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Temperature-dependent hysteretic two-step spin crossover in two-dimensional Hofmann-type compounds

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Published On ::

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00866D, Paper
Jun Tao, Yue Li, Min Liu, Zi-Shuo Yao
Hofmann-type spin-crossover (SCO) frameworks attract much attention due to their predictable structures and diverse SCO behaviours. In this paper, we report two isostructural two-dimensional (2D) Hofmann-type SCO frameworks [FeII(ppe)2MII(CN)4]·3H2O (ppe...
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Color Tuning in Ca3-xMx(PO4)2: Eu2+ (M = Sr, Ba) Phosphors via Cation Substitution

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Published On ::

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01130D, Paper
Huiling Zhang, Dengwen Yuan, Xiaoyun Mi, Xiuling Liu, Jun Lin
A series of Ca3-xMx(PO4)2: Eu2+ (M = Sr, Ba) phosphors were prepared via high-temperature solid-state reaction process. The X-ray diffraction and Rietveld refinements were used to verify the incorporations of...
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Multicolor tunable luminescence and energy transfer of core-shell structured SiO2@Gd2O3 microspheres co-activated with Dy3+/Eu3+ under single UV excitation

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Published On ::

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00735H, Paper
Jie Chen, Yixin Gao, Haifeng Jiang, Yan Liu, Zhaohui Jin
Optimizing structure and varing doped ions are two main strategies to obtain excellent luminescence performance. Spherical morphology is considered to be the most ideal phosphor structure due to the least...
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Influence of Eu valence in the optical activity of BaTiO3 decorated with CaF2 synthesized by microwave-assisted hydrothermal method

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Published On ::

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01321H, Paper
Tatiane Strelow Lilge, Adriano Borges Andrade, Claudiane dos Santos Bezerra, Giordano Frederico da Cunha Bispo, Zélia Soares Macedo, Mario Lucio Lúcio Moreira, Mário Ernesto Giroldo Valerio
Inorganic hybrid materials are promising applications in absorbers and photon harvesting of solar irradiation, such as DSSC cell photoanodes. Moreover, the investigation of the interaction between the photoanode constituent materials...
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Probing the limits of linker substitution in aluminum MOFs through water vapor sorption studies: Mixed-MOF instead of mixed-linker CAU-23 and MIL-160 materials

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Published On ::

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01044H, Paper
Carsten Schlüsener, Dustin Nils Jordan, Mergime Xhinovci, Tobie J. Matemb Ma Ntep, Alexa Schmitz, Beatriz Giesen, Christoph Janiak
We report the systematic study on the possibility of forming mixed-linker MOFs spanning between the aluminum metal-organic frameworks CAU-23 and MIL-160 with their 2,5-thiophenedicarboxylate (TDC) and 2,5 furandicarboxylate (FDC) linkers,...
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MnO2 flowery nanocomposites for efficient and fast removal of mercury(II) from aqueous solution: a facile strategy and mechanistic interpretation

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Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01054E, Paper
Sankar Das, Arnab Samanta, Kanika Kole, Gautam Gangopadhyay, Subhra Jana
MnO2 flowery nanocomposites were explored as a novel and cost effective nanoadsorbent for the fast and efficient extraction of toxic inorganic contaminants from aqueous solution.
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Dehydrogenation of amines in aryl-amine functionalized pincer-like nitrogen-donor redox non-innocent ligands via ligand reduction on a Ni(II) template

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Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00466A, Paper
Manas Khatua, Bappaditya Goswami, Subhas Samanta
A Ni(II)-template directed dehydrogenative imine formation reaction via ligand reduction leading to the formation of new pincer-like azo imine ligands is described.
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Recent advances in coordination-driven polymeric gel materials: design and applications

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Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00863J, Frontier
Papri Sutar, Tapas Kumar Maji
In this article, we reviewed recent advances in coordination-driven polymeric gels and highlighted their design and applications in various fields.
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Effects of ligand substituents on the single-molecule magnetic behavior of quinonoid-bridged dicobalt compounds

