. Chem. Front., 2020, 4,1404-1410
DOI: 10.1039/C9QM00549H, Research Article
Hongyue Zhang, Jiancong Liu, Bolun Wang, Kaikai Liu, Guangrui Chen, Xiaowei Yu, Jiyang Li, Jihong Yu
CD@zeolite composites with tunable TADF emission via an energy transfer process between confined CDs.
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The application of hollow micro-/nanostructured cathodes for sodium-ion batteries

By pubs.rsc.org
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Mater. Chem. Front., 2020, 4,1289-1303
DOI: 10.1039/C9QM00674E, Chemistry Frontiers
Xiao-Hao Liu, Wei-Hong Lai, Shu-Lei Chou
This work will open a new view for the design of hollow micro-/nanostructures used as cathodes for sodium-ion batteries, enclosing the superiority of this unique structure to enhance the electrochemical performance.
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Non-equilibrium kinetics and trajectory thermodynamics of synthetic molecular pumps

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Mater. Chem. Front., 2020, 4,1304-1314
DOI: 10.1039/D0QM00022A, Review Article
R. Dean Astumian, Cristian Pezzato, Yuanning Feng, Yunyan Qiu, Paul R. McGonigal, Chuyang Cheng, J. Fraser Stoddart
Hypothetical transmembrane rotaxane as a model for trajectory thermodynamic theory of synthetic molecular pumps.
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The origin of the unusual red-shifted aggregation-state emission of triphenylamine-imidazole molecules: excimers or a photochemical reaction?

By pubs.rsc.org
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Mater. Chem. Front., 2020, 4,1411-1420
DOI: 10.1039/C9QM00737G, Research Article
Jin Liu, Jianai Chen, Yujie Dong, Yue Yu, Shitong Zhang, Jianli Wang, Qingbao Song, Weijun Li, Cheng Zhang
Revealing the actual origin of the unusual red-shifted aggregation-state emission of triphenylamine-imidazole molecules: is the photochemical reaction rather than the excimers.
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NH4V3O8·0.5H2O nanobelts with intercalated water molecules as a high performance zinc ion battery cathode

By pubs.rsc.org
Published On ::

Mater. Chem. Front., 2020, 4,1434-1443
DOI: 10.1039/D0QM00051E, Research Article
Hanmei Jiang, Yifu Zhang, Zhenghui Pan, Lei Xu, Jiqi Zheng, Zhanming Gao, Tao Hu, Changgong Meng, John Wang
NH4V3O8·0.5H2O nanobelts are synthesized by a low-temperature hydrothermal process, and exhibit high electrochemical performance in ARZIBs.
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The power of dissociation: development of displacement assays for chemosensing and latent catalytic systems

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Mater. Chem. Front., 2020, 4,1328-1339
DOI: 10.1039/C9QM00639G, Review Article
Cheuk-Fai Chow, Anxun Zheng, Min Huang, Chang Shen
Disassembly is an essential process in supramolecular chemistry. In this review, different bimetallic donor–acceptor-based chemosensors, chemodosimeters, catalysts and latent catalysts founded on various displacement assays will be discussed.
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Modulation of ligand conjugation for efficient FAPbBr3 based green light-emitting diodes

By pubs.rsc.org
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Mater. Chem. Front., 2020, 4,1383-1389
DOI: 10.1039/C9QM00768G, Research Article
Feng Zhang, Mengna Sun, Xiyu Luo, Dongdong Zhang, Lian Duan
We put forward a new strategy for efficient PeLEDs by understanding the effect of ligand conjugation on device performance.
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AIE-active Schiff base compounds as fluorescent probes for the highly sensitive and selective detection of Fe3+ ions

By pubs.rsc.org
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Mater. Chem. Front., 2020, 4,1471-1482
DOI: 10.1039/C9QM00792J, Research Article
Jonnagaddala Harathi, Kathavarayan Thenmozhi
AIE-active Schiff base compounds were synthesized and photophysical properties were investigated. The compounds exhibited prominent sensing behaviour towards Fe3+ ion with enhanced selectivity, high association constants and low detection limits.
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Multifunctional ultrasmall-MoS2/graphene composites for high sulfur loading Li–S batteries

By pubs.rsc.org
Published On ::

Mater. Chem. Front., 2020, 4,1483-1491
DOI: 10.1039/D0QM00082E, Research Article
Tianyu Tang, Teng Zhang, Lina Zhao, Biao Zhang, Wei Li, Junjie Xu, Long Zhang, Hailong Qiu, Yanglong Hou
The utilization of hosts with uniform dispersion of sulfur and multifunctional parts which can interact strongly with polysulfides facilitates the improved performance of Li–S batteries.
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Dual-doping of ruthenium and nickel into Co3O4 for improving the oxygen evolution activity

