v Cooperative photoredox and chiral hydrogen-bonding catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2020, Advance ArticleDOI: 10.1039/D0QO00276C, Review ArticleYanli Yin, Xiaowei Zhao, Baokun Qiao, Zhiyong JiangChiral hydrogen-bonding catalysis is a classic strategy in asymmetric organocatalysis. Recently, it has been used to cooperate with photoredox catalysis, becoming a powerful tool to access optical pure compounds via radical-based transformations.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Double allylic defluorinative alkylation of 1,1-bisnucleophiles with (trifluoromethyl)alkenes: construction of all-carbon quaternary centers By pubs.rsc.org Published On :: Org. Chem. Front., 2020, Advance ArticleDOI: 10.1039/D0QO00121J, Research ArticleYingying Cai, Hao Zeng, Chuanle Zhu, Chi Liu, Guangying Liu, Huanfeng JiangSynthesis of symmetric gem-difluoroalkene substituted products bearing all-carbon quaternary centers via double allylic defluorinative alkylation of 1,1-bisnucleophiles with (trifluoromethyl)alkenes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Pd/light-induced alkyl–alkenyl coupling reaction between unactivated alkyl iodides and alkenylboronic acids By pubs.rsc.org Published On :: Org. Chem. Front., 2020, Advance ArticleDOI: 10.1039/D0QO00318B, Research ArticleHsin-Ju Huang, Yi-Ting Wang, Yen-Ku Wu, Ilhyong RyuAlkyl–alkenyl coupling reaction between unactivated alkyl iodides and 2-arylalkenylboronic acids utilizing a Pd/light combined system was studied.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Folding of fluorinated oligoarylenes into non-alternant PAHs with various topological shapes By pubs.rsc.org Published On :: Org. Chem. Front., 2020, Advance ArticleDOI: 10.1039/D0QO00370K, Research ArticleVladimir Akhmetov, Andreas Förtsch, Mikhail Feofanov, Sergey Troyanov, Konstantin AmsharovAn unprecedented [6]helicene's cavity closure indicating the possibility of introducing seven-membered rings via alumina-mediated C–F activation is shown.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Examining the vinyl moiety as a protecting group for hydroxyl (–OH) functionality under basic conditions By pubs.rsc.org Published On :: Org. Chem. Front., 2020, Advance ArticleDOI: 10.1039/D0QO00202J, Research ArticleVladimir V. Voronin, Maria S. Ledovskaya, Konstantin S. Rodygin, Valentine P. AnanikovA method for the protection and deprotection of alcohols via vinylation and devinylation reactions is proposed. Stability of the vinyl protecting group under various conditions is studied and synthetic applicability is demonstrated.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Access to SCN-containing thiazolines via electrochemical regioselective thiocyanothiocyclization of N-allylthioamides By pubs.rsc.org Published On :: Org. Chem. Front., 2020, Advance ArticleDOI: 10.1039/D0QO00300J, Research ArticleYan-An Zhang, Zhong Ding, Peng Liu, Wei-Si Guo, Li-Rong Wen, Ming LiAn electrochemical thiocyclization of N-allylthioamides has been developed for the synthesis of SCN-containing 2-thiazolines and NCS-containing thiazines.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Discovery of new polycyclic polyprenylated acylphloroglucinols with diverse architectures as potent cyclooxygenase-2 inhibitors By pubs.rsc.org Published On :: Org. Chem. Front., 2020, Advance ArticleDOI: 10.1039/D0QO00259C, Research ArticleShuangshuang Xie, Changxing Qi, Yulin Duan, Qianqian Xu, Yaping Liu, Yingying Huang, Xu Yin, Weiguang Sun, Yuan Zhou, Yonghui ZhangCyclooxygenase-2 (COX-2) is a significant therapeutic target of chronic inflammatory diseases.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Visible-light mediated oxidative ring expansion of anellated cyclopropanes to fused endoperoxides with antimalarial activity By pubs.rsc.org Published On :: Org. Chem. Front., 2020, Advance ArticleDOI: 10.1039/D0QO00168F, Research ArticleSimon Budde, Felix Goerdeler, Johannes Floß, Peter Kreitmeier, Elliot F. Hicks, Oren Moscovitz, Peter H. Seeberger, Huw M. L. Davies, Oliver ReiserHetero- and carbocyclic anellated cyclopropanes were converted in one step by a visible light induced photooxidation to their corresponding polycyclic endoperoxides, which show promising antimalarial activity.