no

Ordered crown-ether 2D framework based loose nanofiltration membranes for improved separation and stability

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06349J, Communication
Jae Jun Kim, Hui-Ran Seo, Jinseok Kim, Mun Hyeon Kim, Jinwook Park, Hyunkee Hong, Hee Joong Kim, Jong-Chan Lee
Loose nanofiltration (LNF) membranes, known for high water permeability and dye/salt selectivity, have been widely used. However, LNF membranes fabricated through layer-by-layer (LbL) assembly lack structural stability and uniformity. Herein,...
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no

Enhancing the Thermoelectric Figure of Merit of BiN via Polymorphism, Pressure, and Nanostructuring

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA05891G, Paper
Open Access
Elena R. Remesal, Victor Posligua, Miguel Mahillo-Paniagua, Konstantin Glazyrin, Javier Fernández Sanz, Antonio Márquez, Jose Javier Plata Ramos
Materials discovery extends beyond the synthesis of new compounds. Detailed characterization is essential to understand the potential applications of novel materials. However, experimental characterization can be challenging due to the...
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no

Electrode process regulation for high-efficiency zinc metal anodes

J. Mater. Chem. A, 2024, 12,30169-30189
DOI: 10.1039/D4TA05143B, Review Article
Longkun Wu, Xinyan Zhu, Zhi Peng, Zekun Zhang, Ningning Zhao, Bin Li, Jing Zhu, Lei Dai, Ling Wang, ZhangXing He
Regulation strategies for zinc anode ion deposition.
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no

Effects of hydrothermal etching and conversion on photocatalytic hydrogen evolution and overall water splitting with nanoparticulate and mesoporous TiO2 and SrTiO3/TiO2 composites

J. Mater. Chem. A, 2024, 12,30768-30782
DOI: 10.1039/D4TA03416C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lion Schumacher, Jana Timm, Roland Marschall
Hydrothermal treatment of mesoporous photocatalysts in diluted NaOH solution or H2O might be a simple and promising strategy to improve photocatalytic activities in general, as we show for TiO2 and SrTiO3/TiO2 composites.
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Enhanced electrocatalytic overall alkaline water splitting induced by interfacial electron coupling of Mn3O4 nano-cube@CeO2/γ-FeOOH nanosheet hetero-structure

J. Mater. Chem. A, 2024, 12,30783-30797
DOI: 10.1039/D4TA05336B, Paper
Debasish Ghosh, Dimple K. Bora, Asit Baran Panda
Mn3O4@CeO2/γ-FeOOH hetero-structure showed interfacial electron coupling induced superior bifunctional electrocatalytic activity suitable for AEM electrolyser.
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no

Tuning the acidity and textural properties of polyethyleneimine-supported adsorbents for enhanced economical CO2 capture

J. Mater. Chem. A, 2024, 12,30309-30317
DOI: 10.1039/D4TA05215C, Paper
Bitan Ray, Sathyapal R. Churipard, Arjun Cherevotan, Diku Raj Deka, Devender Goud, Harishankar Kopperi, Sebastian C. Peter
The acidity and textural properties of polyethyleneimine-supported adsorbents are tuned to enhance the capture of carbon dioxide in an economical way.
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A soft molecular single-source precursor approach to synthesize a nanostructured Co9S8 (pre)catalyst for efficient water oxidation and biomass valorization

J. Mater. Chem. A, 2024, 12,30522-30533
DOI: 10.1039/D4TA05436A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Basundhara Dasgupta, Suptish Ghosh, Carsten Walter, Markus S. Budde, Georg J. Marquardt, Han-Hsu Chen, Markus G. M. Breithaupt, Tolga Yilmaz, Christoph Garmatter, Tamanna Ahamad, Ingo Zebger, Matthias Driess, Prashanth W. Menezes
A nanocrystalline Co9S8 (pre)catalyst derived from a novel {CoIIS4} complex is reported for the oxygen evolution reaction (OER) and selective biomass valorization. During OER, Co9S8 reconstructs completely into a CoOOH active phase via S-leaching.
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3D soft lithiophilic current collector of Ag-CuNW/MWCNT@melamine foam enables dendrite-free lithium metal anodes

