en

[ASAP] Metal-Free Room-Temperature Phosphorescence from Amorphous Triarylborane-Based Biphenyl

Organometallics
DOI: 10.1021/acs.organomet.0c00068




en

[ASAP] Synthesis of Boryl-Substituted Disilane, Disilene, and Silyl Cation

Organometallics
DOI: 10.1021/acs.organomet.0c00148




en

[ASAP] Electrochemical CO<sub>2</sub> Reduction — The Effect of Chalcogenide Exchange in Ni-Isocyclam Complexes

Organometallics
DOI: 10.1021/acs.organomet.0c00129




en

[ASAP] Neutral Ni(II) Catalysts Based on Maple-Lactone Derived [N,O] Ligands for the Polymerization of Ethylene

Organometallics
DOI: 10.1021/acs.organomet.0c00061




en

[ASAP] (Isonitrile)platinum(II) Complexes of an Amido Bis(N-heterocyclic carbene) Pincer Ligand

Organometallics
DOI: 10.1021/acs.organomet.0c00065




en

[ASAP] Effect of Ancillary Ligands as a Part of Counteranion in Neodymium-Catalyzed Isoprene Polymerization

Organometallics
DOI: 10.1021/acs.organomet.0c00112




en

[ASAP] Potentiostatically Controlled Olefin Metathesis

Organometallics
DOI: 10.1021/acs.organomet.0c00052




en

[ASAP] Development of P- and N-Chirogenic Ligands Based on Chiral Induction from a Phosphorus Donor to a Nitrogen Donor in Palladium Complexes

Organometallics
DOI: 10.1021/acs.organomet.0c00154




en

[ASAP] Catalytic C–H Bond Alkylation of Azoles with Alkyl Halides Mediated by Nickel(II) Complexes of Phenanthridine-Based <italic toggle="yes">N</italic>^<italic toggle="yes">N</italic><sup><italic tog

Organometallics
DOI: 10.1021/acs.organomet.0c00161




en

[ASAP] Revisiting the Palladium-Catalyzed Carbonylation of Allyl Alcohol: Mechanistic Insight and Improved Catalytic Efficiency

Organometallics
DOI: 10.1021/acs.organomet.0c00117




en

[ASAP] Transformation of a Norbornadiene Unit to Ethylenylcyclopentene Requiring Cooperation between Boron and Rhodium Centers

Organometallics
DOI: 10.1021/acs.organomet.0c00155




en

[ASAP] NHC-Palladium(II) Mononuclear and Binuclear Complexes Containing Phenylene-Bridged Bis(thione) Ligands: Synthesis, Characterization, and Catalytic Activities

Organometallics
DOI: 10.1021/acs.organomet.0c00091




en

[ASAP] Spatial Recognition Within Terpenes: Redox and H-bond Promoted Linkage Isomerizations and the Selective Binding of Complex Alkenes

Organometallics
DOI: 10.1021/acs.organomet.0c00151




en

[ASAP] Linkage Isomerism in Dinuclear Al and Ga Organometallic Complexes: Structural and Reactivity Consequences

Organometallics
DOI: 10.1021/acs.organomet.0c00096




en

[ASAP] Self-Assembled Redox-Active Tetraruthenium Macrocycles with Large Intracyclic Cavities

Organometallics
DOI: 10.1021/acs.organomet.0c00116




en

[ASAP] Effect of the Lead(II) Bond Angle on the Reactivity of Diaminoplumbylenes toward Ammonia: From Inertness to Immediate Ammonolysis

Organometallics
DOI: 10.1021/acs.organomet.0c00196




en

[ASAP] Electrosynthetic Route to Cyclopentadienyl Rhenium Hydride Complexes Enabled by Electrochemical Investigations of their Redox-Induced Formation

Organometallics
DOI: 10.1021/acs.organomet.0c00049




en

[ASAP] Synthesis and Characterization of an Oxo-Centered Homotrimetallic Uranium(IV)–Cyclobutadienyl Dianion Complex

Organometallics
DOI: 10.1021/acs.organomet.0c00104




en

[ASAP] Development of Quinoline-Derived Chiral Diaminocarbene Ligands and Their Transition Metal Complexes: Synthesis, Structural Characterization, and Catalytic Properties

Organometallics
DOI: 10.1021/acs.organomet.0c00141




en

[ASAP] Reactivity of [Ce(NR<sub>2</sub>)<sub>3</sub>] (R = SiMe<sub>3</sub>) with Prospective Carbon Atom Transfer Reagents

Organometallics
DOI: 10.1021/acs.organomet.0c00186




en

[ASAP] Reactivity of Amidinatosilylenes and Amidinatogermylenes with [PtMe<sub>2</sub>(?<sup>4</sup>-cod)]: <italic toggle="yes">cis</italic>- versus <italic toggle="yes">trans</italic>-[

