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The Amazon : what everyone needs to know / Mark J. Plotkin

By prospero.murdoch.edu.au
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Plotkin, Mark J., author


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The Wiley Handbook of Healthcare Treatment Engagement: Theory, Research, and Clinical Practice

By www.wiley.com
Published On :: 2020-04-14T04:00:00Z


 

Against a global backdrop of problematic adherence to medical treatment, this volume addresses and provides practical solutions to the simple question: “Why don’t patients take treatments that could save their lives?”

The Wiley handbook of Healthcare Treatment Engagementoffers a guide to the theory, research and clinical practice of promoting patient engagement in healthcare treatment at individual, organizational and systems levels. The concept of



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Therapeutic Progress in Oncology: Towards a Revolution in Cancer Therapy?

By www.wiley.com
Published On :: 2020-04-28T04:00:00Z


 

The combined effects of population growth and aging have led to an increase in the number of cancers. Preventing, diagnosing, treating and curing cancer are therefore, more than ever, imperatives facing medicine especially to continue the decrease in cancers mortality rates and to improve the quality of survival.

Over time, the classic modes of treatment (surgery, external beam radiotherapy, chemotherapy) have become more refined and efficient. From



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New Territories in Health

By www.wiley.com
Published On :: 2020-04-28T04:00:00Z


 

The third volume in the Health Information set, New Territories in Health focuses on the multifaceted spheres of influence or territories in the field of health.

This book includes nine contributions based on the analysis of stakeholder logics that approach the relationships between health and territories. The authors all specialists offer original insights, enhanced by in-depth studies, on the multiple forms that this territorialization takes: political



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Halt work on hydro projects in JK: Pak tells India

By timesofindia.indiatimes.com
Published On :: Sat, 21 Jan 2017 12:45:34 IST

Pakistan's two parliamentary committees in a joint resolution asked India to immediately suspend the ongoing construction of the Kishanganga and Ratle hydro power projects in Jammu and Kashmir, Dawn reported. ​


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Efficient bifunctional catalysts synthesized from three-dimensional Ni/Fe bimetallic organic frameworks for overall urea electrolysis

By feeds.rsc.org
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Dalton Trans., 2020, 49,5646-5652
DOI: 10.1039/D0DT00605J, Paper
Huizhu Xu, Ke Ye, Kai Zhu, Jinling Yin, Jun Yan, Guiling Wang, Dianxue Cao
MOF-Ni@MOF-Fe–S which has a structure of interwoven and folding nanosheets shows superior electrochemical performance towards urea electrolysis.
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Phase transition tuning by Fe(III)/Co(III) substitution in switchable cyano-bridged perovskites: (C3H5N2)2[KFexCo1−x(CN)6]

By feeds.rsc.org
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Dalton Trans., 2020, 49,5503-5512
DOI: 10.1039/D0DT00615G, Paper
Magdalena Rok, Marcin Moskwa, Andrzej Pawlukojć, Rafał Janicki, Iga Zuba, Piotr Zieliński, Paweł Sobieszczyk, Grażyna Bator
The single-crystals of mixed (C3H5N2)2[KFexCo1−x(CN)6] crystals, with different ratios of x = 0, 0.29, 0.42, 0.51, 0.63, 0.70, 0.85, and 1, have been grown from aqueous solutions.
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Hierarchical Mo-doped CoP3 interconnected nanosheet arrays on carbon cloth as an efficient bifunctional electrocatalyst for water splitting in an alkaline electrolyte

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Dalton Trans., 2020, 49,5563-5572
DOI: 10.1039/D0DT00671H, Paper
Shasha Zhang, Mingjing Guo, Shuyi Song, Ke Zhan, Ya Yan, Junhe Yang, Bin Zhao
Hierarchical Mo-doped CoP3 nanosheet arrays were fabricated on carbon cloth to serve as an efficient and robust bifunctional electrocatalyst for overall water splitting in alkaline media.
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Enhanced photoluminescence and ferro/piezoelectric performance in piezo-luminescent materials with outstanding water resistance and thermal stability

By feeds.rsc.org
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Dalton Trans., 2020, 49,5581-5589
DOI: 10.1039/D0DT00577K, Paper
Chunlin Ma, Xingyu Wang, Weishi Tan, Weiping Zhou, Xiaoxiong Wang, Zhenzhi Cheng, Guibin Chen, Zhangyin Zhai
(1 − x)Na0.5Bi0.5TiO3-xCaTiO3:Sm3+ multifunctional materials were prepared, which exhibit enhanced ferro/piezoelectric performance and photoluminescence, with outstanding water resistance and thermal stability.
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Three metal–organic framework isomers of different pore sizes for selective CO2 adsorption and isomerization studies

