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3-Perfluoroalkylated fluorescent coumarin dyes: rational molecular design and photophysical properties

Mol. Syst. Des. Eng., 2024, 9,332-344
DOI: 10.1039/D4ME00006D, Paper
Ayano Ikemura, Yukiko Karuo, Yuki Uehashi, Tomohiro Agou, Masahiro Ebihara, Yasuhiro Kubota, Toshiyasu Inuzuka, Masaaki Omote, Kazumasa Funabiki
The photochemical properties of a coumarin derivative with a promising electron-withdrawing fluoroalkyl group at the 3-position in solution and in the crystal were investigated in detail.
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Augmentation of inductive effects through short range intramolecular hydrogen bonds for the improvement of cooperativity of trimeric rosettes

Mol. Syst. Des. Eng., 2024, 9,345-351
DOI: 10.1039/D4ME00008K, Paper
Andre Nicolai Petelski, Tamara Bundrea, Nélida María Peruchena
Three key design elements improve the binding strength of trimeric rosettes: the direction of hydrogen bonds, the addition of groups with inductive effects, and the presence of ambifunctional intramolecular hydrogen bonds between the substituents.
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Engineering the interaction of short antimicrobial peptides with bacterial barriers

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00021H, Minireview
Open Access
Costanza Montis, Elisa Marelli, Francesco Valle, Francesca Baldelli Bombelli, Claudia Pigliacelli
Designing short antimicrobial peptides and tuning their interaction with bacterial barriers.
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Tuning the photophysical properties of ESIPT active unsymmetrical azine dyes by the change in the substituent and solvent: TD-PBE0 and TD-CAM-B3LYP studies

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00039K, Paper
Hossein Roohi, Tahereh Pouryahya
The photophysical properties of the designed ESIPT active as well as donor–acceptor structured unsymmetrical azine dyes L1L5 were investigated at PBE0/6-31++G(d,p) and CAM-B3LYP/6-31++G(d,p) levels of theory in the gas phase and solvent media.
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A molecular-design approach for selective sulfate separation from competitive acidic and alkaline aqueous media

Mol. Syst. Des. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4ME00031E, Review Article
Arghya Basu, Sandeep Kumar Dey
Selective and efficient removal of sulfate from aqueous solution having a high concentration of other competing ions is an important aspect of separation science technology and has attracted considerable attention...
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Biobased copoly(acetal-triazole)s with tunable degradable properties

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00005F, Paper
Joseph C. Daniels, Guery Saenz, Colleen N. Scott
Enhanced degradation of acetal-containing polymers in environmental conditions.
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DNA nanostar structures with tunable auxetic properties

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D3ME00202K, Paper
Open Access
Yancheng Du, Ruixin Li, Anirudh S. Madhvacharyula, Alexander A. Swett, Jong Hyun Choi
A nanoscale metastructure with tunable auxetic properties is constructed with DNA origami. This DNA nanostar structure can reconfigure in two orientations that can lead to distinct negative Poisson's ratios.
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Opening a vital window of communication

A new app, Good Vibes, introduces the deaf-blind to a tactile language that could transform their lives




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Life in picture-perfect Mechuka

This Himalayan Buddhist hamlet in Arunachal Pradesh is modernising at its own pace




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It works when women speak in unison

How an anganwadi centre came up in Chittorgarh’s Arania village




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Pelican paradise at Uppalapadu

How a bird habitat in AP is being protected and developed, thanks to the passion of a self-taught ornithologist




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To heal them, open their doors and bring them back to society

Those who have recovered from mental illness need to be mainstreamed




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Reaping profits from perishables

Through innovation, two start-ups help tribal and marginal farmers in Chhattisgarh and Bihar preserve and market their produce




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Looms that dispel the Covid gloom

Despite the isolating pandemic, Manipur’s women strive to weave small success stories




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Out, out, destructive pest

A mass trapping experiment is on in Maharashtra to save cotton crop from pink bollworm




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Let the village be the forest keeper

A project in Himachal Pradesh aims to promote community involvement and sustainability at the grassroots level




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Pedagogy despite the pandemic