Organometallics
DOI: 10.1021/acs.organomet.0c00188




en

[ASAP] Synthesis and Characterization of Tungsten Alkylidene and Alkylidyne Complexes Featuring a New Carbazole-Based Rigid Trianionic ONO<sup>3–</sup> Pincer-Type Ligand

Organometallics
DOI: 10.1021/acs.organomet.0c00150




en

[ASAP] <italic toggle="yes">O</italic>-Carboranylene versus Phenylene Backbones in Cyclization Reactions of 1,2 Diketones with Hydrosilanes

Organometallics
DOI: 10.1021/acs.organomet.0c00208




en

[ASAP] Heteroleptic ß-Ketoiminate Magnesium Catalysts for the Ring-Opening Polymerization of Lactide

Organometallics
DOI: 10.1021/acs.organomet.0c00168




en

[ASAP] C5 Metalation of Imidazole-Based Monothiolates en Route to Selenothiolates

Organometallics
DOI: 10.1021/acs.organomet.0c00201




en

[ASAP] Sesquicarbene Complexes: Bonding at the Interface Between M–C Single Bonds and M-C Double Bonds

Organometallics
DOI: 10.1021/acs.organomet.0c00102




en

[ASAP] Catalytic Dimerization of Alkynes via C–H Bond Cleavage by a Platinum–Silylene Complex

Organometallics
DOI: 10.1021/acs.organomet.0c00195




en

[ASAP] Synthesis, Structures, and Electronic Properties of O- and S-Heterocyclic Carbene Complexes of Iridium, Copper, Silver, and Gold

Organometallics
DOI: 10.1021/acs.organomet.0c00066






en

So Entitled?

As we reach the ripe old age of 30 we sit back and chat about a topic we often come back to over an artisinal flat white – why do people think everything on the web “should” be free? We discuss some possible causes, the backlash against app developers charging for previously free tools and ponder if the rise of big VC has played it’s part too.

Oh and yes there’s yet more microphone drama. All will be explained next week. As always we do apologise for the disruption to the service.

If you like our show please feel free to leave us a review on iTunes.




en

Free Content Forever?

In this week’s episode, we turn our gaze to the topic of ad-blockers and paid content. We discuss Vitaly from Smashing Magazine’s recent post looking at how they are funding their content strategy and discuss our own views on paying for digital content.

As always we book end the show with some “bants” including heartfelt thanks to some of our favourite supporters and a nod to a Cornish brewing companies new site.




en

The Super Lit, Fam, Dope, En Flique Episode

It feels like only last week that the two “K Units” got behind the Samson CO1UPRO‘s and recorded episode #43. So close in fact, that we even manage to think we are still actually recording episode #43!

In this short 53 minute episode, we catch up on recent life goings on, learn that Kieran has been “tamping hard” in his role as “Digital Guy” at the bespoke artisanal coffee roasting company, discuss language used by people under the age of 30, announce our new club, and round out with a chat about Kickstarter. There may even be a mention of earphones!




en

25% jump in mental health cases in Gujarat

(This story originally appeared in AhmedabadMirror on May 8, 2020)




en

IIEBM - Learning experience for gen-next leaders

If you are an aspiring management student, you might have been storming your head after reading about all the academic rigour and jam-packed schedules that o...




en

Covid-19 medical staff to get addl compensation

The Amdavad Municipal Corporation (AMC) has decided to give additional financial compensation to health and paramedical staff of AMC and private designated Covid-19 hospitals who contact coronavirus infection on duty.




en

At frontline, junior docs are soldiers, generals

In the ward of Covid-19 patients, one could expect the medicine, anaesthesia or pulmonology experts at work. But if one visits Civil Hospital, the treating doctor could well be on his/ her way to become ophthalmologist, gynaecologist or general surgeon! In SVP hospital, he or she may be specialising in psychiatry too!




en

Ahd: Patient’s death discovered 7 hours later

In an incident that raises serious questions about Covid-19 care centres run by the city civic body, a 27-year-old coronavirus positive man died in his bed after suffering seizure at room 808-Block G3, at Samras Covid-19 care centre in Navrangpura. Only asymptomatic patients are isolated here so that they can be monitored and sent to hospital if they develop symptoms, or discharged when they turn negative.




en

Parents away, cops celebrate kid's birthday

(This story originally appeared in AhmedabadMirror on May 9, 2020)




en

Resource Showcase: National Emergency Library

Internet Archive has launched a National Emergency Library, containing over 1.4 million ebooks that are usually restricted by institutional passwords and paywalls. These are freely available during the Covid-19 crisis until 30 June 2020. Read more about additional e-resources currently available See what e-resources we currently have on trial See what other resources the library has for your subject




en

Synthesis of lignin-functionalized phenolic nanosphere supported Ag nanoparticles with excellent dispersion stability and catalytic performance