By feeds.rsc.org
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Dalton Trans., 2020, 49,5618-5624
DOI: 10.1039/D0DT00793E, Paper
Rui Zhang, Ju-Hua Huang, De-Xian Meng, Fa-Yuan Ge, Li-Fei Wang, Yong-Kai Xu, Xing-Gui Liu, Mei-Mei Meng, Zhen-Zhong Lu, He-Gen Zheng, Wei Huang
Three MOF isomers including framework-catenation and framework-topological isomers were synthesized for adsorbing carbon dioxide with high selectivity.
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Prediction of ternary fluorooxoborates with coplanar triangular units [BOxF3−x]x− from first-principles

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Dalton Trans., 2020, 49,5424-5428
DOI: 10.1039/D0DT00160K, Communication
Zhonglei Wei, Wenyao Zhang, Hao Zeng, Hao Li, Zhihua Yang, Shilie Pan
From first-principles prediction, we got all the basic structural units of fluorooxoborates, namely, tetrahedral elements [BOxF4−x] (x = 1,2,3) like [BO4] and triangular elements [BOxF3−x] (x = 1,2) like [BO3].
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Efficient CO2 electroreduction to CO at low overpotentials using a surface-reconstructed and N-coordinated Zn electrocatalyst

By feeds.rsc.org
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Dalton Trans., 2020, 49,5434-5439
DOI: 10.1039/D0DT00800A, Communication
Wanan Deng, Shixiong Min, Fang Wang, Zhengguo Zhang, Chao Kong
A surface-reconstructed and N-coordinated Zn electrocatalyst exhibits enhanced activity and selectivity for CO2 electroreduction to CO at reduced overpotentials.
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Hollow-structure engineering of a silicon–carbon anode for ultra-stable lithium-ion batteries

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Dalton Trans., 2020, 49,5669-5676
DOI: 10.1039/D0DT00566E, Paper
Hongbin Liu, Yun Chen, Bo Jiang, Yue Zhao, Xiaolin Guo, Tingli Ma
Hollow silicon nanotubes were successfully synthesized in situ on a carbon substrate, which effectively accommodate the volume expansion of silicon and exhibit ultra-stable performance as the anode of lithium-ion batteries.
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Time-resolved infra-red spectroscopy reveals competitive water and dinitrogen coordination to a manganese(I) carbonyl complex

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Dalton Trans., 2020, 49,5463-5470
DOI: 10.1039/C9DT04878B, Paper
Jonathan B. Eastwood, L. Anders Hammarback, Matthew T. McRobie, Ian P. Clark, Michael Towrie, Ian. J. S. Fairlamb, Jason M. Lynam
Photolysis of [Mn(C^N)(CO)4] (C^N = bis-(4-methoxyphenyl)methanimine) in heptane solution results in ultra-fast CO dissociation and ultimate formation of a rare Mn-containing dinitrogen complex fac-[Mn(C^N)(CO)3(N2)].
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Templated syntheses of heterometal tungsten–cobalt–sulfur clusters with different nuclearities

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Dalton Trans., 2020, 49,5523-5530
DOI: 10.1039/D0DT00765J, Paper
Jia-Ting Guo, Xu-Dong Chen
A series of heterometal tungsten–cobalt–sulfur clusters with different nuclearities have been synthesized rationally using a chelating template.
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Design and synthesis of photoluminescent active interpenetrating metal–organic frameworks using N-2-aryl-1,2,3-triazole ligands

By feeds.rsc.org
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Dalton Trans., 2020, 49,5429-5433
DOI: 10.1039/D0DT00933D, Communication
Jingyang Li, Ying He, Li Wang, Qinhe Pan, Zhiguang Song, Xiaodong Shi
N-2-aryl-1,2,3-triazole derivatives were synthesized as new ligand systems for the construction of photoluminescent active metal–organic frameworks (MOFs).
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Efficient removal of methyl orange by a flower-like TiO2/MIL-101(Cr) composite nanomaterial

