mi

Superior energy storage properties in SrTiO3-based dielectric ceramics through all-scale hierarchical architecture

Mater. Horiz., 2024, 11,1732-1740
DOI: 10.1039/D3MH01965A, Communication
Chengyang Zuo, Jialing Xu, Shilin Yang, Zhiqin Cao, Hongtao Yu, Jingsong Liu, Xianhua Wei
Improving the energy storage performance of SrTiO3-based ceramics through all-scale architectures combining the effects of atomic-level doping, nanoscale domain engineering, submicroscale grain size regulation, and sample thinning.
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mi

A UV non-hydrogen pure selenite nonlinear optical material for achieving balanced properties through framework-optimized structural transformation

Mater. Horiz., 2024, 11,1704-1709
DOI: 10.1039/D3MH01790G, Communication
Peng-Fei Li, Chun-Li Hu, Jiang-Gao Mao, Fang Kong
NCS NaLu(SeO3)2 was designed by framework-optimized structural transformation from CS NaGa(SeO3)2. NaLu(SeO3)2 exhibits large SHG responses, a wide band gap, a short UV cut-off edge, high LIDT, sufficient birefringence and high thermal stability.
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mi

A high-performance and self-powered polarization-sensitive photoelectrochemical-type Bi2O2Te photodetector based on a quasi-solid-state gel electrolyte

Mater. Horiz., 2024, 11,1710-1718
DOI: 10.1039/D3MH01882B, Communication
Song Yang, Shujie Jiao, Yiyin Nie, Yue Zhao, Shiyong Gao, Dongbo Wang, Jinzhong Wang
A quasi-solid-state photoelectrochemical-type Bi2O2Te photodetector exhibits excellent linear polarized light detection capability.
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mi

Integration of fine-tuned chiral donor with hybrid long/short-range charge-transfer for high-performance circularly polarized electroluminescence

Mater. Horiz., 2024, 11,1752-1759
DOI: 10.1039/D3MH02146G, Communication
Xiaojun Yin, Haoxin Huang, Nengquan Li, Wendi Li, Xuechao Mo, Manli Huang, Guohao Chen, Jingsheng Miao, Chuluo Yang
Synergistic integration of a fine-tuned chiral donor with hybrid long/short-range charge-transfer offers desirable circularly polarized emitters with both a high dissymmetry factor of 1.6 × 10−3 and maximum external quantum efficiency of 37.4%.
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mi

Polyethylene fibers containing directional microchannels for passive radiative cooling

Mater. Horiz., 2024, 11,1787-1796
DOI: 10.1039/D3MH01881D, Communication
Mengxia Sun, Fei Peng, Shanshan Xu, Xianhu Liu, Kun Dai, Guoqiang Zheng, Chuntai Liu, Changyu Shen
The fabric woven by polyethylene fiber containing directional microchannels has excellent radiative cooling and self-cleaning property. Therefore, PFCDM fabric shows huge potential in the field of radiative cooling and human thermal management.
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mi

In situ self-reconstructed hierarchical bimetallic oxyhydroxide nanosheets of metallic sulfides for high-efficiency electrochemical water splitting

Mater. Horiz., 2024, 11,1797-1807
DOI: 10.1039/D3MH02090H, Communication
Yaning Fan, Junjun Zhang, Jie Han, Mengyuan Zhang, Weiwei Bao, Hui Su, Nailiang Wang, Pengfei Zhang, Zhenghong Luo
The obtained bimetallic sulfide catalyst can be reconstituted as FeCoOOH, which has high efficacy for water splitting. The activation energy barrier of key reaction steps can be effectively reduced by dual-metal cooperation.
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mi

Heterostructured grafting of NiFe-layered double hydroxide@TiO2 for boosting photoelectrochemical cathodic protection

Mater. Horiz., 2024, 11,1808-1816
DOI: 10.1039/D3MH02134C, Communication
Zhi-Jun Wang, Hui Xie, Seong Chan Jun, Jiang Li, Li Cheng Wei, Yu Chen Fang, Shude Liu, Ming Ma, Zheng Xing
Grafting NiFe-LDH nanosheets onto TiO2 nanorod arrays largely improves the photoexcited charge separation and accelerates the surface oxidation reaction, leading to stable & self-enhancing photoelectrochemical cathodic protection performance.
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mi

