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Light-triggered dual-modality drug release of self-assembled prodrug-nanoparticles for synergistic photodynamic and hypoxia-activated therapy

Nanoscale Horiz., 2020, 5,886-894
DOI: 10.1039/D0NH00034E, Communication
Dongyang Zhao, Wenhui Tao, Songhao Li, Lingxiao Li, Yixin Sun, Guanting Li, Gang Wang, Yang Wang, Bin Lin, Cong Luo, Yongjun Wang, Maosheng Cheng, Zhonggui He, Jin Sun
Prodrug-nanoparticles turn the disadvantage of the aggregation-caused quenching effect into an advantage to promote dual-modality PR104A release. Besides, photodynamic therapy-induced hypoxia activates PR104A for high-efficiency synergistic therapy.
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Enhancing the chemotherapeutic efficacy of platinum prodrug nanoparticles and inhibiting cancer metastasis by targeting iron homeostasis

Nanoscale Horiz., 2020, Advance Article
DOI: 10.1039/D0NH00148A, Communication
Fang Ding, Lingpu Zhang, Hao Chen, Haiqin Song, Shiguo Chen, Haihua Xiao
Combination of cisplatin prodrug nanoparticles and Dp44mT results in enhanced anticancer and anti-metastatic efficiencies.
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Refractive index of nanoconfined water reveals its anomalous physical properties

Nanoscale Horiz., 2020, Advance Article
DOI: 10.1039/D0NH00180E, Communication
T. H. H. Le, A. Morita, T. Tanaka
Anomalously low refractive index of nanoconfined water.
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Reconfigurable all-dielectric Fano metasurfaces for strong full-space intensity modulation of visible light

Nanoscale Horiz., 2020, Advance Article
DOI: 10.1039/D0NH00139B, Communication
Open Access
Sun-Je Kim, Inki Kim, Sungwook Choi, Hyojin Yoon, Changhyun Kim, Yohan Lee, Chulsoo Choi, Junwoo Son, Yong Wook Lee, Junsuk Rho, Byoungho Lee
We demonstrated strong full-space modulation of visible intensities based on Fano resonances in all-dielectric VO2 metasurface gratings.
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M S Sahoo takes charge as Insolvency and Bankruptcy Board chief

Sahoo, a financial markets expert, was appointed as IBBI Chairperson for a period of five years last month




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Design for multi-step mechanochromic luminescence property by enhancement of environmental sensitivity in a solid-state emissive boron complex

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QM00719A, Research Article
Satoru Saotome, Kazumasa Suenaga, Kazuo Tanaka, Yoshiki Chujo
The solid-state emissive boron complex with multi-step mechanochromic luminescence was designed. The crystalline sample showed gradual changes in luminescent color triggered by scratching. The design concept is illustrated.
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Synergy of PVP and ethanol to synthesize Ni3S4 quantum dots for high-performance asymmetric supercapacitors

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00201A, Research Article
Jinfeng Zheng, Xiao Lian, Mingzai Wu, Fangcai Zheng, Yuan hao Gao, Helin Niu
Ni3S4 quantum dots (QDs) have great potential for supercapacitors due to their unique quantum effects, high specific surface area, high water solubility and good stability, but the current preparation process...
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Multi-stimuli responsive cyanostilbene derivatives: pH, amine vapor sensing and mechanoluminescence

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00113A, Research Article
Guangxi Huang, Xiaoyong Chang, Yuqing Jiang, Bei Lin, Bing Shi Li, Ben Zhong Tang
Two carboxyl substituted cyanostilbene derivatives can serve as novel mechanoluminescence materials and fluorescent sensors towards pH change and also amine vapors.
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3D-Nanosponge enabled segregation: a versatile approach for highly dispersed and high content functionalization of metal oxide species

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00115E, Research Article
Min Zhang, Yannan Yang, Yang Liu, Jianye Fu, Jingyi Lu, Yang Yang, Jinqing Jiao, Chengzhong Yu
A general 3D nanosponge enabled strategy is developed to achieve simultaneously highly dispersed and high content functionalization of metal oxide species, ebabling a liabrary of functional nanostructures with great application potential.
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Near-infrared electron acceptors with fused nonacyclic molecular backbones for nonfullerene organic solar cells

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QM00754G, Research Article
Jianquan Zhang, Yunke Li, Zhengxing Peng, Fujin Bai, Lik-Kuen Ma, Harald Ade, Zhengke Li, He Yan
Two strong electron-donating moieties were fused into the molecular backbone of small molecular acceptors showing dramatically extended absorption beyond 900 nm.
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Each phenyl group performs its own functions on luminescence: phenyl substituted effect in tetraphenylpyrazine

