v

Colloidal PbS quantum dot stacking kinetics during deposition via printing

Nanoscale Horiz., 2020, 5,880-885
DOI: 10.1039/D0NH00008F, Communication
Wei Chen, Haodong Tang, Nian Li, Manuel A. Scheel, Yue Xie, Depeng Li, Volker Körstgens, Matthias Schwartzkopf, Stephan V. Roth, Kai Wang, Xiao Wei Sun, Peter Müller-Buschbaum
The particle self-organization behavior of small-sized quantum dots is studied in situ with grazing-incidence small-angle X-ray scattering and during the drying process two phase transitions are found.
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v

Single atom catalysts: a surface heterocompound perspective

Nanoscale Horiz., 2020, 5,757-764
DOI: 10.1039/D0NH00088D, Focus
Zongkui Kou, Wenjie Zang, Peikui Wang, Xin Li, John Wang
Evolution of heterogeneous catalysts with steady down-sizing: from small particles, clusters, dots to single atoms, and now the “surface heterocompound”.
The content of this RSS Feed (c) The Royal Society of Chemistry




v

Light-triggered dual-modality drug release of self-assembled prodrug-nanoparticles for synergistic photodynamic and hypoxia-activated therapy

Nanoscale Horiz., 2020, 5,886-894
DOI: 10.1039/D0NH00034E, Communication
Dongyang Zhao, Wenhui Tao, Songhao Li, Lingxiao Li, Yixin Sun, Guanting Li, Gang Wang, Yang Wang, Bin Lin, Cong Luo, Yongjun Wang, Maosheng Cheng, Zhonggui He, Jin Sun
Prodrug-nanoparticles turn the disadvantage of the aggregation-caused quenching effect into an advantage to promote dual-modality PR104A release. Besides, photodynamic therapy-induced hypoxia activates PR104A for high-efficiency synergistic therapy.
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v

Outstanding Reviewers for Nanoscale Horizons in 2019

Nanoscale Horiz., 2020, 5,756-756
DOI: 10.1039/D0NH90021D, Editorial

We would like to take this opportunity to highlight the Outstanding Reviewers for Nanoscale Horizons in 2019, as selected by the editorial team for their significant contribution to the journal.
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Refractive index of nanoconfined water reveals its anomalous physical properties

Nanoscale Horiz., 2020, Advance Article
DOI: 10.1039/D0NH00180E, Communication
T. H. H. Le, A. Morita, T. Tanaka
Anomalously low refractive index of nanoconfined water.
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Reconfigurable all-dielectric Fano metasurfaces for strong full-space intensity modulation of visible light

Nanoscale Horiz., 2020, Advance Article
DOI: 10.1039/D0NH00139B, Communication
Open Access
Sun-Je Kim, Inki Kim, Sungwook Choi, Hyojin Yoon, Changhyun Kim, Yohan Lee, Chulsoo Choi, Junwoo Son, Yong Wook Lee, Junsuk Rho, Byoungho Lee
We demonstrated strong full-space modulation of visible intensities based on Fano resonances in all-dielectric VO2 metasurface gratings.
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v

Govt appoints Ajay Bhushan Pandey UIDAI CEO

He has been involved with the UIDAI established under the Aadhaar Act and implementation of Aadhaar since September 2010




v

M S Sahoo takes charge as Insolvency and Bankruptcy Board chief

Sahoo, a financial markets expert, was appointed as IBBI Chairperson for a period of five years last month




v

Understanding of copolymers containing pyridine and selenophene simultaneously and their polarity conversion in transistors

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QM00739C, Research Article
So-Huei Kang, Myeonggeun Han, Yongjoon Cho, Jisu Hong, Seongmin Heo, Seonghun Jeong, Yong-Young Noh, Changduk Yang
Two n-type pyridine and selenophene-containing polymers were synthesized and the structure–property relationships were investigated, followed by polarity switching from ambipolarity to unipolar characteristics via the doping method.
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v

Design for multi-step mechanochromic luminescence property by enhancement of environmental sensitivity in a solid-state emissive boron complex

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QM00719A, Research Article
Satoru Saotome, Kazumasa Suenaga, Kazuo Tanaka, Yoshiki Chujo
The solid-state emissive boron complex with multi-step mechanochromic luminescence was designed. The crystalline sample showed gradual changes in luminescent color triggered by scratching. The design concept is illustrated.
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v

A GFP-chromophore-based C3V-symmetric tripodal receptor with selective recognition of Hg(II), Fe(III) and Cr(III)