Non-Hermitian metagrating for perfect absorption of elastic waves

Mater. Horiz., 2024, 11,1658-1667
DOI: 10.1039/D3MH01866K, Communication
Jiali Cheng, Yabin Hu, Bing Li
With only a specific small amount of loss, perfect absorption of elastic waves can be achieved by a compact NHMG composed of only a single type of unit cell, enabling cloaking for arbitrary-shaped targets.
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mi

Correction: Solution-processed white OLEDs with power efficiency over 90 lm W−1 by triplet exciton management with a high triplet energy level interfacial exciplex host and a high reverse intersystem crossing rate blue TADF emitter

Mater. Horiz., 2024, 11,1817-1817
DOI: 10.1039/D4MH90021A, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Liang Chen, Yufei Chang, Song Shi, Shumeng Wang, Lixiang Wang
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A dual-responsive microemulsion with macroscale superlubricity and largely switchable friction

Mater. Horiz., 2024, 11,1668-1678
DOI: 10.1039/D3MH01978K, Communication
Siwei Chen, Hong Sun, Jian Liu, Jinyu Wang, Hongsheng Lu, Jingcheng Hao, Lu Xu, Weimin Liu
A dual-responsive microemulsion capable of providing macroscale superlubrication in a broad temperature range and switching its coefficient of friction by ∼25 fold is reported. It also shows ultrahigh colloidal stability and anti-freezing properties.
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mi

Aluminothermic reduction of CeO2: mechanism of an economical route to aluminum–cerium alloys

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00087K, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Alfred Amon, Emily E. Moore, Hunter B. Henderson, Jibril Shittu, Martin Kunz, Shane Kastamo, Nikolai Huotari, Adam Loukus, Ryan Ott, David Weiss, Scott K. McCall
Time-resolved X-ray diffraction enabled mechanistic insight into the aluminothermic reduction of CeO2. The environmentally friendly process enables a direct route to Al–Ce alloy production and a high-value use for excess Ce from rare earth mining.
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mi

Fabrication of polymeric microspheres for biomedical applications

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D3MH01641B, Review Article
Xuebing Li, Luohuizi Li, Dehui Wang, Jun Zhang, Kangfeng Yi, Yucai Su, Jing Luo, Xu Deng, Fei Deng
A systematic summary of fabrication technologies, a variety of structures and biomedical applications of polymeric microspheres.
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mi

Ultra-high piezoelectric properties and ultra-high Curie temperature of Li/Ce-doped La2Ti2O7 ceramics

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D3MH02098C, Communication
Manjing Tang, Zhi Tan, Jie Xing, Hao Chen, Xinji Yang, Hongjiang Li, Wen Zhang, Jianguo Zhu
Li/Ce dual doping strategy induces local heterogeneity via ion size and charge differences, the modified La2Ti2O7 ceramics exhibit significantly enhanced piezoelectric performance, resistivity, and ultra-high TC.
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mi

N-Type polymeric mixed conductors for all-in-one aqueous electrolyte gated photoelectrochemical transistors

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00267A, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Latifah Almulla, Victor Druet, Christopher E. Petoukhoff, Wentao Shan, Nisreen Alshehri, Sophie Griggs, Yazhou Wang, Maryam Alsufyani, Wan Yue, Iain McCulloch, Frédéric Laquai, Sahika Inal
An n-type organic photoelectrochemical transistor produces large and reversible current changes in response to light-intensity variations in aqueous electrolytes. A long exciton lifetime of the n-type gate ensures a high photovoltage response.
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mi

A mechanochemical process to capture and separate carbon dioxide from natural gas using boron nitride nanosheets

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00188E, Communication
Srikanth Mateti, Ying (Ian) Chen, Gautham Sathikumar, Qi Han, Shiva Prasad, Reza Ghandehari Ferdowsi, Amrito Battacharjee
A mechanochemical process to store and separate CO2 gas using boron nitride nanosheets.
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mi

Intelligent micro/nanorobots based on biotemplates

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00114A, Review Article
Open Access
Ting Chen, Yuepeng Cai, Biye Ren, Beatriz Jurado Sánchez, Renfeng Dong
Micromotors based on biotemplates: nature meets controlled motion. Cutting edge advances and recent developments are described.
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mi

Photo-induced synthesis of polymeric nanoparticles and chemiluminescent degradable materials via flow chemistry

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00106K, Communication
Joshua O. Holloway, Laura Delafresnaye, Emily M. Cameron, Jochen A. Kammerer, Christopher Barner-Kowollik
Polymeric nanospheres can be synthesised within minutes using photo-flow chemistry, without the need for initiators, additives, or surfactants. The particles can be selectively degraded on demand, emitting light in the process.
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mi

