Inorg. Chem. Front., 2020, 7,1643-1650
DOI: 10.1039/C9QI01684H, Research Article

Duoyu Lin, Pan Duan, Weiting Yang, Yanfeng Liu, Qinhe Pan
Through the protection effect of CTAB, a facile controlled synthesis of core–shell/yolk–shell/hollow ZIF-67@Co-LDH/SiO₂ under ambient conditions by adjusting the reaction time was realized.
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Inorg. Chem. Front., 2020, 7,1676-1684
DOI: 10.1039/C9QI01486A, Research Article

Ting Wang, Ming Xu, Xiaohong Li, Chunlei Wang, Weilin Chen
Highly dispersed POM nanoparticles as functional components have been deposited on CNTs to produce periodic functionalized CNTs. The obtained Co₄PW₉/CNTs CE exhibits the best photovoltaic performance with a PCE of 7.60%, higher than both pure CNTs and Pt CE.
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Inorg. Chem. Front., 2020, 7,1685-1690
DOI: 10.1039/D0QI00245C, Research Article

Yuan-Yuan Peng, Si-Guo Wu, Yan-Cong Chen, Wei Liu, Guo-Zhang Huang, Zhao-Ping Ni, Ming-Liang Tong
An unprecedented hysteretic seven-/eight-step spin-crossover behavior is revealed. Most importantly, a molecular alloy based on a Hofmann-type framework is used as a strategy to explore multi-step spin-crossover materials for the first time.
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Inorg. Chem. Front., 2020, 7,1741-1749
DOI: 10.1039/D0QI00102C, Research Article

Wei Jian, Ran Jia, Hong-Xing Zhang, Fu-Quan Bai
An essential understanding is obtained from the cation engineering process into the expected excited-state properties of hybrid perovskite materials.
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Inorg. Chem. Front., 2020, 7,1704-1712
DOI: 10.1039/D0QI00019A, Research Article

Xin Li, Dingsheng Jiang, Yizhuo Fan, Nan Zhang, Caixia Liu, Samira Adimi, Jingran Zhou, Shanpeng Wen, Shengping Ruan
One dimensional Zr-doped α-MoO₃ nanobelts were synthesized, and the influence of Zr doping on xylene sensing properties was studied.
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Inorg. Chem. Front., 2020, 7,1699-1703
DOI: 10.1039/D0QI00040J, Research Article

Hai-Yan Sun, Shi-Hao Sun, Bing Hu, Liao-Kuo Gong, Yan-Min Zou, Ji-Long Li, Mei-Ling Feng, Xiao-Ying Huang
A new layered vanadium selenite single crystal exhibits anisotropic proton conductivities along the [100] and [001] directions with the Grotthuss and Vehicle mechanisms, respectively.
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Inorg. Chem. Front., 2020, 7,1770-1779
DOI: 10.1039/D0QI00117A, Research Article

Feng Guo, Lijing Wang, Haoran Sun, Mingyang Li, Weilong Shi
N-Doped porous g-C₃N₄ nanosheets for high-efficiency photocatalytic water splitting were prepared by mixing the precursor of N,N-dimethylformamide and urea through a simple one-step thermal copolymerization method.
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Inorg. Chem. Front., 2020, 7,1667-1675
DOI: 10.1039/D0QI00099J, Research Article

Weihua Gu, Jing Zheng, Xiaohui Liang, Xiaoqing Cui, Jiabin Chen, Zhu Zhang, Guangbin Ji
Upon introducing Gibbs free energy to effectively control the final products, the as-prepared carbon-based composites show excellent absorbing ability at 1.4 mm.
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Inorg. Chem. Front., 2020, 7,1726-1740
DOI: 10.1039/D0QI00200C, Research Article

Lei Xu, Ning Pu, Gaoyang Ye, Chao Xu, Jing Chen, Xingwang Zhang, Lecheng Lei, Chengliang Xiao
The separation and complexation mechanisms of actinide(III) and lanthanide(III) with a new phenanthroline-derived phosphonate ligand were studied experimentally and theoretically.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00119H, Research Article

Wenna Li, Lang He, Xue Bai, Lujia Liu, Muhammad Ikram, He Lv, Mohib Ullah, Mawaz Khan, Kan Kan, Keying Shi
S-Doped biomorphic SnO₂ with active S-terminations and S–Sn–O chemical bonds has significantly improved gas sensing performance to NO₂ at room temperature.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00208A, Research Article

Lei Qiu, Hang Yang, Zhigao Dai, Fengxu Sun, Jiarui Hao, Mengyu Guan, Peipei Dang, Chunjie Yan, Jun Lin, Guogang Li
A highly stable and efficient CsPbBr₃@SiO₂ composite phosphor is achieved by protecting the CsPbBr₃ QDs from direct exposure to the atmosphere by encapsulating CsPbBr₃ into dual-shell hollow silica nanospheres.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QI01478K, Research Article