J. Mater. Chem. A, 2024, 12,30601-30610
DOI: 10.1039/D4TA05955G, Paper
Song-Bai Xiang, Xiyu Zhang, Yue Hou, Wenjing Li, Chengri Yin, Zhenxing Yin
A 3D soft current collector with excellent lithiophilicity was obtained by constructing a conductive Ag-CuNW/MWCNT network on a melamine foam, which can effectively reduce the local current density and guide the uniform Li deposition.
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Modulating the band gap of a pyrazinoquinoxaline-based metal–organic framework through orbital hybridization for enhanced visible light-driven CN bond construction

J. Mater. Chem. A, 2024, 12,30582-30590
DOI: 10.1039/D4TA06282E, Paper
Zitong Chen, Linghui Cao, Aogang Liu, Pengda Liu, Yuan Chen, Juntao Yan, Bao Li
An indium-based metal–organic framework bearing a pyrazinoquinoxaline derivative is synthesized to facilitate two methods for the construction of CN bonds, and their mechanisms are investigated through detailed theoretical calculations.
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no

Promoting fast potassium storage in CoSe2/VSe2 non-layered/layered heterostructured nanofibers

J. Mater. Chem. A, 2024, 12,30289-30297
DOI: 10.1039/D4TA06049K, Paper
Shuhao Xiao, Ying Zhu, Ximeng Liu, Ruichuan Zhang, Jiaqian Qin, Haiyuan Chen, Xiaobin Niu, John Wang, Jinxia Jiang, Jun Song Chen
A heterostructure of non-layered CoSe2 and layered VSe2 was designed to enhance K storage. The lattice mismatch created significant distortion at phase boundaries, facilitating K diffusion and improving electrochemical performance in PIBs.
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Fe-single-atom-coupled Fe3C multifunctional catalysts on P-, F-, N-doped carbon nanotubes for stable Zn–air batteries with ultra-high power densities

J. Mater. Chem. A, 2024, 12,30798-30809
DOI: 10.1039/D4TA04194A, Paper
Manigandan Ramadoss, Hesheng Yu, Anand Rajkamal, Gun Jin Yun, Ziheng Zhang, Chengtao Yang, Fei Ma, Yu Wu, Chen Daiqian, Yuanfu Chen
Fe-single-atom-coupled Fe3C multifunctional catalysts on P-, F-, N-doped CNT deliver comparable OER behavior to RuO2, better ORR performance than Pt/C, and better ZAB performance than Pt/C–RuO2, due to the nanoarchitecture and abundant active sites.
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no

Free-standing films of nickel nanowires anchored with Ni3S2 nanosheets for stable Li anodes

J. Mater. Chem. A, 2024, 12,30534-30547
DOI: 10.1039/D4TA06163B, Paper
Yang Xu, Gang Li, Jiangtao Hai, Hewei Yuan, Haotian Weng, Kun Li, Xiaolu Huang, Yanjie Su, Nantao Hu, Yafei Zhang
A free-standing 3D scaffold of nickel nanowires decorated with lithiophilic Ni3S2 nanosheets was successfully constructed for stable Li anodes.
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no

Ultrathin two-dimensional membranes by assembling graphene and MXene nanosheets for high-performance precise separation

J. Mater. Chem. A, 2024, 12,30121-30168
DOI: 10.1039/D4TA05097E, Review Article
Yifan He, Shanshan Guo, Xueji Zhang, Lijun Qu, Tingting Fan, Jinlei Miao
Ultrathin 2D membranes were assembled by graphene and MXene nanosheets for separation to overcome the “trade-off” limitation between permeability and selectivity.
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no

Characterization of pitch carbon coating properties affecting the electrochemical behavior of silicon nanoparticle lithium-ion battery anodes