Construction of hierarchical porous and polydopamine/salicylaldoxime functional zeolite imidazolate framework-8 via controlled etching for uranium adsorption

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D3MH02108D, Communication
Kai Tuo, Jin Li, Yi Li, Chuyao Liang, Cuicui Shao, Weifeng Hou, Zhijian Li, Shouzhi Pu, Chunhui Deng
Efficient uranium extraction from seawater is critical for developing the nuclear industry. Herein, a polydopamine/salicylaldoxime decorated hierarchical zeolite imidazolate framework-8 (H-PDA/SA-ZIF-8) is constructed by using a controlled etching process. Benefiting...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Differential-targeting core-shell microneedle patch with coordinated and prolonged releases of mangiferin and MSC-derived exosomes for scarless skin regeneration

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D3MH01910A, Communication
Shang LYU, Qi Liu, Ho-Yin Yuen, Huizhi Xie, Yuhe Yang, Kelvin Yeung, Chak-Yin Tang, Shuqi Wang, Yaxiong Liu, Bin Li, Yong He, Xin Zhao
Microneedles for skin regeneration are conventionally restricted by uncontrollable multi-drug release, limited types of drugs, and poor wound adhesion. Here, a novel core-shell microneedle patch is developed for scarless skin...
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mi

Engineering a polyvinyl butyral hydrogel as a thermochromic interlayer for energy-saving windows

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00158C, Communication
Zequn Lin, Zican Yang, Liang Gao
The subtle amphiphilic of PVB makes for a well-structured network. Its design enables fast, consistent and reversible phase transitions of LCST. Overall, smart windows incorporating the gel have excellent light control capabilities.
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mi

Time-averaged atomic volume spectrum: locating and identifying vacancies

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00140K, Communication
YongQuan Wu, Hao Wang, JiaHao Fu, BoYang Zhang, Xu Zhao, Kai Zhang
We developed the TAVS method to accurately locate and fully identify vacancies based on a new concept of the atomic cage enwrapping vacancies. This flexible method is believed to be applicable to any type of vacancy in any type of material.
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mi

Giant auxetic behavior in remote-plasma synthesized few-layer tungsten semicarbide

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D3MH02193A, Communication
Noah B. Stocek, Farman Ullah, Giovanni Fanchini
We show how remote-plasma synthesis far from thermodynamic equilibrium yields unprecedented 2D crystals and demonstrates the first synthesis of 2D tungsten semicarbide, which was known from theoretical predictions to exhibit giant auxetic behavior.
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mi

Aggregation-induced emission organic metal halide complex for X-ray scintillation

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00142G, Communication
Open Access
Tunde Blessed Shonde, He Liu, Oluwadara Joshua Olasupo, Alexander Bouchard, Sara Bouchard, Annaliese Franklin, Xinsong Lin, Luis M. Stand, Biwu Ma
An AIE organic zinc chloride complex scintillator, in which the metal halide serves as X-ray sensitizer for the organic component, is discovered to exhibit a light yield of 13 423 Photon per MeV and a radioluminescence decay lifetime of 5.24 ns.
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mi

Atomic Scale Quantum Anomalous Hall Effect in Monolayer Graphene/MnBi2Te4 Heterostructure

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D4MH00165F, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yueh-Ting Yao, Su-Yang Xu, Tay-Rong Chang
The two-dimensional quantum anomalous Hall (QAH) effect is direct evidence of non-trivial Berry curvature topology in condensed matter physics. Searching for QAH in 2D materials, particularly with simplified fabrication methods,...
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Transforming Patterned Defects into Dynamic Poly-Regional Topographies in Liquid Crystal Oligomers

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D4MH00131A, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yuxin You, Youssef Golestani, Dirk J. Broer, Tinghong Yang, Guofu Zhou, Robin L. B. Selinger, Dong Yuan, Danqing Liu
We create high-aspect-ratio dynamic poly-regional surface topographies in a coating of a main-chain liquid crystal oligomer network (LCON). The topographies form at the topological defects in the director pattern organized...
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Photochemical engineering unsaturated Pt islands on supported Pd nanocrystals for a robust pH-universal hydrogen evolution reaction