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Dalton Trans., 2020, 49,5722-5729
DOI: 10.1039/D0DT00778A, Paper
Wan Wu, Tiantian Yao, Ye Xiang, Hao Zou, Yi Zhou
Nano-scale MOF composite materials prepared by combining inorganic semiconductors with controllable pore structures and functional active sites for the effective removal of organic dyes will exhibit more excellent adsorption activity.
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Two amino acid-templated metal phosphates: surfactant-thermal synthesis, water stability, and proton conduction

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Dalton Trans., 2020, 49,5440-5444
DOI: 10.1039/D0DT00966K, Communication
Lijuan Huang, Lei Wang, Yan Zhao, Ling Huang, Jian Bi, Guohong Zou, Zhien Lin, Daojiang Gao
An amino acid-templated gallium phosphate with a zeolitic topology has been prepared under surfactant-thermal conditions and it shows exceptional water stability and interesting proton-conducting properties.
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Two novel lead-based coordination polymers for luminescence sensing of anions, cations and small organic molecules

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Dalton Trans., 2020, 49,5695-5702
DOI: 10.1039/D0DT00533A, Paper
Xue-Yan Zhao, Bing Liang, Ke-Cai Xiong, Yu-Wen Shi, Si-Lei Yang, Ting-Yu Wei, Hui Zhang, Qing-Fu Zhang, Yan-Li Gai
A novel lead-based compound is reported as a multi-responsive luminescent sensor for detecting anions, cations and small organic molecules, especially Cr2O72−, CrO42−, Fe3+ and nitrobenzene.
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Oxaliplatin and [Pt(R,R-DACH)(panobinostat-2H)] show nanomolar cytotoxicity towards diffuse intrinsic pontine glioma (DIPG)

By feeds.rsc.org
Published On ::

Dalton Trans., 2020, 49,5703-5710
DOI: 10.1039/C9DT04862F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Marie H. C. Boulet, Laura K. Marsh, Alison Howarth, Alice Woolman, Nicola J. Farrer
Oxaliplatin and the platinum(II) panobinostat complex (2) demonstrate nanomolar cytotoxicity towards diffuse intrinsic pontine glioma cells (DIPG); with 2 exhibiting improved solubility in comparison to panobinostat.
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Syntheses, characterization and properties of two new dodeca-niobates presenting unprecedented features

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00953A, Paper
Ting-Ting Zhang, Po-Han Lin, Gui-Yang Yu, Xiao Zhang, Xiao-Bing Cui
Two new dodeca-niobate materials, K3[Nb2O2][H7SiNb12O40]·16H2O (1) and [Cu(en)2]9[(VNb12V1.69Nb0.31O42en0.31)2]·20.69H2O (2), have been obtained and characterized by IR, UV-Vis, XRD, and single crystal X-ray diffraction analysis.
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Retraction: Determination of chemical affinity of graphene oxide nanosheets with radionuclides investigated by macroscopic, spectroscopic and modeling techniques

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Dalton Trans., 2020, 49,5741-5741
DOI: 10.1039/D0DT90074E, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Congcong Ding, Wencai Cheng, Yubing Sun, Xiangke Wang
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Enhancing the energy barrier by replacing the counterions in two holmium(III)-pentagonal bipyramidal single-ion magnets

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00905A, Paper
Lei-Lei Li, Hong-Dan Su, Shuang Liu, Wen-Zhen Wang
Upon changing the employed halide ions as counterions, Ueff increases from 290 K to 320 K in two HoIII-SIMs with pentagonal-bipyramidal structures.
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Pyridylamido hafnium complexes with a silylene bridge: synthesis and olefin polymerization

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01031F, Paper
Pavel S. Kulyabin, Dmitry V. Uborsky, Alexander Z. Voskoboynikov, Jo Ann M. Canich, John R. Hagadorn
Pyridylamido hafnium complexes with a silylene bridge were synthesized, characterized with X-ray crystal structure analysis and shown to polymerize 1-hexene and propene and copolymerize ethylene and 1-octene.
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Structural design of cubic Sr,V:CeFeO3 thin films with a strong magneto-optical effect and high compatibility with a Si substrate

