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Alternative countrysides : Anthropological approaches to rural Western Europe today [Electronic book] / ed. by Jeremy Macclancy.

By encore.st-andrews.ac.uk
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Manchester : Manchester University Press, [2019]


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Advances in Architectural Geometry 2023 [Electronic book] / ed. by Kathrin Dörfler, Jan Knippers, Achim Menges, Stefana Parascho, Helmut Pottmann, Thomas Wortmann.

By encore.st-andrews.ac.uk
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Berlin ; Boston : De Gruyter, [2023]


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Academic women : voicing narratives of gendered experiences [Electronic book] / [edited by] Michelle Ronksley-Pavia, Michelle M. Neumann, Jane Manakil and Kelly Pickard-Smith.

By encore.st-andrews.ac.uk
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London [England] : Bloomsbury Academic, 2022.


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Abundance : Sexuality's History [Electronic book] / Anjali Arondekar.

By encore.st-andrews.ac.uk
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Durham : Duke University Press, [2023]


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Fluke [electronic resource] : chance, chaos, and why everything we do matters / Brian Klaas.

By darius.uleth.ca
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New York : Scribner, 2024.


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Spinless formulation of linearized adiabatic connection approximation and its comparison with second order N-electron valence state perturbation theory

By pubs.rsc.org
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Faraday Discuss., 2024, Accepted Manuscript
DOI: 10.1039/D4FD00054D, Paper
Yang Guo, Katarzyna Pernal
The adiabatic connection (AC) approximation, along with its linearized variant AC0, was introduced as a method of obtaining dynamic correlation energy. When using a complete active space self-consistent field (CASSCF)...
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Cumulant Green's function methods for molecules

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Faraday Discuss., 2024, Accepted Manuscript
DOI: 10.1039/D4FD00037D, Paper
Pierre-Francois Loos, Antoine Marie, Abdallah Ammar
The cumulant expansion of the Green’s function is a computationally efficient beyond-GW approach renowned for its significant enhancement of satellite features in materials. In contrast to the ubiquitous GW approximation...
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Unravelling the complex speciation of halozincate ionic liquids using X-ray spectroscopies and calculations

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Faraday Discuss., 2024, Accepted Manuscript
DOI: 10.1039/D4FD00029C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jake Seymour, Ekaterina Gousseva, Frances Towers Tompkins, Lewis Parker, Najaat Alblewi, Coby James Clarke, Shusaku Hayama, Robert Palgrave, Roger Bennett, Richard Paul Matthews, Kevin R. J. Lovelock
Using a combination of liquid-phase experimental X-ray spectroscopy experiments and small-scale calculations we have gained new insights into the speciation of halozincate anions in ionic liquids (ILs). Both core and...
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Force and stress calculation with neural network wavefunction for solids

By pubs.rsc.org
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Faraday Discuss., 2024, Accepted Manuscript
DOI: 10.1039/D4FD00071D, Paper
Yubing Qian, Xiang Li, Ji Chen
Accurate ab initio calculations of real solids are of fundamental importance in fields such as chemistry, phases and materials science. Recently, variational Monte Carlo (VMC) based on neural network wavefunction...
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Enhancement of essential cofactors for in vivo biocatalysis

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Faraday Discuss., 2024, Accepted Manuscript
DOI: 10.1039/D4FD00013G, Paper
Pattarawan Intasian, Chalermroj Sutthaphirom, Oliver Bodeit , Duangthip Trisrivirat, Ninlapan Kimprasoot, Juthamas Jaroensuk, Barbara Bakker, Edda Klipp, Pimchai Chaiyen
A scarcity of cofactors, necessary metabolites or substrates for in vivo enzymatic reactions are among the major barriers of product synthesis in metabolically engineered cells. This work compares our recently...
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Stabilization of lithium metal in concentrated electrolytes: effects of electrode potential and solid electrolyte interphase formation

By pubs.rsc.org
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Faraday Discuss., 2024, Accepted Manuscript
DOI: 10.1039/D4FD00038B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Anusha Pradhan, Shoma Nishimura, Yasuyuki Kondo, Tomoaki Kaneko, Yu Katayama, Keitaro Sodeyama, Yuki Yamada
Lithium (Li) metal negative electrodes have enticed a wide attention for high-energy-density batteries. However, its low Coulombic efficiency (CE) due to parasitic electrolyte reduction has been an alarming concern. Concentrated...
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Permutation Symmetry in Spin Adapted Many-Body Wave Functions

