Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02645J, Communication

Jiwei Wang, Licheng Zhan, Gendi Wang, Yin Wei, Min Shi, Jun Zhang
Oxidative addition of Pd/Au vinylene species with iodobenzene reveals the effect of a strong metallophilic Pd⋯Au interaction on phenyl transmetalation from Pd^IV to Au^I, which allows subsequent reductive elimination of LAuI at Pd and Au.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC00188K, Communication

Wei Zhang, Jin-Hong Lin, Pengfei Zhang, Ji-Chang Xiao
Described herein is the convenient transformation of aldoximes into nitriles or isonitriles by slightly modifying reaction conditions.
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00962H, Communication

Rongfang Zhao, Yue Han, Wenlong Li, Jinhua Li, Ming Chen, Lingxin Chen
Nanocage-structured materials-heterogeneous binary metal sulfides (MoS2 and Co9S8) in carbon nanocages (Co9S8/MoS2@CNCs) via step-by-step confined growth display superior Li-storage performance, profiting from the synergistic effect of bimetallic sulfides, high filling...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02176H, Communication

Haobo Sun, Yunliang Qiu, Yajie Lu, Jinming Kong, Xueji Zhang
In this paper, an ultrasensitive, highly selective and green electrochemical biosensor for quantifying DNA sequences (aM DNA) based on MnTBAP catalyst for AGET ATRP reaction is proposed. For the first...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01915A, Communication

Sian-Hong Tseng, Lian-Ming Lyu, Kai-Yuan Hsiao, Wan-Hua Ho, Ming-Yen Lu
The present study employed the surfactant-free growth of ultralong (~50 μm) silver nanowires (AgNWs) with high aspect ratio (up to 500) by galvanic replacement. AgNW conducting film were fabricated as...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02300K, Communication

ZHILONG LI, Vincent Gandon, Christophe Bour
Styrene derivatives can be easily synthesized from vinyl triflates and arenes under mild reaction conditions, using [Li][Al(OC(CF₃)₃)₄] as a catalyst and LiHMDS as a base. This transformation is likely to...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00478B, Communication

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Glenn Wright, Chaoyi Yao, Tom Moody, A. P. De Silva
Molecular AND logic gates 1, 3, 5 and 7, which are designed according to principles of photoinduced electron transfer (PET) switching, respond to co-existing Candida antarctica lipase B and H+...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00564A, Communication

Tianshu Chen, Xin Fu, Qianqian Zhang, Dongsheng Mao, Yuchen Song, Chang Feng, Xiaoli Zhu
We have designed a DNA logic gate that can integrate multiple biomarkers recognition with signal amplification to perform accurate and and sensitive analysis of circulating tumor cells (CTCs). It also...
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01164A, Communication

Changjin Ou, Yewei Zhang, Wei Ge, Liping Zhong, Yong Huang, Weili Si, Wenjun Wang, Yongxiang Zhao, Xiaochen Dong
3D boron dipyrromethene (BODIPY)–Fe(III) coordination polymer nanoparticles with NIR-II absorption were developed as photothermal and chemodynamic agent to effectively kill cancer cells.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01505A, Communication

Jian-Xin Wang, Yi-Shuai Yu, Li-Ya Niu, Bo Zou, Kai Wang, Qing-Zheng Yang
Difluoroboron β-diketonate complexes that manifested temperature-dependent emission wavelength are reported.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01856B, Communication

Miantai Ye, Wei Hu, Meng He, Chenchen Li, Shuyang Zhai, Zhihong Liu, Yanying Wang, Huijuan Zhang, Chunya Li
A near-infrared two-photon fluorescent probe for selective detection and deep-depth imaging of NO helps to discover the relationship between NO and resistance to antitumor drugs.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01876G, Communication

Meng Yu, Da Xie, Rahul T. Kadakia, Weiran Wang, Emily L. Que
A Tm(III) complex displays an “off–on” ¹⁹F NMR/MRI response to Zn(II) upon tuning the chemical exchange rate.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01930E, Communication

Yanfei Qin, Lingjing Chen, Gui Chen, Zhenguo Guo, Lei Wang, Hongbo Fan, Marc Robert, Tai-Chu Lau
[Fe(qnpy)(H₂O)₂]²⁺ is a highly efficient and robust catalyst for visible-light-driven reduction of CO₂ to CO, with a TON for CO of up to 14 095 and selectivity of 98% using Ru(phen)₃Cl₂ as photosensitizer and BIH as sacrificial reductant.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01517B, Communication

Weiyuan Ding, Hongquan Yu, Yu Tang, Zhuxin Li, Bijiao Liu, Dechong Liu, Yuyu Wang, Shu hong Liu, Hong Zhao, Daniel Mandler
A Fe–NC catalyst containing carbon nanotubes, mesopores and macropores with a measurable 3D framework structure was prepared by electrospinning.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01756F, Communication

