Faraday Discuss., 2024, Accepted Manuscript
DOI: 10.1039/D4FD00038B, Paper

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Anusha Pradhan, Shoma Nishimura, Yasuyuki Kondo, Tomoaki Kaneko, Yu Katayama, Keitaro Sodeyama, Yuki Yamada
Lithium (Li) metal negative electrodes have enticed a wide attention for high-energy-density batteries. However, its low Coulombic efficiency (CE) due to parasitic electrolyte reduction has been an alarming concern. Concentrated...
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01249F, Research Article

Rongmei Zhu, Yuxuan Jiang, Bingxin Sun, Wang Zhang, Huan Pang
Hollow CoS_x/MoO₃ derived from ZIF-67 shows preferred selective trapping and conversion of LiPSs as a modified separator material for LSBs.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01389A, Research Article

Zi-Qi Zhou, Shu-Qi Wu, Qi-Rui Shui, Wen-Wei Zheng, Akari Maeda, Xiao-Peng Zhang, Jing Chu, Shinji Kanegawa, Sheng-Qun Su, Osamu Sato
A solvent-free neutral cobalt complex featuring a non-centrosymmetric polar structure exhibits macroscopic polarization switching induced by charge transfer.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02264E, Research Article

Xiaoqiang Li, Guangguang Guan, Siyi Tong, Xin Chen, Kaiyin Zhang, Jun Xiang
It is highly desirable but challenging to design multi-functional materials for energy storage and electromagnetic (EM) wave absorption.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02126F, Research Article

Changhao Wang, Jiaxi Hao, Longxiao Duan, Jianfan Zhang, Wenfeng Yue, Zhenhao Fan, Dandan Han, Raz Muhammad, Fanxu Meng, Dawei Wang
A composition and structure optimization strategy combined with a two-step sintering (TSS) process is proposed to design and fabricate (1−x)Ba_0.85Ca_0.15Zr_0.1Ti_0.9O₃−xBi(Mg_1/2Sn_1/2)O₃ (BCZT-BMSx-TSS) lead-free ceramics.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02194K, Research Article

Jia-Wei Li, Wenke Dong, Yanjie Liu, Yuhan Li, Lu-Yuan Qiao, Guang-Lu Liu, Hui Zhang, Chunjie Wang, Hui-Li Zheng, Jian-Qiang Zhao
Waterproof 0D hybrid Zn halide with highly efficient blue emission and third-order nonlinear optical response was constructed by the microregulating of π–π interactions, offering new insights for designing stable multifunctional halide materials.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01842G, Research Article

Sha Jianchun, Wang Qiang, Li Xue, Liu Zhoulin, Bao Jiaxin, Li Lianhui, Tian Jie, Chen Weilong, Liu Wenhong, Zhang Zhiqiang
Aqueous Mg–air batteries are promising candidates for large-scale energy storage, but their practical application is significantly hindered by water-induced parasitic reactions and the chunk effect.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02572E, Research Article

Fang Xu, Jialin Zheng, Dai-Huo Liu, Ao Wang, Zhenjiang Li, Chunyan Xu, Mengqin Song, Beinuo Zhang, Zhengyu Bai, Zhongwei Chen
The prepared of τ-MnO₂–Mg₂(OH)₃Cl·4H₂O heterostructure cathode material enhances Zn-ion diffusion, increases the proportion of Mn(IV) and suppresses structural instability, thereby improving the cycling stability of τ-MnO₂.
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI01691B, Research Article

Meng-Jia Shang, Han-Han Lu, Qiang Liu, Ren-He Zhou, Hui-Ying Sun, Zhen Shao, Liang Zhao, Yin-Shan Meng, Tao Liu
The development of single-chain magnets with reversible and adjustable properties is of great significance for achieving high-density information storage and switching devices with multi-stimuli responsiveness whilst remains a challenging task....
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02149E, Research Article

Jing-Ning Lv, Na Lin, Jia-Yi Zhang, Yu-Meng Liu, Li-Chuang Niu, Jie Shi, Xiao-Wu Lei, Zhi-Wei Chen
A cuprous hybrid halide with high efficient photoluminescence and anti-water stability was prepared by reasonably selecting a hydrophobic organic cation, which allows this halide as a high-performance scintillator for X-ray imaging.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02182G, Research Article