How children without access to online education in Jharkhand and Bihar villages get their lessons




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Cellular Jail’s unfettered appeal

The 104-year-old prison in Andaman & Nicobar Islands, steeped in history, is fascinating, says its top official




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Free Prototype Program

Bocoup is trying something new! We’re launching an opportunity to build a free prototype for you or your organization. We want to ensure that funding is not a barrier to entry to get new ideas out into the world, and we believe prototypes can open doors. Application Information Application link: https://freeprototype.bocoup.com Application deadline: Rolling until […]




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Israeli Strikes Kill 46 People In The Gaza Strip And 33 In Lebanon, Medics Say

In Lebanon, large explosions shook Beirut's southern suburbs — an area known as Dahiyeh, where Hezbollah has a significant presence — soon after the Israeli military issued evacuation warnings for 11 houses there.




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Influence of polyol impurities on the transesterification kinetics, molecular structures and properties of isosorbide polycarbonate

Polym. Chem., 2024, 15,4204-4220
DOI: 10.1039/D4PY00840E, Paper
Mingfa Guo, Yaning Wang, Zhenguang Li, Jielin Xu, Qian Chen, Jing Wu, Huaping Wang
A so-called “reverse-addition” model protocol based on two kinds of polyol impurities (glycerol and 2-deoxy-D-ribose) was established to systematically demonstrate their influence on the polymerization and properties of PIC.
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Polymerization of isoprene and butadiene with unparalleled stereoselectivity catalysed by rare-earth metal cationic species bearing a novel tridentate ligand

Polym. Chem., 2024, 15,4255-4263
DOI: 10.1039/D4PY00781F, Paper
Xiuling Wang, Yang Wang, Zhonglei Qin, Liying Shen, Xiaochao Shi
Phenylthiol-functionalized rare-earth metal cationic species showed unparalleled stereoselectivity in the polymerization of isoprene and butadiene to respectively produce cis-1,4-polyisoprene and trans-1,4-polybutadiene.
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Mechanical properties and molecular adhesion exhibited by inorganic–organic composite elastomers

Polym. Chem., 2024, 15,4196-4203
DOI: 10.1039/D4PY00879K, Paper
Naoki Yamashita, Ryohei Ikura, Kenji Yamaoka, Nobu Kato, Masanao Kamei, Kentaro Ogura, Minoru Igarashi, Hideo Nakagawa, Yoshinori Takashima
Organic–inorganic composite elastomers with reversible cross-links formed by β-cyclodextrin and adamantane (Ad) were prepared. Excess Ad units improve the mixability of polydimethylsiloxane and poly(ethyl acrylate) to increase the healing ratio.
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Versatile poly(N-vinylcaprolactam)-grafted-hydroxypropyl cellulose polymers with tailored thermo- and pH-responsive properties via sustainable organocatalyzed atom transfer radical polymerization

Polym. Chem., 2024, 15,4244-4254
DOI: 10.1039/D4PY00931B, Paper
Muhammad Asif Iqbal, Asif Mahmood, Waheed Al-Masry, Chan Ho Park, Sadaf Ul Hassan, Toheed Akhter
This study explores the synthesis of dual pH- and thermo-responsive poly(N-vinylcaprolactam)-grafted-hydroxypropyl cellulose (PNVCL-g-HPC) polymers via visible-light-driven, metal-free organocatalyzed atom transfer radical polymerization (O-ATRP).
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Materials designed to degrade: structure, properties, processing, and performance relationships in polyhydroxyalkanoate biopolymers

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00623B, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jessica N. Lalonde, Ghanshyam Pilania, Babetta L. Marrone
A materials tetrahedron framework is applied to PHA biopolymers to highlight design challenges and frame potential future research exploring structure, property, processing, and performance relationships.
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Green perspective drives the renaissance of anionic diene polymerization

Polym. Chem., 2024, 15,4297-4311
DOI: 10.1039/D4PY00805G, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Moritz Rauschenbach, Moritz Meier-Merziger, Holger Frey
Polymers based on 1,3-diene monomers play a pivotal role in many commercial elastomers and thermoplastic elastomers. This review summarizes the state of the art and recent developments in the living anionic polymerization of dienes.
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Crystal structure of poly(trimethylene 2,5-furandicarboxylate) redux – a new model supported by computational spectroscopy