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/C9DT04837E, Paper
Nanxi Lin, Shengnan Zhang, Haixin Chen, Yunjin Chen, Xin Chen, Yongfan Zhang, Xiaolin Hu, Naifeng Zhuang
Orthorhombic CeFeO3 is optimized to be cubic perovskite with high compatibility with Si substrate by introducing Sr, V ions into lattice. Cubic Sr,V:CeFeO3 film exhibit strong magneto-optical effect due to spin-coupling hybrid of Ce 4f with Fe/V 3d.
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Theoretical rationalization for the equilibrium between (μ–η2:η2-peroxido)CuIICuII and bis(μ-oxido)CuIIICuIII complexes: perturbational effects from ligand frameworks

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01001D, Paper
Tsukasa Abe, Yoshihito Shiota, Shinobu Itoh, Kazunari Yoshizawa
DFT calculations are carried out to investigate the geometric effects of the supporting ligands in the relative energies of the (μ–η2:η2-peroxido)CuIICuII complex 1 and the bis(μ-oxido)CuIIICuIII complex 2.
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Facile synthesis of Mn-doped NiCo2O4 nanoparticles with enhanced electrochemical performance for a battery-type supercapacitor electrode

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01177K, Paper
To Van Nguyen, Le The Son, Vu Van Thuy, Vu Dinh Thao, Masahito Hatsukano, Koichi Higashimine, Shinya Maenosono, Sang-Eun Chun, Tran Viet Thu
We report the synthesis of manganese-doped nickel cobalt oxide (Mn-doped NiCo2O4) nanoparticles (NPs) by an efficient hydrothermal and subsequent calcination route.
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Self-assembly of mixed-valent and heterometallic metallocycles: efficient catalyst for oxidation of alcohols to aldehydes with ambient air

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01340D, Communication
Ya-Liang Lai, Xue-Zhi Wang, Rui-Rong Dai, Yong-Liang Huang, Xian-Chao Zhou, Xiao-Ping Zhou, Dan Li
Two mixed-valent CuII/CuI and two heterometallic CuII/AgI metallocycles have been synthesized by the assembly of designed metalloligands and CuI/AgI ions, respectively. The CuII/CuI metallocycle can catalyze oxidation of alcohols to...
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Water-locking molecule-assisted fabrication of natural-inspired Mg(OH)2 for high-efficient and economical uranium capture

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00618A, Paper
Hengbin Xu, Zhenyuan Bai, Milin Zhang, Jun Wang, Yongde Yan, Min Qiu, Jiaming Chen
With the depletion of uranium terrestrial deposits, researchers have focused on the development of adsorbents to extract radioactive uranium from seawater/wastewater. However, there are still considerable challenges to manipulate this...
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Accelerating charge transfer in ultrafine NiFe-LDHs/CB interface during electrocatalyst activation process for water oxidation

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00824A, Paper
Mengke Cai, Qinglin Liu, Yiyue Zhao, Zhenyu Wang, Yinle Li, Guangqin Li
Owing to coordinating of intriguing activity and conductivity, the hybrid compositions of layered double hydroxides (LDHs) and carbon-based materials have been extensively and widely applied to evolve oxygen gas for...
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Modulation of the driving forces for adsorption on MIL-101 analogues by decoration with sulfonic acid functional groups: superior selective adsorption of hazardous anionic dyes

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00978D, Paper
Ji-Min Yang, Wei Zhang, Run-Zhi Zhang, Meng-Xuan Tong
MIL-101-SO3H analogues functionalized with –SO3H groups exhibited superior CR, MO and AC adsorption capacities because of their distinct adsorption mechanisms.
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Structural, spectroscopic and electronic properties of a family of bi-octahedral Ru25+/6+ complexes with a bridging 2,5-di(2-pyridyl)pyrrolide ligand

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01325K, Paper
Shi-Rui Kang, Qin Zi Zhou, Chang-Fang Xiong, Bin Liu, John E. McGrady, Mohammed Obies, Chao Liu, Piao He, Xiao-Yi Yi
A family of Ru2 dimers, [Ru2(μ-κ2N,N’:κ2N’,N’’-dpp)2(μ-X)(X)2]q+ (X = Cl, Br, q = 0 and X = I, q = 1) is synthesized from a [Ru2(OAc)4Cl] paddlewheel starting material. The neutral...
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An ultra-effective pathway for fully removing the oxygen components of graphene oxide by a flame-assisted microwave process

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01483D, Communication
Xuefeng Zou, Qin Hu, Hengxiu Yang, Feng Chen, Bin Xiang, Xinyue Liang, Qibing Wu, Hujun Shen
Here we report an ultra-effective, reliable pathway to reduce GO into graphene by an about 4-seconds flame-assisted microwave process. A holey graphene with a C/O atom ratio of 31.1, a...
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Temperature-dependent hysteretic two-step spin crossover in two-dimensional Hofmann-type compounds