J. Mater. Chem. A, 2024, 12,30465-30475
DOI: 10.1039/D4TA04478A, Paper
Zoey Huey, Maxwell C. Schulze, G. Michael Carroll, Chaiwat Engtrakul, Chun-Sheng Jiang, Steven C. DeCaluwe, Bertrand J. Tremolet de Villers, Sang-Don Han
700 °C is the optimal heat treatment temperature for pitch-coated silicon electrodes. Both the amorphous carbon/pitch and silicon are active materials but store Li+ ions through different ion storage mechanisms and contribute to overall performance.
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no

Unsaturated coordination modulation and enlarged pore size in nanoflower-like metal organic frameworks for enhanced lithium–oxygen battery performance

J. Mater. Chem. A, 2024, 12,30591-30600
DOI: 10.1039/D4TA06346E, Paper
Lingwen Zhao, Juanjuan Feng, Adeel Abbas, Hao Sun, Chunlei Wang, Hongchao Wang
Unsaturated coordination modulation alters the discharge path and increased pore size accelerates ion exchange and oxygen transport, synergistically improving the electrochemical performance of LOBs.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Multifunctional characteristics of a one-dimensional bimetallic oxyhydroxide nanorod-coupled polyaniline interface for accelerated water and urea electrolysis

J. Mater. Chem. A, 2024, 12,30743-30756
DOI: 10.1039/D4TA05082G, Paper
Niranjanmurthi Lingappan, Sandhiya Lakshmanan, Wonoh Lee
Designing an efficient and durable electrocatalyst is central to hydrogen production technologies such as hydrogen evolution reaction, oxygen evolution reaction, and urea oxidation reaction.
The content of this RSS Feed (c) The Royal Society of Chemistry




no

Optimization of the electron transfer kinetics between a photoanode and biocathode for enhanced carbon-neutral pollutant removal in photocatalytic fuel cells

J. Mater. Chem. A, 2024, 12,30371-30379
DOI: 10.1039/D4TA05290K, Paper
Xiaofei Gu, Jianyu Han, Zhi Wang, Yixin Hong, Tianyi Huang, Yafeng Wu, Yuanjian Zhang, Songqin Liu
A PFC system with collaborative dynamics between the photoanode and biocathode is constructed for using solar energy to efficiently convert refractory organic pollutants into green fuel and generate electricity.
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no

Synthesis of a Cu@ZnO1−x/Al2O3 catalyst with high-density ZnO1−x–Cu interfacial sites for enhanced CO2 hydrogenation to methanol

J. Mater. Chem. A, 2024, 12,30692-30706
DOI: 10.1039/D4TA05801A, Paper
Yunshuo Wu, Haiqiang Wang, Zhongbiao Wu
The development of catalysts with high-density interfacial sites is crucial for enhancing catalytic performance.
The content of this RSS Feed (c) The Royal Society of Chemistry




no

A review on instability factors of mono- and divalent metal ion batteries: from fundamentals to approaches

J. Mater. Chem. A, 2024, 12,30190-30248
DOI: 10.1039/D4TA05386A, Review Article
Elmira Kohan, Roushan Khoshnavazi, Mir Ghasem Hosseini, Abdollah Salimi, Mehdi Salami-Kalajahi
Degradation phenomena in different components (cathode, anode, current collectors (CCs)) of mono- and divalent metal-based batteries affect their performance.
The content of this RSS Feed (c) The Royal Society of Chemistry




no

Microphase-separation-induced polyzwitterionic ionogel with tough, highly conductive, self-healing and shape–memory properties for wearable electrical devices

J. Mater. Chem. A, 2024, 12,30618-30628
DOI: 10.1039/D4TA04228J, Paper
Guang Zeng, Wenshuo Gao, Weicheng Qiu, Guanling Li, Shousen Chen, Xin He, Guoxing Sun, Weijia Yang, Yue Xin
A polyzwitterionic ionogel with a phase separation structure was designed to achieve a balance between mechanical robustness and ionic conductivity. This design holds immense potential for applications in wearable sensors.
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no

Electrochemical synthesis of wormcast-like Pd-based polycrystalline high entropy aggregates for methanol water co-electrocatalysis