Polym. Chem., 2024, 15,4349-4363
DOI: 10.1039/D4PY00779D, Paper
Catarina F. Araújo, Simão V. Pandeirada, Inês M. Oliveira, Guilherme B. Rosa, Beatriz Agostinho, Armando J. D. Silvestre, Andreia F. Sousa, Svemir Rudić, Pedro D. Vaz, Mariela M. Nolasco, Paulo Ribeiro-Claro
The crystal structure of biobased poly(trimethylene 2,5-furandicarboxylate) is revisited following new evidence from vibrational spectroscopy and computational chemistry tools.
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Scalable design of uniform oligourethanes for impact study of chain length, sequence and end groups on thermal properties

Polym. Chem., 2024, 15,4319-4326
DOI: 10.1039/D4PY01001A, Paper
Open Access
Jens Van Hoorde, Nezha Badi, Filip E. Du Prez
A bidirectional growth-based protocol is used for the synthesis of a series of sequence-defined oligourethanes in large scale (50 g). The effect of chain length, sequence and end group functionalities on the thermal properties is evaluated.
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Functionalization of nano-objects in living anionic polymerization-induced self-assembly and their use for improving thermal properties of epoxy resins

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY01008F, Paper
Guicun Guo, Jiali Wu, Jingwei Zhang, Peng Zhou, Ding Shen, Penghan Li, Guowei Wang
Using LAPISA or LAPICA, stabilized PDVB@(PI-b-PS) and PDVB@(PI-b-PS/PS) nano-objects were prepared, functionalized and used as additives for epoxy resin, providing improved Tgs, integrated interfaces, uniform distributions, and scalable applications.
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Control over membrane fluidity and biophysical properties of synthetic terpolymer stabilized complex coacervates

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00978A, Paper
Open Access
Sebastian Novosedlik, Alexander B. Cook, Tim J. F. M. Voermans, Henk M. Janssen, Jan C. M. van Hest
Cell membranes are vital barriers that regulate the composition of the intracellular environment and facilitate communication processes essential for cellular function and survival.
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Enhanced mechanical properties of acrylate and 5-vinyl-2-norbornene-based ethylene terpolymers: rational design and synthesis using remotely modulated phosphine–sulfonate palladium complexes

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00722K, Paper
Yong-Qing Li, Gui-Ping Cao, Yu-Cai Cao
From a practical perspective, it is important to maintain or increase the mechanical properties of functional ethylene copolymers to those of nonpolar polyethylene (PE).
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Solvent quality shape control in continuous flow block copolymer self-assembly

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY01174K, Communication
Axel-Laurenz Buckinx, Lakshani J. Weerarathna, Anna Sokolova, Tanja Junkers
The influence of solvent quality on block copolymer self assembly is studied in detail using SANS online monitoring.
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Constructing self-healing flexible supercapacitors via graphene oxide synergistic multi-network polymer-supramolecular hydrogel electrolyte

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00809J, Paper
Xiaoyan Li, Xiuting Shi, Anbai Li, Mengmeng Xun, Shuzhen Cui, Kanjun Sun, Hui Peng, Guofu Ma, Yuxi Xu
Hydrogels are increasing interest and have great potential as electrolytes for flexible supercapacitors (FSCs) in wearable and portable electronic devices. However, the hydrogel electrolytes for practical applications are hampered by...
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Synthesis of degradable polyester with high molecular weight and excellent mechanical properties through copolymerization modification of poly(butylene succinate)

Polym. Chem., 2024, 15,4570-4579
DOI: 10.1039/D4PY01050G, Paper
Hongji Wang, Xiaojun Ma, Hanyu Yao, Haohao Chang, Yin Lv, Zhong Wei
The degradable copolymer of polybutylene succinate (PBS) modified with tricyclodecane dimethanol (TCD) presented significantly enhanced tensile strength and elongation at break.
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Interpretable machining learning assisted insights into bifunctional squaramide catalyzed ring-opening polymerization of lactide