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04311J, Paper
Shilin Chen, Guanhua Wang, Wenjie Sui, Ashak Mahmud Parvez, Chuanling Si
This work presents a novel and green lignin-based nanocomposite and highlights the synergism of lignin's multiple functions (surfactant, sacrificial template, and reducing agent) in the material preparation process.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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en

One-pot hydrodeoxygenation of biomass furan derivatives into decane under mild conditions over Pd/C combined with phosphotungstic acid

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00428F, Paper
Song Li, Long Yan, Qiying Liu, Jianguo Liu, Qiyu Liu, Wei Fan, Xuelai Zhao, Xinghua Zhang, Chenguang Wang, Longlong Ma, Qi Zhang
One-pot hydrodeoxygenation of δ-furfurylidenelevulinic acid over Pd/C combined with phosphotungstic acid through successive hydrogenolysis and HDO of furans and lactones.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Water Effects in the Heterogeneous Catalytic Valorization of Levulinic Acid into γ-Valerolactone and its Derivatives

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01082K, Critical Review
Rengui Weng, Zhihao Yu, Jian Xiong, Xuebin Lu
Levulinic acid (LA), which has been hailed as a versatile biomass-derived platform molecular, typically occupy a core position in the cellulosic biorefinery system. The heterogeneous catalytic valorization of LA for...
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Humin based resin for wood modification and property improvement

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC03620B, Paper
Open Access
Anna Sangregorio, Anitha Muralidhara, Nathanael Guigo, Lisbeth G. Thygesen, Guy Marlair, Carlo Angelici, Ed de Jong, Nicolas Sbirrazzuoli
Focus on humins, a co-product from sugar conversion, to highlight their capacity to impregnate wood cell walls for making durable wood products.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Ni-Catalyzed hydrocyanation of alkenes with formamide as the cyano source

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04275J, Communication
Xiao Shu, Yuan-Yuan Jiang, Lei Kang, Luo Yang
A novel Ni-catayzed hydrocyanation of various alkenes to provide aliphatic nitriles is developed by generating hydrocyanic acid in situ from safe and readily available formamide.
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en

Ni-Based Heterogeneous Catalysts for the Transformation of Fatty Acids into Higher Yields of O-Free Hydrocarbons

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00853B, Paper
Diego Valencia, Citlalli Zenteno, Diana Gomora-Herrera, María Teresa Gómez-Pérez, Jorge Aburto
A series of novel catalytic materials were synthesized by changing the chemical compounds in the impregnation solutions. A rigid, aromatic and bidentate molecule 1,10-phenanthroline (PhN) was used as a ligand...
The content of this RSS Feed (c) The Royal Society of Chemistry




en

Photocatalyst-free visible light promoted E → Z isomerization of alkenes

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04303A, Communication
Jianbin Xu, Na Liu, Haiping Lv, Chixian He, Zining Liu, Xianfu Shen, Feixiang Cheng, Baomin Fan
A photocatalyst-free, simple and green method of visible light driven photocatalytic E to Z isomerization of alkenes has been developed.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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en

Eco-friendly and sustainable synthesis of biocompatible nanomaterials for diagnostic imaging: current challenges and future perspectives

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00734J, Critical Review
Ghazaleh Jamalipour Soufi, Siavash Iravani
Current advancements, important challenges and future perspectives of biocompatible nanomaterials for diagnostic imaging are discussed as well as their greener synthesis.
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en

New biobased-zwitterionic ionic liquids: efficiency and biocompatibility for the development of sustainable biorefinery processes

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC01002B, Paper
Gaël Huet, Monica Araya-Farias, Ranim Alayoubi, Sylvain Laclef, Benjamin Bouvier, Isabelle Gosselin, Christine Cézard, Romain Roulard, Matthieu Courty, Caroline Hadad, Eric Husson, Catherine Sarazin, Albert Nguyen Van Nhien
A combination of experiments and modeling reveals the influence of alkyl chain lengths in biobased ZILs on the biocompatibility towards various microorganisms.
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en

Synthesis of amorphous Geobacter-manganese oxide biohybrid as efficient water oxidation catalysts

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9GC04353E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shafeer Kalathil, Krishna Katuri, Pascal Saikaly
The development of low cost and efficient oxygen evolution reaction (OER) catalyst has paramount importance to meet future sustainable energy demand. Nature’s photosynthetic machinery deploy manganese-based complex in photosystem II...
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