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Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00033G, Paper
Xiao-Quan Zhu, Wen-Hai Cao, Shao-Dong Su, Xin-Tao Wu, Tian-Lu Sheng
The SMM behavior weakens until its disappearance with the substituent changing from Br, H to OMe in the quinonoid-bridged dicobalt compounds [(N4Co)2LX](ClO4)2, (X = H, Cl, Br, and OMe).
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Amorphous Ni–Fe–Se hollow nanospheres electrodeposited on nickel foam as a highly active and bifunctional catalyst for alkaline water splitting

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/C9DT04755G, Paper
Xuerui Yi, Xiaobo He, Fengxiang Yin, Biaohua Chen, Guoru Li, Huaqiang Yin
The electrodeposition of amorphous Ni–Fe–Se hollow nanospheres as a highly efficient bifunctional catalyst for the sustainable production of hydrogen.
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Metal–metal bond formation of triplatinum cores with a silver(I) ion affording a heptanuclear cluster bearing four Pt–Ag bonds

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01227K, Communication
Natsuki Yabune, Hiroshi Nakajima, Takanori Nishioka
A triplatinum complex with chelating NHC ligands reacts with Ag(I) and affords a heptanuclear cluster bearing four Ag–Pt bonds.
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Synthesis and reactivity of cyclobutadiene nickel bromide

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01510E, Paper
Nikita V. Shvydkiy, Egor A. Dlin, Klimentiy V. Ivanov, Anastasiya G. Buyanovskaya, Yulia V. Nelyubina, Dmitry S. Perekalin
The reaction of NiBr2 with 3-hexyne provides new access to various cyclobutadiene nickel complexes.
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Selenotungstates incorporating organophosphonate ligands and metal ions: synthesis, characterization, magnetism and catalytic efficiency in Knoevenagel condensation reaction

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Published On ::

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00444H, Paper
Jingyang Niu, Hui Kong, Peipei He, Zongfei Yang, Qiaofei Xu, Jiawei Wang, Ran Ban, Pengtao Ma, Jingping Wang
Three sandwich-type TM-containing (TM = transition metal) organophosphonate-based polyoxotungstate clusters, [TM(H2O)4(SeW6O21)2{Co(OOCCH2NCH2PO3)2}3]12– (TM = Co, Ni), have been successfully synthesized, which is the first reported TMs-containing organophosphonate-based selenotungstates. They were structurally...
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Luminescent lanthanide complexes with a pyridine-bis(carboxamide)-bithiophene sensitizer showing wavelength-dependent singlet oxygen generation

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01034K, Paper
Katherine R. Johnson, Sebastian B. Vittardi, Manuel A. Gracia-Nava, Jeffrey J. Rack, Ana de Bettencourt-Dias
A new pyridine-bis(carboxamide)-based ligand with a bithiophene pendant, 2Tcbx, was synthesized.
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Amorphous Co-doped MoSex Effectively Enhances Photocatalysis in Visible Light

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01295E, Paper
Rui Feng, Rong Wu, Yuncheng Cao, Xiaolin Guo, Xu Ma
Molybdenum selenide has great potential for degradation of water pollutants，but its performance is limited by the active sites and recombination of photogenerated electron-hole pairs. In this study, amorphous Co-doped MoSex...
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Tin based organic-inorganic hybrid semiconductors with reversible phase transition and dielectric anomaly

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01401J, Paper
Zhenhong Wei, Xiuli You, Jiaojiao Yao
Organic−inorganic hybrid materials with perovskite structure have recently attracted tremendous interest due to their structural tunability and rich functional properties, such as phase transition and photoelectric properties. Within this context,...
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Oxacalix[4]arene Derived Dual Sensing Fluorescence Probe for the Detection of As (V) and Cr (VI) Oxyanions in Aqueous Media

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Published On ::