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00108B, Research Article
Chun-Yen Chou, Robert Sung, Wei-Luen Chang, Kuangsen Sung
A novel green-fluorescent-protein-chromophore-based tripodal receptor 1 is synthesized. Its single crystal X-ray diffraction structure looks like a straight, long tube with one end closed. The diameter of the inner cavity...
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Synergy of PVP and ethanol to synthesize Ni3S4 quantum dots for high-performance asymmetric supercapacitors

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00201A, Research Article
Jinfeng Zheng, Xiao Lian, Mingzai Wu, Fangcai Zheng, Yuan hao Gao, Helin Niu
Ni3S4 quantum dots (QDs) have great potential for supercapacitors due to their unique quantum effects, high specific surface area, high water solubility and good stability, but the current preparation process...
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Charge density modulation on asymmetric fused-ring acceptors for high-efficiency photovoltaic solar cells

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00123F, Research Article
Zhuohan Zhang, Linqiang Yang, Zhenghao Hu, Jiangsheng Yu, Xin Liu, Hongtao Wang, Jinru Cao, Fujun Zhang, Weihua Tang
Charge density modulation on thieno[2'',3'':5',6']-s-indaceno[2',1':4,5]dithieno[3,2-b:2',3'-d]pyrrole core has been conducted for a systematic study of its impact on the electronic structure, molecular packing and photovoltaic performance of asymmetric fused-ring acceptors.
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v

Multi-stimuli responsive cyanostilbene derivatives: pH, amine vapor sensing and mechanoluminescence

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00113A, Research Article
Guangxi Huang, Xiaoyong Chang, Yuqing Jiang, Bei Lin, Bing Shi Li, Ben Zhong Tang
Two carboxyl substituted cyanostilbene derivatives can serve as novel mechanoluminescence materials and fluorescent sensors towards pH change and also amine vapors.
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A robust 3D printed multilayer conductive graphene/polycaprolactone composite electrode

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QM00780F, Research Article
Chong-Yong Lee, Sepidar Sayyar, Paul J. Molino, Gordon G. Wallace
We fabricated a 3D-printed multilayer conductive graphene/polycaprolactone composite electrode that shows excellent robustness, biocompatibility and electrochemical response.
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3D-Nanosponge enabled segregation: a versatile approach for highly dispersed and high content functionalization of metal oxide species

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00115E, Research Article
Min Zhang, Yannan Yang, Yang Liu, Jianye Fu, Jingyi Lu, Yang Yang, Jinqing Jiao, Chengzhong Yu
A general 3D nanosponge enabled strategy is developed to achieve simultaneously highly dispersed and high content functionalization of metal oxide species, ebabling a liabrary of functional nanostructures with great application potential.
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Highly efficient exciplex-based OLEDs incorporating a novel electron donor

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00116C, Research Article
Qi-Sheng Tian, Xiang-Dong Zhu, Liang-Sheng Liao
A high performance green exciplex OLED comprising a novel electron donor DEX with an acceptor PO-T2T can reach an EQEmax of 11.2%, and a red phosphorescent OLED incorporating the green exciplex forming co-host achieves an EQEmax of 24.5%.
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The content of this RSS Feed (c) The Royal Society of Chemistry




v

Oxygen Vacancy Induced Superior Visible-light-driven Photo-catalytic Performance in BiOCl Homojunction

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00187B, Research Article
Si-Ying Niu, Ruoyu Zhang, Chongfeng Guo
The photocatalytic performance of semiconductor can be enhanced by expanding the spectral response and accelerating the photo-induced charge separation. Introduction of oxygen vacancies and construction of homo-junction in BiOCl were...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Dimensional Anisotropic Graphene with High Mobility and High On-Off Ratio in three-terminal RRAM device

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00152J, Research Article
Bo Liu, Han Hsiang Tai, Hanyuan Liang, En-Yan Zheng, Mamina Sahoo, Chih-Hsien Hsu, Tsung Cheng Chen, Ching-An Huang, Jer-Chyi Wang, Tuo-Hung Hou, Chao-Sung Lai
In the past decade, graphene has aroused worldwide academic passion in electronic community, due to its unique two dimensional lattice structure and high mobility properties. Meanwhile, the utilization of graphene...
The content of this RSS Feed (c) The Royal Society of Chemistry




v

Lithium bis(oxalate)borate additive in electrolyte to improve Li-rich layered oxide cathode materials