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00098A, Research Article
Haozhong Wu, Xiaojuan Song, Bing Zhang, Zhiming Wang, Tian Zhang, Anjun Qin, Ben Zhong Tang
Three phenyl groups of TPP derivatives affect the luminescence process in various modes. TPPs show AIE thanks to the ortho substituted groups, while meta and para groups can modulate their luminescence in different extents.
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Single-crystalline CoFe nanoparticles encapsulated in N-doped carbon nanotubes as a bifunctional catalyst for water splitting

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00126K, Research Article
Xiaojun Zeng, Myeong Je Jang, Sung Mook Choi, Hyun-Seok Cho, Chang-Hee Kim, Nosang Vincent Myung, Yadong Yin
We utilize a simple heat-treatment process to synthesize single-crystalline CoFe alloy nanoparticles encapsulated in N-doped carbon nanotubes, which exhibit excellent catalytic activity and superior stability towards overall water splitting.
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Aromatic imide/amide-based organic small-molecule emitters for organic light-emitting diodes

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00084A, Review Article
Yuanyuan Qin, Guoping Li, Ting Qi, Hui Huang
Aromatic imide/amide-based organic small molecules as emitters in organic light-emitting diodes have caught increasing attention. This study summarized their advances in terms of device performance and molecular design rules over the past 20 years.
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Multicationic AIEgens for unimolecular photodynamic theranostics and two-photon fluorescence bioimaging

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00119H, Research Article
Yuting Gao, Haoke Zhang, Zhenyan He, Fang Fang, Chao Wang, Kanghua Zeng, Shangbang Gao, Fanling Meng, Liang Luo, Ben Zhong Tang
This work reports multicationic AIEgens for unimolecular photodynamic theranostics, and an investigation of the relationship between their structures and activities, including PDT performance, 2-photon bioimaging, and self-reporting characteristics.
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Intentional modification of the optical spectral response and relative sensitivity of luminescent thermometers based on Fe3+,Cr3+,Nd3+ co-doped garnet nanocrystals by crystal field strength optimization

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00097C, Research Article
K. Kniec, K. Ledwa, K. Maciejewska, L. Marciniak
The relative sensitivity and usable temperature range of Fe3+,Cr3+-based luminescent thermometers can be tuned by modification of the crystal field strength.
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AIEgen based polymorphs with solvent regulated crystal-to-crystal switch properties

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00154F, Research Article
Liming Lai, Bing Fang, Wenyu Cheng, Pengyu Li, Yantu Zhang, Meizhen Yin
An AIEgen with tunable polymorphism-dependent emission and solvent regulated crystal-to-crystal switch properties is reported. Our study has provided insight into the relationship between molecular stacking and emission properties.
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One-pot quaternization of dual-responsive poly(vinyl alcohol) with AIEgens for pH-switchable imaging and killing of bacteria

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00014K, Research Article
Jin Wang, Meng Gao, Zhong-Kai Cui, Yong-Guang Jia, Sa Liu, Kai-Feng Chen, Xiaohui Chen, Yiqing Zhang, Zhou Fang, Yunhua Chen, Kaojin Wang, Huatang Zhang, Lin Wang, Li Ren
Dual-responsive poly(vinyl alcohol) derivatives bearing AIEgens and quaternary ammonium moieties were prepared through a facile one-pot quaternization for the pH-switchable imaging and killing of bacteria.
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Fluoro-alkyl substituted isothianaphthene bisimides as stable n-type semiconductors

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00137F, Research Article
Xiaolong Chen, Dongwei Zhang, Yaowu He, Muhammad Umair Ali, Yuting Wu, Changbin Zhao, Peiheng Wu, Chaoyi Yan, Fred Wudl, Hong Meng
Two fluoro-alkyl substituted isothianaphthene bisimide materials with high solubility and their applications in stable n-type OTFTs are demonstrated.
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Novel cathode buffer layer of Al(acac)3 enables efficient, large area and stable semi-transparent organic solar cells

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00198H, Research Article
Yiming Bai, Chunyan Zhao, Rongkang Shi, Jun Wang, Fuzhi Wang, Tasawar Hayat, Ahmed Alsaedi, Zhan'ao Tan
Electrode buffer layer plays a more crucial in semi-transparent organic solar cells (ST-OSCs) than that of the opaque devices due to the additional requirements of the average visible transmittance (AVT)...
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Chain-Length Effect on Binary Superlattices of Polymer-Tethered Nanoparticles