Haiyan He, Yue Lan, Jinlong Qin, Quanguo Jiang, Lu Yang, Jian Zhang, Huajie Huang
An in situ soft-chemistry approach is adopted for fabricating 3D porous rhodium–copper alloy nanoflowers stereoassembled on ultrathin Ti₃C₂T_x lamellas, which are able to serve as highly-efficient electrocatalysts toward alkaline methanol oxidation.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01947D, Research Article

Hyeonggeun Choi, Seunghwan Jo, Ki Hoon Shin, HeeYoung Lim, Liting Zhang, Keon Beom Lee, Young-Woo Lee, Jung Inn Sohn
A charge valence state and surface-electronegativity-modulated NiMoCuCo composite is proposed as an active and durable alkaline hydrogen evolution reaction electrocatalyst with moderated hydroxide adsorption energy.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01996B, Research Article

Alexander V. Artem'ev, Maxim I. Rogovoy, Ilia M. Odud, Maria P. Davydova, Marianna I. Rakhmanova, Pavel A. Petrov, Valery K. Brel, Oleg I. Artushin, Konstantin A. Brylev, Denis G. Samsonenko, Alexey S. Berezin, Dmitry E. Gorbunov, Nina P. Gritsan
Tetraphosphine-carbene Cu(I), Ag(I) and Au(I) complexes, synthesized via a symmetry-based design strategy, exhibit cyan to yellow TADF with excellent quantum yields (58–89%) and reduced lifetimes.
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Inorg. Chem. Front., 2024, 11,7793-7802
DOI: 10.1039/D4QI00970C, Research Article

Xin Xu, Zhongyi Wang, Qingkun Kong, Siping Liu, Ruiling Zhang, Xiaojing Liu, Keli Han
Metastable 1D β-Cs₃Cu₂Br₅ synthesized by rapid cooling could be stabilized by Ag⁺. Ag-alloyed samples exhibit tunable emission from blue-greenish to yellow, which is attributed to different degrees of lattice distortion regulated by Ag⁺.
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Inorg. Chem. Front., 2024, 11,7812-7821
DOI: 10.1039/D4QI02131B, Research Article

Oshan J. Jinarathne, Malkanthi K. Karunananda
Metal–metal bonds facilitate a red-shift in the maximum absorption wavelength and an enhancement of the oscillator strength in photosensitizers.
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Inorg. Chem. Front., 2024, 11,7886-7897
DOI: 10.1039/D4QI02020K, Research Article

Zhiyuan Liu, Qixuan Xiang, Hao Zhang, Xianglong Zhang, Huijun Tan, Yaping Zhao
Complete conversion of MgCo₂O₄ with excellent electrochemical performance has been successfully achieved.
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Inorg. Chem. Front., 2024, 11,7936-7946
DOI: 10.1039/D4QI01835D, Research Article

Xinxin Guo, Mengmeng Zhou, Ziwu Liu, Shiheng Mu, Kaijia Wang, Huanqiang Shi, Fang Wang, Shijian Lu, Zhonghai Ni, Guiqing Liu
A self-standing high-entropy FeCoMnCuNiSe₂ electrode exhibited superior HER activity and OWS performance due to high entropy, lattice distortion and tip-enhancement effects.
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Inorg. Chem. Front., 2024, 11,8047-8069
DOI: 10.1039/D4QI01943A, Research Article

Michal Liberka, Mikolaj Zychowicz, Laurine Vasseur, James Hooper, Szymon Chorazy
Modification of an organic linker bonding two cyanido-nitrido Re(V) complexes enables the tuning of the emission mechanism that non-trivially modulates the photoluminescence and its applicability for temperature sensing.
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Inorg. Chem. Front., 2024, 11,7921-7929
DOI: 10.1039/D4QI01818D, Research Article

Miriam Abán, J. Marco Cuenca, Irene Embid, Alba de Toro, Pilar Gómez-Sal, Ernesto de Jesús, Marta Valencia, Cristina G. Yebra
[CpIr(CO)H₂] efficiently catalyses formic acid dehydrogenation, forming in situ from pyridyl-triazole pre-catalysts [Cp*Ir(k²-NN)(Cl)][OTf]. Neat formic acid is dehydrogenated with a TON of up to 26876 and a TOF exceeding 10700 h⁻¹.
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Inorg. Chem. Front., 2024, 11,7831-7842
DOI: 10.1039/D4QI02064B, Research Article