Sriram Sundaresan, Jonathan A. Kitchen, Sally Brooker
Linear correlation of the hydrophobic alkyl tail length R employed in [Fe^II(L^H-OR)(NCBH₃)₂] with the spin crossover switching temperature is a very convenient method of predictably tuning the iron(II) spin state.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00023J, Research Article

Yao Yuan, Xiaoyu Chen, Xing Zhang, Zumin Wang, Ranbo Yu
A CuCo(O)-embedded nitrogen-enriched porous carbon framework catalyst derived from doped metal–organic frameworks for efficient hydrolysis of ammonia borane.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00259C, Research Article

Ping He, Jiehua Ding, Zhengxing Qin, Lingxue Tang, Kok-Giap Haw, Yiying Zhang, Qianrong Fang, Shilun Qiu, Valentin Valtchev
Organic structure directing agent (OSDA)- and binder-free preparation of ZSM-5@silica beads and their use for aniline removal.
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00361A, Research Article

Ran Wang, Guoan Lin, Xiaoxiang Xu
La/Zr co-doped SrTaO2N has been investigated as visible-light-active photocatalysts for water reduction. Unlike previous aliovalent doping that leads to degradation of light absorption, La/Zr co-doping largely preserves the visible light...
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00319K, Research Article

Fabrice Pointillart, Jessica Flores-Gonzalez, Vincent Montigaud, Lorenzo Tesi, Vladimir Kuz'mich Cherkasov, Boris Le Guennic, Olivier Cador, Lahcene Ouahab, Roberta Sessoli, Viacheslav Kuropatov
The first simultaneous redox and solvato-magnetic switching was achieved. The dinuclear complex [Dy2(hfac)6(H2SQ)]CH2Cl2 (Dy2H2SQ) (where hfac = 1,1,1,5,5,5-hexafluoroacethylacetonate and H2SQ = 2,2’-benzene-1,4-diylbis(6-hydroxy-4,7-di-tert-butyl-1,3-benzodithiol-2-ylium-5-olate) was reversibly oxidized into the dinuclear complex [Dy2(hfac)6(H2O)2(Q)]...
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00025F, Research Article

Liang Hou, Jianyu Han, Chong Wang, Yuwei Zhang, Yuanbin Wang, Zhiming Bai, Yousong Gu, Yan Gao, Xiaoqin Yan
The Ag/Cu composites present excellent catalytic activity for the reduction of CO₂ to C₂H₄, and exhibit a maximum Faraday Efficiency 41.3%.
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00276C, Research Article

Shuang Lü, Hongli Huang, Ru-Fen Zhang, Chunlin Ma, Qianli Li, Jiao He, Ting Li, jun yang, Yulong Li
In order to enrich the chemistry of the Fe/Te cluster compounds related to the active site of [FeFe]-hydrogenase, the reactions of compound Fe2(μ-TeAr)2(CO)6 with tertiary phosphines were described. Three types...
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00095G, Research Article

Zhenglong Fan, Fan Liao, Huixian Shi, Yang Liu, Mingwang Shao, Zhenhui Kang
A RuO₂/F-graphene catalyst with a low Ru content of 6.9 wt% only needs potentials of 1.56 V in alkaline medium and 1.73 V in neutral medium to reach a current density of 10 mA cm⁻² for electrocatalytic water splitting.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00346H, Research Article

Alexander V. Artem'ev, Alexey S. Berezin, Ilya V. Taidakov, Irina Yu. Bagryanskaya
An unprecedented structure-directing effect of solvents in halocuprate self-assembly reactions was discovered. The compounds presented show remarkable dual luminescence, strongly changing the emission color upon varying temperature.
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Inorg. Chem. Front., 2020, 7,1851-1863
DOI: 10.1039/D0QI00101E, Research Article

Emilia Kuzniak, James Hooper, Monika Srebro-Hooper, Jedrzej Kobylarczyk, Magdalena Dziurka, Bogdan Musielak, Dawid Pinkowicz, Jesus Raya, Sylvie Ferlay, Robert Podgajny
Comprehensive studies on a concerted evolution of supramolecular interactions with multicomponent synthon reproduction provide a new tool to describe the trapping of flat [M(L)₄]²⁻ complexes within π-acidic cavities.
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Inorg. Chem. Front., 2020, 7,1892-1899
DOI: 10.1039/D0QI00124D, Research Article

Jia-sen Zhu, Hao Yang, Weihong Zhang, Yanchao Mao, Shu-shen Lyu, Jian Chen
An in situ Raman study of the mechanism of HER catalytic performance enhanced by high-index facets on Ti@TiO₂ nanosheets.
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Inorg. Chem. Front., 2020, 7,1880-1891
DOI: 10.1039/D0QI00088D, Research Article

