es

[ASAP] Pd-Catalyzed Regiodivergent Synthesis of Diverse Oxindoles Enabled by the Versatile Heck Reaction of Carbamoyl Chlorides

Organic Letters
DOI: 10.1021/acs.orglett.0c01197




es

[ASAP] Carbocation versus Carbene Controlled Chemoselectivity: DFT Study on Gold- and Silver-Catalyzed Alkylation/Cyclopropanation of Indoles with Vinyl Diazoesters

Organic Letters
DOI: 10.1021/acs.orglett.0c01476




es

[ASAP] K<sub>2</sub>S as Sulfur Source and DMSO as Carbon Source for the Synthesis of 2-Unsubstituted Benzothiazoles

Organic Letters
DOI: 10.1021/acs.orglett.0c00994




es

[ASAP] Palladium-Catalyzed Cascade Decarboxylative Amination/6-<italic toggle="yes">endo-dig</italic> Benzannulation of <italic toggle="yes">o</italic>-Alkynylarylketones with <italic toggle="yes"&g

Organic Letters
DOI: 10.1021/acs.orglett.0c01183




es

[ASAP] Selective Synthesis of Secondary Alkylboronates: Markovnikov-Selective Hydroboration of Vinylarenes with Bis(pinacolato)diboron Catalyzed by a Nickel Pincer Complex

Organic Letters
DOI: 10.1021/acs.orglett.0c01416




es

[ASAP] Organocatalytic Regiodivergent Ring Expansion of Cyclobutanones for the Enantioselective Synthesis of Azepino[1,2-<italic toggle="yes">a</italic>]indoles and Cyclohepta[<italic toggle="yes">b</italic>]ind

Organic Letters
DOI: 10.1021/acs.orglett.0c01406




es

[ASAP] Hydrogenation or Dehydrogenation of N-Containing Heterocycles Catalyzed by a Single Manganese Complex

Organic Letters
DOI: 10.1021/acs.orglett.0c01273




es

[ASAP] Catalytic, Enantioselective C2-Functionalization of 3-Aminobenzofurans Using N-Heterocyclic Carbenes

Organic Letters
DOI: 10.1021/acs.orglett.0c01112




es

[ASAP] Stereoselective Asymmetric Synthesis of Pyrrolidines with Vicinal Stereocenters Using a Memory of Chirality-Assisted Intramolecular S<sub>N</sub>2' Reaction

Organic Letters
DOI: 10.1021/acs.orglett.0c01307




es

[ASAP] Nickel-Catalyzed Cyclization Strategy for the Synthesis of Pyrroloquinolines, Indoloquinolines, and Indoloisoquinolines

Organic Letters
DOI: 10.1021/acs.orglett.0c01055




es

[ASAP] Enantioselective Copper-Catalyzed Remote C(sp<sup>3</sup>)–H Alkynylation of Linear Primary Sulfonamides

Organic Letters
DOI: 10.1021/acs.orglett.0c01325




es

[ASAP] Synthesis of Aspidodispermine via Pericyclic Framework Reconstruction

Organic Letters
DOI: 10.1021/acs.orglett.0c01242




es

[ASAP] Nickel(II)-Catalyzed Addition of Aryl-, Alkenyl-, and Alkylboronic Acids to Alkenylazaarenes

Organic Letters
DOI: 10.1021/acs.orglett.0c01425




es

[ASAP] Designing Homogeneous Copper-Free Sonogashira Reaction through a Prism of Pd–Pd Transmetalation

Organic Letters
DOI: 10.1021/acs.orglett.0c01227




es

[ASAP] Iron-Catalyzed Oxidative Coupling of Indoline-2-ones with Aminobenzamides via Dual C–H Functionalization

Organic Letters
DOI: 10.1021/acs.orglett.0c01066




es

[ASAP] Total Synthesis of Echinomycin and Its Analogues

Organic Letters
DOI: 10.1021/acs.orglett.0c01268




es

[ASAP] Total Synthesis of (±)-Sceptrin

Organic Letters
DOI: 10.1021/acs.orglett.0c01381




es

[ASAP] Sequential Visible-Light and <italic toggle="yes">N</italic>-Heterocyclic Carbene Catalysis: Stereoselective Synthesis of Tetrahydropyrano[2,3-<italic toggle="yes">b</italic>]indoles