Ao Xu, Yan Liu, Jiahui Wang, Yijing Wang, Fuyi Jiang, Yanli Zhou
Limited by the poor electronic conductivity and strong interaction between Mg²⁺ and MoS₂, the 2H phase of MoS₂ as a cathode material exhibits low capacity and poor rate capability.
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Inorg. Chem. Front., 2024, 11,7955-7965
DOI: 10.1039/D4QI01767F, Research Article

Zhijiao Zhao, Mengmeng Dai, Kejie Li, Guiying Liang, Yanling Wei, Zuoling Fu
An effective full-spectrum thermometer covering from the visible to NIR-II band was designed based on garnet Lu₂CaMg₂Ge₃O₁₂:Yb³⁺,Er³⁺/Nd³⁺ phosphors; meanwhile, Er³⁺ (⁴I_13/2) split into four Stark sublevels due to high crystal field strength.
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Inorg. Chem. Front., 2024, 11,7843-7852
DOI: 10.1039/D4QI02234C, Research Article

Chenxu Li, Abudukadi Tudi, Huanhuan Cheng, Qingyu Liu, Zhihua Yang, Shilie Pan
High-throughput screening of 222 hydroxyborates identified three as promising short-wavelength ultraviolet nonlinear optical. with phase-matching second harmonic generation capacity extending to the solar blind region (200–280 nm).
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Inorg. Chem. Front., 2024, 11,8070-8077
DOI: 10.1039/D4QI02119C, Research Article

Yun Fan, Junyang Yan, Siyao Zhang, Ruifa Su, Baoli Zha, Weina Zhang
The MOF shell of an E. coli@ZIF-8 micro–nano reactor, used as armour for E. coli, not only protects the internal E. coli and improves its survival rate, but also delays the transport of oxygen to enable E. coli to produce hydrogen in air.
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Inorg. Chem. Front., 2024, 11,7775-7792
DOI: 10.1039/D4QI01978D, Review Article

Tianshu Zhang, Yijun Qian, Changyong Zhang, Tao Qian, Chenglin Yan
This review overviews the recent advances in electrodialysis (ED) in extracting critical metals from spent battery leachate. In addition, strategies and challenges regarding ED techniques toward battery recycling are pointed out.
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Inorg. Chem. Front., 2024, 11,8146-8146
DOI: 10.1039/D4QI90072C, Correction

Open Access

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Ru-Ling Tang, Gang-Xiang Liu, Wen-Dong Yao, Li-Nan Zhang, Wenlong Liu, Sheng-Ping Guo
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02426E, Research Article

Weiwei Han, Wenyi Wang, Jiahong Liao, Yi He, Xingwang Zhang, Chunlin Yu
Sustainable hydrogen production by electrocatalytic water splitting is a promising energy storage technology yet challenging due to the sluggish kinetics of the oxygen evolution reaction (OER). Rationally designed robust and...
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02343A, Research Article

Yu-Xuan Zhang, Yi-Jie Ma, Yu-Jia Zhao, Zi-Yan Wang, Cai-Xia Yu, Xiaoqiang Li, Lei-Lei Liu
Exploration of non-noble-metal-based catalysts with high catalytic activity and selectivity is significant for driving innovation in green chemistry and technology. Herein, we report a facile synthesis of two-dimensional (2D) NiCo-MOF...
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02350A, Research Article

Zongyi Wang, Jiuli Chang, Zhiyong Gao
Nitrate–methanol co-electrolysis by the pairwise cathodic NO₃RR and anodic MOR is a viable way to coproduce ammonia (NH₃) and formate via gentle, sustainable and energy-saving “E-refining” and “E-reforming” means.
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02280G, Research Article

Qixian Ren, Wangfei Che, Mengmeng Chen, Chen Cui, Yabo Wu, Zhi Su
Thioantimonates containing high oxidation state Sb5+ have proven to exhibit excellent performance in the design of new materials such as infrared optics crystals and lithium-ion batteries. However, as described by...
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02340D, Research Article

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  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Ruyi Bi, Jilu Zhao, Mei Yang, Jiangyan Wang, Ranbo Yu, Dan Wang
A multifunctional separator modified with a multi-shelled CoS₂ structure is developed to simultaneously inhibit the shuttle effect and effectively catalyze the redox reactions.
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI01916D, Research Article