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00452A, Paper
Shuvankar Dey, Anshu Kumar, Pradip Mondal, Krunal M. Modi, Deepak Chopra, Vinod K. Jain
An oxacalix[4]arene-Ce (III) complex viz. L-Ce(III) has been introduced for selective detection of As (V) and Cr (VI) oxyanions in aqueous medium. Binding mode of L-Ce(III) + AsO43-/ CrO42- was...
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Amide and ester derivatives of chlorido[4-carboxy-1,2-disalicylideneaminobenzene]iron(III) as necroptosis and ferroptosis inducers

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Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00168F, Paper
Daniel Baecker, Benjamin N. Ma, Jessica Sagasser, Lukas Schultz, Carina Hörschläger, Maria Weinreich, Lucy Steiner, Brigitte Kircher, Ronald Gust
Amide and ester derivatives of chlorido[4-carboxy-1,2-disalicylideneaminobenzene]iron(III) were synthesized and characterized as necroptosis and ferroptosis inducers using the acute myeloid leukemia cell line HL-60.
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Reactive metallocene cations as sensitive indicators of gas-phase oxygen and water

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00798F, Paper
Anuj Joshi, Sofia Donnecke, Ori Granot, Dongju Shin, Scott Collins, Irina Paci, J. Scott McIndoe
Gas-phase oxidation of air-sensitive organometallic compounds does not proceed to a significant extent in mass spectrometric analysis unless a vacant coordination site is generated, making nitrogen generators a suitable source of desolvation gas.
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Heat-resistant Pb(II)-based X-ray scintillating metal-organic frameworks for sensitive dosage detection via the aggregation-induced luminescent chromophore

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Published On ::

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00974A, Communication
Jian Lu, Shuai-Hua Wang, Yan Li, Wen-Fei Wang, Cai Sun, Pei-Xin Li, Fa-Kun Zheng, Guo-Cong Guo
The synergy of unusual X-aggregation induced luminescent chromophores and heavy Pb(II) ions has facilitated excellent X-ray scintillation of two structurally similar Pb-SMOFs, which are heat-resistant due to solvent-free lattices. Owing...
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High Pressure and Elastic properties of a Guanidinium -formate Hybrid Perovskite

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Published On ::

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/C9DT04805G, Paper
Hong-Qiang Gao, Chao Li, Lin-Sui Li, Wen-Juan Wei, Yu-hui Tan, Yun Zhi Tang
The high pressure and elastic properties in a hybrid ABX3-type perovskite, [C(NH2)3][Cd(HCOO)3] (CdGF), based on the A-site guest molecular is revealed via combining the high-pressure synchrotron X-ray diffraction experiments with...
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Photophysical, photodynamical, redox properties and BSA-interactions of novel isomeric tetra-cationic peripheral palladium(II)-bipyridyl porphyrins

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Published On ::

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01063D, Paper
Fabiano S Santos, Carolina H. da Silveira, Fabio Souza Nunes, Daniele Ferreira, Henrique Victória, Klaus Krambrock, Otávio Augusto Chaves, Fabiano Severo Rodembusch, Bernardo Almeida Iglesias
New isomeric tetra-cationic porphyrins containing peripheral [Pd(bpy)Cl]+ units attached at pyridyl substituents were synthetized and fully characterized. The porphyrins present an intense Soret band located in the blue spectral region...
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Impacts of hydrogen bonding interactions with Np(V/VI)O2Cl4 complexes: vibrational spectroscopy, redox behavior, and computational analysis

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Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00848F, Paper
Mikaela M. Pyrch, Jennifer L. Bjorklund, James M. Williams, Daniel L. Parr IV, Sara E. Mason, Johna Leddy, Tori Z. Forbes
Crystallization of neptunyl(V) tetrachlorides over neptunyl(VI) species occurs simultaneously with charge assisted hydrogen bonding in our solid state materials, which we explored by DFT calculations, cyclic voltammograms, and Raman spectroscopy.
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The differential magnetic relaxation behaviours of slightly distorted triangular dodecahedral dysprosium analogues in a type of cyano-bridged 3d–4f zig-zag chain compounds

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Published On ::