Pernille Rose Jensen, Sebastian Meier
Structures and rates in the catalytic cycle of carbohydrate dehydration by Lewis acidic salt are determined through the systematic use of complementary NMR approaches.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01936D, Communication

Yunfei Fan, Yahang Xie, Zhen Zhao, Yang Zhao, Rui Yu, Xiang-yang Liu, Youhui Lin, Changxu Lin
A wettability read-out strategy for an aptasensor is setup with a bilayer surface. It targets on methamphetamine and uses hydrophobicity reduction as the signal induced by recognition by the supporting aptamer layer.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01250E, Communication

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

G. Ferrand-Drake del Castillo, R. L. N. Hailes, Z. Adali-Kaya, T. Robson, Andreas Dahlin
A new and generic method for protein capture-release by polyelectrolyte brushes and pH control.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02550J, Communication

Hao Zeng, Chuanle Zhu, Chi Liu, Yingying Cai, Fulin Chen, Huanfeng Jiang
The three component hydroxyletherification and hydroxylazidation reactions of (trifluoromethyl)alkenes are reported, providing various useful α-trifluoromethyl β-heteroatom substituted tertiary alcohols in high yields.
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02520H, Communication

Emily Lythell, Reynier Suardiaz, Philip Hinchliffe, Chonnikan Hanpaibool, Surawit Visitsatthawong, Sofia Oliveira, Eric Lang, Panida Surawatanawong, Vannajan Sanghiran Lee, Thanyada Rungrotmongkol, Natalie Fey, James Spencer, Adrian John Mulholland
MCR (mobile colistin resistance) enzymes catalyse phosphoethanolamine (PEA) addition to bacterial lipid A, threatening the “last-resort” antibiotic colistin. Molecular dynamics and density functional theory simulations indicate that monozinc MCR supports...
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC90201B, Correction

Open Access

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Cheng-Ying Chan, Chao-Hung Chang, Hsing-Yu Tuan
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02620D, Communication

Ruoyu Fan, Zhi Hu, Chun Chen, Xiaoguang Zhu, Haimin Zhang, Yunxia Zhang, Huijun Zhao, Guozhong Wang
ZIF-8 was employed as template to synthesize HD-Ni/N-CMS containing highly dispersed Ni at atomic-level anchored on N-doped carbon molecular sieve for vanillin hydrodeoxygenation. The ZIF-8 structure was inherited and Ni-N...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01833C, Communication

Hyeon Jin Park, Chang Wook Song, Sourav Sarkar, Yong Woong Jun, Ye Jin Reo, Mingchong Dai, Kyo Han Ahn
Near-infrared-emitting hemicyanine dyes are widely used in activatable fluorescent probes for various biological analytes, which fact, on the contrary, poses a chemical stability issue along with photoinstability as shown here...
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Chem. Commun., 2020, 56,5058-5061
DOI: 10.1039/D0CC00641F, Communication

Xiao-Yue Chen, Xiao-Xue Nie, Yichen Wu, Peng Wang
Using thianthrene S-oxide (TTSO) as a transient mediator, para-arylation and alkenylation of mono-substituted arenes have been demonstrated via a para-selective thianthrenation/Pd-catalyzed thio-Suzuki–Miyaura coupling sequence under mild conditions.
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Chem. Commun., 2020, 56,5054-5057
DOI: 10.1039/D0CC01188F, Communication

Suman Pradhan, Sandeep Patel, Indranil Chatterjee
Aromatic amines and (hetero)arenes, such as indoles and pyrroles, are regioselectively sulfinylated under mild aerobic conditions using nitrosoarenes as a redox-catalyst.
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Chem. Commun., 2020, 56,5006-5009
DOI: 10.1039/D0CC01197E, Communication

Wenhuai Feng, Chengxi Zhang, Jun-Xing Zhong, Liming Ding, Wu-Qiang Wu
Anchoring of amine ligands with different alkyl chain lengths on perovskites mitigates non-radiative charge recombination in perovskite solar cells.
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Chem. Commun., 2020, 56,5014-5017
DOI: 10.1039/D0CC01643H, Communication

Lixia Zhang, Zhenhua Li, Zhijun Chen
A curli fluorescent light-up probe called bromophenol blue, which binds to curli via recognizing CsgA.
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Chem. Commun., 2020, 56,5026-5029
DOI: 10.1039/D0CC01339K, Communication

Ignacio Rosa-Pardo, Carla Casadevall, Luciana Schmidt, Miguel Claros, Raquel E. Galian, Julio Lloret-Fillol, Julia Pérez-Prieto
The cooperative action between the CsPbBr₃ surface and capping makes the photoredox homo-/cross-coupling of benzyl bromides under mild conditions possible.
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Chem. Commun., 2020, 56,4990-4993
DOI: 10.1039/D0CC01488E, Communication

Dan Guo, Huayu Chen, Hanmin Tian, Shuxin Ouyang, Jianbo Wang, Jun Lv
A strategy involving modulating the intermediate layer of an electrode was developed to promote the electrocatalysis kinetics of the electrode and therefore enhance its performance.
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Chem. Commun., 2020, 56,5046-5049
DOI: 10.1039/C9CC09563B, Communication