Organic Letters
DOI: 10.1021/acs.orglett.0c01447




es

[ASAP] Synthesis of Spiroisoxazolines via an Oximation/Dearomatization Cascade under Air

Organic Letters
DOI: 10.1021/acs.orglett.0c01429




es

[ASAP] Oxidative Coupling of Aldehydes with Alcohol for the Synthesis of Esters Promoted by Polystyrene-Supported N-Heterocyclic Carbene: Unraveling the Solvent Effect on the Catalyst Behavior Using NMR Relaxation

Organic Letters
DOI: 10.1021/acs.orglett.0c01188




es

[ASAP] Copper-Catalyzed 1,2-Aminocyanation of Unactivated Alkenes via Cyano Migration

Organic Letters
DOI: 10.1021/acs.orglett.0c01217




es

[ASAP] Phosphorus(III)-Mediated, Tandem Deoxygenative Geminal Chlorofluorination of 1,2-Diketones

Organic Letters
DOI: 10.1021/acs.orglett.0c01258




es

[ASAP] Copper-Mediated DNA-Compatible One-Pot Click Reactions of Alkynes with Aryl Borates and TMS-N<sub>3</sub>

Organic Letters
DOI: 10.1021/acs.orglett.0c01219




es

[ASAP] Photoredox Catalysis toward 2-Sulfenylindole Synthesis through a Radical Cascade Process

Organic Letters
DOI: 10.1021/acs.orglett.0c01297




es

[ASAP] A General One-Pot Protocol for Hindered <italic toggle="yes">N</italic>-Alkyl Azaheterocycles from Tertiary Carboxylic Acids

Organic Letters
DOI: 10.1021/acs.orglett.0c01254




es

[ASAP] Studies of the Enantiocontrolled Synthesis of the C(10)–C(25) Subunit of Amphidinolide C

Organic Letters
DOI: 10.1021/acs.orglett.0c01177




es

[ASAP] Palladium-Catalyzed Regio- and Stereoselective Cross-Coupling of Vinylethylene Carbonates with Ketimine Esters to Generate (<italic toggle="yes">Z</italic>)-Tri- and Tetra-substituted Allylic Amino Acid Derivatives

Organic Letters
DOI: 10.1021/acs.orglett.0c01211




es

[ASAP] Addition to “Selective Methylation of Amides, <italic toggle="yes">N</italic>-Heterocycles, Thiols, and Alcohols with Tetramethylammonium Fluoride”

Organic Letters
DOI: 10.1021/acs.orglett.0c01524




es

[ASAP] Nickel-Catalyzed Formal Aminocarbonylation of Secondary Benzyl Chlorides with Isocyanides

Organic Letters
DOI: 10.1021/acs.orglett.0c01284




es

[ASAP] Benzo- and Thieno-Annulated Tetracenes: A One-Pot Synthesis via Cross-Dehydrogenative Annulation

Organic Letters
DOI: 10.1021/acs.orglett.0c01244




es

[ASAP] Stereospecific Isomerization of Allylic Halides via Ion Pairs with Induced Noncovalent Chirality

Organic Letters
DOI: 10.1021/acs.orglett.0c01200




es

[ASAP] Rh(I)-Catalyzed C6-Selective Decarbonylative Alkylation of 2-Pyridones with Alkyl Carboxylic Acids and Anhydrides

Organic Letters
DOI: 10.1021/acs.orglett.0c01277




es

Report: ‘Tremendous Progress’ Ahead for Religious Freedom Worldwide

USCIRF chair Tony Perkins gives CT a behind-the-scenes look at today’s annual report on “systematic, ongoing, and egregious” violations.

A new report aims to “unflinchingly criticize the records of US allies and adversaries alike” on religious freedom.

And there’s a lot to report, with more headlines each month confirming the Pew Research Center’s 10-year analysis that government restrictions and social hostilities involving religion have reached record levels worldwide.

Today’s 21st annual report by the US Commission on International Religious Freedom (USCIRF) identifies significant problems in 29 countries—but sees “an upward trajectory overall.”

“Our awareness is going to grow greater, and the problem will appear more pronounced,” USCIRF chair Tony Perkins told CT. “But as we continue to work on it, I think we will see tremendous progress in the next few years if we stay the present course.”