Mater. Horiz., 2024, 11,1964-1974
DOI: 10.1039/D3MH02041J, Communication
Yidan Liu, Nuttapon Yodsin, Ting Li, Haocheng Wu, Rongrong Jia, Liyi Shi, Zhuangchai Lai, Supawadee Namuangruk, Lei Huang
Novel core–shell Pd7@Ptx heterostructured nanocrystals with Pt-islands shell of unsaturated coordination edges could be directly photodeposited on a reduced graphene oxide support as a highly efficient HER electrocatalyst in a wide pH range.
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mi

Kirigami-enabled stretchable laser-induced graphene heaters for wearable thermotherapy

Mater. Horiz., 2024, 11,2010-2020
DOI: 10.1039/D3MH01884A, Communication
Junyu Chen, Yichao Shi, Binbin Ying, Yajie Hu, Yan Gao, Sida Luo, Xinyu Liu
Stretchable later-induced graphene (LIG) heaters with kirigami structures are produced via laser engraving/cutting for wearable thermotherapy. Such a heater has a rapid electrothermal response and robust performance for on-body use.
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Injectable extracellular matrix-mimetic hydrogel based on electrospun Janus fibers

Mater. Horiz., 2024, 11,1944-1956
DOI: 10.1039/D3MH01789C, Communication
Jinzhong Zhang, Xiaolong Zha, Gengxin Liu, Huipeng Zhao, Xiaoyun Liu, Liusheng Zha
To date, the reported injectable hydrogels have failed to mimic the fibrous architecture of the extracellular matrix (ECM), limiting their biological effects on cell growth and phenotype.
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mi

Seeding ductile nanophase in ceramic grains

Mater. Horiz., 2024, 11,1908-1922
DOI: 10.1039/D3MH02233A, Communication
Chong Zhao, Hao Lu, Haibin Wang, Xuemei Liu, Zhigang Zak Fang, Chao Hou, Xiaoyan Song
A novel strategy is proposed to achieve coordinated strengthening and toughening of brittle composites by introducing and tailoring ductile nanoparticles within ceramic grains. Transgranular fractures of the ceramic phase were remarkably reduced.
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Exploring the Mpemba effect: a universal ice pressing enables porous ceramics

Mater. Horiz., 2024, 11,1899-1907
DOI: 10.1039/D3MH01869E, Communication
Open Access
Xiaodan Yang, Yao Shan, Ying Hong, Zhuomin Zhang, Shiyuan Liu, Xiaodong Yan, Xuetian Gong, Guangzu Zhang, Zhengbao Yang
A unique technique of “ice and fire” is proposed, that is, manipulation of force via water freezing (ice) and high-temperature sintering (fire) to fabricate ideal porous ceramics.
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Bicolour, large area, inkjet-printed metal halide perovskite light emitting diodes

Mater. Horiz., 2024, 11,1989-1996
DOI: 10.1039/D3MH02025H, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Vincent R. F. Schröder, Nicolas Fratzscher, Nicolas Zorn Morales, Daniel Steffen Rühl, Felix Hermerschmidt, Eva L. Unger, Emil J. W. List-Kratochvil
Using a sequential inkjet printing process, we realize bicoloured PeLEDs by selectively dissolving a bromide-based perovskite film with an iodide-based perovskite ink, resulting in red light-emitting features on a green light-emitting background.
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Electrochemical modulation of mechanical properties of glycolated polythiophenes

Mater. Horiz., 2024, 11,2021-2031
DOI: 10.1039/D3MH01827J, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ilaria Abdel Aziz, Johannes Gladisch, Chiara Musumeci, Maximilian Moser, Sophie Griggs, Christina J. Kousseff, Magnus Berggren, Iain McCulloch, Eleni Stavrinidou
This work investigates the changes in the mechanical properties of glycolated polythiophenes induced by electrochemical addressing and by electrolyte concentration, due to its ability to stabilize water.
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mi

Microcage flame retardants with complete recyclability and durability via reversible interfacial locking engineering

Mater. Horiz., 2024, 11,1867-1876
DOI: 10.1039/D4MH00116H, Communication
Furong Zeng, Lei He, Jianwen Ma, Danxuan Fang, Zhiwei Zeng, Tongyu Bai, Rong Ding, Bowen Liu, Haibo Zhao, Yuzhong Wang
A new facile and scalable interfacial locking engineering strategy is exploited to endow reversible microcages with infinite chemical recyclability to starting monomers, exceptional durability, high flame-retardant efficiency, and extensive applicability across diverse polymers.
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mi

Correction: Exploring the Mpemba effect: a universal ice pressing enables porous ceramics