By pubs.rsc.org
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Mater. Chem. Front., 2020, 4,1390-1396
DOI: 10.1039/D0QM00079E, Research Article
Beibei Guo, Ruguang Ma, Zichuang Li, Jun Luo, Minghui Yang, Jiacheng Wang
Ru and Ni co-doped Co3O4 with improved OER activity were synthesized by a one-step hydrothermal method. Ru doping increases the intrinsic activity, while Ni doping creates more oxygen vacancies and exposes more active sites.
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Fused-ring phenazine building blocks for efficient copolymer donors

By pubs.rsc.org
Published On ::

Mater. Chem. Front., 2020, 4,1454-1458
DOI: 10.1039/D0QM00080A, Research Article
Wenting Li, Qishi Liu, Ke Jin, Ming Cheng, Feng Hao, Wu-Qiang Wu, Shengjian Liu, Zuo Xiao, Shangfeng Yang, Shengwei Shi, Liming Ding
Phenazine copolymer donors demonstrate an efficiency of 15.14% in nonfullerene organic solar cells.
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Sandwich structured dielectrics for air-stable and flexible low-voltage organic transistors in ultrasensitive pressure sensing

By pubs.rsc.org
Published On ::

Mater. Chem. Front., 2020, 4,1459-1470
DOI: 10.1039/D0QM00062K, Research Article
Yue Jiang, Ziyang Liu, Zhigang Yin, Qingdong Zheng
A novel type of polymer sandwich dielectric is developed for air-stable, hysteresis-free and flexible OTFTs which can be used for low-power pressure sensors with ultrahigh sensitivity, wide detection range and fast response.
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A turn-off fluorescent probe for the detection of Cu2+ based on a tetraphenylethylene-functionalized salicylaldehyde Schiff-base

By pubs.rsc.org
Published On ::

Mater. Chem. Front., 2020, 4,1500-1506
DOI: 10.1039/C9QM00759H, Research Article
Hai-Fang Xie, Chang-Jin Yu, Ya-Li Huang, Hong Xu, Qi-Long Zhang, Xiao-Hong Sun, Xing Feng, Carl Redshaw
A tetraphenylethylene-functionalized salicylaldehyde Schiff-base fluorescent probe (TPE-An-Py) with aggregation-induced enhanced emission (AIEE) characteristics exhibited high sensitivity towards copper(II) ions in aqueous media with a “turn-off” fluorescence mechanism; limit of detection is 2.36 × 10−7 mol L−1.
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Multiring-induced multicolour emission: hyperbranched polysiloxane with silicon bridge for data encryption

By pubs.rsc.org
Published On ::

Mater. Chem. Front., 2020, 4,1375-1382
DOI: 10.1039/D0QM00075B, Research Article
Yuanbo Feng, Hongxia Yan, Fan Ding, Tian Bai, Yufeng Nie, Yan Zhao, Weixu Feng, Ben Zhong Tang
The presented work shows an impressive multicolour luminescence hyperbranched polysiloxane attributed to the multiring through-space conjugation named “multiring induced multicolor emission” (MIE), as well as its application in data encryption.
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The role of dipole moment in two fused-ring electron acceptor and one polymer donor based ternary organic solar cells

By pubs.rsc.org
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Mater. Chem. Front., 2020, 4,1507-1518
DOI: 10.1039/D0QM00016G, Research Article
Xunfan Liao, Yongjie Cui, Xueliang Shi, Zhaoyang Yao, Heng Zhao, Yongkang An, Peipei Zhu, Yaxiao Guo, Xiang Fei, Lijian Zuo, Ke Gao, Francis Lin, Qian Xie, Lie Chen, Wei Ma, Yiwang Chen, Alex K.-Y. Jen
The dipole moment of FREAs’ terminals has been unveiled as an important factor and its working mechanism has been thoroughly investigated. Our results demonstrate that the dipole moment should also be taken into account in designing ternary OSCs.
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The pressing-induced formation of a large-area supramolecular film for oil capture

By pubs.rsc.org
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Mater. Chem. Front., 2020, 4,1530-1539
DOI: 10.1039/D0QM00006J, Research Article
Wenkai Wang, Mengqi Xie, Hongjun Jin, Wanwan Zhi, Kaerdun Liu, Cheng Ma, Peilong Liao, Jianbin Huang, Yun Yan
A rejuvenable large-area polyelectrolyte–surfactant supramolecular film formed by applying pressure can be used in a recyclable manner to rapidly capture spilled oil.
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Design and construction of bi-metal MOF-derived yolk–shell Ni2P/ZnP2 hollow microspheres for efficient electrocatalytic oxygen evolution

By pubs.rsc.org
Published On ::

Mater. Chem. Front., 2020, 4,1366-1374
DOI: 10.1039/D0QM00128G, Research Article
Jinyang Zhang, Xuan Sun, Yang Liu, Linrui Hou, Changzhou Yuan
Hierarchical yolk–shell Ni2P/ZnP2 hollow microspheres are smartly synthesized, and exhibit exceptional OER performance, benefiting from their unique compositional/structural merits.
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Highly-selective synthesis of trimetallic PtRuCu nanoframes as robust catalysts for the methanol oxidation reaction