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00866D, Paper
Jun Tao, Yue Li, Min Liu, Zi-Shuo Yao
Hofmann-type spin-crossover (SCO) frameworks attract much attention due to their predictable structures and diverse SCO behaviours. In this paper, we report two isostructural two-dimensional (2D) Hofmann-type SCO frameworks [FeII(ppe)2MII(CN)4]·3H2O (ppe...
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Multicolor tunable luminescence and energy transfer of core-shell structured SiO2@Gd2O3 microspheres co-activated with Dy3+/Eu3+ under single UV excitation

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00735H, Paper
Jie Chen, Yixin Gao, Haifeng Jiang, Yan Liu, Zhaohui Jin
Optimizing structure and varing doped ions are two main strategies to obtain excellent luminescence performance. Spherical morphology is considered to be the most ideal phosphor structure due to the least...
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Influence of Eu valence in the optical activity of BaTiO3 decorated with CaF2 synthesized by microwave-assisted hydrothermal method

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01321H, Paper
Tatiane Strelow Lilge, Adriano Borges Andrade, Claudiane dos Santos Bezerra, Giordano Frederico da Cunha Bispo, Zélia Soares Macedo, Mario Lucio Lúcio Moreira, Mário Ernesto Giroldo Valerio
Inorganic hybrid materials are promising applications in absorbers and photon harvesting of solar irradiation, such as DSSC cell photoanodes. Moreover, the investigation of the interaction between the photoanode constituent materials...
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Probing the limits of linker substitution in aluminum MOFs through water vapor sorption studies: Mixed-MOF instead of mixed-linker CAU-23 and MIL-160 materials

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01044H, Paper
Carsten Schlüsener, Dustin Nils Jordan, Mergime Xhinovci, Tobie J. Matemb Ma Ntep, Alexa Schmitz, Beatriz Giesen, Christoph Janiak
We report the systematic study on the possibility of forming mixed-linker MOFs spanning between the aluminum metal-organic frameworks CAU-23 and MIL-160 with their 2,5-thiophenedicarboxylate (TDC) and 2,5 furandicarboxylate (FDC) linkers,...
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MnO2 flowery nanocomposites for efficient and fast removal of mercury(II) from aqueous solution: a facile strategy and mechanistic interpretation

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01054E, Paper
Sankar Das, Arnab Samanta, Kanika Kole, Gautam Gangopadhyay, Subhra Jana
MnO2 flowery nanocomposites were explored as a novel and cost effective nanoadsorbent for the fast and efficient extraction of toxic inorganic contaminants from aqueous solution.
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Amorphous Ni–Fe–Se hollow nanospheres electrodeposited on nickel foam as a highly active and bifunctional catalyst for alkaline water splitting

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/C9DT04755G, Paper
Xuerui Yi, Xiaobo He, Fengxiang Yin, Biaohua Chen, Guoru Li, Huaqiang Yin
The electrodeposition of amorphous Ni–Fe–Se hollow nanospheres as a highly efficient bifunctional catalyst for the sustainable production of hydrogen.
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Metal–metal bond formation of triplatinum cores with a silver(I) ion affording a heptanuclear cluster bearing four Pt–Ag bonds

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01227K, Communication
Natsuki Yabune, Hiroshi Nakajima, Takanori Nishioka
A triplatinum complex with chelating NHC ligands reacts with Ag(I) and affords a heptanuclear cluster bearing four Ag–Pt bonds.
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Rapid mechanochemical synthesis of metal–organic frameworks using exogenous organic base

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01240H, Paper
Zihao Wang, Zongzhe Li, Marcus Ng, Phillip J. Milner
We describe the mechanochemical, solvent-free synthesis of metal–organic frameworks using liquid organic base for the first time.
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Luminescent lanthanide complexes with a pyridine-bis(carboxamide)-bithiophene sensitizer showing wavelength-dependent singlet oxygen generation

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01034K, Paper
Katherine R. Johnson, Sebastian B. Vittardi, Manuel A. Gracia-Nava, Jeffrey J. Rack, Ana de Bettencourt-Dias
A new pyridine-bis(carboxamide)-based ligand with a bithiophene pendant, 2Tcbx, was synthesized.
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Tin based organic-inorganic hybrid semiconductors with reversible phase transition and dielectric anomaly