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Faraday Discuss., 2024, Accepted Manuscript
DOI: 10.1039/D4FD00061G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Maru Song, Ali Alavi, Giovanni Li Manni
In the domain of exchange-coupled PNTM clusters, local emergent symmetries exist which can be exploited to greatly increase the sparsity of the CI eigensolutions of such systems. Sparsity of the...
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Synergistic Fe,Ce doping of Ni3S2 for enhancing oxygen evolution reaction performance

By pubs.rsc.org
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Inorg. Chem. Front., 2024, 11,7623-7632
DOI: 10.1039/D4QI02187H, Research Article
Yu He, Kefan Shi, Xueqin Wang, Xingzi Zheng, Lanke Luo, Liu Lin, Zemin Sun, Genban Sun
Fe,Ce-Ni3S2@NF nanoneedle catalysts synthesised via a one-step hydrothermal route showed good OER performance.
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ZnIn2S4 nanosheets with tunable dual vacancies for efficient sacrificial-agent-free H2O2 photosynthesis

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02030H, Research Article
Chen Zhang, Gao Xu, Qifeng Liang, Li Liang, Zebo Fang, Rong Wu, Shunhang Wei, Lei Wang, Xiaoxiang Xu
ZnIn2S4 nanosheets with tunable concentration of dual vacancies were prepared. Introducing dual vacancies effectively promotes photocarrier separation, facilitates O2 adsorption, and inhibits H2O2 decomposition by increasing hydrophilicity.
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Multifunctional core–shell CaSnO3@N-doped carbon coaxial nanocables with excellent lithium storage performance and efficient microwave absorption

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02264E, Research Article
Xiaoqiang Li, Guangguang Guan, Siyi Tong, Xin Chen, Kaiyin Zhang, Jun Xiang
It is highly desirable but challenging to design multi-functional materials for energy storage and electromagnetic (EM) wave absorption.
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Superior energy storage performance with a record high breakdown strength in bulk Ba0.85Ca0.15Zr0.1Ti0.9O3-based lead-free ceramics via multiple synergistic strategies

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02126F, Research Article
Changhao Wang, Jiaxi Hao, Longxiao Duan, Jianfan Zhang, Wenfeng Yue, Zhenhao Fan, Dandan Han, Raz Muhammad, Fanxu Meng, Dawei Wang
A composition and structure optimization strategy combined with a two-step sintering (TSS) process is proposed to design and fabricate (1−x)Ba0.85Ca0.15Zr0.1Ti0.9O3−xBi(Mg1/2Sn1/2)O3 (BCZT-BMSx-TSS) lead-free ceramics.
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Water-stable zero-dimensional hybrid zinc halide modulated by π–π interactions: efficient blue light emission and third-order nonlinear optical response

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02194K, Research Article
Jia-Wei Li, Wenke Dong, Yanjie Liu, Yuhan Li, Lu-Yuan Qiao, Guang-Lu Liu, Hui Zhang, Chunjie Wang, Hui-Li Zheng, Jian-Qiang Zhao
Waterproof 0D hybrid Zn halide with highly efficient blue emission and third-order nonlinear optical response was constructed by the microregulating of π–π interactions, offering new insights for designing stable multifunctional halide materials.
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Significant adsorption enhancements driven by pore microenvironment tuning for efficient C2H2/C2H4 separation in a chemically stable Ni7-cluster-based framework

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01856G, Research Article
Yunli Wang, Rizhao Zhang, Jin-Peng Xue, Yuqiao Chai, Bao Li, Jia Li
This study presents a stable Ni7-cluster MOF with enhanced adsorption through pore microenvironment tuning. Two types of guest-free frameworks achieve C2H2/C2H4 separation, providing deep insights into separation mechanisms.
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Vibrational analysis of auranofin complexes with cysteine and selenocysteine unveils distinct binding motifs and specific unimolecular reactivity

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02023E, Research Article
Open Access
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Roberto Paciotti, Davide Corinti, Cecilia Coletti, Nazzareno Re, Giel Berden, Jos Oomens, Simonetta Fornarini, Maria Elisa Crestoni
The [(Et3P)AuCys]+ and [(Et3P)AuSec]+ ions and their deamination products were characterized using IRMPD spectroscopy backed by DFT calculations finding differences in binding motifs and reactivity.
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A narrowband ultraviolet-B-emitting LiCaPO4:Gd3+ phosphor with super-long persistent luminescence for over 100 h