By pubs.rsc.org
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Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00033G, Research Article
Hai-Jing Yin, Zhi-Ping Zhang, Yu Guo, Kun Yuan, Ya-Wen Zhang
PtRuCu NFs/C exhibited much higher mass activity and specific activity than commercial Pt/C and PtRuCu NPs/C towards the MOR due to the frame nanostructures and the synergistic effect of the trimetallics.
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Optical nonlinearity of Zeolitic Imidazolate Framework-67 in the near-infrared region

By pubs.rsc.org
Published On ::

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00226G, Research Article
Han Pan, Hongwei Chu, Xiao Wang, Ying Li, Shengzhi Zhao, Guiqiu Li, Dechun Li
In this paper, we report the large optical nonlinearities of Zeolitic Imidazolate Framework-67 (ZIF-67) in the near-infrared (NIR) region. Typical Z-scan techniques were carried out to determine the nonlinear optical...
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Opportunities and critical factors of porous metal-organic frameworks for the industrial separation of light olefins

By pubs.rsc.org
Published On ::

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00186D, Review Article
Tianhao Lan, Libo Li, Yang Chen, Xiaoqing Wang, Jiangfeng Yang, Jinping Li
Light olefins (ethylene, propylene, and 1,3-butadiene) are widely used as building blocks in the petrochemical industry and for the fabrication of everyday products. Developing energy cost-efficient porous materials for the...
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Tread and Other Stories—Barry Dempster

By tightropebooks.com
Published On :: Mon, 13 Aug 2018 14:03:11 +0000

ISBN: 9781988040424 Price: $21.95 Pub date: Fall 2018 Tread and Other Stories is a moving, unsettling, and ferociously humane collection of short fiction. The characters are achingly real: the moments at once gut-wrenchingly singular and utterly recognizable. There’s a satisfying range here—from a female prison guard with a yen for bad boys to a lost young man who [...]


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[ASAP] Amine <italic toggle="yes">N</italic>-Oxide Kinetic Hydrate Inhibitor Polymers for High-Salinity Applications

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Published On :: Fri, 24 Apr 2020 04:00:00 GMT

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00838


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[ASAP] Chemical Looping Gasification of Torrefied Biomass Using NiFe<sub>2</sub>O<sub>4</sub> as an Oxygen Carrier for Syngas Production and Tar Removal

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Published On :: Fri, 24 Apr 2020 04:00:00 GMT

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00584


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[ASAP] Influence of Carbon Dioxide on the Adsorption of Methane by Coal Using Low-Field Nuclear Magnetic Resonance

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Published On :: Fri, 24 Apr 2020 04:00:00 GMT

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00474


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[ASAP] Enhanced Performance of Adsorptive Removal of Thiophene from Model Fuel over Micro–Mesoporous Binderless ZSM-5 Prepared by <italic toggle="yes">In Situ</italic> Crystallization

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Published On :: Fri, 24 Apr 2020 04:00:00 GMT

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00198


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[ASAP] Superhydrophobic Surface Fabrication for Strengthened Selective Water Shut-off Technology

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Published On :: Fri, 24 Apr 2020 04:00:00 GMT

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00498


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[ASAP] Pore Systems of the Different Lithofacies of the Longmaxi Formation at Depths Exceeding 3500 m in the Zigong Area, Sichuan Basin

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Published On :: Sun, 26 Apr 2020 04:00:00 GMT

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00456


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[ASAP] Effects of Graphene Oxide on the Mechanical and Microscopic Characteristics of Cement-Based Plugging Material for Preventing Spontaneous Combustion of Coal

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Published On :: Sun, 26 Apr 2020 04:00:00 GMT

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00493


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[ASAP] Oxygen Uncoupling Property and Kinetics of a Copper Manganese Composite Oxygen Carrier in a Packed-Bed Reactor

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Published On :: Mon, 27 Apr 2020 04:00:00 GMT

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00574


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[ASAP] Adsorption Behavior of CH<sub>4</sub> and C<sub>2</sub>H<sub>6</sub> on Shale under the Influence of CO<sub>2</sub> and Flue Gas

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Published On :: Mon, 27 Apr 2020 04:00:00 GMT

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00339


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[ASAP] Pore Network Changes Due to Polymer Flooding: Hebron Field Case

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Published On :: Mon, 27 Apr 2020 04:00:00 GMT

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00487


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[ASAP] Designing Novel High-Performance Shale Inhibitors by Optimizing the Spacer Length of Imidazolium-Based Bola-Form Ionic Liquids

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Published On :: Mon, 27 Apr 2020 04:00:00 GMT

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00788


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[ASAP] Investigation of Mechanisms for Gravity Drainage of Heavy Oil and Solvent Mixtures in a Hele-Shaw Cell

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Published On :: Tue, 28 Apr 2020 04:00:00 GMT

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00599


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[ASAP] Zinc Nitrate as an Activation Agent for the Synthesis of Nitrogen-Doped Porous Carbon and Its Application in CO<sub>2</sub> Adsorption

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Published On :: Tue, 28 Apr 2020 04:00:00 GMT

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00305


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