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01401J, Paper
Zhenhong Wei, Xiuli You, Jiaojiao Yao
Organic−inorganic hybrid materials with perovskite structure have recently attracted tremendous interest due to their structural tunability and rich functional properties, such as phase transition and photoelectric properties. Within this context,...
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A molecular boron cluster-based chromophore with dual emission

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00826E, Paper
Kierstyn P. Anderson, Mary A. Waddington, Gary J. Balaich, Julia M. Stauber, Nicholas A. Bernier, Justin R. Caram, Peter I. Djurovich, Alexander M. Spokoyny
Bromination of the luminescent borane, anti-B18H22, via electrophilic substitution using AlCl3 and Br2, yields the monosubstituted derivative 4-Br-anti-B18H21 as an air-stable crystalline solid.
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Reactive metallocene cations as sensitive indicators of gas-phase oxygen and water

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00798F, Paper
Anuj Joshi, Sofia Donnecke, Ori Granot, Dongju Shin, Scott Collins, Irina Paci, J. Scott McIndoe
Gas-phase oxidation of air-sensitive organometallic compounds does not proceed to a significant extent in mass spectrometric analysis unless a vacant coordination site is generated, making nitrogen generators a suitable source of desolvation gas.
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Two [Ln4] molecular rings folded as compact tetrahedra

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01259A, Paper
Guillem Aromi, Olivier Roubeau, Leoní Alejandra Barrios, Jorge Salinas-Uber
The design of photoactive ligands may provide an entry into multifunctional molecular nanomagnets. We report here the design and synthesis of a new multitopic chelating ligand, 1,2-bis-(5-(N’-(pyridine-2-yl-methylene)-carbohydrazide)-3-methyl-thien-3-yl)-cyclopentene (H2L), bearing a...
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Heat-resistant Pb(II)-based X-ray scintillating metal-organic frameworks for sensitive dosage detection via the aggregation-induced luminescent chromophore

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT00974A, Communication
Jian Lu, Shuai-Hua Wang, Yan Li, Wen-Fei Wang, Cai Sun, Pei-Xin Li, Fa-Kun Zheng, Guo-Cong Guo
The synergy of unusual X-aggregation induced luminescent chromophores and heavy Pb(II) ions has facilitated excellent X-ray scintillation of two structurally similar Pb-SMOFs, which are heat-resistant due to solvent-free lattices. Owing...
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Spin-frustration with two quasi-degenerated spin states of a copper(II) heptanuclear complex obtained from an amino acid ligand

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/C9DT04501E, Paper
Catiúcia Rodrigues Marcelino Oliveira Matos, Henrique Silva Jr, Dayenny D’Amato, Guilherme Guedes, Glaucio Braga Ferreira, Odivaldo Cambraia Alves, Filipe Barra de Almeida, Sergio Pinheiro, Acácio Souza, Flavio Garcia, Célia Machado Ronconi
The Cu(II) heptanuclear complex (Cu7atac) was synthesised using the hydrated amino acid ligand 2-(5-amino-1H-1,2,4-triazol-3-yl)acetic acid (Hatac.H2O). Single crystal X-ray diffraction analysis revealed a μ3-hydroxo bridged Cu(II) heptanuclear complex, consisting of...
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Impacts of hydrogen bonding interactions with Np(V/VI)O2Cl4 complexes: vibrational spectroscopy, redox behavior, and computational analysis

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Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00848F, Paper
Mikaela M. Pyrch, Jennifer L. Bjorklund, James M. Williams, Daniel L. Parr IV, Sara E. Mason, Johna Leddy, Tori Z. Forbes
Crystallization of neptunyl(V) tetrachlorides over neptunyl(VI) species occurs simultaneously with charge assisted hydrogen bonding in our solid state materials, which we explored by DFT calculations, cyclic voltammograms, and Raman spectroscopy.
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A Review: Recent Advances in Preparations and Applications of Heteroatom-Doped Carbon Quantum Dots

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Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01004A, Perspective
Xiaoli Kou, Shicui Jiang, Soo-Jin Park, Long-Yue Meng
Carbon quantum dots (CQDs) are widely used in optoelectronic catalysis, biological imaging, and ion probes owing to their low toxicity, stable photoluminescence, and ease of chemical modification. However, the low...
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