Rong-Yun Li, Hou-Ting Liu, Chuan-Cong Zhou, Zhi-Tong Chu, Jing Lu, Su-Na Wang, Juan Jin, Wen-Fu Yan
Two Ni(II) coordination compounds can reversibly SC–SC transform into each other induced by ligand substitution, causing changes in their proton conductivities.
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Inorg. Chem. Front., 2020, 7,1949-1956
DOI: 10.1039/D0QI00098A, Research Article

Juan Sun, Jing Xie, Licun Li, Jean-Pascal Sutter
New nitronyl nitroxide biradical-bridged 3d–4f chains have been constructed in which improved SCM behavior is observed.
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Inorg. Chem. Front., 2020, 7,1909-1917
DOI: 10.1039/D0QI00166J, Research Article

Jiguo Tu, Mingyin Kou, Mingyong Wang, Shuqiang Jiao
The degradation mechanism of the Al-NiCl₂ cell is confirmed to be mainly due to mass loss and electrode cracking caused by the dissolution of some Ni metal as the reduction product of NiCl₂ during discharging in acidic AlCl₃-based electrolyte.
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Inorg. Chem. Front., 2020, 7,1927-1938
DOI: 10.1039/D0QI00148A, Research Article

Meiyuan Guo, Xiaorui Liu, Rongxing He
The metal L-edge spectra of cobalt compounds have been interpreted through restricted active space calculations.
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Inorg. Chem. Front., 2020, 7,1939-1948
DOI: 10.1039/D0QI00231C, Review Article

Junxiong Liao, Wenjiang Zeng, Baishu Zheng, Xiyang Cao, Zhaoxu Wang, Guanyu Wang, Qingyuan Yang
A microporous acylamide functionalized rht-type MOF (HNUST-9) with Lewis acidic open copper sites and CO₂-philic acylamide groups exhibits high performance for CO₂ capture, separation and chemical conversion.
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Inorg. Chem. Front., 2020, 7,1957-1964
DOI: 10.1039/D0QI00181C, Research Article

Gang-Ding Wang, Yong-Zhi Li, Wen-Juan Shi, Lei Hou, Zhonghua Zhu, Yao-Yu Wang
A stable Cd-MOF was built by a carboxylate-tetrazolate ligand, which contains hexagonal channels and reveals multiple functions including separation of CO₂/CH₄, C₂H₂/CO₂, C₂H₂/CH₄ and benzene/cyclohexane, and catalytic conversion of CO₂ with epoxides.
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Inorg. Chem. Front., 2020, 7,1864-1871
DOI: 10.1039/D0QI00224K, Research Article

Cheng Zhang, Ruilin Guan, Xinxing Liao, Cheng Ouyang, Jiangping Liu, Liangnian Ji, Hui Chao
A dinuclear complex [(ppy)Ir(tpy)PtCl]²⁺ (Ir–Pt) can exhibit strong antitumor activity towards cisplatin-resistant cancer cells and induce cell necrosis via mtDNA damage and mitochondrial dysfunction.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00254B, Research Article

Nikita A. Shekhovtsov, Katerina A. Vinogradova, Alexei S. Berezin, Taisiya S. Sukhikh, Viktor P. Krivopalov, Elena B. Nikolaenkova, Mark B. Bushuev
Interplay of three emission mechanisms for silver(I) complexes leads to luminescence thermochromism and color tunable emission.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00359J, Research Article

Juan Zhang, Yueying Chu, Feng Deng, Zhaochi Feng, Xiangju Meng, Feng-Shou Xiao
The formation and evolution of building units for zeolites play an important role during crystallization.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00050G, Research Article

Reza Abazari, Ali Morsali, Deepak P. Dubal
Pharmaceuticals are considered as emerging organic contaminants that have become a serious environmental problem, which endanger human health and environmental bio-diversity.
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Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00318B, Research Article

Shasha Tang, Xiaogang Li, Marc Courté, Jingjing Peng, Denis Fichou
Interconnected porous nanoflakes of the bimetallic CoMo₂S₄ are synthesized and investigated as bifunctional catalysts for highly efficient overall water electrolysis.
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00338G, Research Article

Mingkai Fu, Huajun Xu, Xin Li
Highly reducible and thermally-stable lanthanum-manganese perovskites represent a promising class of materials for solar thermochemical hydrogen production. However, such materials suffer from low hydrogen production rate, resulting in incomplete re-oxidation...
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00295J, Research Article

Lisi Yin, Xinran Ding, Wenxian Wei, YiHui Wang, Zizheng Zhu, Kai Xu, Ziming Zhao, Hong Zhao, Tingting Yu, Tao Yang
As an energy carrier, hydrogen shows great promise superior to the traditional fossil fuel to meet the ever-increasing global energy demands. Electrochemical water splitting has been considered to be an...
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Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00001A, Review Article

Sunhee Lee, Won-Sik Han
The main difficulties hindering development of a deep-blue phosphorescent cyclometalated Ir(III) complex are insufficient colour purity, i.e., failure to achieve ideal Commission Internationale de L’Eclairage (CIE) coordinates of (0.14, 0.09),...
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