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Transition metal-catalyzed coupling of heterocyclic alkenes via C-H activation: Recent trends and applications By pubs.rsc.org Published On :: Org. Chem. Front., 2020, Accepted ManuscriptDOI: 10.1039/D0QO00279H, Review ArticleSundaravel Vivek Kumar, Sonbidya Banerjee, Tharmalingam PunniyamurthyHeterocyclic alkenes represent an important class of reactive feedstock and valuable synthons for the synthesis of biologically important heterocyclic scaffolds. Although functionalized heterocyclic alkenes and their derivatives can be accessed...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Access to cyano-substituted pyrazolines through copper-catalyzed cascade cyanation/cyclization of unactivated olefins By pubs.rsc.org Published On :: Org. Chem. Front., 2020, Advance ArticleDOI: 10.1039/D0QO00282H, Research ArticleFei Meng, Qin Fang, Weidong Yuan, Ning Xu, Shujun Cao, Jianlin Chun, Jie Li, Honglin Zhang, Yingguang ZhuA mild copper-catalyzed cascade cyanation/cyclization of hydrazone-tethered unactivated olefins was developed for the efficient and practical synthesis of cyano-containing pyrazolines.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Organocatalytic 1,5-trifluoromethylthio-sulfonylation of vinylcyclopropane mediated by visible light in the water phase By pubs.rsc.org Published On :: Org. Chem. Front., 2020, Advance ArticleDOI: 10.1039/D0QO00343C, Research ArticleJunkai Liu, Hong Yao, Xinnan Li, Hongyu Wu, Aijun Lin, Hequan Yao, Jinyi Xu, Shengtao Xu1,2-Difunctionalization has developed into a robust tool for the preparation of complex organic molecules, and remote difunctionalization has also aroused widespread interest to achieve pluripotency of difunctionalization.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Ag2O-catalysed nucleophilic isocyanation: selective formation of less-stable benzylic isonitriles By pubs.rsc.org Published On :: Org. Chem. Front., 2020, Advance ArticleDOI: 10.1039/D0QO00336K, Research ArticleTaiga Yurino, Yuji Tange, Ryutaro Tani, Takeshi OhkumaBoth primary and secondary benzylic isonitriles were exclusively produced by the Ag2O-catalysed reaction of benzylic phosphates and trimethylsilyl cyanide without formation of the thermodynamically favoured regioisomers, benzylic nitriles.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Discrete boronate ester ladders from the dynamic covalent self-assembly of oligo(phenylene ethynylene) derivatives and phenylenebis(boronic acid) By pubs.rsc.org Published On :: Org. Chem. Front., 2020, 7,1082-1094DOI: 10.1039/D0QO00083C, Research ArticleVasileios Drogkaris, Brian H. NorthropReversible boronate ester chemistry enables the controlled, dynamic self-assembly of olig(phenylene ethynylene)s into highly conjugated ladder frameworks.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Differential formation of nitrogen-centered radicals leading to unprecedented, regioselective bromination of N,N'-(1,2-phenylene)bisamides and 2-amidophenols By pubs.rsc.org Published On :: Org. Chem. Front., 2020, 7,1095-1106DOI: 10.1039/C9QO01508F, Research ArticleDamoder Reddy Motati, Dilipkumar Uredi, Amarender Goud Burra, J. Phillip Bowen, Frank R. Fronczek, Clint R. Smith, E. Blake WatkinsA highly efficient, site-selective, visible light-accelerated, remote C–H halogenation of unsymmetrical aromatic bisamides/amidoesters has been developed.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Synthesis and biological evaluation of suffrutines A, B and their N-fused analogues By pubs.rsc.org Published On :: Org. Chem. Front., 2020, 7,1122-1131DOI: 10.1039/D0QO00050G, Research ArticleZefeng Zhu, Chun Chen, Jingxing Jiang, Qianzhong Zhang, Zhibo Du, Shuxian Wei, Xianheng Song, Jie Tang, Jinping Lei, Zhuofeng Ke, Yong ZouThe synthesis, structure confirmation, stability and isomerization features of suffrutines A, B and their N-fused analogues were reported. Biological tests showed that the introduction of nitrogen atom might be beneficial to the anticancer activity.