Jinggao Wu, Canyu Zhong, Xiaofan Chen, Jing Huang
Li3V2(PO4)3 (LVP)-coated with N and S co-doped carbon (NSC) is investigated by DFT calculation, suggesting that NSC significantly enhances electronic conductivity and lowers Li+ migration energy barrier in comparison to...
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02228A, Review Article

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Zongsu Han, Joshua Rushlow, Yihao Yang, Jiatong Huo, Wei Shi, Hong-Cai Zhou
Lithium extraction attracts great attention due to the rising demand for batteries, but faces challenges related to low natural abundance and environmental concerns. MOFs show promise in lithium extraction, benefitting from customizable structures.
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02262A, Research Article

Tamara A. Bazhenova, Vyacheslav Kopotkov, Denis V. Korchagin, Elena Yureva, Michael V. Zhidkov, Alexey I Dmitriev, Ilya Yakushev, N. N. Efimov, Konstantin Andreevich Babeshkin, Vladimir Sergeevich Mironov, Eduard B. Yagubskii
A series of three new seven-coordinate pentagonal-bipyramidal (PBPY-7) Dy(III) complexes [Dy(L^CH3)(Cy₃PO)₂]ClO₄∙CH₃CN (1), [Dy(L^2(t-Bu))(Ph₃PO)₂]ClO₄∙0.63C₂H₅OH (2), [Dy(L^OCH3)(Ph₃PO)₂]ClO₄∙2H₂O (3) including various chelating pentadentate ligands with a [N₃O₂]²⁻ binding node in the equatorial plane,...
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Lab Chip, 2024, 24,1875-1886
DOI: 10.1039/D3LC01100C, Paper

Yunong Zhao, Juan Han, Jing Huang, Qing Huang, Yanbing Tao, Ruiqin Gu, Hua-Yao Li, Yang Zhang, Houjin Zhang, Huan Liu
We developed an on-chip laboratory for biomolecule interactions and kinetics analysis based on the three-electrode and high electron mobility transistor (HEMT) chip platform.
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Lab Chip, 2024, 24,2049-2057
DOI: 10.1039/D3LC00707C, Paper

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Fumiaki Yokoyama, André Kling, Petra S. Dittrich
A microdevice with narrow winding channels is introduced to trap and culture single bacterial cells. It is used to study growth patterns of the cells and to monitor secretion of extracellular vesicles under treatment with an antibiotic drug.
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Lab Chip, 2024, 24,1918-1929
DOI: 10.1039/D3LC00793F, Paper

Lauren M. Delong, Colby E. Witt, Madison Pennell, Ashley E. Ross
Here, we have developed a 3D printed microfluidic device capable of oxygen gradient formation within intestinal tissue slices ex vivo. The device is open-welled and compatible with external electrochemical recording during tissue analysis.
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Lab Chip, 2024, 24,1930-1946
DOI: 10.1039/D3LC00859B, Paper

Open Access

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Felix Richter, Maryline Calonne-Salmon, Marcel G. A. van der Heijden, Stéphane Declerck, Claire E. Stanley
A new microfluidic platform – the AMF-SporeChip – enables immobilisation of arbuscular mycorrhizal fungal spores and confrontation of asymbiotic hyphae with physical obstacles, allowing the identification of various exploration strategies.
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Lab Chip, 2024, 24,1887-1902
DOI: 10.1039/D3LC00507K, Paper

Open Access

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Chu-Chun Liang, Po-Yen Chen, Nien-Che Liu, I-Chi Lee
A 3D neural spheroid-based system with an interstitial level of flow for simulating the brain microenvironment toward a dynamic amyloid-β induced neuronal toxic model was established. A real-time impedance recording was used to monitor the neural network formation and disconnection.
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Lab Chip, 2024, 24,2080-2093
DOI: 10.1039/D3LC00838J, Paper

Open Access

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Katharina Schlünder, Madalena Cipriano, Aline Zbinden, Stefanie Fuchs, Torsten Mayr, Katja Schenke-Layland, Peter Loskill
Pancreatic in vitro models are crucial for research on diseases such as diabetes mellitus. A novel thermoplastic organ-on-chip with integrated real-time read-outs models the complex microphysiological structure and function of the endocrine pancreas.
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Lab Chip, 2024, 24,1947-1956
DOI: 10.1039/D3LC00656E, Paper