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00990C, Paper
An-Qi Xue, Yang-Yu Liu, Jia-Xin Li, Yan Zhang, Yin-Shan Meng, Wen-Hua Zhu, Yi-Quan Zhang, Hao-Ling Sun, Fei Wang, Guan-Xia Qiu, Lu-Yu Liang, Xiang Wang, Song Gao
Differential magnetic properties were observed for triangular dodecahedral dysprosium analogues in a type of cyano-bridged 3d–4f zig-zag chain compound.
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A Review: Recent Advances in Preparations and Applications of Heteroatom-Doped Carbon Quantum Dots

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01004A, Perspective
Xiaoli Kou, Shicui Jiang, Soo-Jin Park, Long-Yue Meng
Carbon quantum dots (CQDs) are widely used in optoelectronic catalysis, biological imaging, and ion probes owing to their low toxicity, stable photoluminescence, and ease of chemical modification. However, the low...
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Highly cytotoxic gold(I)-phosphane dithiocarbamate complexes trigger an ER stress-dependent immune response in ovarian cancer cells

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Published On ::

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01411G, Paper
Hai Van Le, Maria Babak, Muhammad Ali Ehsan, Mohammad Altaf , Lisa Reichert, Artem Gushchin, Wee Han Ang, Anvarhusein Isab
Ovarian cancer is a highly aggressive disease which is treated by surgery and platinum chemotherapy. However, a significant proportion of treated patients develop resistance to platinum treatment resulting in tumor...
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What is a “third place,” and do you have one?

By www.berkshirepublishing.com
Published On :: Fri, 01 Nov 2019 11:05:34 +0000

The term “happy place” is not in the Oxford English Dictionary (though “happy slap” is), but I’ve been hearing the term a lot. There’s even a new shop in Great Barrington called HappyPlace Berkshires. I first dismissed it as therapeutic slang, but discovered that the concept actually goes back to the Greeks: a utopia is

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Big History Ebooks Now Available For WH & BHP Classes

By www.berkshirepublishing.com
Published On :: Thu, 09 Jan 2020 09:56:10 +0000

Cynthia Stokes Brown wrote BIG HISTORY, SMALL WORLD to help Big History Project students and their teachers, many of whom she knew and befriended in the earliest days of big history education. David Christian's THIS FLEETING WORLD is widely used in AP World History as well as big history courses. BIG HISTORY: A BERKSHIRE ESSENTIAL is a collection of essays by

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Gastrodiplomacy in China; T S Eliot’s Love Letters

By www.berkshirepublishing.com
Published On :: Fri, 21 Feb 2020 10:04:19 +0000

Chinese food, anyone? I'll be co-presenting a program about gastrodiplomacy at Schwarzman College in Beijing next month, and I am looking for stories to share, from history as well as personal experience. Schwarzman College 苏世民书院 is a residential college at Tsinghua University. Schwarzman scholarships are modeled on the Rhodes Scholarships at Oxford. The one-year MA

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  • Seeing the World
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Letter from Beijing: Love in the Time of COVID-19

By www.berkshirepublishing.com
Published On :: Fri, 21 Feb 2020 16:48:46 +0000

My son Tom works in healthcare finance, and has lived in China since graduating from college. He was quarantined in Lanzhou during the 2009 swine flu epidemic, and now he's experiencing the semi-quarantine of 2020. In fact, I expected to be there right now and was looking forward to time with him and his wife

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COVID-19 is here (& where has all the toilet paper gone?)

By www.berkshirepublishing.com
Published On :: Tue, 31 Mar 2020 09:19:45 +0000

We lived through the ‘80s. We lived through the ‘90s. We lived through the ‘00s. We lived through the ‘10s. And we’ve lived through March. Most of us, that is, have lived. I’m still coming to terms with what is happening. It’s like grief. I go about my day, getting absorbed in work, or a

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Berkshire Joins COVID-19 Support Efforts With JStor, EBSCO, ProQuest

By www.berkshirepublishing.com
Published On :: Tue, 07 Apr 2020 08:45:20 +0000

We want to make sure you know about some of the ways in which publishers - including Berkshire - are making our books and reference publications available online at reduced cost, or even free, during the COVID-19 crisis. We're well aware that taking classes and doing research papers online is a huge challenge for many