J. Mater. Chem. A, 2024, 12,30757-30767
DOI: 10.1039/D4TA06304J, Paper
Yaxing Liu, Wenhao Ding, Jiaxin Liu, Guizhe Zhao, Weiyin Li, Yaqing Liu
A wormcast-like nanostructure of PdFeCoNiCu-pHENs with enriched grain boundary defects was synthesized via electrodeposition. This work opens new possibilities for designing advanced nanomaterials aimed at efficient electrochemical energy conversion.
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no

Sodium storage performance of a high entropy sulfide anode with reduced volume expansion

J. Mater. Chem. A, 2024, 12,30629-30641
DOI: 10.1039/D4TA05122J, Paper
Jianping Ma, Jinyi Guo, Weizheng Li, Xiaohan Yang, Chengde Huang
The introduction of a high-entropy structure into multi-metal sulfides has successfully mitigated volume expansion during the cycling process of sodium-ion batteries!
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no

Enhancing the surface Lewis basicity of phosphorene-hosted NiO nanosheets for sensitive and selective H2S gas sensing

J. Mater. Chem. A, 2024, 12,30380-30387
DOI: 10.1039/D4TA05682E, Paper
Yahui Tian, Wenfang Zhai, Jie Su, Yuxin Zhao, Zhengfei Dai, Wei Gan, Hui Li
A black phosphorene-hosted NiO nanosheet heterostructure achieves enhanced surface Lewis basicity, delivering sensitive and selective sensor properties to trace H2S gas.
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no

Regulating NO2 adsorption at ambient temperature by manipulating copper species as binding sites in copper-modified SSZ-13 zeolites

J. Mater. Chem. A, 2024, 12,30329-30339
DOI: 10.1039/D4TA04399E, Paper
Open Access
Mingzhe Sun, Tianqi Wang, Calvin Ku, Aamir Hanif, Tian Tian, Bernt Johannessen, Qinfen Gu, Ziyi Li, Patrick Sit, Jin Shang
A Cu-modified SSZ-13 zeolite for enhanced NO2 adsorption at ambient temperature.
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Tailoring the electrocatalytic properties of novel microwave synthesized CuNd(2−x)GdxO4 nanoparticles for efficient total water splitting in alkaline media

J. Mater. Chem. A, 2024, 12,30850-30861
DOI: 10.1039/D4TA05919K, Paper
Anto Priyanka E, Sreenivasan Nagappan, J. Judith Vijaya, Angappan Sankaramahalingam, Subrata Kundu
CuNd(2−x)GdxO4 nanoparticles synthesized via microwave method as efficient OER and HER catalysts require low overpotentials exhibiting remarkable stability. Gd doping enhances charge transfer leading to optimized electrocatalysis.
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no

Understanding the crucial roles of natural clinochlore in reinforcing Li–S batteries

J. Mater. Chem. A, 2024, 12,30655-30666
DOI: 10.1039/D4TA05849F, Paper
Yumei Qin, Yashuai Pang, Chujie Zeng, Xue Li, Pengfei Wang, Yan Meng, Guangfeng Zeng, Yunchen Ge, Xiang-Long Huang
Random dendrite growth and the severe shuttle effect of lithium polysulfides are major obstacles to exploiting dependable high-capacity Li–S batteries.
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A C8P monolayer with cross-sp-hybridized phosphorus atoms and ultrahigh energy density as a K-ion battery anode

J. Mater. Chem. A, 2024, 12,30842-30849
DOI: 10.1039/D4TA04961F, Paper
Xu Yan, Sheng Wang, Shicong Ding, Javed Rehman, Yong Liu, Guochun Yang
The proposed C8P monolayer and its derivatives are promising candidates as anode materials for high performance K-ion batteries.
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no

Room-temperature thermochemical water splitting: efficient mechanocatalytic hydrogen production

J. Mater. Chem. A, 2024, 12,30906-30918
DOI: 10.1039/D4TA04650A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Takuya Yamamoto, Sho Ashida, Nanami Inubuse, Shintaro Shimizu, Yui Miura, Tomoya Mizutani, Ken-ichi Saitow
We report the accidental discovery and subsequent investigation of room-temperature thermochemical water splitting in a ball mill. High-purity H2 (>99%) was produced using water and/or seawater feedstocks in a compact (∼50 cm) low-power reactor.
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no