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Klaudia Staskiewicz, Maria Dabrowska-Zawada, Lukasz Kozon, Zofia Olszewska, Lukasz Drewniak, Tomasz S. Kaminski
Novel microfluidic technique for functional selection of biosurfactant-producing microorganisms. Single bacterial cells are encapsulated into picoliter droplets for clonal cultivation and passively sorted at high throughput by interfacial tension.
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Lab Chip, 2024, 24,1867-1874
DOI: 10.1039/D3LC00796K, Perspective

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Umut A. Gurkan, David K. Wood, Dorn Carranza, Luke H. Herbertson, Scott L. Diamond, E. Du, Suvajyoti Guha, Jorge Di Paola, Patrick C. Hines, Ian Papautsky, Sergey S. Shevkoplyas, Nathan J. Sniadecki, Vamsee K. Pamula, Prithu Sundd, Asif Rizwan, Pankaj Qasba, Wilbur A. Lam
In this perspective article, we present the state of the microfluidic field regarding current limitations and propose future directions and new approaches for the field to advance lab-on-a-chip technologies closer to translation and clinical use.
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Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00006D, Paper

Seyedaydin Jalali, Ponnambalam Ravi Selvaganapathy
A scalable method for creating perfusable 3D tissue constructs using self-assembly is introduced. Unlike conventional cell injection methods, here we leverage cell migration to form tissue barriers of low permeability, mimicking in vivo environments.
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Lab Chip, 2024, Advance Article
DOI: 10.1039/D3LC00933E, Paper

Open Access

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Huynh Quoc Nguyen, Van Dan Nguyen, Vu Minh Phan, Tae Seok Seo
The COVID-19 pandemic greatly impacted the in vitro diagnostic market, leading to the development of new technologies such as point-of-care testing (POCT), multiplex testing, and digital health platforms.
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Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00131A, Paper

Fahima Akther, Hedieh Fallahi, Jun Zhang, Nam-Trung Nguyen, Hang Thu Ta
An atherothrombosis-on-chip model to evaluate thrombosis risk and patient-specific treatment strategy.
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Lab Chip, 2024, Advance Article
DOI: 10.1039/D3LC01061A, Paper

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Felix Reichel, Ruchi Goswami, Salvatore Girardo, Jochen Guck
We use hyperbolic microchannels to create a flow field with linearly increasing velocity, leading to a constant tensile stress to probe the viscoelastic properties of cells. We verify our approach on oil droplets and polyacrylamide beads.
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Lab Chip, 2024, Accepted Manuscript
DOI: 10.1039/D3LC00854A, Paper

Lu Xin, Xi Xiao, Wen Xiao, Ran Peng, Hao Wang, Feng Pan
The incidence of urothelial carcinoma continue to rise annually, particularly among the elderly. Prompt diagnosis and treatment can significantly enhance patient survival and quality of life. Urine cytology remains a...
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Lab Chip, 2024, 24,2193-2201
DOI: 10.1039/D3LC00979C, Paper

Bingbing Zhang, Jinxin Fu, Maohua Du, Kai Jin, Qi Huang, Jiahao Li, Dongping Wang, Siyi Hu, Jinhua Li, Hanbin Ma
Advancing active-matrix digital microfluidics through polar coordinates for precise concentration gradients. Demonstrated with chip photography, concentration gradient solution demo, and efficiency comparison.
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Lab Chip, 2024, 24,2253-2261
DOI: 10.1039/D3LC01053H, Paper

Ziran Ye, Ping Lu, Yiben Chen, Zhixian Xu, Haixia Huang, Mingjia Zhi, Zi Ang Chen, Bo Yan
We present an efficient approach for the consecutive synthesis of Au–TiO₂ nanocomposites with controlled morphologies in a microfluidic chip.
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Lab Chip, 2024, 24,2280-2286
DOI: 10.1039/D3LC00822C, Paper

Mingwei Zhao, Jing Yang, Zhenqing Li, Yuan Zeng, Chunxian Tao, Bo Dai, Dawei Zhang, Yoshinori Yamaguchi
Concentration gradient generation and mixed combinations of multiple solutions are of great value in the field of biomedical research.
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