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Webinar: Learning Together to Prevent Homelessness for Youth and Young Adults with Child Welfare Involvement




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Serving Medicaid Beneficiaries Who Need Long-Term Services and Supports: Better Outcomes at Lower Costs

In the past two decades, many federal and state Medicaid initiatives have been designed to rebalance the long-term services and supports (LTSS) system by increasing access to home and community-based services (HCBS) in order to reduce the use of expensive institutional care.




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Progress Together: Becoming Data Driven

Mathematica brought together leaders from a variety of sectors to discuss the challenges of becoming data driven and offer action-oriented, accessible advice on how organizations can take their first steps, or their next steps, to progress together.




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A Framework for Educational Equity and Culturally Responsive Pedagogy

This webinar defined educational inequity and discussed its implications. It included a brief introduction to culturally responsive pedagogy and what broader systemic changes may be necessary to implement equity and culturally responsive pedagogy.




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Research and Practice in Culturally Responsive Pedagogy and How to Sustain Systemic Changes

This webinar explored research on culturally responsive pedagogy and what is known about its effectiveness.




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Implementing District and School Policies and Practices to Support Culturally Responsive Pedagogy

This webinar explored how a school and district have approached the challenge of implementing culturally responsive practice. It elaborated on programs, policies, and practices that were implemented to support efforts to achieve equity and use culturally responsive pedagogy.




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Developing Culturally Responsive Educators in Pre-Service Programs

This webinar explored how best to prepare educators to implement culturally responsive pedagogy, including and exploration of how programs train future teachers and school administrators and what changes programs may need to consider to effectively prepare these educators.




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Innovations in Medicare ACOs’ Approaches to Care Delivery Improvement

Hear from ACOs about their approaches to improving care delivery, and from CMS about new policy opportunities.




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Join Us and Partners for a Grantmakers for Education Webinar—Making the Case: Establishing Evidence to Support Practitioners, Strategy, and Outcomes

Interested in learning how to build more evidence into philanthropic practice? Join Mathematica, The Wallace Foundation, and the Afterschool Alliance for a Grantmakers for Education webinar.




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Does School Choice Leave Anyone Behind?

At Mathematica, we’re uncovering evidence about the effects of school choice policies on nonparticipating students and schools. Learn more about our systematic review, which covers two decades of relevant research and evaluation.




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Evidence for Educators by Educators: New Approaches to Building Evidence for Continuous Improvement

Join us for a webinar for a discussion about the role of evidence in a continuous improvement process and how a free, online platform—the Evidence to Insights Coach—can help educators generate the evidence they need when they need it.




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Q-CCIIT: Measuring the Quality of Caregiver–Child Interactions: Free Webinar for Early Childhood Professionals

Mathematica will launch a groundbreaking new quality measurement observation tool, now available to the early childhood community (including program administrators, professional development providers, researchers, and others) during a webinar.




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Free Webinar: How States, Districts, and REL Mid-Atlantic Partner to Create New Diagnostic Measures Using Existing Data

This webinar highlights three research-to-practice partnerships between state and local policymakers and the Regional Educational Laboratory Mid-Atlantic to address this challenge, connecting educators and policymakers with researchers who provide analytic support and help education agencies build capacity to conduct their own analyses.




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Learning Remotely in the Age of COVID-19: Lessons from Evidence and Concerns for Equity

The spread of COVID-19 has caused schools and districts across the country to shutter their doors. States, districts, and schools must suddenly and unexpectedly grapple with the new reality of providing a quality education to every student remotely.




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Refining Your Remote Learning Strategies Using a Data-Driven Approach: The Evidence to Insights Coach

With school buildings closed by COVID-19, schools and districts across the country are rapidly (and sometimes frantically) transitioning to remote learning.