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02407A, Research Article
Xihui Shan, Xulong Lv, Dongxun Chen, Yi Zhang, Lixin Ning, Yanjie Liang
Intense NB-UVB emission at 312 nm and super-long persistent luminescence for >100 h have been realized in a LiCaPO4:Gd3+ phosphor after ceasing X-ray excitation, accompanied by a remarkable white-to-brown photochromism phenomenon.
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Revealing the effect of host–guest complementarity in supramolecular monofunctional platinum(II) drugs

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02012J, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shib Shankar Paul, Jan Novotný, Jakub Jakubec, Kateřina Petrláková, Pia Jurček, Klára Rašková, Michaela Kuchynka, Michal Masařík, Petr Kulhánek, Radek Marek
Host–guest complementarity is shown to influence the chemical activation by aquation and the biological activity of platinum(II) drugs.
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Heterointerface synergy between a 3 × 3 tunnel τ-MnO2 cathode and Mg2(OH)3Cl·4H2O for achieving long cycle-life aqueous zinc-ion batteries

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02572E, Research Article
Fang Xu, Jialin Zheng, Dai-Huo Liu, Ao Wang, Zhenjiang Li, Chunyan Xu, Mengqin Song, Beinuo Zhang, Zhengyu Bai, Zhongwei Chen
The prepared of τ-MnO2–Mg2(OH)3Cl·4H2O heterostructure cathode material enhances Zn-ion diffusion, increases the proportion of Mn(IV) and suppresses structural instability, thereby improving the cycling stability of τ-MnO2.
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The „chemical tug-of-war” in carborane clusters: distinct tuning on different sides of the cluster

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02566K, Research Article
Dalma Gál, Daniel Buzsaki, Balázs Szathmári, Tamas Holczbauer, Antal Udvardy, Júlia Kertész Szilágyiné, Denis Kargin, Clemens Bruhn, Rudolf Pietschnig, Zsolt Kelemen
The special C-C bond in the icosahedral closo-dicarbadodecaboranes and its high plasticity have been highlighted several times, which is reflected in the ease of tuning the C-C bond distance with...
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Boosted aluminum storage performance by d–p orbital modulation in zinc selenide with manganese element dopants

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02173H, Research Article
Han Wang, Rongkai Kang, Boya Zhang, Xingchang Zhang, Guowen Chen, Yiqun Du, Jianxin Zhang
By modulating the band center, Mn-ion doping strategy enhances electronic conductivity and improves interaction with solvent groups, thereby achieving high capacity, enhanced kinetics, and long-term cycling in rechargeable aluminum batteries.
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Strontium doping RuO2 electrocatalyst with abundant oxygen vacancies for boosting OER performance

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02070G, Research Article
Bei An, Xiaoqian Li, Yuan Lin, Fanfan Shang, Huijie He, Hairui Cai, Xiaoxiao Zeng, Weitong Wang, Shengchun Yang, Bin Wang
Oxygen evolution reaction (OER) plays a crucial role as the anode reaction of electrolytic water in various applications. To date, it is still a great challenge to develop highly active...
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Large optical anisotropy in noncentrosymmetric phosphate with pseudo 2D intercalated layer

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02245A, Research Article
Qiao Xia, Xingxing Jiang, Lu Qi, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark G. Humphrey, Kazuyuki Tatsumi, Chi Zhang
A noncentrosymmetric phosphate (C3H5N2)(H2PO4) with pseudo 2D intercalated layers, which exhibits large birefringence and wide band gap, was successfully synthesized by simultaneously introducing the planar and tetrahedral motifs.
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Exploring the optimal post-treatment strategy for boosting the electrochemical performances of a new bimetal–organic framework-based supercapacitor

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02314E, Research Article
Xinwen Dou, Mingyue Liu, Tian Cao, Chan Wang, Yingjie Zhang, Yuhang Jia, Qiang Ju, Zhenlan Fang
Effects of four kinds of post-treatment strategies on the structures, morphologies, and electrochemical behaviors of MOF derivatives are systematically investigated for the first time.
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Reconstruction and immobilization of polymolybdate induced by metal-organic coordination units for enhanced electrocatalytic hydrogen generation