Created as an independent, bipartisan federal commission by the 1998 International Religious Freedom Act, USCIRF casts a wider net than the US State Department, which annually designates Countries of Particular Concern (CPC) for such nations’ violations of religious freedom, or places them on a Special Watch List (SWL) if less severe.

Last December, Secretary of State Mike Pompeo announced CPC status for Burma, China, Eritrea, Iran, North Korea, Pakistan, Saudi Arabia, Tajikistan, and Turkmenistan.

USCIRF now recommends adding India, Nigeria, Russia, Syria, and Vietnam.

And where the State Department put only Cuba, Nicaragua, Sudan, and Uzbekistan on the watch list, USCIRF recommends also including Afghanistan, Algeria, Azerbaijan, Bahrain, Central African Republic, Egypt, Indonesia, Iraq, Kazakhstan, Malaysia, and Turkey.

USCIRF’s mandate is to provide oversight and advice to the State Department. ...

Continue reading...




es

LifeWay Makes Cuts After VBS, Sunday School Sales Drop

The Southern Baptist publisher plans to restrict its budget by at least $25 million through reducing staff and salaries.

LifeWay Christian Resources, the publishing entity of the Southern Baptist Convention, has announced it will cut roughly 10 percent of its operating budget through staff reductions, a hiring freeze, and salary cuts.

The move comes after five consecutive weeks of steep revenue decline in the wake of the coronavirus and the expectation that sales may not rebound anytime soon.

The Nashville-based Christian publisher said revenue is down 24 percent compared with the same period last year, largely due to a sharp drop in bulk orders from churches for resources such as Sunday school curricula, Bible study materials, and Vacation Bible School curricula.

It’s not clear yet if SBC churches or other churches that buy LifeWay materials will hold VBS or camp programming this year.

LifeWay’s budget for this fiscal year is $281.3 million. It said it planned to cut between $25 million and $30 million from its budget.

The announcement is just the first indication of the financial blow many US churches and denominational agencies are facing as a result of the COVID-19 shutdowns—a blow that could reshape the religious landscape for decades to come.

“LifeWay stands to lose tens of millions of dollars of revenue that the organization would normally generate over the summer months from camps, events, VBS, and ongoing curriculum sales,” said Ben Mandrell, LifeWay’s CEO, in a news release. “LifeWay is mitigating these losses as much as possible through various expense reduction plans, including staff reductions and cuts in non-employee expenses.”

LifeWay said members of its executive leadership team will give up one month’s salary beginning in May. It did not say how it would achieve a staff reduction, ...

Continue reading...




es

In Inner-City Black Churches: More Grief, Fewer Resources, Stronger Faith

How the pandemic concentrated pressures on small churches—and how the body of Christ is stepping up to help, one $3,000 grant at a time.

Philadelphia pastor Kevin Cropper’s heart sank last month when he saw a message asking for food among the prayer requests emailed to his church.

“It was a request for something tangible, and we didn’t have it,” Cropper said.

His congregation, Ark of Safety Christian Church, had canceled its weekly food distribution since it ran out of donations when it stopped gathering in March. “It makes you feel bad because isn’t that what our mission is? We want to be able to help in this type of crisis, but we need the resources to do it.”

That’s the problem with being a small, inner-city black church during a pandemic. Black adults are more than twice as likely as whites or Hispanic Americans to know someone who has been hospitalized or died due to COVID-19. Their communities are afraid, grieving, and suffering from the virus themselves; and they are far less likely to have the staff, budgets, or space to help as much as they feel called.

“We are in the city. We don’t have acres, we stay close to each other, and it’s very easy to spread the virus,” said Kato Hart Jr., pastor of Hold the Light Ministries, a Church of God in Christ (COGIC) congregation in Detroit.

American counties with a higher-than-average proportion of black residents now account for half of coronavirus cases and 60 percent of deaths. Even in a church of 50, word keeps spreading of which members have lost relatives to the virus: aunties, uncles, grandparents. Hart has lost fellow brothers in ministry, citing a letter from denominational leadership saying 30 COGIC bishops have fallen to COVID-19—including a dozen in Michigan alone.

“We’re in a fight, and we need help. These megachurches, ...

Continue reading...




es

Died: Darrin Patrick, Who Used His Fall and Restoration to Help Struggling Pastors

(UPDATED) The St. Louis pastor spoke up about the difficulties faced by leaders and critiqued “celebrity culture” in ministry.

Darrin Patrick, a megachurch pastor, author, and speaker, has died.