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00194E, Research Article
Ke Wang, Fan Li, Seon-Mi Jin, Kui Wang, Di Tian, Mubashir Hussain, Jiangping Xu, Lianbin Zhang, Yonggui Liao, Eunji Lee, Gi Yi, Xiaolin Xie, Jintao Zhu
Binary inorganic nanoparticles (NPs) can be assembled into various types of superlattices depending on the size ratio, shape, and interparticle potential, which may tailor mechanical, optical and electronic properties. Here,...
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Zeolite-confined carbon dots: tuning thermally activated delayed fluorescence emission via energy transfer

Mater. Chem. Front., 2020, 4,1404-1410
DOI: 10.1039/C9QM00549H, Research Article
Hongyue Zhang, Jiancong Liu, Bolun Wang, Kaikai Liu, Guangrui Chen, Xiaowei Yu, Jiyang Li, Jihong Yu
CD@zeolite composites with tunable TADF emission via an energy transfer process between confined CDs.
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The application of hollow micro-/nanostructured cathodes for sodium-ion batteries

Mater. Chem. Front., 2020, 4,1289-1303
DOI: 10.1039/C9QM00674E, Chemistry Frontiers
Xiao-Hao Liu, Wei-Hong Lai, Shu-Lei Chou
This work will open a new view for the design of hollow micro-/nanostructures used as cathodes for sodium-ion batteries, enclosing the superiority of this unique structure to enhance the electrochemical performance.
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Nitro-graphene oxide in iridium oxide hybrids: electrochemical modulation of N-graphene redox states and charge capacities

Mater. Chem. Front., 2020, 4,1421-1433
DOI: 10.1039/C9QM00752K, Research Article
Open Access
E. Pérez, N. M. Carretero, S. Sandoval, A. Fuertes, G. Tobias, N. Casañ-Pastor
Electrochemical modulation of N-graphene oxide in IrOx hybrids results in an oxidizing range of graphenes and large charge capacities.
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The origin of the unusual red-shifted aggregation-state emission of triphenylamine-imidazole molecules: excimers or a photochemical reaction?

Mater. Chem. Front., 2020, 4,1411-1420
DOI: 10.1039/C9QM00737G, Research Article
Jin Liu, Jianai Chen, Yujie Dong, Yue Yu, Shitong Zhang, Jianli Wang, Qingbao Song, Weijun Li, Cheng Zhang
Revealing the actual origin of the unusual red-shifted aggregation-state emission of triphenylamine-imidazole molecules: is the photochemical reaction rather than the excimers.
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Blue quantum dot-based electroluminescent light-emitting diodes

Mater. Chem. Front., 2020, 4,1340-1365
DOI: 10.1039/D0QM00029A, Review Article
Fei Chen, Qingli Lin, Huaibin Shen, Aiwei Tang
This review about the development of blue QD-LEDs will provide the reference to demonstrate the excellent blue devices.
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NH4V3O8·0.5H2O nanobelts with intercalated water molecules as a high performance zinc ion battery cathode

Mater. Chem. Front., 2020, 4,1434-1443
DOI: 10.1039/D0QM00051E, Research Article
Hanmei Jiang, Yifu Zhang, Zhenghui Pan, Lei Xu, Jiqi Zheng, Zhanming Gao, Tao Hu, Changgong Meng, John Wang
NH4V3O8·0.5H2O nanobelts are synthesized by a low-temperature hydrothermal process, and exhibit high electrochemical performance in ARZIBs.
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A zinc non-halide dopant strategy enables efficient perovskite CsPbI3 quantum dot-based light-emitting diodes

Mater. Chem. Front., 2020, 4,1444-1453
DOI: 10.1039/C9QM00734B, Research Article
Jinhang Li, Jiawei Chen, Leimeng Xu, Sinan Liu, Si Lan, Xiansheng Li, Jizhong Song
A zinc non-halide dopant strategy is employed to clarify the internal mechanism of Zn2+ doping without the introduction of halide ions and enhance the emission properties evidenced by the EQE of the QLEDs from 7.5% to 14.6% after Zn2+ doping.
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Modulation of ligand conjugation for efficient FAPbBr3 based green light-emitting diodes