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Insights into N-heterocyclic carbene and Lewis acid cooperatively catalyzed oxidative [3 + 3] annulation reactions of α,β-unsaturated aldehyde with 1,3-dicarbonyl compounds By pubs.rsc.org Published On :: Org. Chem. Front., 2020, 7,1113-1121DOI: 10.1039/D0QO00091D, Research ArticleXinghua Wang, Yang Wang, Jinshuai Song, Donghui WeiN-Heterocyclic carbene and Lewis acid cooperatively catalyzed oxidative [3 + 3] annulation reactions of 1,3-dicarbonyl compounds have been systematically studied in theory.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Access to branched allylsilanes by nickel-catalyzed regioselective hydrosilylation of allenes By pubs.rsc.org Published On :: Org. Chem. Front., 2020, 7,1132-1136DOI: 10.1039/D0QO00156B, Research ArticleJia-Hao Zeng, Jun-Jia Chen, Li Chen, Zhuang-Ping ZhanA Ni(acac)2/Xantphos-catalyzed hydrosilylation of allenes has been developed.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v The origin of regioselectivity in Cu-catalyzed hydrocarbonylative coupling of alkynes with alkyl halides By pubs.rsc.org Published On :: Org. Chem. Front., 2020, 7,1137-1148DOI: 10.1039/D0QO00214C, Research ArticleShengnan Liu, Jianbiao Liu, Qiong Wang, Jin Wang, Fang Huang, Wenjuan Wang, Chuanzhi Sun, Dezhan ChenSteric interactions mediate a switch between a ketone and allylic alcohol in Cu-catalyzed hydrocarbonylative coupling of alkynes with alkyl halides.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Transition-metal-free aerobic C–O bond formation via C–N bond cleavage By pubs.rsc.org Published On :: Org. Chem. Front., 2020, 7,1077-1081DOI: 10.1039/D0QO00173B, Research ArticleLirong Guo, Fengting Liu, Liying Wang, Hairui Yuan, Lei Feng, Haifeng Lu, Hongyin GaoWe disclosed a TM-free cascade SNAr-[3,3] rearrangement–rearomatization process for the efficient construction of NOBIN-type biaryls from readily available (hetero)arylhydroxylamines and aryltrimethylammonium salts under mild conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Anthranils: versatile building blocks in the construction of C–N bonds and N-heterocycles By pubs.rsc.org Published On :: Org. Chem. Front., 2020, 7,1177-1196DOI: 10.1039/D0QO00163E, Review ArticleYang Gao, Jianhong Nie, Yanping Huo, Xiao-Qiang HuThis review article provides an overview of the recent progress in the transformations of anthranils, which have emerged as versatile building blocks in the assembly of various C–N bonds and medicinally active heterocyclic systems.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Recent developments in palladium-catalyzed C–S bond formation By pubs.rsc.org Published On :: Org. Chem. Front., 2020, Advance ArticleDOI: 10.1039/D0QO00377H, Research ArticleJianxiao Li, Shaorong Yang, Wanqing Wu, Huanfeng JiangThis review summarized the recent developments in palladium-catalyzed C–S bond formation involving sulfenylation and sulfonylation reactions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v An Aspidosperma-type alkaloid dimer from Tabernaemontana bovina as a candidate for the inhibition of microglial activation By pubs.rsc.org Published On :: Org. Chem. Front., 2020, Advance ArticleDOI: 10.1039/D0QO00296H, Research ArticleYang Yu, Si-Meng Zhao, Mei-Fen Bao, Xiang-Hai CaiAs a representative of twelve undescribed Aspidosperma-type alkaloid dimers, tabernaemontine F (6) inhibited microglial activation by blocking P38 MAPK activation, revealing a potential candidate for chronic neurodegenerative diseases.