Kostadin V. Petrov, Laura Paltrinieri, Lukasz Poltorak, Louis C. P. M. de Smet, Ernst J. R. Sudhölter
A novel ion separation methodology using a cation-exchange membrane modified with iron oxide nanoparticles (Fe₃O₄ NPs) coated with polyhexamethylene guanidine (PHMG) is proposed.
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Chem. Commun., 2020, 56,4986-4989
DOI: 10.1039/D0CC01557A, Communication

Jordan P. Hooker, Florian Feist, Laura Delafresnaye, Federica Cavalli, Leonie Barner, Christopher Barner-Kowollik
Polymer particles are synthesized using a photo-active ortho-methyl benzaldehyde with a terminal alkyne for cross-linking. The reactive 1,4-dihydronaphthalene at every cross-linking point undergoes aromatisation to a fluorescent naphthalene upon exposure to acid.
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Chem. Commun., 2020, 56,4970-4981
DOI: 10.1039/D0CC00841A, Highlight

Gilles Berger, Pierre Frangville, Franck Meyer
This review highlights recent developments of halogen bonding in materials and biological sciences with a short discussion on the nature of the interaction.
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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01331E, Communication

Jun Li, Ke Yi, Yanli Lei, Zhihe Qing, Zhen Zou, Yuedong Zhang, Haiyan Sun, Ronghua Yang
In this work, an Al centre-powered graphitic nanozyme (Fe/Al-GNE) was developed for chemodynamic cancer therapy, which afforded pH-independent catalytic activity and high reaction kinetics.
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02214D, Communication

Rong Fu, Junying Zhang, Shaojie Liu, Xing-Dong XU, Shengyu Feng
Reticulated copolymer hosts pillar[5]arene crosslinked with poly(dimethylsiloxane) (PDMS) were synthesized for the facile construction of double network crosslinked elastomer upon noncovalently cross-linking with tetraphenyethylene (TPE)-based tetratopic guests through host-guest interactions....
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00536C, Communication

Xiang Hao, ZeJian Leng, Dan Sun, Feng Peng, Akram Yasin
We herein report a 12-armed photo-responsive supramolecular star centered by a pillar[6]arene-coated M6L12 metal-organic polyhedron (MOP) via core-first approach.
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02164D, Communication

María José Dávila-Rodríguez, Thales Souza Freire, Erik Lindahl, Ignez Caracelli, Júlio Zukerman-Schpector, Ran Friedman
Drug resistance is a serious problem in cancer, viral, bacterial, fungal and parasitic diseases. Examination of crystal structures of protein-drug complexes is often not enough to explain why a certain...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02943B, Communication

Le Yu, Jun Feng Zhang, Mingle Li, Dewei Jiang, Ying Zhou, Peter Verwilst, Jong Seung Kim
We report a novel fluorescent molecular conjugate V-M1 enabling an accurate visualization of tumor tissues. The emission wavelength of V-M1 exceeds 650 nm, well within the near-infrared therapeutic window. Tumor...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02851G, Communication

Sheuli Sasmal, Soumya Kumar Sinha, Goutam Kumar Lahiri, Debrabrata Maiti
A meta selective C‒H nitration of phenol derivatives have been developed using a Ru-catalyzed σ-activation strategy. Cu(NO3)2.3H2O has been employed as the nitrating source while Ru3(CO)12 was found to be...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02329A, Communication

Lijian Zhang, Fei Ma, Ao Qi, Lulu Liu, Junjie Zhang, Simin Xu, Qisheng Zhong, Yusen Chen, Chun-yang Zhang, Chun Cai
We report for the first time the integration of ultra-high-pressure liquid chromatography-tandem mass spectrometry with machine learning for identifying fatty acid metabolite biomarkers of ischemic stroke. Especially, we develop an...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01854F, Communication

Indrani Bhowmick, David Washburn Shaffer, Jenny Y Yang, Matthew Shores
We report the first example of field-induced single molecule magnet (SMM) behaviour in a square-planar S = ½ Co(II) pincer complex [(P^NN^NP)CoBr]Br (2). The related five-coordinate complexes [(P^CN^CP)CoBr₂] (1) and...
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02506B, Communication

Takehiro Hirao, Yoshiki Iwabe, Naoyuki Hisano, Takeharu HAINO
Chiral biscalixarenes and a C60-appended polyphenylacetylene have been synthesized. The chiral biscalixarene encapsulated the C60 unit of the phenylpolyacetylene, which induced the preferred helicity of the polyacetylene.
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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02252G, Communication

Batul Ismail Habibullah, Vasvi Tripathi, Parag Surana, Ranabir Das
Ubiquitin (Ub) is a highly conserved 76-amino acid polypeptide that is abundant throughout the eukaryotes. The covalent conjugation of Ub and Ub polymers to substrate proteins governs a variety of...
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