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00094A, Research Article
Zi Xiao, Jiuding Liu, Guilan Fan, Meng Yu, Junxiang Liu, Xinglong Gou, Mingjian Yuan, Fangyi Cheng
Lithium-rich layered oxides (LLO), as the most attractive cathode materials for high-energy lithium-ion batteries (LIBs), are plagued by poor cyclability due to structural and electrode/electrolyte interface instability. Herein, we report...
The content of this RSS Feed (c) The Royal Society of Chemistry




v

Advanced functional polymer materials

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00025F, Review Article
Kaojin Wang, Kamran Amin, Zesheng An, Zhengxu Cai, Hong Chen, Hongzheng Chen, Yuping Dong, Xiao Feng, Weiqiang Fu, Jiabao Gu, Yanchun Han, Doudou Hu, Rongrong Hu, Die Huang, Fei Huang, Feihe Huang, Yuzhang Huang, Jian Jin, Xin Jin, Qianqian Li, Tengfei Li, Zhen Li, Zhibo Li, Jiangang Liu, Jing Liu, Shiyong Liu, Huisheng Peng, Anjun Qin, Xin Qing, Youqing Shen, Jianbing Shi, Xuemei Sun, Bin Tong, Bo Wang, Hu Wang, Lixiang Wang, Shu Wang, Zhixiang Wei, Tao Xie, Chunye Xu, Huaping Xu, Zhi-Kang Xu, Bai Yang, Yanlei Yu, Xuan Zeng, Xiaowei Zhan, Guangzhao Zhang, Jie Zhang, Ming Qiu Zhang, Xian-Zheng Zhang, Xiao Zhang, Yi Zhang, Yuanyuan Zhang, Changsheng Zhao, Weifeng Zhao, Yongfeng Zhou, Zhuxian Zhou, Jintao Zhu, Xinyuan Zhu, Ben Zhong Tang
This review presents the recent developments in the research hotspots of advanced functional polymers; their concepts, design strategies, and applications are briefly discussed.
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Electrical stability study of polymer-based organic transistors in ambient air using an active semiconducting/insulating polyblend-based pseudo-bilayer

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00048E, Research Article
Bo-Ren Lin, Horng-Long Cheng, Hung-Han Lin, Fu-Chiao Wu, Jia-Hui Lin, Wei-Yang Chou, Jrjeng Ruan, Yu-Wu Wang
Polymeric transistors with unexpected nondecaying features even in ambient air are fabricated based on a P3HT/PMMA pseudo-bilayer with microphase separation morphology.
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Intentional modification of the optical spectral response and relative sensitivity of luminescent thermometers based on Fe3+,Cr3+,Nd3+ co-doped garnet nanocrystals by crystal field strength optimization

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00097C, Research Article
K. Kniec, K. Ledwa, K. Maciejewska, L. Marciniak
The relative sensitivity and usable temperature range of Fe3+,Cr3+-based luminescent thermometers can be tuned by modification of the crystal field strength.
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v

AIEgen based polymorphs with solvent regulated crystal-to-crystal switch properties

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00154F, Research Article
Liming Lai, Bing Fang, Wenyu Cheng, Pengyu Li, Yantu Zhang, Meizhen Yin
An AIEgen with tunable polymorphism-dependent emission and solvent regulated crystal-to-crystal switch properties is reported. Our study has provided insight into the relationship between molecular stacking and emission properties.
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One-pot quaternization of dual-responsive poly(vinyl alcohol) with AIEgens for pH-switchable imaging and killing of bacteria

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00014K, Research Article
Jin Wang, Meng Gao, Zhong-Kai Cui, Yong-Guang Jia, Sa Liu, Kai-Feng Chen, Xiaohui Chen, Yiqing Zhang, Zhou Fang, Yunhua Chen, Kaojin Wang, Huatang Zhang, Lin Wang, Li Ren
Dual-responsive poly(vinyl alcohol) derivatives bearing AIEgens and quaternary ammonium moieties were prepared through a facile one-pot quaternization for the pH-switchable imaging and killing of bacteria.
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v

Novel cathode buffer layer of Al(acac)3 enables efficient, large area and stable semi-transparent organic solar cells

Mater. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QM00198H, Research Article
Yiming Bai, Chunyan Zhao, Rongkang Shi, Jun Wang, Fuzhi Wang, Tasawar Hayat, Ahmed Alsaedi, Zhan'ao Tan
Electrode buffer layer plays a more crucial in semi-transparent organic solar cells (ST-OSCs) than that of the opaque devices due to the additional requirements of the average visible transmittance (AVT)...
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v