Mater. Chem. Front., 2020, 4,1383-1389
DOI: 10.1039/C9QM00768G, Research Article
Feng Zhang, Mengna Sun, Xiyu Luo, Dongdong Zhang, Lian Duan
We put forward a new strategy for efficient PeLEDs by understanding the effect of ligand conjugation on device performance.
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AIE-active Schiff base compounds as fluorescent probes for the highly sensitive and selective detection of Fe3+ ions

Mater. Chem. Front., 2020, 4,1471-1482
DOI: 10.1039/C9QM00792J, Research Article
Jonnagaddala Harathi, Kathavarayan Thenmozhi
AIE-active Schiff base compounds were synthesized and photophysical properties were investigated. The compounds exhibited prominent sensing behaviour towards Fe3+ ion with enhanced selectivity, high association constants and low detection limits.
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Multifunctional ultrasmall-MoS2/graphene composites for high sulfur loading Li–S batteries

Mater. Chem. Front., 2020, 4,1483-1491
DOI: 10.1039/D0QM00082E, Research Article
Tianyu Tang, Teng Zhang, Lina Zhao, Biao Zhang, Wei Li, Junjie Xu, Long Zhang, Hailong Qiu, Yanglong Hou
The utilization of hosts with uniform dispersion of sulfur and multifunctional parts which can interact strongly with polysulfides facilitates the improved performance of Li–S batteries.
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From simple Katritzky salts to AIEgens: mechanochromic luminescence and heparin detection

Mater. Chem. Front., 2020, 4,1492-1499
DOI: 10.1039/C9QM00783K, Research Article
Faxu Lin, Yang Feng, Xiaoqing Liu, Lei Wang, Zhen-Qiang Yu, Yi Liu
A series of novel AIEgens based on Katritzky pyridinium salts were readily synthesized and exhibited interesting aggregation-induced emission behaviors, remarkable mechanochromic luminescence, and promising heparin detection.
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Sandwich structured dielectrics for air-stable and flexible low-voltage organic transistors in ultrasensitive pressure sensing

Mater. Chem. Front., 2020, 4,1459-1470
DOI: 10.1039/D0QM00062K, Research Article
Yue Jiang, Ziyang Liu, Zhigang Yin, Qingdong Zheng
A novel type of polymer sandwich dielectric is developed for air-stable, hysteresis-free and flexible OTFTs which can be used for low-power pressure sensors with ultrahigh sensitivity, wide detection range and fast response.
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A turn-off fluorescent probe for the detection of Cu2+ based on a tetraphenylethylene-functionalized salicylaldehyde Schiff-base

Mater. Chem. Front., 2020, 4,1500-1506
DOI: 10.1039/C9QM00759H, Research Article
Hai-Fang Xie, Chang-Jin Yu, Ya-Li Huang, Hong Xu, Qi-Long Zhang, Xiao-Hong Sun, Xing Feng, Carl Redshaw
A tetraphenylethylene-functionalized salicylaldehyde Schiff-base fluorescent probe (TPE-An-Py) with aggregation-induced enhanced emission (AIEE) characteristics exhibited high sensitivity towards copper(II) ions in aqueous media with a “turn-off” fluorescence mechanism; limit of detection is 2.36 × 10−7 mol L−1.
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The pressing-induced formation of a large-area supramolecular film for oil capture

Mater. Chem. Front., 2020, 4,1530-1539
DOI: 10.1039/D0QM00006J, Research Article
Wenkai Wang, Mengqi Xie, Hongjun Jin, Wanwan Zhi, Kaerdun Liu, Cheng Ma, Peilong Liao, Jianbin Huang, Yun Yan
A rejuvenable large-area polyelectrolyte–surfactant supramolecular film formed by applying pressure can be used in a recyclable manner to rapidly capture spilled oil.
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Intervaginal space injection of a liquid metal can prevent breast cancer invasion and better-sustain concomitant resistance

Mater. Chem. Front., 2020, 4,1397-1403
DOI: 10.1039/C9QM00753A, Research Article
Open Access
Yupeng Cao, Xiajun Hu, Qiang Zhang, Wenda Hua, Nan Hu, Yifeng Nie, Xue Xu, Yonggang Xu, Chongqing Yang, Xiaohan Zhou, Wentao Liu, Dong Han
CW invasion by the primary tumor was inhibited by ISI of an LM. DCs were activated by the LM to sustain CR.
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Design and construction of bi-metal MOF-derived yolk–shell Ni2P/ZnP2 hollow microspheres for efficient electrocatalytic oxygen evolution

