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A MOF-derived CuCo(O)@ carbon–nitrogen framework as an efficient synergistic catalyst for the hydrolysis of ammonia borane

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00023J, Research Article
Yao Yuan, Xiaoyu Chen, Xing Zhang, Zumin Wang, Ranbo Yu
A CuCo(O)-embedded nitrogen-enriched porous carbon framework catalyst derived from doped metal–organic frameworks for efficient hydrolysis of ammonia borane.
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A sponge-like small pore zeolite with great accessibility to its micropores

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00261E, Research Article
Kok-Giap Haw, Simona Moldovan, Lingxue Tang, Zhengxing Qin, Qianrong Fang, Shilun Qiu, Valentin Valtchev
The accessibility of SSZ-13 is enhanced by having a sponge-like structure after etching under neutral pH conditions.
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A single-ligand-protected Eu60−nGd(Tb)n cluster: a reasonable new approach to expand lanthanide aggregations

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00226G, Research Article
Xi-Ming Luo, Ning-Fang Li, Qing-Fang Lin, Jia-Peng Cao, Peng Yuan, Yan Xu
Two fascinating configurations were obtained based on mixed-lanthanide conditions, abbreviated as mixed-Ln60. The synthesis provides a way to obtain similar metal-core Ln high-nuclearity clusters, breaking the ionic radius limitation.
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A slowly magnetic relaxing SmIII monomer with a D5h equatorial compressed ligand field

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00326C, Research Article
Ji-Dong Leng, Qiu-Yan Hua, Li-Shan Lin, Wei-Quan Lin, Jun-Liang Liu, Yong-Ze Pan, Yi-Bo Qiu, Ai-Ju Zhou
By using a bi-dentate phosphine oxide ligand L (L = bis(diphenylphosphino)methane dioxide), two mono-nuclear lanthanide complexes [LnL2(DMF)Cl2]Cl (Ln = Sm, 1; Dy, 2) with a D5h equatorial ligand field (LF)...
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SrTaO2N co-doped with La/Zr as promising photocatalysts for water reduction under visible light illumination

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00361A, Research Article
Ran Wang, Guoan Lin, Xiaoxiang Xu
La/Zr co-doped SrTaO2N has been investigated as visible-light-active photocatalysts for water reduction. Unlike previous aliovalent doping that leads to degradation of light absorption, La/Zr co-doping largely preserves the visible light...
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Redox- and Solvato-Magnetic Switching in a Tetrathiafulvalene-Based Triad Single-Molecule Magnet

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00319K, Research Article
Fabrice Pointillart, Jessica Flores-Gonzalez, Vincent Montigaud, Lorenzo Tesi, Vladimir Kuz'mich Cherkasov, Boris Le Guennic, Olivier Cador, Lahcene Ouahab, Roberta Sessoli, Viacheslav Kuropatov
The first simultaneous redox and solvato-magnetic switching was achieved. The dinuclear complex [Dy2(hfac)6(H2SQ)]CH2Cl2 (Dy2H2SQ) (where hfac = 1,1,1,5,5,5-hexafluoroacethylacetonate and H2SQ = 2,2’-benzene-1,4-diylbis(6-hydroxy-4,7-di-tert-butyl-1,3-benzodithiol-2-ylium-5-olate) was reversibly oxidized into the dinuclear complex [Dy2(hfac)6(H2O)2(Q)]...
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Ag nanoparticle embedded Cu nanoporous hybrid arrays for the selective electrocatalytic reduction of CO2 towards ethylene

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00025F, Research Article
Liang Hou, Jianyu Han, Chong Wang, Yuwei Zhang, Yuanbin Wang, Zhiming Bai, Yousong Gu, Yan Gao, Xiaoqin Yan
The Ag/Cu composites present excellent catalytic activity for the reduction of CO2 to C2H4, and exhibit a maximum Faraday Efficiency 41.3%.
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Ni-Doped magnesium manganese oxide as a cathode and its application in aqueous magnesium-ion batteries with high rate performance