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02311K, Research Article
Jingyi Ma, Zhihan Chang, Xue Xi, Juju Liang, Yuchun Lin, Yaling Zhu, Xiuli Wang
Electrocatalytic water cracking for hydrogen evolution has drawn the concern from researchers owing to its high efficiency. Polymolybdate has excellent redox behaviors and O-rich surface, becoming attractive electrocatalytic materials. In...
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High-efficiency tunable self-trapped exciton emission in one-dimensional β-Cs3Cu2Br5via Ag alloying for optoelectronic applications

By pubs.rsc.org
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Inorg. Chem. Front., 2024, 11,7793-7802
DOI: 10.1039/D4QI00970C, Research Article
Xin Xu, Zhongyi Wang, Qingkun Kong, Siping Liu, Ruiling Zhang, Xiaojing Liu, Keli Han
Metastable 1D β-Cs3Cu2Br5 synthesized by rapid cooling could be stabilized by Ag+. Ag-alloyed samples exhibit tunable emission from blue-greenish to yellow, which is attributed to different degrees of lattice distortion regulated by Ag+.
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Effects of metal–metal bonding in photosensitizers: red-shifted absorption and oscillator strength enhancement

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Inorg. Chem. Front., 2024, 11,7812-7821
DOI: 10.1039/D4QI02131B, Research Article
Oshan J. Jinarathne, Malkanthi K. Karunananda
Metal–metal bonds facilitate a red-shift in the maximum absorption wavelength and an enhancement of the oscillator strength in photosensitizers.
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Scalable complete conversion of MgCo2O4 by mechanochemistry for high-performance supercapacitors

By pubs.rsc.org
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Inorg. Chem. Front., 2024, 11,7886-7897
DOI: 10.1039/D4QI02020K, Research Article
Zhiyuan Liu, Qixuan Xiang, Hao Zhang, Xianglong Zhang, Huijun Tan, Yaping Zhao
Complete conversion of MgCo2O4 with excellent electrochemical performance has been successfully achieved.
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Copper-doped Bi2MoO6 with concurrent oxygen vacancies for enhanced CO2 photoreduction

By pubs.rsc.org
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Inorg. Chem. Front., 2024, 11,8003-8015
DOI: 10.1039/D4QI02005G, Research Article
Jiawei Liu, Xin Liu, Chunhui Dai, Chao Zeng, Sajjad Ali, Mohamed Bououdina, Yushuai Jia
Bi2MoO6 catalysts doped by monovalence Cu with self-adapting O vacancies (Ov) are prepared. The optimal Bi2MoO6–10% Cu exhibits an outstanding CO evolution rate of 11.40 μmol g−1 h−1, about 6 times higher than that of Bi2MoO6 (1.94 μmol g−1 h−1).
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In situ growth of δ-MnO2/C fibers as a binder-free and free-standing cathode for advanced aqueous Zn-ion batteries

By pubs.rsc.org
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Inorg. Chem. Front., 2024, 11,8016-8024
DOI: 10.1039/D4QI01661K, Research Article
Yan Li, Fei Zhang, Miaomiao Wu, Yong Guo, Yuanyuan Liang, Reyihanguli Ababaikeri, Luyang Wang, Qiao Liu, Xingchao Wang
δ-MnO2 anchored in N-doped carbon fibers, derived from coal, was prepared using an electrospinning method, demonstrating enhanced performance in AZIBs.
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A high-entropy FeCoMnCuNi diselenide self-standing electrode with outstanding water-electrolysis performance in alkaline medium

By pubs.rsc.org
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Inorg. Chem. Front., 2024, 11,7936-7946
DOI: 10.1039/D4QI01835D, Research Article
Xinxin Guo, Mengmeng Zhou, Ziwu Liu, Shiheng Mu, Kaijia Wang, Huanqiang Shi, Fang Wang, Shijian Lu, Zhonghai Ni, Guiqing Liu
A self-standing high-entropy FeCoMnCuNiSe2 electrode exhibited superior HER activity and OWS performance due to high entropy, lattice distortion and tip-enhancement effects.
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Equivalent cation-tuning to realize a new Ce(IV) fluoride with excellent comprehensive nonlinear optical performances