Zeolite-confined carbon dots: tuning thermally activated delayed fluorescence emission via energy transfer

Mater. Chem. Front., 2020, 4,1404-1410
DOI: 10.1039/C9QM00549H, Research Article
Hongyue Zhang, Jiancong Liu, Bolun Wang, Kaikai Liu, Guangrui Chen, Xiaowei Yu, Jiyang Li, Jihong Yu
CD@zeolite composites with tunable TADF emission via an energy transfer process between confined CDs.
The content of this RSS Feed (c) The Royal Society of Chemistry




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NH4V3O8·0.5H2O nanobelts with intercalated water molecules as a high performance zinc ion battery cathode

Mater. Chem. Front., 2020, 4,1434-1443
DOI: 10.1039/D0QM00051E, Research Article
Hanmei Jiang, Yifu Zhang, Zhenghui Pan, Lei Xu, Jiqi Zheng, Zhanming Gao, Tao Hu, Changgong Meng, John Wang
NH4V3O8·0.5H2O nanobelts are synthesized by a low-temperature hydrothermal process, and exhibit high electrochemical performance in ARZIBs.
The content of this RSS Feed (c) The Royal Society of Chemistry




v

The power of dissociation: development of displacement assays for chemosensing and latent catalytic systems

Mater. Chem. Front., 2020, 4,1328-1339
DOI: 10.1039/C9QM00639G, Review Article
Cheuk-Fai Chow, Anxun Zheng, Min Huang, Chang Shen
Disassembly is an essential process in supramolecular chemistry. In this review, different bimetallic donor–acceptor-based chemosensors, chemodosimeters, catalysts and latent catalysts founded on various displacement assays will be discussed.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A zinc non-halide dopant strategy enables efficient perovskite CsPbI3 quantum dot-based light-emitting diodes

Mater. Chem. Front., 2020, 4,1444-1453
DOI: 10.1039/C9QM00734B, Research Article
Jinhang Li, Jiawei Chen, Leimeng Xu, Sinan Liu, Si Lan, Xiansheng Li, Jizhong Song
A zinc non-halide dopant strategy is employed to clarify the internal mechanism of Zn2+ doping without the introduction of halide ions and enhance the emission properties evidenced by the EQE of the QLEDs from 7.5% to 14.6% after Zn2+ doping.
The content of this RSS Feed (c) The Royal Society of Chemistry




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AIE-active Schiff base compounds as fluorescent probes for the highly sensitive and selective detection of Fe3+ ions

Mater. Chem. Front., 2020, 4,1471-1482
DOI: 10.1039/C9QM00792J, Research Article
Jonnagaddala Harathi, Kathavarayan Thenmozhi
AIE-active Schiff base compounds were synthesized and photophysical properties were investigated. The compounds exhibited prominent sensing behaviour towards Fe3+ ion with enhanced selectivity, high association constants and low detection limits.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Dual-doping of ruthenium and nickel into Co3O4 for improving the oxygen evolution activity

Mater. Chem. Front., 2020, 4,1390-1396
DOI: 10.1039/D0QM00079E, Research Article
Beibei Guo, Ruguang Ma, Zichuang Li, Jun Luo, Minghui Yang, Jiacheng Wang
Ru and Ni co-doped Co3O4 with improved OER activity were synthesized by a one-step hydrothermal method. Ru doping increases the intrinsic activity, while Ni doping creates more oxygen vacancies and exposes more active sites.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Sandwich structured dielectrics for air-stable and flexible low-voltage organic transistors in ultrasensitive pressure sensing

Mater. Chem. Front., 2020, 4,1459-1470
DOI: 10.1039/D0QM00062K, Research Article
Yue Jiang, Ziyang Liu, Zhigang Yin, Qingdong Zheng
A novel type of polymer sandwich dielectric is developed for air-stable, hysteresis-free and flexible OTFTs which can be used for low-power pressure sensors with ultrahigh sensitivity, wide detection range and fast response.
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Highly active hydrogen evolution catalysis on oxygen-deficient double-perovskite oxide PrBaCo2O6−δ