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00067A, Research Article
Hongyu Zhang, Dianxue Cao, Xue Bai
Aqueous magnesium-ion batteries feature good safety and high energy density and represent promising energy storage systems.
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Highly efficient water splitting over a RuO2/F-doped graphene electrocatalyst with ultra-low ruthenium content

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00095G, Research Article
Zhenglong Fan, Fan Liao, Huixian Shi, Yang Liu, Mingwang Shao, Zhenhui Kang
A RuO2/F-graphene catalyst with a low Ru content of 6.9 wt% only needs potentials of 1.56 V in alkaline medium and 1.73 V in neutral medium to reach a current density of 10 mA cm−2 for electrocatalytic water splitting.
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Synthesis of dual emitting iodocuprates: can solvents switch the reaction outcome?

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00346H, Research Article
Alexander V. Artem'ev, Alexey S. Berezin, Ilya V. Taidakov, Irina Yu. Bagryanskaya
An unprecedented structure-directing effect of solvents in halocuprate self-assembly reactions was discovered. The compounds presented show remarkable dual luminescence, strongly changing the emission color upon varying temperature.
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Enabling high performance n-type metal oxide semiconductors at low temperatures for thin film transistors

Inorg. Chem. Front., 2020, 7,1822-1844
DOI: 10.1039/D0QI00038H, Review Article
Nidhi Tiwari, Amoolya Nirmal, Mohit Rameshchandra Kulkarni, Rohit Abraham John, Nripan Mathews
The review highlights low temperature activation processes for high performance n-type metal oxide semiconductors for TFTs.
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Ligand substitution induced single-crystal-to-single-crystal transformations in two Ni(II) coordination compounds displaying consequential changes in proton conductivity

Inorg. Chem. Front., 2020, 7,1880-1891
DOI: 10.1039/D0QI00088D, Research Article
Rong-Yun Li, Hou-Ting Liu, Chuan-Cong Zhou, Zhi-Tong Chu, Jing Lu, Su-Na Wang, Juan Jin, Wen-Fu Yan
Two Ni(II) coordination compounds can reversibly SC–SC transform into each other induced by ligand substitution, causing changes in their proton conductivities.
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Single-chain magnet behavior in a 2p–3d–4f spin array with a nitronyl nitroxide biradical

Inorg. Chem. Front., 2020, 7,1949-1956
DOI: 10.1039/D0QI00098A, Research Article
Juan Sun, Jing Xie, Licun Li, Jean-Pascal Sutter
New nitronyl nitroxide biradical-bridged 3d–4f chains have been constructed in which improved SCM behavior is observed.
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Luminescent metal–organic frameworks (LMOFs) as potential probes for the recognition of cationic water pollutants

Inorg. Chem. Front., 2020, 7,1801-1821
DOI: 10.1039/D0QI00167H, Review Article
Partha Samanta, Sumanta Let, Writakshi Mandal, Subhajit Dutta, Sujit K. Ghosh
This review aims to provide an overview regarding the development of luminescent metal–organic frameworks (LMOFs) based sensory materials for the detection of cationic inorganic and organic water pollutants.
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Highly efficient CO2 capture and conversion of a microporous acylamide functionalized rht-type metal–organic framework

Inorg. Chem. Front., 2020, 7,1939-1948
DOI: 10.1039/D0QI00231C, Review Article
Junxiong Liao, Wenjiang Zeng, Baishu Zheng, Xiyang Cao, Zhaoxu Wang, Guanyu Wang, Qingyuan Yang
A microporous acylamide functionalized rht-type MOF (HNUST-9) with Lewis acidic open copper sites and CO2-philic acylamide groups exhibits high performance for CO2 capture, separation and chemical conversion.
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A new honeycomb metal–carboxylate-tetrazolate framework with multiple functions for CO2 conversion and selective capture of C2H2, CO2 and benzene