Review of electro-spun carbon nanofiber electrode materials for electrochemical capacitors

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06221C, Review Article
Yutian Peng, Xingyu Zhang, Ruiling Sun, Xunlong Zhang, Can Ge, Yuqing Liu
Schematic illustration demonstrating various approaches to enhance the electrochemical performance of carbon nanofiber electrode materials.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Ir nanoparticles decorated NiFe metal–organic framework as a highly efficient and stable heterostructure electrocatalyst for overall seawater splitting

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06515H, Communication
Hefeng Wang, Zixiao Li, Zhengwei Cai, Chaoxin Yang, Shengjun Sun, Xiaoyan Wang, Min Zhang, Meng Yue, Dongdong Zheng, Asmaa Farouk, Mohamed S. Hamdy, Xuping Sun, Bo Tang
Ir nanoparticle decorated NiFe metal–organic framework on Ni foam (Ir@NiFe-MOF/NF) acts as a bifunctional catalyst for the oxygen evolution reaction and the hydrogen evolution reaction in alkaline seawater with excellent performance and stability.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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no

Recent Advances on Non-noble Metal Catalysts toward N-ethylcarbazole Hydrogen Storage

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06468B, Review Article
Hansai Wu, junming Zhang, Zicong Wang, Xianglong Kong, Gaofu Li, Ying Zhao, Piaoping Yang, Zhiliang Liu
N-ethylcarbazole (NEC) hydrogen storage has garnered significant attention owing to its large-scale safe storage of hydrogen superiority. However, the sluggish hydrogenation kinetics in NEC are extremely dependent on catalysts with...
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PEO/cysteine composite nanofiber-based triboelectric nanogenerator for tiny mechanical energy harvesting

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06845A, Paper
Yijun Hao, Jia Yang, Xiaopeng Zhu, Keke Hong, Jiayu Su, Yong Qin, Wei Su, Hongke Zhang, Chuguo Zhang, Xiuhan Li
Triboelectric nanogenerator (TENG) has acted as a promising method for capturing mechanical energy. However, traditional polymer triboelectric materials result burden to environment, the natural/biodegradable tribo-materials have the disadvantages of poor...
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Scalable Synthesis of N–Doped Graphene–Oxide–Supported FeCo(OH)x Nanosheets for Efficient Co–Doped Fe3O4 Nanoparticle-Based Oxygen Reduction Reaction Electrocatalysis

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06684G, Paper
Open Access
Sunglun Kwon, Jong Hyeon Lee
Developing efficient and cost-effective materials is crucial for advancing electrochemical oxygen reduction reaction (ORR). This study presents a synthesis route for high-performance spinel Fe and Co oxide nanoparticles on N-doped...
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A π–d conjugated metal–organic framework decorated on a MXene-carbon nanofiber as a self-standing electrode for flexible supercapacitors

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06232A, Paper
Zahir Abbas, Shaikh M. Mobin
A c-MOF is grown on MX-CNF, which was prepared via electrospining method. Furthermore, it utilized for flexible supercapcitors with different flexibility angles.
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no

Regulating oxygen redox reactions in lithium-rich materials via an Al2O3-doped ZnO layer for enhanced stability and performance

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06843B, Paper
Xinyu Cheng, Yuke Wang, Jia Lu, Wangqi Dai, Huanhao Lei, Jinning Zuo, Hong Li, Zhengwen Fu
An ultrathin Al2O3-doped ZnO (AZO) layer on LRM regulates oxygen redox by suppressing anion migration and inhibiting surface oxygen oxidation, enhancing cycling performance.
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no

Retraction: Thermally reduced graphene oxide/polymelamine formaldehyde nanocomposite as a high specific capacitance electrochemical supercapacitor electrode

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA90211D, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ali A. Ensafi, Hossein A. Alinajafi, B. Rezaei
To cite this article before page numbers are assigned, use the DOI form of citation above.
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no

Advancing Paper-Based Sensors with MXenes and MOFs: Exploring the Cutting-Edge Innovations