Polym. Chem., 2024, 15,4562-4569
DOI: 10.1039/D4PY00866A, Paper
Shaoju Cao, Mengting Hong, Junyuan Hu, Zhenjiang Li, Jin Huang, Kai Guo
A bifunctional squaramide catalyst with tunable activity enables the controlled ring-opening polymerization of lactide. Combining bench experiments and interpretable machine learning offer insights into catalyst structures, promoting catalyst design.
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Composition-dependent emission colors for biomass-based main-chain luminescent liquid crystalline copolyesters with excellent tensile properties

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00946K, Paper
Wei Wang, Jing Wang, Wenting Li, Guangjian Liao, Yuan Qiu, Guochuan Yin, Yonggui Liao, Xiaolin Xie
The emission colors of high-performance MCLCPs with biomass-based bifuran and AIE-active cyanostilbene units can be tuned by the composition from blue to cyan, and then to green. Upon UV exposure, the thin film can undergo an emission color change.
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Eugenol-based polyester and its bamboo fiber composite with enhanced mechanical and anti-ultraviolet properties

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00998C, Paper
Meiran Xie, Qiubo Wang, Xinyu Hu, Shuyao Wang, Ruyi Sun, Xiaojuan Liao
Eugenol (UG) is a sustainable allyl-substituted guaiacol that easily becomes the monomers for acyclic diene metathesis (ADMET) polymerization. Nevertheless, the ADMET polymers usually have a moderate molecular weight and poor...
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Development of substrate-independent heparin coating to mitigate surface-induced thrombogenesis: efficacy and mechanism

J. Mater. Chem. B, 2024, 12,10994-11011
DOI: 10.1039/D4TB01779J, Paper
Shengjun Cheng, Haifeng Ji, Tao Xu, Xianda Liu, Lin Xu, Weifeng Zhao, Changsheng Zhao
A facile and substrate independent heparin-based coating was developed in this study. And the associated anticoagulant mechanism of this coating was clarified.
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Mercaptoimidazole-capped gold nanoparticles as a potent agent against plant pathogenic fungi

J. Mater. Chem. B, 2024, 12,10949-10961
DOI: 10.1039/D4TB01032A, Paper
Open Access
Tang Xu, Wenshuai Hao, Ran Du, Dai Dai, Cuixia Wang, Suhua Li, Carol Sze Ki Lin, Ruitao Cha, Jianbin Yan, Chong Li
The first evidence that MI-Au NPs prevent plants from fungal infection is presented.
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High-temperature emulsification coupled with low-temperature gelation for fabrication of agarose microsphere implants with well-controlled size for skin tissue enhancement

J. Mater. Chem. B, 2024, 12,10983-10993
DOI: 10.1039/D4TB01564A, Paper
Qi Wang, Huiyu Yan, Ying Guo, Bei Tian, Jianxi Xiao
Agarose offers self-gelation, biodegradability, and biocompatibility. We have developed a high-temperature emulsification followed by low-temperature gelation method to create agarose microsphere implants for skin tissue augmentation.
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Crystallization ripening and erosion of calcium oxalate under the effect of bacteria and a polymer materials surface

J. Mater. Chem. B, 2024, 12,10893-10901
DOI: 10.1039/D4TB01780C, Paper
Xiran Shen, Wentao Chen, Li Guo, Huayu Li, Hong Chen, Fan Liu
New insights into the role of bacteria in pathological biomineralization inspire novel anti-encrustation polymer material design for biomedical use.
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Phase-separated structures of tunable thermoresponsive and matrix polymers for large-scale temperature monitoring coatings

J. Mater. Chem. B, 2024, 12,10886-10892
DOI: 10.1039/D4TB01743A, Paper
Risako Shibata, Satoru Matsuda, Hirofumi Kawakubo, Hiroaki Imai, Yuya Oaki
Layered polydiacetylene (PDA) exhibits a thermoresponsive color change. The thermoresponsivity and large-scale coatability are controlled for medical applications by the intercalated guests and matrix polymer, respectively.
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Engineering disease analyte response in peptide self-assembly