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Inorg. Chem. Front., 2024, 11,8130-8138
DOI: 10.1039/D4QI02088J, Research Article
Bei-Bei Zhang, Wen-Ye Gao, Wei Xu, Liang Ma, Wenlong Liu, Ru-Ling Tang, Sheng-Ping Guo
The acentric Ce(IV) fluoride NH4Ce3F13 is systematically studied, exhibiting the strong SHG effect (1.2 × KDP) and high LIDTs (39 × AGS). It also possesses the largest band gap among NLO materials containing Ce(IV).
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Tuning the phototherapeutic activity of Pt(IV) complexes for bladder cancer via modification of trans N-heterocyclic ligands

By pubs.rsc.org
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Inorg. Chem. Front., 2024, 11,7898-7909
DOI: 10.1039/D4QI01765J, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Huayun Shi, Guy J. Clarkson, Peter J. Sadler
The photochemotherapeutic activity of diazido Pt(IV) complexes towards bladder cancer, a common cancer with expensive treatment, has been tuned via modification of trans N-heterocyclic ligands, to give a candidate for preclinical development.
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Mesoscopic spiral nanoplates formed by porphyrin-spaced coordination frameworks for enhanced H2O2 photosynthesis

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Inorg. Chem. Front., 2024, 11,8037-8046
DOI: 10.1039/D4QI01580K, Research Article
Liang He, Er-Xia Chen, Ju-Qiang Xiang, Yu-Jun Guo, Jian Zhang, Qipu Lin
Two-dimensional chiral bismuth–porphyrin metal–organic frameworks featuring mesoscopic square spiral terrace morphology significantly enhance H2O2 photosynthesis.
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Governing efficiency and thermoresponsivity of luminescence in dirhenium(V) molecules by a highly tunable emission mechanism

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Inorg. Chem. Front., 2024, 11,8047-8069
DOI: 10.1039/D4QI01943A, Research Article
Michal Liberka, Mikolaj Zychowicz, Laurine Vasseur, James Hooper, Szymon Chorazy
Modification of an organic linker bonding two cyanido-nitrido Re(V) complexes enables the tuning of the emission mechanism that non-trivially modulates the photoluminescence and its applicability for temperature sensing.
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Highly defective and conductive Cu-doped 1T/2H-MoS2 nanosheets as high-capacity cathode materials for enhanced magnesium-ion storage

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Inorg. Chem. Front., 2024, 11,7831-7842
DOI: 10.1039/D4QI02064B, Research Article
Ao Xu, Yan Liu, Jiahui Wang, Yijing Wang, Fuyi Jiang, Yanli Zhou
Limited by the poor electronic conductivity and strong interaction between Mg2+ and MoS2, the 2H phase of MoS2 as a cathode material exhibits low capacity and poor rate capability.
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Multicolor luminescence and afterglow from Cs2NaScCl6:Sb3+,Mn2+ crystals

By pubs.rsc.org
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Inorg. Chem. Front., 2024, 11,8123-8129
DOI: 10.1039/D4QI02019G, Research Article
Xiaojia Wang, Wei Zheng, Xiangzhou Zhang, Xiangxiang Chen, Yuhai Zhang
Cs2NaScCl6 crystals exhibit a pure blue emission originating from self-trapped excitons, which is significantly boosted by Mn2+/Sb3+ doping. The doped crystals shows not only a PL QY up to 62.4% but also a long afterglow after X-ray excitation.
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Shooting short-wavelength nonlinear optical materials with targeted balance performances in hydroxyborates through first-principles high-throughput screening

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Inorg. Chem. Front., 2024, 11,7843-7852
DOI: 10.1039/D4QI02234C, Research Article
Chenxu Li, Abudukadi Tudi, Huanhuan Cheng, Qingyu Liu, Zhihua Yang, Shilie Pan
High-throughput screening of 222 hydroxyborates identified three as promising short-wavelength ultraviolet nonlinear optical. with phase-matching second harmonic generation capacity extending to the solar blind region (200–280 nm).
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Coordination tuning of Ni/Fe complex-based electrocatalysts for enhanced oxygen evolution

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Inorg. Chem. Front., 2024, 11,8110-8122
DOI: 10.1039/D4QI01934B, Research Article
Hongbo Zhou, Xuan Hao, Jiexin Guan, Yilin Deng, Zi Wei, Yashu Liu, Guoxing Zhu
The 2,2'-bpy coordination shells surrounding the Ni/Fe active sites of NiFe(2,2'-bpy)n@CNT materials effectively boost OER catalysis.
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Linker engineering in mixed-ligand metal–organic frameworks for simultaneously enhanced benzene adsorption and benzene/cyclohexane separation