Mater. Chem. Front., 2020, 4,1519-1529
DOI: 10.1039/D0QM00056F, Research Article
Hayato Togano, Kaisei Asai, Seiji Oda, Hidekazu Ikeno, Shogo Kawaguchi, Kengo Oka, Kouhei Wada, Shunsuke Yagi, Ikuya Yamada
Oxygen-deficient double perovskite oxides PrBaCo2O6−δ exhibit highly active hydrogen evolution reaction catalysis, which is associated with multiple factors: oxygen deficiency, high Co valence, and A-site cation ordering.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Intervaginal space injection of a liquid metal can prevent breast cancer invasion and better-sustain concomitant resistance

Mater. Chem. Front., 2020, 4,1397-1403
DOI: 10.1039/C9QM00753A, Research Article
Open Access
Yupeng Cao, Xiajun Hu, Qiang Zhang, Wenda Hua, Nan Hu, Yifeng Nie, Xue Xu, Yonggang Xu, Chongqing Yang, Xiaohan Zhou, Wentao Liu, Dong Han
CW invasion by the primary tumor was inhibited by ISI of an LM. DCs were activated by the LM to sustain CR.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Design and construction of bi-metal MOF-derived yolk–shell Ni2P/ZnP2 hollow microspheres for efficient electrocatalytic oxygen evolution

Mater. Chem. Front., 2020, 4,1366-1374
DOI: 10.1039/D0QM00128G, Research Article
Jinyang Zhang, Xuan Sun, Yang Liu, Linrui Hou, Changzhou Yuan
Hierarchical yolk–shell Ni2P/ZnP2 hollow microspheres are smartly synthesized, and exhibit exceptional OER performance, benefiting from their unique compositional/structural merits.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Highly-selective synthesis of trimetallic PtRuCu nanoframes as robust catalysts for the methanol oxidation reaction

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00033G, Research Article
Hai-Jing Yin, Zhi-Ping Zhang, Yu Guo, Kun Yuan, Ya-Wen Zhang
PtRuCu NFs/C exhibited much higher mass activity and specific activity than commercial Pt/C and PtRuCu NPs/C towards the MOR due to the frame nanostructures and the synergistic effect of the trimetallics.
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v

[ASAP] Chemical Looping Gasification of Torrefied Biomass Using NiFe<sub>2</sub>O<sub>4</sub> as an Oxygen Carrier for Syngas Production and Tar Removal

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00584




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[ASAP] Enhanced Performance of Adsorptive Removal of Thiophene from Model Fuel over Micro–Mesoporous Binderless ZSM-5 Prepared by <italic toggle="yes">In Situ</italic> Crystallization

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00198




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[ASAP] Superhydrophobic Surface Fabrication for Strengthened Selective Water Shut-off Technology

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00498




v

[ASAP] Effects of Graphene Oxide on the Mechanical and Microscopic Characteristics of Cement-Based Plugging Material for Preventing Spontaneous Combustion of Coal

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00493




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[ASAP] Adsorption Behavior of CH<sub>4</sub> and C<sub>2</sub>H<sub>6</sub> on Shale under the Influence of CO<sub>2</sub> and Flue Gas

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00339




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[ASAP] Interplay between Viscous Pressure and Capillary Pressure on Polymer Gel Dehydration and Water Shutoff in Hydraulically Fractured Reservoirs

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00368




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[ASAP] Designing Novel High-Performance Shale Inhibitors by Optimizing the Spacer Length of Imidazolium-Based Bola-Form Ionic Liquids

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00788




v

[ASAP] Investigation of Mechanisms for Gravity Drainage of Heavy Oil and Solvent Mixtures in a Hele-Shaw Cell

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00599




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[ASAP] Zinc Nitrate as an Activation Agent for the Synthesis of Nitrogen-Doped Porous Carbon and Its Application in CO<sub>2</sub> Adsorption

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00305




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[ASAP] Experimental Determinations of Minimum Miscibility Pressures Using Hydrocarbon Gases and CO<sub>2</sub> for Crude Oils from the Bakken and Cut Bank Oil Reservoirs

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00570




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[ASAP] Effect of Partial Rapid Pyrolysis on Bituminous Properties: From Structure to Reactivity

Energy & Fuels
DOI: 10.1021/acs.energyfuels.9b04439




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[ASAP] Enhanced Oil Recovery Using Oleic Acid-Modified Titania Nanofluids: Underlying Mechanisms and Oil-Displacement Performance

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00594




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[ASAP] Kinetics and Mechanism of Catalytic Oxidation of NO in Coal Combustion Flue Gas over Co-Doped Mn–Ti Oxide Catalyst

Energy & Fuels
DOI: 10.1021/acs.energyfuels.0c00122