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Chiral strong Brønsted acid-catalyzed enantioselective addition reaction of simple olefins with ethyl glyoxylate By pubs.rsc.org Published On :: Org. Chem. Front., 2020, Advance ArticleDOI: 10.1039/D0QO00448K, Research ArticleJun Kikuchi, Yuki Aizawa, Masahiro TeradaAn enantioselective intermolecular addition reaction of 1,1,2-trisubstituted and 1,2- disubstituted simple olefins with ethyl glyoxylate was developed using F10BINOL-derived N-sulfonyl phosphoramide as a chiral strong Brønsted acid catalyst.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Phosphine/Palladium Cooperative Catalysis: Enantioselective [5+4] Annulations of ortho-Quinone Methides and Vinylethylene Carbonates By pubs.rsc.org Published On :: Org. Chem. Front., 2020, Accepted ManuscriptDOI: 10.1039/D0QO00128G, Research ArticleChao Xia, Dong-Chao Wang, Gui-Rong Qu, Hai-Ming GuoHighly enantioselective [5+4] annulations of ortho-quinone methides with vinylethylene carbonates were enabled by phosphine/palladium asymmetric cooperative catalysis for the first time. Efficient synthesis of various nine-membered benzo-heterocycles was achieved in...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Mechanism and Origins of Stereo- and Enantioselectivities of Palladium-Catalyzed Hydroamination of Racemic Internal Allenes via Dynamic Kinetic Resolution: A Computational Study By pubs.rsc.org Published On :: Org. Chem. Front., 2020, Accepted ManuscriptDOI: 10.1039/D0QO00174K, Research ArticleZhenzhen Wu, Mei Zhang, Yu Shi, Genping HuangDensity functional theory calculations have been performed to investigate the Pd-catalyzed hydroamination of racemic internal allenes with pyrazoles. The computations show that the originally proposed reaction mechanisms initiated by the...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Catalyst-Controlled Formal [4+1] Annulation of N-Vinyl Fluorenone Nitrones and Allenoates to Prepare Spirofluorenylpyrrolines By pubs.rsc.org Published On :: Org. Chem. Front., 2020, Accepted ManuscriptDOI: 10.1039/D0QO00224K, Research ArticleCui Wei, Jin-Qi Zhang, Jia-Jie Zhang, Cui Liang, Dong-Liang MoWe report a readily commercial Gimeracil-catalyzed formal [4+1] annulation approach for the synthesis of spirofluorenylpyrrolines in good yields with high diastereoselectivity from easily available N-vinyl fluorenone nitrones and allenoates. The...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v A Vinylogous Michael Reaction of 2-Furanones Dimers to α, β-Unsaturated Nitroolefins for Constructing Chiral γ, γ-Disubstituted Butenolides By pubs.rsc.org Published On :: Org. Chem. Front., 2020, Accepted ManuscriptDOI: 10.1039/D0QO00376J, Research ArticleZhushuang Bai, Cairong Zhang, Yongyi Chen, Aiqin Liu, Xinyu Wang, Chuna Yan, Xuechao Liu, Xiaoru Zhang, Ying Li, Ye Yuan, Zemei Ge, Jingxiang Pang, Yongshuai Chai, Xin Wang, Runtao LiAn efficient bifunctional thiourea catalyzed asymmetric vinylogous Michael addition of 2-furanones dimers to α, β-unsaturated nitroolefins has been developed to give the functional chiral γ,γ-disubstituted butenolides in good yields (up...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Rhodium(III)-catalyzed synthesis of 3-trifluoromethylindanones from N-Methoxybenzamides via C-H activation and Claisen/Retro-Claisen reaction By pubs.rsc.org Published On :: Org. Chem. Front., 2020, Accepted ManuscriptDOI: 10.1039/D0QO00330A, Research ArticleSatyasheel Sharma, Bharatkumar Chaudhary, Neeraj KulkarniThe Rhodium(III)-catalyzed reaction of N-methoxybenzamides as a directing group with β-trifluoromethyl-α,β-unsaturated ketones is reported. The reaction involved sp2 C−H activation, followed by Claisen condensation involving C-N bond cleavage to form...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
v Writing scientific papers in English : an ELSE-Ciba Foundation guide for authors / Maeve O'Connor and F.Peter Woodford By prospero.murdoch.edu.au Published On :: O'Connor, Maeve Full Article
v The ACS style guide : a manual for authors and editors / Janet S. Dodd, editor ; Marianne C. Brogan, advisory editor By prospero.murdoch.edu.au Published On :: Full Article
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