Inorg. Chem. Front., 2020, 7,1957-1964
DOI: 10.1039/D0QI00181C, Research Article
Gang-Ding Wang, Yong-Zhi Li, Wen-Juan Shi, Lei Hou, Zhonghua Zhu, Yao-Yu Wang
A stable Cd-MOF was built by a carboxylate-tetrazolate ligand, which contains hexagonal channels and reveals multiple functions including separation of CO2/CH4, C2H2/CO2, C2H2/CH4 and benzene/cyclohexane, and catalytic conversion of CO2 with epoxides.
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Ir3Pb alloy nanodendrites with high performance for ethanol electrooxidation and their enhanced durability by alloying trace Au

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00233J, Research Article
Genlei Zhang, Zhenxi Zhang
Porous Ir3Pb nanodendrites exhibit excellent activity and superior CO2 selectivity for the EOR under acidic conditions, and their durability can be enhanced dramatically by alloying trace Au.
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Excitation wavelength dependent emission of silver(I) complexes with a pyrimidine ligand

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00254B, Research Article
Nikita A. Shekhovtsov, Katerina A. Vinogradova, Alexei S. Berezin, Taisiya S. Sukhikh, Viktor P. Krivopalov, Elena B. Nikolaenkova, Mark B. Bushuev
Interplay of three emission mechanisms for silver(I) complexes leads to luminescence thermochromism and color tunable emission.
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An advanced composite with ultrafast photocatalytic performance for the degradation of antibiotics by natural sunlight without oxidizing the source over TMU-5@Ni–Ti LDH: mechanistic insight and toxicity assessment

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00050G, Research Article
Reza Abazari, Ali Morsali, Deepak P. Dubal
Pharmaceuticals are considered as emerging organic contaminants that have become a serious environmental problem, which endanger human health and environmental bio-diversity.
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Interconnected porous nanoflakes of CoMo2S4 as an efficient bifunctional electrocatalyst for overall water electrolysis

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00318B, Research Article
Shasha Tang, Xiaogang Li, Marc Courté, Jingjing Peng, Denis Fichou
Interconnected porous nanoflakes of the bimetallic CoMo2S4 are synthesized and investigated as bifunctional catalysts for highly efficient overall water electrolysis.
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Mechanism of oxygen vacancy assisted water-splitting of LaMnO3: Inorganic perovskite prediction for fast solar thermochemical H2 production

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00338G, Research Article
Mingkai Fu, Huajun Xu, Xin Li
Highly reducible and thermally-stable lanthanum-manganese perovskites represent a promising class of materials for solar thermochemical hydrogen production. However, such materials suffer from low hydrogen production rate, resulting in incomplete re-oxidation...
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Exploiting cation aggregation in new magnesium amidohaloaluminate electrolytes for magnesium batteries

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QI01606F, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Etienne V. Brouillet, Marco Amores, Serena A. Corr, Stuart D. Robertson
The active species in magnesium electrolytes is regularly assigned as being the thermodynamically stable dinuclear [Mg2Cl3]+ cation. By deliberately targeting other implicated aggregates, their effect on Mg-ion battery performance is easily ascertained.
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Improving Catalysis for Electrochemical Water Splitting Using Phosphosulphide Surface

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00295J, Research Article
Lisi Yin, Xinran Ding, Wenxian Wei, YiHui Wang, Zizheng Zhu, Kai Xu, Ziming Zhao, Hong Zhao, Tingting Yu, Tao Yang
As an energy carrier, hydrogen shows great promise superior to the traditional fossil fuel to meet the ever-increasing global energy demands. Electrochemical water splitting has been considered to be an...
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Cyclometalated Ir(III) Complexes Towards Blue-Emissive Dopant for Organic Light-Emitting Diodes: Fundamentals of Photophysics and Designing Strategies

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00001A, Review Article
Sunhee Lee, Won-Sik Han
The main difficulties hindering development of a deep-blue phosphorescent cyclometalated Ir(III) complex are insufficient colour purity, i.e., failure to achieve ideal Commission Internationale de L’Eclairage (CIE) coordinates of (0.14, 0.09),...
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Aerobic Oxidation Catalyzed by Polyoxometalates Associated to an Artificial Reductase at Room Temperature and in Water