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v

A Letter is Better: Love and Remembrance

By www.berkshirepublishing.com
Published On :: Thu, 16 Apr 2020 17:25:57 +0000

Messenger of Sympathy and Love Servant of Parted Friends Consoler of the Lonely Bond of the Scattered Family Enlarger of the Common Life Carrier of News and Knowledge Instrument of Trade and Industry Promoter of Mutual Acquaintance Of Peace and of Goodwill Among Men and Nations. A business consultant once passed around copies of the

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Karen’s Letter: The Libraries We Love

By www.berkshirepublishing.com
Published On :: Thu, 30 Apr 2020 16:21:54 +0000

Last month I wrote about third places ("What is a “third place,” and do you have one?"). Along with some great stories about your favorite third places, I received a few emails blasting me for not mentioning libraries. That was a shock, since Berkshire Publishing has close ties to libraries: we’ve written and published about

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Do exclusionary rules ensure a fair trial?: a comparative perspective on evidentiary rules / Sabine Gless, Thomas Richter, editors

By library.mit.edu
Published On :: Sun, 21 Jul 2019 09:24:23 EDT

Online Resource


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Selma and the Liuzzo murder trials: the first modern civil rights convictions / by James P. Turner

By library.mit.edu
Published On :: Sun, 21 Jul 2019 09:24:23 EDT

Dewey Library - KF224.K7 T87 2018


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First: Sandra Day O'Connor / Evan Thomas

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Dewey Library - KF8745.O25 T46 2019


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Our selfish tax laws: toward tax reform that mirrors our better selves / Anthony C. Infanti

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Dewey Library - KF6289.I49 2018


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Real estate finance in a nutshell / Vada Waters Lindsey, Associate Professor of Law, Marquette University Law School

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Rotch Library - KF695.Z9 L56 2018


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Implementing environmental constitutionalism: current global challenges / edited by Erin Daly, James R. May

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Rotch Library - K3585.I596 2018


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Contempt: a memoir of the Clinton investigation / Ken Starr

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Dewey Library - KF5076.C57 S72 2018


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Practitioner's guide to project-based vouchers: a successor to the Beginner's guide / Sarah Molseed and Julie S. McGovern

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Rotch Library - KF5735.M654 2018


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No property in man: slavery and antislavery at the nation's founding / Sean Wilentz

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Hayden Library - KF4545.S5 W59 2018


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Religious exemptions / edited by Kevin Vallier and Michael Weber

By library.mit.edu
Published On :: Sun, 28 Jul 2019 10:20:39 EDT

Dewey Library - K3258.R453 2018


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Separate: the story of Plessy v. Ferguson, and America's journey from slavery to segregation / Steve Luxenberg

By library.mit.edu
Published On :: Sun, 4 Aug 2019 10:22:43 EDT

Hayden Library - KF223.P56 L88 2019


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Winning together: the natural resource negotiation playbook / Bruno Verdini Trejo

By library.mit.edu
Published On :: Sun, 4 Aug 2019 10:22:43 EDT

Dewey Library - KZ6047.V47 2017


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Strategic indeterminacy in the law / David Lanius

By library.mit.edu
Published On :: Sun, 4 Aug 2019 10:22:43 EDT

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Authors, users, and pirates: copyright law and subjectivity / James Meese

By library.mit.edu
Published On :: Sun, 4 Aug 2019 10:22:43 EDT

Dewey Library - K1420.5.M44 2018


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Armed conflict and forcible displacement: individual rights under international law / edited by Elena Katselli Proukaki

By library.mit.edu
Published On :: Sun, 4 Aug 2019 10:22:43 EDT

Dewey Library - KZ6530.A75 2018


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Silenced victims of wartime sexual violence / Olivera Simić

By library.mit.edu
Published On :: Sun, 11 Aug 2019 10:25:18 EDT

Dewey Library - KZ7162.S56 2018


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