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Macrocyclization of 3-Triflyloxybenzynes with Tetrahydrofuran via Anionic Thia-Fries Rearrangement

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00135J, Communication
Chaorong Qi, Ruixiang Cheng, Wenfang Xiong, Lu Wang, Yanwei Ren, Huanfeng Jiang
A novel and uncommon macrocyclization reaction between 3-triflyloxybenzynes and tetrahydrofuran has been developed for the first time, providing a direct method for the synthesis of a range of functionalized 19-membered...
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A fentanyl vaccine constructed upon opsonizing antibodies specific for the Galα1-3Gal epitope

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02107E, Communication
Jiaxing Wang, Beverly A Ellis, Bin Zhou, Lisa M. Eubanks, Steven Blake, Kim D Janda
A double conjugation strategy was implemented to produce an anti-fentanyl vaccine, which was predicated upon preformed-antibody-assisted antigen presentation. The new vaccine was found to reduce the psychoactive effects of fentanyl...
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Photochemical α-carboxyalkylation of tryptophols and tryptamines via C–H functionalization

Chem. Commun., 2020, 56,4930-4933
DOI: 10.1039/D0CC00847H, Communication
Zhiqiang Pan, Yuchang Liu, Fengchi Hu, Qinglong Liu, Wenbin Shang, Chengfeng Xia
A process for the α-carboxyalkylation of tryptophols and tryptamines by the functionalization of C–H bonds under visible light irradiation has been developed.
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On-surface synthesis of planar acenes via regioselective aryl–aryl coupling

Chem. Commun., 2020, 56,4890-4893
DOI: 10.1039/D0CC01043J, Communication
Lin Feng, Tao Wang, Hongxing Jia, Jianmin Huang, Dong Han, Wenzhao Zhang, Honghe Ding, Qian Xu, Pingwu Du, Junfa Zhu
The reaction of 2,2'-dibromo-biphenyl (DBBP) on a Ag(111) surface leads to the generation of planar dibenzo[e,l]pyrene, in contrast to the nonplanar saddle-shaped tetraphenylene formed in solution.
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Noncovalent structural locking of thermoresponsive polyion complex micelles, nanowires, and vesicles via polymerization-induced electrostatic self-assembly using an arginine-like monomer

Chem. Commun., 2020, 56,4954-4957
DOI: 10.1039/D0CC00427H, Communication
Qingqing Zhao, Qizhou Liu, Chao Li, Lei Cao, Lei Ma, Xiyu Wang, Yuanli Cai
The noncovalent locking of nanostructured thermoresponsive polyion complexes can be achieved via polymerization-induced electrostatic self-assembly (PIESA) using an arginine-like cationic monomer.
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Synthesis of chiral α-substituted α-amino acid and amine derivatives through Ni-catalyzed asymmetric hydrogenation

Chem. Commun., 2020, 56,4934-4937
DOI: 10.1039/D0CC01220C, Communication
Gongyi Liu, Xianghe Zhang, Heng Wang, Hengjiang Cong, Xumu Zhang, Xiu-Qin Dong
Efficient Ni-catalyzed asymmetric hydrogenation of cyclic N-sulfonyl ketimino esters and ketimines was successfully developed to prepare a series of chiral α-monosubstituted α-amino acid derivatives and amine derivatives with excellent results.
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Structural elucidation of the degradation mechanism of nickel-rich layered cathodes during high-voltage cycling

Chem. Commun., 2020, 56,4886-4889
DOI: 10.1039/D0CC00327A, Communication
Open Access
Jing Lai, Jun Zhang, Zuowei Li, Yao Xiao, Weibo Hua, Zhenguo Wu, Yanxiao Chen, Yanjun Zhong, Wei Xiang, Xiaodong Guo
A splitting of two O3 phases, rather than the often observed O1 phases in the conventional LiCoO2 electrode, was discovered in the LiNi0.85Co0.10Mn0.05O2 at high-voltage region (>4.6 V) by in situ high-resolution synchrotron radiation diffraction.
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Fe3Pt intermetallic nanoparticles anchored on N-doped mesoporous carbon for the highly efficient oxygen reduction reaction

Chem. Commun., 2020, 56,4898-4901
DOI: 10.1039/D0CC00895H, Communication
Danke Chen, Zhuoyi Li, Yu Zhou, Xu Ma, Hanqing Lin, Wen Ying, Xinsheng Peng
N-Doped mesoporous carbon catalysts dispersed with Fe3Pt intermetallic nanoparticles, exhibiting excellent ORR performance, were synthesised by direct pyrolysis of Pt–Fe co-functionalized ZIF-8.
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Unexpected persistence of cis-bridged chains in compressed AuF3