Inorg. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QI00442A, Research Article
Ahmad Naim, Yoan Chevalier, Younes Bouzidi, Priyanka Gairola, Pierre Mialane, Anne Dolbecq-Bastin, Frédéric Avenier, Jean-Pierre Mahy
Four polyoxometalates (POMs) were combined with an artificial reductase based on polyethyleneimine (PEI) and flavin mononucleotide (FMN) which is capable of delivering single electrons upon addition of nicotinamide adenine dinucleotide...
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Crimson tide [videorecording] / Hollywood Pictures presents a Don Simpson/Jerry Bruckheimer production ; produced by Don Simpson, Jerry Bruckheimer ; story by Michael Schiffer and Richard P. Henrick ; screenplay by Michael Schiffer ; directed by Tony Scot

1 videodisc (116 min.) sound, color; 4 3/4 in




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Professor Marston and the Wonder Women [videorecording]/ Annapurna Pictures presents in association with Stage 6 Films ; a Topple Pictures & Boxspring Entertainment production ; produced by Terry Leonard, Amy Redford ; written and directed by Angela R

1 videodisc (approximately 108 minutes) : sound, color ; 4 3/4 in




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Wonder Woman [videorecording] / directed by Patty Jenkins ; screenplay by Allan Heinberg ; story by Zack Snyder & Allan Heinberg and Jason Fuchs ; produced by Charles Roven, Deborah Snyder, Zack Snyder, Richard Suckle ; a Warner Bros. Pictures present

2 videodiscs (141 min.) : sound, color ; 4 3/4 in




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We cannot run away to moon, need to develop herd immunity: Epidemiologist

Muliyil tells Somesh Jha that the days of eradicating the disease is over and the country should move towards developing 'herd immunity'




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Will consider raising duties on fuel and liquor: Manpreet Badal, Punjab FM

Punjab would like to help the Centre in any way possible to deal with the coronavirus disease (Covid-19) pandemic, said state Finance Minister Manpreet Singh Badal




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Early lockdowns in India may flatten Covid-19 curve: Nimhans virologist

In a Q&A, V Ravi says at some later stage two-thirds of the population will have gotten Covid-19 but that stage many would have recovered without even knowing they had been infected




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India could use 3-5% of GDP stabilising economy: World Bank economists

The lockdown of economies around the world causes a much sharper decline in economic activity than in normal recessions, says World Bank chief economist south Asia region, Hans Timmer




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‘The Two Popes’ Pits Tradition Against Progress

What the new Netflix drama can teach us about the interdependency of orthodoxy and reform.




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‘Little Women’ and the Feminist Search for Righteousness

The real story is not whether the four young women will marry, but whether they will become better people.




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Netflix’s ‘Messiah’ Says the World Needs a Savior

The problem is, which one?




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Bryan Stevenson Wants to Liberate People from the Lie That Their Life Doesn’t Matter

The author of the book behind the new film ‘Just Mercy’ shows the church a way forward.




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Rising Above the Streaming Wars

Faith-driven streaming services can’t compete with the ever-growing number of entertainment giants flooding into homes. Maybe they don’t have to.




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Article :: Scream of the Crop: how to resize and crop photos

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Article :: Orthographic Views

Learn how to create and interpret orthographic views with Solidworks 2016.




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Article :: My Workflow: here's my typical start-to-finish project

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Article :: Sketchnoters' Stories: 8th-grader Allison Huang revolutionizes her school notes with sketchnotes

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Article :: Compositing with Green Screen Effects

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Article :: Isometric Drawing with AutoCAD 2020

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Article :: Orthographic Views

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Article :: Simplicity: Why It Matters

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How nature’s recipes help in combating cholesterol




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Cleaning the mobile germ warehouse




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‘Overweight people who pick diet drinks eat more food’




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In new report, list of smoking-related illnesses grows