Mater. Horiz., 2024, 11,2041-2042
DOI: 10.1039/D4MH90030H, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiaodan Yang, Yao Shan, Ying Hong, Zhuomin Zhang, Shiyuan Liu, Xiaodong Yan, Xuetian Gong, Guangzu Zhang, Zhengbao Yang
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Atomic-scale Ru anchored on chromium-shavings as a precursor for a pH-universal hydrogen evolution reaction electrocatalyst

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D3MH01951A, Communication
Qingxin Han, Qiangqiang Lu, Xuechuan Wang, Chao Wei, Xiaoyu Guan, Luming Chen, Xiao Wang, Ji Li
Chrome shavings produce electrocatalysts with atomically dispersed Ru sites. The CN/Cr2O3/Ru-1 catalyst has excellent HER catalytic performance under the synergistic effect of RuN4 and Cr2O3.
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mi

Polycatechols inhibit ferroptosis and modulate tau liquid–liquid phase separation to mitigate Alzheimer's disease

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00023D, Communication
Hariharan Moorthy, Madhu Ramesh, Dikshaa Padhi, Prayasee Baruah, Thimmaiah Govindaraju
Polycatechols modulate amyloid-associated toxicities, arrest labile iron, inhibit lipid peroxidation, and regulate tau liquid–liquid phase separation (LLPS) to mitigate the pathological nexus between ferroptosis and AD.
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mi

Decorin in the spatial control of collagen mineralization

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D3MH02216A, Communication
Yuming Bai, Peng Wu, Qiufang Zhang, Feng Lin, Ling Hu, Zhisheng Zhang, Wenxia Huang, Yin Xiao, Qiliang Zuo
Understanding the molecular mechanism by which the periodontal ligament (PDL) is maintained un-calcified between two mineralized tissues (cementum and bone), may facilitate the functional repair and regeneration of the periodontium...
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Construction of phase-separated Co/MnO synergistic catalysts and integration onto sponge for rapid removal of multiple contaminants

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00285G, Communication
Mengting Liu, Wanyu Zhang, Ruiting Ni, Zhenxiao Wang, Hongyao Zhao, Xiu Zhong, Yanyun Wang, Danhong Shang, Zengjing Guo, Edison Huixiang Ang, Fu Yang
Novel metallic Co integration onto MnO nanorods enhances catalyst efficiency for wastewater treatment.
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mi

Chemically Fueled Dynamic Switching Between Assembly-Encoded Emissions

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D4MH00251B, Communication
Manirul Islam, Malay Kumar Baroi, Basab Kanti Das, Aanchal Kumari, Krishnendu Das, Sahnawaz Ahmed
Self-assembly provides access to non-covalently synthesized supramolecular materials with distinct properties from a single building block. However, dynamic switching between functional states still remains challenging but holds enormous potential in...
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Watch | An online design studio inspired by Tamil literature




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Watch | A Kashmir papier-mâché artisan's dream project




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Watch | The revival of Waguw in Kashmir




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Contemporary artist and collector Amit Ambalal on the commerce-led revival of pichwai art

Pichwai’s iconic cow and lotus motifs are seeing a revival almost everywhere, from fashion to interior design




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Mark your dates: Malayalam and Tamil 2023 calendars to shop

Two regional 2023 calendars for the language enthusiasts 



  • Life & Style

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Call of duty: AAN Comics celebrates the courage of the Indian armed forces through its war books

Ahead of Republic Day, AAN Comics creator Rishi Kumar tells us how he brings alive tales of derring-do by our defence forces



  • Life & Style

mi

Guru Dutt's sister and famous painter Lalitha Lajmi passes away at 90

Over the decades, Lajmi has held several exhibitions at international art galleries in Paris, London and Holland




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New Delhi | Artist-collector Shalini Passi’s photo exhibition shows a deserted capital city in the early days of the COVID-19 pandemic

The black-and-white series titled ‘Forever Delhi’ is on display at the India Design ID 2023 till February 26




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Dutch DJ and EDM star Armin Van Buuren will perform for Sunburn Arena on a four-city tour in India this October

The trance legend commends Indian fans on their willingness to receive new sounds in dance music




mi

The global struggle for a pandemic treaty

The world must strive to overcome the obstacles as the treaty is a blueprint for a more equitable and resilient global health system




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New migrant realities in Karnataka’s gig sector

In the context of the broader ramifications of Karnataka’s local employment law, five State-level reports from the southern States — on the Editorial and Opinion Pages — on labour conditions on the ground. In Karnataka, social security schemes which demand domicile status could be ignorant of the migrant realities of today