Chem. Commun., 2020, 56,4902-4905
DOI: 10.1039/D0CC01374A, Communication
Dominik Kurzydłowski, Serhiy Kobyakov, Zoran Mazej, Sharad Babu Pillai, Brahmananda Chakraborty, Prafulla K. Jha
Raman scattering measurements and DFT calculations indicate that solid AuF3 adopts a metastable cis-bridge structure upon room-temperature compression.
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Stepwise assembly of nanoclusters guided by DNA origami frames with high-throughput

Chem. Commun., 2020, 56,4918-4921
DOI: 10.1039/D0CC00274G, Communication
Xiaodong Xin, Lihui Wang, Kaiwei Wang, Lizhi Dai, Hai Cao, Zheng Li, Ye Tian
We propose two strategies to construct nanoclusters efficiently with explicit positions of nanoparticles by the surface-encoded method.
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Oxyanion transport across lipid bilayers: direct measurements in large and giant unilamellar vesicles

Chem. Commun., 2020, 56,4910-4913
DOI: 10.1039/C9CC09888G, Communication
Krzysztof M. Bąk, Bartjan van Kolck, Krystyna Maslowska-Jarzyna, Panagiota Papadopoulou, Alexander Kros, Michał J. Chmielewski
A simple, carbazole-based dithioamide receptor transports a variety of biologically relevant anions through lipid bilayers, as shown by direct fluorescent assays in LUVs and GUVs.
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CRISPR/Cas-directed programmable assembly of multi-enzyme complexes

Chem. Commun., 2020, 56,4950-4953
DOI: 10.1039/D0CC01174F, Communication
Samuel Lim, Jiwoo Kim, Yujin Kim, Dawei Xu, Douglas S. Clark
We describe a versatile CRISPR/Cas-based strategy to construct precisely organized, scaffolded multi-enzyme systems with improved productivity.
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A dual-round signal amplification strategy for colorimetric/photoacoustic/fluorescence triple read-out detection of prostate specific antigen

Chem. Commun., 2020, 56,4942-4945
DOI: 10.1039/D0CC01086C, Communication
Chao Jiang, Yan Huang, Ting He, Peng Huang, Jing Lin
A colorimetric/fluorescence/photoacoustic triple read-out detection of prostate specific antigen (PSA) was developed by using a silica coated Au@Ag core–shell nanorod (denoted Au@Ag@SiO2) based enzyme-linked immunosorbent assay (ELISA) system.
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The design of hypercrosslinked polymers from benzyl ether self-condensing compounds and external crosslinkers

Chem. Commun., 2020, 56,4938-4941
DOI: 10.1039/D0CC01002B, Communication
Robert T. Woodward
Hypercrosslinked polymers were produced via the self-condensation of benzyl ether compounds, providing a one-component route to highly porous networks and significant reductions in catalyst waste compared to conventional routes.
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Atomically thin TiO2 nanosheets synthesized using liquid metal chemistry

Chem. Commun., 2020, 56,4914-4917
DOI: 10.1039/D0CC01456G, Communication
Turki Alkathiri, Nripen Dhar, Azmira Jannat, Nitu Syed, Md Mohiuddin, Manal M. Y. A. Alsaif, Robi S. Datta, Kibret A. Messalea, Bao Yue Zhang, Muhammad Waqas Khan, Aaron Elbourne, Naresh Pillai, Jian Zhen Ou, Ali Zavabeti, Torben Daeneke
The library of two-dimensional materials is limited since many transition metal compounds are not stratified and can thus not be easily isolated as nanosheets. Liquid metal-based synthesis provides a new approach to overcome this limitation.
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Conformational control of N-methyl-N,N'-diacylhydrazines by noncovalent carbon bonding in solution

Chem. Commun., 2020, 56,4874-4877
DOI: 10.1039/D0CC00943A, Communication
Jugal Kishore Rai Deka, Biswajit Sahariah, Kalpita Baruah, Arun Kumar Bar, Bani Kanta Sarma
Unusual N(amide)⋯C–X noncovalent carbon bonding interactions stabilize the transcis (tc) amide bond rotamers of N-methyl-N,N'-diacylhydrazines over the expected transtrans (tt) rotamers in solution.
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Beyond temperature: controlling collagen fibrillogenesis under physiological conditions via interaction with cucurbit[7]uril