Mater. Chem. Front., 2020, 4,1366-1374
DOI: 10.1039/D0QM00128G, Research Article
Jinyang Zhang, Xuan Sun, Yang Liu, Linrui Hou, Changzhou Yuan
Hierarchical yolk–shell Ni2P/ZnP2 hollow microspheres are smartly synthesized, and exhibit exceptional OER performance, benefiting from their unique compositional/structural merits.
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Current progress in carbon dots: synthesis, properties and applications

Mater. Chem. Front., 2020, 4,1287-1288
DOI: 10.1039/D0QM90015J, Editorial
Bai Yang, Raz Jelinek, Zhenhui Kang
Bai Yang, Raz Jelinek and Zhenhui Kang introduce the Materials Chemistry Frontiers themed collection on carbon dots.
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Highly-selective synthesis of trimetallic PtRuCu nanoframes as robust catalysts for the methanol oxidation reaction

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00033G, Research Article
Hai-Jing Yin, Zhi-Ping Zhang, Yu Guo, Kun Yuan, Ya-Wen Zhang
PtRuCu NFs/C exhibited much higher mass activity and specific activity than commercial Pt/C and PtRuCu NPs/C towards the MOR due to the frame nanostructures and the synergistic effect of the trimetallics.
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Opportunities and critical factors of porous metal-organic frameworks for the industrial separation of light olefins

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00186D, Review Article
Tianhao Lan, Libo Li, Yang Chen, Xiaoqing Wang, Jiangfeng Yang, Jinping Li
Light olefins (ethylene, propylene, and 1,3-butadiene) are widely used as building blocks in the petrochemical industry and for the fabrication of everyday products. Developing energy cost-efficient porous materials for the...
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When Centipedes Dream—Sue Bracken

ISBN: 9781988040387 Pub date: Spring 2018   Sue Bracken often finds the bizarre and the beautiful in what she sees. When Centipedes Dream, her debut book of poems, is a collection of these sightings. It  ranges from the familial love in a small blue bracelet,  the roar surrounding the loss of a sibling, the balletic thoughts of a [...]




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The Best Canadian Poetry in English, 2018

ISBN: 9781988040448 Pub date: Fall 2018 The 2018 edition of Canada’s go-to yearly anthology, guest edited by Hoa Nguyen, ushers readers into the heart of the vibrant Canadian poetry scene. The Best Canadian Poetry Series annually features the fifty finest Canadian poems published in periodicals during the previous year. A must-read for anyone with a stake in [...]




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Tread and Other Stories—Barry Dempster

ISBN: 9781988040424 Price: $21.95 Pub date: Fall 2018 Tread and Other Stories is a moving, unsettling, and ferociously humane collection of short fiction. The characters are achingly real: the moments at once gut-wrenchingly singular and utterly recognizable. There’s a satisfying range here—from a female prison guard with a yen for bad boys to a lost young man who [...]




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Best Canadian Essays 2018

ISBN: 9781988040455 Pub Date: Fall 2018 Featuring trusted series editor Christopher Doda and acclaimed guest editor Mark Kingwell, this tenth installment of Canada’s annual volume of essays showcases diverse nonfiction writing from across the country. Culled from leading Canadian magazines and journals, Best Canadian Essays 2018 contains award-winning and award-nominated nonfiction articles that are topical and engaging [...]




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Best Canadian Essays 2018 Launch

Join the Tightrope team for the launch of Best Canadian Essays 2018, edited by Mark Kingwell and Christopher Doda. Thursday, October 11, 6:30-8:30pm, 77 Carlton Street Event Centre, Toronto.




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[ASAP] Amine <italic toggle="yes">N</italic>-Oxide Kinetic Hydrate Inhibitor Polymers for High-Salinity Applications

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00838




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[ASAP] Influence of Carbon Dioxide on the Adsorption of Methane by Coal Using Low-Field Nuclear Magnetic Resonance

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00474




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[ASAP] Enhanced Performance of Adsorptive Removal of Thiophene from Model Fuel over Micro–Mesoporous Binderless ZSM-5 Prepared by <italic toggle="yes">In Situ</italic> Crystallization

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00198




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[ASAP] Pore Systems of the Different Lithofacies of the Longmaxi Formation at Depths Exceeding 3500 m in the Zigong Area, Sichuan Basin

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00456




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[ASAP] Oxygen Uncoupling Property and Kinetics of a Copper Manganese Composite Oxygen Carrier in a Packed-Bed Reactor

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00574




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[ASAP] Pore Network Changes Due to Polymer Flooding: Hebron Field Case

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00487