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Inorg. Chem. Front., 2024, 11,8101-8109
DOI: 10.1039/D4QI01796J, Research Article
Yong-Zheng Zhang, Xin-Dan Zhang, Yan-Kai Zhang, Fu-Tian Wang, Longlong Geng, Hui Hu, Zhen Li, Da-Shuai Zhang, Hongliang Huang, Xiuling Zhang
A novel mixed-ligand metal–organic framework, featuring naphthalene rings in its secondary linker, exhibits exceptional benzene adsorption and separation capacities.
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Modulating the birefringence of two-dimensional hybrid lead bromide perovskites using pyridine derivative cations

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Inorg. Chem. Front., 2024, 11,7853-7859
DOI: 10.1039/D4QI01547A, Research Article
Li-Ling Zhang, Hua Huang, Qingran Ding, Hui-Ping Xiao, Qing-Yan Liu, Yu-Ling Wang
Crystal structures and optoelectronic performance of hybrid two-dimensional lead bromide halide perovskites are elaborately regulated by pyridyl cations, which achieve a significantly enhanced birefringence of 0.315 (550 nm) for crystal 2.
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Ru-anchoring Co-MOF-derived porous Ru-Co3O4 nanomaterials for enhanced oxygen evolution activity and structural stability

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Inorg. Chem. Front., 2024, 11,8139-8145
DOI: 10.1039/D4QI02061H, Research Article
Nan Li, Lujiao Mao, Yuting Fu, Haoran Wang, Yuchang Shen, Xuemei Zhou, Qipeng Li, Jinjie Qian
This study demonstrates a new approach for Ru-anchoring CoOF-1-derived porous Ru-Co3O4 nanomaterials with high activity and durability, showcasing great potential in the field of practical energy storage and conversion.
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Optimizing the spin qubit performance of lanthanide-based metal–organic frameworks

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02324B, Research Article
Xiya Du, Lei Sun
Reducing the spin concentration, spin-orbit coupling strength, and ground spin state of lanthanide ions embedded in metal–organic frameworks improves their spin qubit performance.
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Reversible single-crystal to single-crystal photoreaction between a coordination comb and a ladder displays photo-switchable fluorescence

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02162B, Research Article
Ni-Ya Li, Xin-Yu Wang, Pei-Xuan Zhang, Ning-Ning Zou, Wen Qiu, Yu-Fei Xing, Yun-Jian Wang, Xiao-Yan Tang, Dong Liu
A unique coordination polymer can transform between comb-like and ladder-like bistable structures through reversible single-crystal-to-single-crystal photoreaction and exhibit photo-switchable fluorescence.
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Dual effects of Ag+ intercalation boosting the kinetics and stability of NH4V4O10 cathodes for enhanced zinc ion storage

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01942C, Research Article
Zhou Fang, Yi Tong, Yue Yang, Anjun Hu, Jianping Long, Yan Zhao, Xin Lai, Daojiang Gao, Mengjiao Liu
The present work simultaneously addresses the structural instability and poor diffusion kinetics of NH4V4O10 cathodes using Ag+ intercalation, providing a new perspective on transition metal ion intercalation towards high-performance cathodes for AZIBs.
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A non-equivalent Ni doped La-MOF for enhanced photocatalytic CO2 reduction through oxygen vacancy regulation and electronic structure optimization

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02143F, Research Article
Tongzheng Zhang, Zhaohui Huang, Guanshun Xie, Le Liao, Changqiang Yu, Xiuqiang Xie, Nan Zhang
La/Ni-MOF with oxygen vacancies and regulated electronic structures is prepared and exhibits enhanced visible-light photocatalytic activity for CO2-to-CO conversion.
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Enhancing CO2 electroreduction with decamethylcucurbit[5]uril-alkaline earth metal modified Pd nanoparticles

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02135E, Research Article
Tao Shao, Xianmeng Song, Zongnan Wei, Shuaibing Yang, Siying Zhang, Rong Cao, Minna Cao
Pd NP modification with Me10CB[5]–M capsules boosted CO2RR by enhancing CO2 adsorption, tuning Pd's electronic structure, and optimizing *COOH/*CO binding.
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