Patrick was a teaching pastor at Seacoast Church, a multi-site megachurch based in Mount Pleasant, South Carolina, and the founding pastor of the Journey Church in St. Louis, where he lived.

In a Friday evening update, Seacoast Church stated: “Darrin was target shooting with a friend at the time of his death. An official cause of death has not been released but it appears to be a self-inflicted gunshot wound. No foul play is suspected.”

Patrick’s unexpected death came as a shock to friends and colleagues. Robby Gallaty, pastor of Long Hollow Baptist, in Hendersonville, Tennessee, said that Patrick was scheduled to speak at his church next weekend.

“I just talked to him Tuesday and Wednesday,” said Gallaty. “This is the second close friend I have lost in a year.”

Gallaty first met Patrick in 2015 and had invited him to speak the following year at a men’s ministry event at Long Hollow. Just before the event, he said, Patrick called and said he was leaving the ministry.

At the time, Patrick had been a rising star among Reformed evangelical circles and was serving as vice-president of the Acts 29 church planting network. He was fired from Journey for what church elders called misconduct including “inappropriate meetings, conversations, and phone calls with two women” and an abuse of power.

Despite Patrick’s fall from ministry, the two stayed friends. Patrick admitted his faults and got counseling. He went through a restoration process that lasted 26 months, according to a 2019 blog interview posted at Christianity Today. He returned to the ministry as a preacher but not as a senior pastor of a church. ...

Continue reading...




es

Inflow in equity MF plunges 27% to Rs 81,600 cr in FY20

However, this was the sixth successive year of net inflows in equity mutual funds, according to data by the Association of Mutual Funds in India (AMFI).




es

HCL Tech Q4 net up 24.3% to Rs 3,154 cr, sees short-term impact of COVID-19

Shares of the company were trading at Rs 517.80, marginally lower than the previous close on BSE.




es

Oppo to resume mobile production at 30% capacity

The company has also started sales of mobile phones through Amazon, Flipkart and retail stores in permitted areas.




es

Elon Musk delays release of Tesla's Roadster sports car

Tesla Inc Chief Executive Elon Musk said in a podcast interview released on Thursday that the company`s planned Roadster sports car would take a backseat to the development of other vehicle models.




es

IndiGo Airlines to cut salary for senior employees from May

The company will also put in place a leave without pay program for the months of May, June and July




es

Ratan Tata invests in 17-year-old kid's pharma start-up Generic Aadhaar

Generic Aadhaar supplies quality generic drugs from reputed manufacturers at up to 80 per cent lesser cost and other medicines 20-30 per cent cheaper.




es

BMW launches 8 Series Gran Coupe at Rs 1.3 crore, M8 Coupe at Rs 2.15 crore in India

The BMW 8 Series Gran Coupe is powered by a 3-litre, 6-cylinder in-line BSVI petrol engine. This is the most luxurious sports coupe ever built by BMW, the company said in a statement




es

Invest Rs 10,000 and earn Rs 30,000 per month by starting pickle making business

For pickle making business you will be required to obtain a license. 




es

Markets end higher, Sensex closes above 31,600

The BSE Sensex jumped 199.32 points or 0.63 per cent to close at 31,642.70. On the other hand, the NSE Nifty rose 52.45 points, or 0.57 per cent, to settle at 9,251.50.




es

CBI court extends Kapil Wadhawan, Dheeraj Wadhawan's custody in Yes Bank scam till May 10

The businessmen-brothers are facing charges of financial irregularities in cases filed by both Enforcement Directorate (ED) and CBI.




es

Service charges for Post office savings a/c, issue of duplicate passport and more

Here are some details of service charges that the Post Office charges you.




es

Dharmendra Pradhan hints at new gas policy, says low oil prices no answer

Pradhan also said that India favours reasonable prices that give some space to the producer countries.




es

Lava resumes operations at Noida factory with 600 employees

Domestic mobile brand Lava on Saturday said it has resumed production at its manufacturing facility in Noida with over 20 per cent production capacity.




es

Franklin Templeton issues apology to SEBI, says top executive's remark 'taken out of context'

Franklin Templeton Mutual Fund on Friday said it is making every effort to ensure an orderly and equitable exit to all investors affected by closure of six debt schemes, a day after it was asked by regulator sebi to focus on returning investors' money at the earliest.