Chem. Commun., 2020, 56,4946-4949
DOI: 10.1039/D0CC01444C, Communication
Qiuping Xie, Delong Hou, Jinming Chang, Zhou Xu, Qi Zeng, Zhonghui Wang, Yi Chen
A supramolecular strategy as efficient as temperature that enabled facile control over collagen fibrillogenesis under physiological conditions was reported.
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Chemically synthesized circular RNAs with phosphoramidate linkages enable rolling circle translation

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02140G, Communication
Kosuke Nakamoto, Naoko Abe, Genichiro Tsuji, Yasuaki Kimura, Fumiaki Tomoike, Yoshihiro Shimizu, Hiroshi Abe
Circular RNA without a stop codon enables rolling circle translation. we carried out one-pot chemical synthesis of circular RNA from RNA fragments. The synthesized circular RNAs acted as translation templates, despite the presence of unnatural phosphoramidate linkages.
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A convenient reagent for the conversion of aldoximes into nitriles and isonitriles

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00188K, Communication
Wei Zhang, Jin-Hong Lin, Pengfei Zhang, Ji-Chang Xiao
Described herein is the convenient transformation of aldoximes into nitriles or isonitriles by slightly modifying reaction conditions.
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Construction of Nanocage-Structured Heterogeneous Binary Metal Sulfides via Step-by-Step Confined Growth for Boosted Lithium Storage Properties

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00962H, Communication
Rongfang Zhao, Yue Han, Wenlong Li, Jinhua Li, Ming Chen, Lingxin Chen
Nanocage-structured materials-heterogeneous binary metal sulfides (MoS2 and Co9S8) in carbon nanocages (Co9S8/MoS2@CNCs) via step-by-step confined growth display superior Li-storage performance, profiting from the synergistic effect of bimetallic sulfides, high filling...
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Surfactant-free synthesis of ultralong silver nanowires for endurable transparent conducting electrodes

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01915A, Communication
Sian-Hong Tseng, Lian-Ming Lyu, Kai-Yuan Hsiao, Wan-Hua Ho, Ming-Yen Lu
The present study employed the surfactant-free growth of ultralong (~50 μm) silver nanowires (AgNWs) with high aspect ratio (up to 500) by galvanic replacement. AgNW conducting film were fabricated as...
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Bimolecular Vinylation of Arenes by Vinyl Cations

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02300K, Communication
ZHILONG LI, Vincent Gandon, Christophe Bour
Styrene derivatives can be easily synthesized from vinyl triflates and arenes under mild reaction conditions, using [Li][Al(OC(CF3)3)4] as a catalyst and LiHMDS as a base. This transformation is likely to...
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Host-guest interaction based supramolecular photodynamic therapy system: a promising candidate in the battle against cancer

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02001J, Feature Article
Kui Yang, Zhihua Zhang, Jie Du, Wei Li, Zhichao Pei
Owing to its spatiotemporal selectivity and noninvasive nature, photodynamic therapy (PDT) has become a promising approach for the treatment of cancer. However, the non-targeting capability and the accompanying side effects...
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Fluorescent Molecular Logic Gates based on Photoinduced Electron Transfer (PET) Driven by a Combination of Atomic and Biomolecular Inputs

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00478B, Communication
Open Access
Glenn Wright, Chaoyi Yao, Tom Moody, A. P. De Silva
Molecular AND logic gates 1, 3, 5 and 7, which are designed according to principles of photoinduced electron transfer (PET) switching, respond to co-existing Candida antarctica lipase B and H+...
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Intra-mitochondrial self-assembly to overcome the intracellular enzymatic degradation of L-peptides

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02029J, Communication
M. T. Jeena, Seokyoung Lee, Ayan Kumar Barui, Seongeon Jin, Yuri Cho, Suk-Won Hwang, Sehoon Kim, Ja-Hyoung Ryu
The design of peptide-based therapeutics is generally based on the replacement of L-amino acids with D-isomers to obtain improved therapeutic efficiency.
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A three-dimensional BODIPY–iron(III) compound with improved H2O2-response for NIR-II photoacoustic imaging guided chemodynamic/photothermal therapy