J. Mater. Chem. B, 2024, 12,10757-10769
DOI: 10.1039/D4TB01860E, Review Article
Open Access
Sihan Yu, Matthew J. Webber
The need to enhance the precision and specificity of therapeutic nanocarriers has led to the development of nanoscale peptide assemblies capable of sensing and responding to disease-related analytes.
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Decellularization of caprine forestomach rumen tissue modified with silver nanowires as an antibacterial skin substitute scaffold in wound care therapeutics

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01560F, Paper
Athmana P. A., Asna Jaleel K. I., Sinduja Malarkodi Elangovan, Riza Paul, Naveen Subbaiyan, Parthiban Shanmugam, Gopal Shankar Krishnakumar
Caprine forestomach native collagen (CFNC) modified with silver nanowires (AgNWs) as a new class of biomimetic xenograft for skin regeneration with strong antimicrobial properties.
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Cell-specific spatial profiling of targeted protein expression to characterize the impact of intracortical microelectrode implantation on neuronal health

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01628A, Paper
Open Access
Lindsey N. Druschel, Niveda M. Kasthuri, Sydney S. Song, Jaime J. Wang, Allison Hess-Dunning, E. Ricky Chan, Jeffrey R. Capadona
Multiplex immunochemistry for proteins examining neuronal structure or function in NeuN+ regions adjacent intracortical microelectrodes (MEA) more closely matched historic intracortical MEA recording performance than traditional IHC quantification.
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Porous helical supramolecular columns self-organized via the fluorophobic effect of a semifluorinated tapered dendron

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01951B, Paper
Open Access
Dipankar Sahoo, Mihai Peterca, Mohammad R. Imam, Devendra S. Maurya, Virgil Percec
Fluorophobic effect enhances supramolecular microsegregation.
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Intrafibrillar Calcium Carbonate Mineralization of Electrospinning Polyvinyl Alcohol/Collagen Films with Improved Mechanical and Bioactive Properties

J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01472C, Paper
Yin Liu, Xin Gao, Yuqi Li, Anqi Gao, Zhuozhi Zheng, Jingjiang Wei, Hongye Yang, Hang Ping, Hao Xie, Hao Wang, Weiming Wang, Zhengyi Fu
Collagen films play an essential role in guided bone regeneration (GBR) techniques, which creat space, promote cell adhesion, and induce osteogenic differentiation. It is therefore crucial to design appropriate GBR...
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Long-term leaching kinetics and solution chemistry of aqueous BaTiO3 powder suspensions: a numerical model supported experiment

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01708K, Paper
Marcus Bentzen, Vojtěch Lindauer, Pavel Mokrý, Ragnhild Elizabeth Aune, Julia Glaum
The advent of lead-free perovskite materials with favorable toxicity profiles has made them candidates for in vivo and environmental applications.
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Tuning the affinity of probes with transmembrane proteins by constructing peptide-conjugated cis/trans isomers based on molecular scaffolds

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01801J, Paper
Jing-Jing Hu, Juliang Yang, Yiheng Liu, Guangwen Lu, Zujin Zhao, Fan Xia, Xiaoding Lou
Peptide-conjugated cis/trans isomers were designed. cis-RTP interacts more stably with cell membranes than trans-RTP, and it has shown more excellent properties in inhibiting cell migration and killing cells.
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Evaluation of Alkyl Chain Length and Photocatalytic Antibacterial Performance of Cation g-C3N4

J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01118J, Paper
Junling Leng, Xuanwei Liu, Yin Xu, shien zhu, Yuefei Zhang, Zhongbing Tan, Xiaofei Yang, Jia-En Jin, YuFeng Shi, Fan Hongying, Yi Yang, Hang Yao, Yu Zhang, Hui Chong, Chengyin Wang
Several cation graphite carbon nitrides (g-C3N4-(CH2)n-ImI+) were synthesized by chemically attaching imidazolium appended alkane chains with different lengths (n = 2, 4, 8, 12 and 16) to g-C3N4. Introduction of...
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