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06561A, Review Article
Sepehr Larijani, Atefeh Zarepour, Arezoo Khosravi, Siavash Iravani, Mahnaz Eskandari, Ali Zarrabi
MXenes and metal-organic frameworks (MOFs) are emerging as promising materials for integration into paper-based sensors (PSs), offering unique properties that can enhance sensor performance in various applications. MXenes, with their...
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Pre-lithiation carbon anodes mitigating potassium loss toward for high-performance potassium-ion energy storage devices

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06451H, Paper
Danni Du, Qingyuan Liu, Jing Gao, Yuying Qin, Xiaobo Jiang, Yuanchang Shi, Minghao Hua, Xiaohang Lin, Zhiwei Zhang, Chengxiang Wang, Long-Wei Yin, Rutao Wang
Pre-potassiation technologies with the functions of providing additional potassium sources and/or mitigating potassium loss during cycling, make them capable of enhancing the energy density and cycling life of potassium-ion capacitors...
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Electrochemical PET recycling to formate through ethylene glycol oxidation on Ni-Co-S nanosheet arrays

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA07156E, Paper
Yi Ma, Luming Li, Jialing Tang, Zongkun Hu, Yong Zhang, Ning Jian, Huan Ge, Jun Zhao, Andreu Cabot, Junshan Li
Plastics have become an integral part of modern society due to their excellent mechanical properties, lightweight, chemical stability and low cost. However, their continuous production and use worldwide have resulted...
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Flexible multifunctional MXene@Ag nanowires/cotton fabric inspired by transport of nutrients by roots for electromagnetic shielding, infrared stealth, Joule/solar heating and flame retardancy

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06712F, Paper
Jiatong Yan, Meimei Chen, Rui Tan, Chuanxi Lin, Shan Jiang, Weijie Wang, Songyue Pan, Hongyan Xiao, Erhui Ren, Ronghui Guo
With the rapid development of 5G intelligent detection technology, electromagnetic shielding/infrared stealth fabrics with Joule/solar heating performance can meet the needs of wearable electronic devices for multi-application scenarios.
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Mike Tomlin on run of AFC North games: I don't care when we play teams

The Steelers will make a little NFL history this weekend.




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Kyle Hamilton, Isaiah Likely not spotted at Tuesday practice

After defeating the Bengals last Thursday, the Ravens got back on the field for an extra practice on Tuesday in advance of their Week 11 matchup with the Steelers.




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DeMeco Ryans: No setback for Nico Collins, game-time decision to sit him Sunday night

The Texans activated wide receiver Nico Collins from injured reserve last Saturday, but he wound up being on the inactive list for their loss to the Lions on Sunday night.




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Bears pivot to another potential location for Chicago stadium

The Bears can't get their effort to muster political support — and taxpayer money — for a new stadium off the ground.




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Lamar Jackson's MVP dominance, Deebo’s sideline meltdown & Chiefs’ grit | McCoy & Van Noy

6x Pro Bowl DT Gerald McCoy and 2x Super Bowl winner Kyle Van Noy recap their favorite moments from week 10 in the NFL, give their praise for Lamar Jackson and make their week 11 picks.




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Jets claim C Connor McGovern off waivers from Saints

The Saints cut center Connor McGovern on Monday, a sign that starter Erik McCoy is ready to return from injured reserve.




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Niners CB Deommodore Lenoir agrees to five-year, $92 million extension, per report

One of the NFL's best slot cornerbacks got paid.




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Report: 49ers, CB Deommodore Lenoir agree to five-year, $92 million extension

Lenoir is in the final year of his rookie deal and was scheduled to become a free agent in March.




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Report: Lenoir, 49ers agree to five-year, $92M contract extension

Cornerback Deommodore Lenoir and the San Francisco 49ers reportedly have agreed to a five-year contract extension worth $92 million.




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Why timing worked for Lenoir, 49ers to get extension done now

Matt Maiocco explains why the timing was perfect for 49ers cornerback Deommodore Lenoir and San Francisco to finalize a contract extension now.