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01164A, Communication
Changjin Ou, Yewei Zhang, Wei Ge, Liping Zhong, Yong Huang, Weili Si, Wenjun Wang, Yongxiang Zhao, Xiaochen Dong
3D boron dipyrromethene (BODIPY)–Fe(III) coordination polymer nanoparticles with NIR-II absorption were developed as photothermal and chemodynamic agent to effectively kill cancer cells.
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Deep imaging for visualizing nitric oxide in lipid droplets: discovering the relationship between nitric oxide and resistance to cancer chemotherapy drugs

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01856B, Communication
Miantai Ye, Wei Hu, Meng He, Chenchen Li, Shuyang Zhai, Zhihong Liu, Yanying Wang, Huijuan Zhang, Chunya Li
A near-infrared two-photon fluorescent probe for selective detection and deep-depth imaging of NO helps to discover the relationship between NO and resistance to antitumor drugs.
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Harnessing chemical exchange: 19F magnetic resonance OFF/ON zinc sensing with a Tm(III) complex

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01876G, Communication
Meng Yu, Da Xie, Rahul T. Kadakia, Weiran Wang, Emily L. Que
A Tm(III) complex displays an “off–on” 19F NMR/MRI response to Zn(II) upon tuning the chemical exchange rate.
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Smart azobenzene-containing tubular polymersomes: fabrication and multiple morphological tuning

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01934H, Communication
Lishan Li, Songbo Cui, An Hu, Wei Zhang, Yiwen Li, Nianchen Zhou, Zhengbiao Zhang, Xiulin Zhu
Several kinds of novel azobenzene-containing tubular polymersomes were fabricated via self-assembly, and their shape could be tuned precisely by changing the chemical structure, self-assembly condition and external stimuli.
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A radical-mediated 1,3,4-trifunctionalization cascade of 1,3-enynes with sulfinates and tert-butyl nitrite: facile access to sulfonyl isoxazoles

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01659D, Communication
Xin Yue, Ming Hu, Xingyi He, Shuang Wu, Jin-Heng Li
An unprecedented indium-promoted three-component 1,3,4-trifunctionalization cascade of 1,3-enynes with sulfinates and tert-butyl nitrite for producing 5-sulfonylisoxazoles via [3+2] annulation is reported.
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Enhancing the catalytic properties of well-defined electrophilic platinum complexes

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01438A, Feature Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Pablo Ríos, Amor Rodríguez, Salvador Conejero
Well-defined electrophilic or low-electron count platinum complexes are very versatile catalysts for a variety of chemical transformations.
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Catalytic cycle of carbohydrate dehydration by Lewis acids: structures and rates from synergism of conventional and DNP NMR

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01756F, Communication
Pernille Rose Jensen, Sebastian Meier
Structures and rates in the catalytic cycle of carbohydrate dehydration by Lewis acidic salt are determined through the systematic use of complementary NMR approaches.
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Three component hydroxyletherification and hydroxylazidation of (trifluoromethyl)alkenes: access to α-trifluoromethyl β-heteroatom substituted tertiary alcohols

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02550J, Communication
Hao Zeng, Chuanle Zhu, Chi Liu, Yingying Cai, Fulin Chen, Huanfeng Jiang
The three component hydroxyletherification and hydroxylazidation reactions of (trifluoromethyl)alkenes are reported, providing various useful α-trifluoromethyl β-heteroatom substituted tertiary alcohols in high yields.
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Resistance to the “Last Resort” Antibiotic Colistin: A Single-Zinc Mechanism for Phosphointermediate Formation in MCR Enzymes

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02520H, Communication
Emily Lythell, Reynier Suardiaz, Philip Hinchliffe, Chonnikan Hanpaibool, Surawit Visitsatthawong, Sofia Oliveira, Eric Lang, Panida Surawatanawong, Vannajan Sanghiran Lee, Thanyada Rungrotmongkol, Natalie Fey, James Spencer, Adrian John Mulholland
MCR (mobile colistin resistance) enzymes catalyse phosphoethanolamine (PEA) addition to bacterial lipid A, threatening the “last-resort” antibiotic colistin. Molecular dynamics and density functional theory simulations indicate that monozinc MCR supports...
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Liquid metal exfoliation of two dimensional polydopamine nanosheets for templated assembly of noble metal nanoparticles

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02108C, Communication
Yong Liu, Juanjuan Li, Wei Zhang
A liquid metal-assisted exfoliation strategy is developed for synthesizing two-dimensional polydopamine nanosheets.
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